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公开(公告)号：US20130230443A1
公开(公告)日：2013-09-05
申请号：US13777175
申请日：2013-02-26
Applicant: Claus Hviid Christensen , Tue Johannessen , Ulrich Quaade , Jens Kehlet Norskøv , Rasmus Zink Sørensen
Inventor： Claus Hviid Christensen , Tue Johannessen , Ulrich Quaade , Jens Kehlet Norskøv , Rasmus Zink Sørensen
IPC: B01D53/56
CPC classification number: B01D53/565 , B01D53/90 , B01D53/9431 , B01J20/046 , B01J20/28011 , B01J20/3035 , C01C1/006 , C01F5/00 , C01G3/14 , C01G9/00 , C01G45/00 , C01G49/00 , C01G51/12 , C01G53/12 , C01P2006/10 , F01N3/2066 , F01N2610/02 , F01N2610/06 , F01N2610/10 , F17C11/00 , Y02T10/24
Abstract: Disclosed is a method for the selective catalytic reduction of NOx in waste/exhaust gas by using ammonia provides by heating one or more salts of formula Ma(NH3)nXz, wherein M represents one or more cations selected from alkaline earth metals and transition metals, X represents one or more anions, a represents the number of cations per salt molecule, z represents the number of anions per salt molecule, and n is a number of from 2 to 12, the one or more salts having been compressed to a bulk density above 70% of the skeleton density before use thereof.
Abstract translation: 公开了一种通过使用通过加热一种或多种式M a（NH 3）n X z的盐提供的氨来选择性催化还原废气/废气中的NOx的方法，其中M表示一种或多种选自碱土金属和过渡金属的阳离子， X表示一个或多个阴离子，a表示每个盐分子的阳离子数，z表示每个盐分子的阴离子数，n表示2至12的数，该一种或多种盐已被压缩至体积密度 高于其使用前骨架密度的70％。
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22.发明申请METHOD AND DEVICE FOR CONTROLLING EFFECTIVE HEAT TRANSFER IN A SOLID GAS STORAGE SYSTEM 有权用于控制固体气体储存系统中的有效热传递的方法和装置公开(公告)号：US20130118152A1
公开(公告)日：2013-05-16
申请号：US13634298
申请日：2011-03-16
Applicant: Ulrich Joachim Quaade , Tue Johannessen , Jacob Hjerrild Zeuthen , Henning Schmidt
Inventor： Ulrich Joachim Quaade , Tue Johannessen , Jacob Hjerrild Zeuthen , Henning Schmidt
CPC classification number: F01N3/208 , B01D53/0438 , B01D53/0454 , B01D2251/2062 , B01D2259/4525 , C01C1/006 , F17C11/00 , Y02P20/129
Abstract: A method for controlling the effective heat transfer from a storage unit (1). During gas release from storage material (3) in the storage unit the storage material is heated by a heater (2). During re-saturation of the storage material (3) with gas the heater is off. Controlling of the effective heat transfer from the storage unit (1) is performed, during gas release, by ceasing convection of a convection gas and, during re-saturation, by performing or enabling convection of a convection gas to cool the storage unit (1).
Abstract translation: 一种用于控制来自存储单元（1）的有效热传递的方法。 在从存储单元中的储存材料（3）释放气体期间，储存材料由加热器（2）加热。 在用气体重新饱和存储材料（3）时，加热器关闭。 在气体释放期间，通过停止对流气体的对流并且在再饱和期间，通过执行或使对流气体对流以冷却存储单元（1）来控制来自存储单元（1）的有效热传递 ）。
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公开(公告)号：US20120231949A1
公开(公告)日：2012-09-13
申请号：US13496914
申请日：2010-09-30
Applicant: Jakob Svagin , Ulrich J. Quaade , Johnny Johansen , Henrik Wagner-Pedersen , Tue Johannessen
Inventor： Jakob Svagin , Ulrich J. Quaade , Johnny Johansen , Henrik Wagner-Pedersen , Tue Johannessen
CPC classification number: C01C1/006 , B01J20/0214 , B01J20/0218 , B01J20/0222 , B01J20/0225 , B01J20/0237 , B01J20/0244 , B01J20/0281 , B01J20/0288 , B01J20/0292 , B01J20/0296 , B01J20/28011 , B01J20/2805 , B01J20/3007 , C01F11/24 , C09K5/16 , F01N2610/10 , F28F2013/006
Abstract: A compacted block of material constructed of one or more units consisting of matter comprising an ammonia-saturated material capable of reversibly desorbing and ad- or absorbing ammonia surrounded by a gas-permeable enclosure made of a flexible material having a thermal conductivity of at least about five times the thermal conductivity of said ammonia-saturated material at −70° C.. to 250° C.. and methods for producing the same are described.
