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    Hydrocarbon disproportionation
    21.
    发明授权
    Hydrocarbon disproportionation 有权
    碳氢化合物歧化

    公开(公告)号：US06573416B1

    公开(公告)日：2003-06-03

    申请号：US09444426

    申请日：1999-11-19

    申请人： Bruce B. Randolph

    发明人： Bruce B. Randolph

    IPC分类号： C07C608

    CPC分类号： C07C6/10 ,  C07C2527/03 ,  C07C2527/054 ,  C07C2527/1206 ,  C07C2529/89 ,  C10G2400/02

    摘要： A process for disproportionating isoparaffins and paraffins in the presence of at least one initiator is disclosed. The product from the disproportionation contains a gasoline range material having a higher octane-rating than the isoparaffins and paraffins in the feed and a diesel range material having a higher cetane number than the isoparaffins and paraffins in the feed.

    摘要翻译： 公开了在至少一种引发剂存在下歧化异链烷烃和链烷烃的方法。 来自歧化的产物含有比进料中的异链烷烃和链烷烃具有更高辛烷值的汽油范围材料和具有比进料中的异链烷烃和链烷烃高的十六烷值的柴油范围材料。

    Method for reducing organic fluoride levels in hydrocarbons
    24.
    发明授权
    Method for reducing organic fluoride levels in hydrocarbons 有权

    公开(公告)号：US06426441B1

    公开(公告)日：2002-07-30

    申请号：US09612723

    申请日：2000-07-10

    申请人： Bruce B. Randolph ,  Kenneth Charles Hoover

    发明人： Bruce B. Randolph ,  Kenneth Charles Hoover

    IPC分类号： C07C258

    CPC分类号： C10G29/205 ,  C07C2/62 ,  C07C7/148

    摘要： A system and/or process for decreasing the level of at least one organic fluoride present in a hydrocarbon mixture by first passing the hydrocarbon mixture to an eductor and educting into the hydrocarbon mixture a catalyst comprising a volatility reducing additive and hydrofluoric acid to produce a hydrocarbon-catalyst mixture, permitting the hydrocarbon-catalyst mixture to undergo a phase separation to produce a hydrocarbon phase having a lower concentration of at least one organic fluoride than the hydrocarbon mixture and to produce a catalyst phase, and withdrawing at least a portion of the hydrocarbon phase to thereby form a hydrocarbon product stream, are disclosed. In an alternative embodiment, a system and/or process for controlling the concentration of at least one organic fluoride and/or the RON of the hydrocarbon mixture by adjusting the amount of volatility reducing additive present in the catalyst are disclosed.

    Acid catalyst regeneration control
    25.
    发明授权
    Acid catalyst regeneration control 失效
    酸催化剂再生控制

    公开(公告)号：US06228650B1

    公开(公告)日：2001-05-08

    申请号：US09206801

    申请日：1998-12-07

    申请人： William P. Moore ,  Mark A. Clark ,  Bruce B. Randolph

    发明人： William P. Moore ,  Mark A. Clark ,  Bruce B. Randolph

    IPC分类号： G01N2100

    CPC分类号： C07C2/62 ,  B01J19/0006 ,  B01J19/0013 ,  B01J2219/00121 ,  B01J2219/00164 ,  B01J2219/00186 ,  C07C2527/1206 ,  G01N21/3577 ,  G01N21/359 ,  Y02P20/584 ,  Y10T436/12 ,  Y10T436/15 ,  Y10T436/153333

    摘要： In an HF alkylation process where an acid catalyst regeneration column separates HF acid from ASO and water to provide regenerated catalyst for a catalyst circulation stream, and where buildup of ASO in the catalyst circulation stream is encountered, an improved control scheme uses an on-line analyzer/controller to maintain desired concentrations of HF acid, or ASO or water in the catalyst circulation stream. In one embodoment, a continuously flowing catalyst slip stream is piped to the analyzer/controller for simultaneously determining concentration of HF acid, ASO and water, and in a preferred embodiment the ASO concentration is maintained at a desired low level by manipulating temperature of a stripping fluid charged to a lower section of the column. An alternate manipulated variable is temperature of the acid catalyst feed to the regenerator column. Alternate controlled variables are the HF acid, and water concentration in the catalyst circulation stream.