Abstract translation: 由一个或多个由包含能够可逆地解吸和吸收或吸收由包含由至少约 描述了在-70℃至250℃下所述氨饱和材料的热导率的5倍及其制备方法。
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24.发明申请METHOD FOR STORING AND DELIVERING AMMONIA FROM SOLID STORAGE MATERIALS USING A VACUUM PUMP 有权使用真空泵从固体储存材料储存和输送氨的方法公开(公告)号：US20120045379A1
公开(公告)日：2012-02-23
申请号：US13257195
申请日：2010-03-18
Applicant: Tue Johannessen , Ulrich Quaade
Inventor： Tue Johannessen , Ulrich Quaade
CPC classification number: F01N3/2066 , B01D53/90 , B01D53/9495 , B01D2251/2062 , B01D2257/402 , C01C1/006 , F01N3/206 , F01N13/009 , F01N13/011 , F01N2610/06 , F01N2610/10 , F01N2610/1406 , Y02C20/10 , Y02P20/129 , Y02P20/153 , Y02T10/24
Abstract: In a method of storing and releasing gaseous ammonia from solid storage materials a first solid storage material (14) capable of releasing ammonia by desorption in a first container (10) and a second solid storage material (24) capable of ad- or absorbing ammonia reversibly and having a higher affinity for ammonia than the first storage material (14) in a second container (20) smaller than said first container (10) are in fluid communication. The pressure in at least the first container (10) is kept below the equilibrium pressure between ammonia and the storage material contained therein by means of a pump (28). When the pressure in the first container (10) is below a pressure threshold where the first storage material (14) does not release an amount of ammonia required by an ammonia consuming device connected with the containers via the vacuum pump (28), the second storage material (24) is heated such that the ammonia pressure of the second material (24) is higher than the ammonia pressure of the first material (14). The ammonia released by the second material (24) is continuously pumped off so as to deliver sufficient ammonia to said ammonia consuming unit. A device for carrying out the method is also described.
Abstract translation: 在从固体储存材料储存和释放气态氨的方法中，能够通过在第一容器（10）中解吸而释放氨的第一固体储存材料（14）和能够吸附或吸收氨的第二固态储存材料（24）的方法 在比第一容器（10）小的第二容器（20）中可逆地并且具有比第一存储材料（14）更高的氨的亲和力是流体连通的。 至少第一容器（10）中的压力通过泵（28）保持在氨和容纳在其中的储存材料之间的平衡压力以下。 当第一容器（10）中的压力低于第一储存材料（14）不经由真空泵（28）释放与容器连接的氨消耗装置所需的氨的量的压力阈值时，第二容器 储存材料（24）被加热，使得第二材料（24）的氨压力高于第一材料（14）的氨压力。 由第二材料（24）释放的氨被连续泵送，以便向氨消耗单元输送足够的氨。 还描述了用于执行该方法的装置。
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公开(公告)号：US20110073806A1
公开(公告)日：2011-03-31
申请号：US12570426
申请日：2009-09-30
Applicant: Jakob Svagin , Ulrich J. Quaade , Johnny Johansen , Henrik Wagner-Pedersen , Tue Johannessen
Inventor： Jakob Svagin , Ulrich J. Quaade , Johnny Johansen , Henrik Wagner-Pedersen , Tue Johannessen
CPC classification number: C01F11/00 , B01D53/90 , B01D53/9409 , B01D2251/2062 , B01J20/046 , B01J20/28011 , B01J20/28042 , B01J20/3035 , B29C2043/3628 , B29K2105/26 , C01C1/006 , C01F5/00 , C09K5/00
Abstract: A compacted block of material constructed of one or more units consisting of matter comprising an ammonia-saturated material capable of reversibly desorbing and ad- or absorbing ammonia surrounded by a gas-permeable, flexible material having a thermal conductivity of at least five times the thermal conductivity of said ammonia-saturated material at −70° C. to 250° C. and methods for producing the same are described.