    摘要翻译： 在HF烷基化方法中，其中酸催化剂再生塔将HF酸与ASO和水分离以提供用于催化剂循环流的再生催化剂，并且其中遇到催化剂循环流中的ASO积聚，改进的控制方案使用在线 分析仪/控制器，以保持催化剂循环流中所需浓度的HF酸或ASO或水。 在一个实施例中，连续流动的催化剂滑流被管道输送到分析器/控制器，用于同时测定HF酸，ASO和水的浓度，并且在优选的实施方案中，通过操纵汽提温度将ASO浓度维持在期望的低水平 流体充入塔的下部。 替代的操作变量是酸催化剂进料到再生塔的温度。 替代的控制变量是HF酸和催化剂循环流中的水浓度。

    Method for prolonging the life of alkylation product stream defluorinator beds
    26.
    发明授权
    Method for prolonging the life of alkylation product stream defluorinator beds 失效
    延长烷基化产物流除氟剂床的寿命的方法

    公开(公告)号：US5689030A

    公开(公告)日：1997-11-18

    申请号：US611588

    申请日：1996-03-06

    申请人： Bruce B. Randolph

    发明人： Bruce B. Randolph

    IPC分类号： C07C2/62 ,  C07C7/12 ,  C10C2/62

    CPC分类号： C07C2/62 ,  C07C7/12 ,  C07C2527/1206 ,  C07C2531/02

    摘要： A method for prolonging the life of a defluorinator material contained within an alkylation process product stream defluorination zone used to remove organic fluorides from a product stream produced by an alkylation process that utilizes an alkylation catalyst containing HF and sulfone. The life of the defluorinator material is extended by reducing the amount of organic fluorides produced in the alkylation process through the addition of trifluoromethanesulfonic acid to the HF/sulfone alkylation catalyst.

    摘要翻译： 用于延长用于从利用含有HF和砜的烷基化催化剂的烷基化方法产生的产物流中除去有机氟化物的烷基化工艺产物流脱氟区内所含的除氟剂材料的寿命的方法。 通过向HF /砜烷基化催化剂中加入三氟甲磺酸，减少在烷基化方法中产生的有机氟化物的量来延长除氟材料的寿命。

    Alkylation process for reacting an olefin feed being substantially free of isobutylene which utilizes a hydrogen fluoride and sulfone catalyst
    27.
    发明授权
    Alkylation process for reacting an olefin feed being substantially free of isobutylene which utilizes a hydrogen fluoride and sulfone catalyst 失效
    用于使烯烃进料基本上不含异丁烯的烷基化方法，其使用氟化氢和砜催化剂

    公开(公告)号：US5347066A

    公开(公告)日：1994-09-13

    申请号：US57372

    申请日：1993-05-06

    申请人： Bruce B. Randolph

    发明人： Bruce B. Randolph

    IPC分类号： C07C2/62

    CPC分类号： C07C2/62 ,  C07C2527/1206

    摘要： A process for producing an alkylate product having an improved octane value from an olefin stream having a reduced concentration of the butene isomer of isobutylene. The olefin feed stream to the process system is substantially free of isobutylene and can have undergone prior processing to remove isobutylene therefrom. The olefin feed is subjected to an alkylation reaction catalyzed by a mixture of hydrogen fluoride and sulfone.

    摘要翻译： 一种由具有降低的异丁烯丁烯异构体浓度的烯烃流产生具有改进的辛烷值的烷基化产物的方法。 进入工艺系统的烯烃进料流基本上不含异丁烯并且可以经过先前的处理从其中除去异丁烯。 使烯烃进料进行由氟化氢和砜的混合物催化的烷基化反应。