Abstract translation: 由一个或多个由包含氨饱和材料的物质构成的压块的材料块，其能够可逆地解吸和吸收或吸收由气体可渗透的柔性材料包围的氨，所述气体可渗透的柔性材料具有至少五倍于热的热导率 描述所述氨饱和材料在-70℃至250℃的电导率及其制备方法。
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Patent Agency Ranking
26.发明申请METHOD AND DEVICE FOR SAFE AND CONTROLLED DELIVERY OF AMMONIA FROM A SOLID AMMONIA STORAGE MEDIUM 审中-公开用于安全和控制从固体氨储存介质输送氨的方法和装置公开(公告)号：US20100293927A1
公开(公告)日：2010-11-25
申请号：US11993731
申请日：2006-06-29
Applicant: Tue Johannessen , Rasmus Zink Sorensen , Claus Hviid Christensen , Ulrich Quaade , Jens Kehlet Norskov
Inventor： Tue Johannessen , Rasmus Zink Sorensen , Claus Hviid Christensen , Ulrich Quaade , Jens Kehlet Norskov
CPC classification number: B01D53/9431 , B01D53/79 , C01C1/006 , F01N3/208 , F01N5/02 , F01N2610/02 , F01N2610/06 , F01N2610/08 , F01N2610/10 , Y02A50/2325 , Y02E60/364 , Y02P20/129 , Y02T10/16 , Y02T10/24 , Y10T137/0379
Abstract: Solid metal ammine complexes are applied for safe and high-density storage of ammonia to be released for use as reducing agent in selective catalytic reduction of NOx in exhaust gases. The compositional formula of the metal ammine complexes is M(NH3)nXz, where MZ+ represents one or more metal ions capable of binding ammonia, X represents one or more anions, n is the coordination number (from 2 to 12), and z the valency of the metal ion (and thus the total number of compensating anion charges). Ammonia is released by generating a reduced gas-phase pressure of ammonia inside the container, which is below the equilibrium desorption pressure of ammonia at the operating temperature of the storage material thus enabling the unit to be operated is a safe manner with lower operating temperature and pressure.
Abstract translation: 应用固体金属氨络合物用于安全和高密度地储存氨，以用作废气中选择性催化还原NOx的还原剂。 金属络合物的组成式为M（NH 3）n X z，其中MZ +表示一种或多种能够结合氨的金属离子，X表示一种或多种阴离子，n为配位数（2至12），z为 金属离子的化合价（因此补偿阴离子电荷的总数）。 通过在储存材料的工作温度下产生氨的气相压降低于储存材料的操作温度下的氨的平衡解吸压力来释放氨，从而能够使操作该装置的操作更安全，并具有较低的操作温度和 压力。
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公开(公告)号：US20090123361A1
公开(公告)日：2009-05-14
申请号：US11815146
申请日：2006-02-03
Applicant: Tue Johannessen , Claus Hviid Christensen , Jens Kehlet Norskov , Ulrich Quaade , Rasmus Zink Sorensen
Inventor： Tue Johannessen , Claus Hviid Christensen , Jens Kehlet Norskov , Ulrich Quaade , Rasmus Zink Sorensen
CPC classification number: C01G3/14 , B01D53/56 , B01D53/79 , B01D53/8625 , B01D53/90 , B01D53/9409 , B01J20/046 , B01J20/28011 , B01J20/28014 , B01J20/2803 , B01J20/28042 , B01J20/3042 , C01C1/006 , C01F11/24 , F01N2610/02 , F01N2610/06 , F17C11/00 , Y02E60/364
Abstract: A solid ammonia storage and delivery material comprising an ammonia absorbing/desorbing solid material, said storage and delivery material having been compacted to a density above 50% of the theoretic skeleton density provides a solid ammonia storage material which is easy to produce and handle and has a very high density of stored ammonia which is readily released under controlled conditions even though the porosity of the material is very low, and which storage material is safe for storage and transport of ammonia without special safety measures.
Abstract translation: 包含氨吸收/解吸固体材料的固体氨储存和输送材料，所述储存和输送材料已压实至理论骨架密度的50％以上的密度，提供了易于生产和处理的固体氨储存材料，并具有 尽管材料的孔隙率非常低，但在受控条件下容易释放的非常高密度的储存氨，并且哪些储存材料在没有特别的安全措施的情况下可以安全地存储和运输氨。
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公开(公告)号：US09889403B2
公开(公告)日：2018-02-13
申请号：US13777175
申请日：2013-02-26
Applicant: Claus Hviid Christensen , Tue Johannessen , Ulrich Quaade , Jens Kehlet Nørskov , Rasmus Zink Sørensen
Inventor： Claus Hviid Christensen , Tue Johannessen , Ulrich Quaade , Jens Kehlet Nørskov , Rasmus Zink Sørensen
IPC: B01D53/94 , B01D53/56 , B01D53/90 , B01J20/04 , B01J20/30 , C01C1/00 , C01F5/00 , C01G3/14 , C01G9/00 , C01G45/00 , C01G49/00 , C01G51/12 , C01G53/12 , F01N3/20 , B01J20/28
CPC classification number: B01D53/565 , B01D53/90 , B01D53/9431 , B01J20/046 , B01J20/28011 , B01J20/3035 , C01C1/006 , C01F5/00 , C01G3/14 , C01G9/00 , C01G45/00 , C01G49/00 , C01G51/12 , C01G53/12 , C01P2006/10 , F01N3/2066 , F01N2610/02 , F01N2610/06 , F01N2610/10 , F17C11/00 , Y02T10/24
Abstract: Disclosed is a method for the selective catalytic reduction of NOx in waste/exhaust gas by using ammonia provides by heating one or more salts of formula Ma(NH3)nXz, wherein M represents one or more cations selected from alkaline earth metals and transition metals, X represents one or more anions, a represents the number of cations per salt molecule, z represents the number of anions per salt molecule, and n is a number of from 2 to 12, the one or more salts having been compressed to a bulk density above 70% of the skeleton density before use thereof.
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29.发明授权System for storing ammonia in and releasing ammonia from a storage material and method for storing and releasing ammonia 有权用于从储存材料中储存氨并释放氨的系统和用于储存和释放氨的方法公开(公告)号：US09010091B2
公开(公告)日：2015-04-21
申请号：US13479402
申请日：2012-05-24
Applicant: Tue Johannessen , Henning Schmidt
Inventor： Tue Johannessen , Henning Schmidt
CPC classification number: F17C11/00 , B01D53/8631 , B01D53/90 , B01D53/9431 , B01D53/9495 , B01D2251/2062 , C01C1/006 , F01N3/2066 , F01N3/208 , F01N11/00 , F01N2560/026 , F01N2610/02 , F01N2610/06 , F01N2610/10 , F01N2610/14 , F01N2610/1406 , F01N2610/146 , F01N2900/0411 , F01N2900/08 , F01N2900/12 , F01N2900/1808 , F01N2900/1811 , F17C13/00 , F17C2221/01 , F17C2227/0302 , F17C2270/0581 , H01M8/0606 , H01M8/222 , Y02A50/2325 , Y02E60/321 , Y02T10/24
Abstract: A system for storing ammonia in and releasing ammonia from a storage material capable of binding and releasing ammonia reversibly by adsorption or absorption for a process with a gradual ammonia demand that can vary over the time. The system has a container capable of housing the ammonia-containing storage material; a heating source arranged to supply heat for the desorption of ammonia from the solid storage medium; and a controller arranged to control the heating source to release ammonia. The heating source may be arranged inside the container and surrounded by ammonia storage material. A controllable dosing valve is arranged to dose released ammonia according to the ammonia demand. The controller comprises a feed-forward control arranged to control the heat supplied by the heating source, based on the ammonia demand.
Abstract translation: 一种用于将氨从储存材料中储存和释放氨的系统，该储存材料能够通过吸附或吸收可逆地结合和释放氨，以达到可随时间变化的逐渐氨需求的过程。 该系统具有能容纳含氨储存材料的容器; 加热源，其设置用于从固体储存介质中提供氨以解吸氨; 以及控制器，其布置成控制加热源以释放氨。 加热源可以布置在容器内部并被氨储存材料包围。 布置可控计量阀以根据氨需求量剂量释放氨。 该控制器包括一个前馈控制装置，其基于氨的需求来控制由加热源供应的热量。
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公开(公告)号：US08951437B2
公开(公告)日：2015-02-10
申请号：US12570426
申请日：2009-09-30
Applicant: Jakob Svagin , Ulrich J. Quaade , Johnny Johansen , Henrik Wagner-Pedersen , Tue Johannessen
Inventor： Jakob Svagin , Ulrich J. Quaade , Johnny Johansen , Henrik Wagner-Pedersen , Tue Johannessen
IPC: C09K3/00 , B01J20/02 , B01J20/30 , C01F11/00 , B01J20/04 , B01J20/28 , C01C1/00 , C01F5/00 , C09K5/00 , B01D53/90 , B01D53/94 , B29C43/36 , B29K105/26
CPC classification number: C01F11/00 , B01D53/90 , B01D53/9409 , B01D2251/2062 , B01J20/046 , B01J20/28011 , B01J20/28042 , B01J20/3035 , B29C2043/3628 , B29K2105/26 , C01C1/006 , C01F5/00 , C09K5/00
Abstract: A compacted block of material constructed of one or more units consisting of matter comprising an ammonia-saturated material capable of reversibly desorbing and ad- or absorbing ammonia surrounded by a gas-permeable, flexible material having a thermal conductivity of at least five times the thermal conductivity of said ammonia-saturated material at −70° C. to 250° C. and methods for producing the same are described.
Abstract translation: 由一个或多个由包含氨饱和材料的物质构成的压块的材料块，其能够可逆地解吸和吸收或吸收由气体可渗透的柔性材料包围的氨，所述气体可渗透的柔性材料具有至少五倍于热的热导率 描述所述氨饱和材料在-70℃至250℃的电导率及其制备方法。
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