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    Preparation of high activity catalysts; the catalysts and their use
    21.
    发明授权
    Preparation of high activity catalysts; the catalysts and their use 有权
    制备高活性催化剂; 催化剂及其用途

    公开(公告)号：US06331575B1

    公开(公告)日：2001-12-18

    申请号：US09153364

    申请日：1998-09-15

    申请人： Charles H. Mauldin

    发明人： Charles H. Mauldin

    IPC分类号： C07C2700

    CPC分类号： B01J37/0203 ,  B01J23/8896 ,  B01J35/0066 ,  C07C1/0445 ,  C07C2523/36 ,  C07C2523/889 ,  Y10S502/506 ,  Y10S502/514

    摘要： A process for the preparation of a catalyst useful for conducting carbon monoxide conversion reactions, especially a Fischer-Tropsch catalyst, use of the catalyst for conducting such reactions, especially Fischer-Tropsch reactions, and the composition produced by said process. In the preparation of the catalyst, a solution of a polyol is employed to impregnate and disperse a compound or salt of a catalytic metal, or metals, e.g., copper or an Iron Group metal such as iron, cobalt, or nickel, or in a preferred embodiment both a compound or salt of rhenium and a compound or salt of a catalytic metal, or metals, e.g., copper or an Iron Group metal such as iron, cobalt, or nickel onto a refractory inorganic oxide support, e.g., titania. The rhenium, when present only in small amount permits full and complete reduction of the catalytic metal, or metals, dispersed by the polyol. Higher catalyst activities with lower rhenium loadings are thus achieved than in previous preparations where higher concentrations of rhenium were required to both effectively disperse, and reduce the catalytic metal, or metals, during the preparation. Surprisingly, as little as about {fraction (1/10)} of the rhenium is required to accomplish the reduction promotion where the dispersion is effected with the polyol.

    摘要翻译： 用于制备用于进行一氧化碳转化反应的催化剂，特别是费 - 托催化剂的方法，所述催化剂用于进行这种反应，特别是费 - 托反应，以及由所述方法制备的组合物。 在催化剂的制备中，使用多元醇溶液来浸渍和分散催化金属的化合物或盐，或金属，例如铜或铁族金属如铁，钴或镍，或在 优选的实施方案是将铼的化合物或盐和催化金属的化合物或盐，或诸如铜或铁族金属如铁，钴或镍的金属加入耐火无机氧化物载体（例如二氧化钛）上。 当仅存在少量的铼允许充分和完全地还原由多元醇分散的催化金属或金属。 因此实现了较低的铼负载量的较高催化剂活性，而不需要较高浓度的铼在制备期间有效地分散和还原催化金属或金属的以前制备。 令人惊奇的是，为了实现其中分散体与多元醇进行的还原促进，需要少至约{分数（1/10）}的铼。

    Preparation of high activity catalysts; the catalysts and their use
    22.
    发明授权
    Preparation of high activity catalysts; the catalysts and their use 失效
    制备高活性催化剂; 催化剂及其用途

    公开(公告)号：US5856260A

    公开(公告)日：1999-01-05

    申请号：US845015

    申请日：1997-04-22

    申请人： Charles H. Mauldin

    发明人： Charles H. Mauldin

    IPC分类号： B01J23/889 ,  B01J37/02 ,  C07B61/00 ,  C07C1/04 ,  C10G2/00 ,  B01J23/00 ,  B01J23/56 ,  B01J23/70 ,  B01J23/72

    CPC分类号： B01J37/0203 ,  B01J23/8896 ,  C07C1/0445 ,  B01J35/0066 ,  C07C2523/36 ,  C07C2523/889 ,  Y10S502/506 ,  Y10S502/514

    摘要： A process for the preparation of a catalyst useful for conducting carbon monoxide conversion reactions, especially a Fischer-Tropsch catalyst, use of the catalyst for conducting such reactions, especially Fischer-Tropsch reactions, and the composition produced by said process. In the preparation of the catalyst, a solution of a polyol is employed to impregnate and disperse a compound or salt of a catalytic metal, or metals, e.g., copper or an Iron Group metal such as iron, cobalt, or nickel, or in a preferred embodiment both a compound or salt of rhenium and a compound or salt of a catalytic metal, or metals, e.g., copper or an Iron Group metal such as iron, cobalt, or nickel onto a refractory inorganic oxide support, e.g., titania. The rhenium, when present only in small amount permits full and complete reduction of the catalytic metal, or metals, dispersed by the polyol. Higher catalyst activities with lower rhenium loadings are thus achieved than in previous preparations where higher concentrations of rhenium were required to both effectively disperse, and reduce the catalytic metal, or metals, during the preparation. Surprisingly, as little as about 1/10 of the rhenium is required to accomplish the reduction promotion where the dispersion is effected with the polyol.

    摘要翻译： 用于制备用于进行一氧化碳转化反应的催化剂，特别是费 - 托催化剂的方法，所述催化剂用于进行这种反应，特别是费 - 托反应，以及由所述方法制备的组合物。 在催化剂的制备中，使用多元醇溶液来浸渍和分散催化金属的化合物或盐，或金属，例如铜或铁族金属如铁，钴或镍，或在 优选的实施方案是将铼的化合物或盐和催化金属的化合物或盐，或诸如铜或铁族金属如铁，钴或镍的金属加入耐火无机氧化物载体（例如二氧化钛）上。 当仅存在少量的铼允许充分和完全地还原由多元醇分散的催化金属或金属。 因此实现了较低的铼负载量的较高催化剂活性，而不需要较高浓度的铼在制备期间有效地分散和还原催化金属或金属的以前制备。 令人惊奇的是，只要约+ E，需要铼的1/10 + EE即可完成分散体与多元醇的还原促进。

    Ruthenium catalysts, and use thereof for Fischer-Tropsch synthesis
    24.
    发明授权
    Ruthenium catalysts, and use thereof for Fischer-Tropsch synthesis 失效
    钌催化剂及其在费 - 托合成中的应用

    公开(公告)号：US4567205A

    公开(公告)日：1986-01-28

    申请号：US735783

    申请日：1985-05-20

    申请人： Kym B. Arcuri ,  Charles H. Mauldin ,  Dave H. Shaw

    发明人： Kym B. Arcuri ,  Charles H. Mauldin ,  Dave H. Shaw

    IPC分类号： B01J21/06 ,  B01J23/656 ,  C07C1/04

    CPC分类号： B01J23/6567 ,  C07C1/0435 ,  B01J21/063 ,  C07C2521/06 ,  C07C2523/36 ,  C07C2523/46 ,  C07C2523/656

    摘要： A novel ruthenium catalyst, notably a ruthenium-titania catalyst, is disclosed to which is added sufficient rhenium to obtain, at corresponding process conditions, improved activity maintenance in the production of hydrocarbons via carbon monoxide-hydrogen synthesis reactions vis-a-vis a catalyst composition otherwise similar except that it does not contain rhenium. High quality middle distillate fuels, characterized generally as admixtures of linear paraffins and olefins, are formed in a process wherein a feed mixture of carbon monoxide and hydrogen are contacted at reaction conditions over such catalyst.

    摘要翻译： 公开了一种新型的钌催化剂，特别是钌 - 二氧化钛催化剂，其中加入足够的铼，以在相应的工艺条件下获得通过一氧化碳 - 氢合成反应相对于催化剂生产烃的改进的活性维持 组合物除了不含铼以外，其他方面相似。 在其中一氧化碳和氢气的进料混合物在这种催化剂上的反应条件下接触的过程中形成了高质量的中间馏分燃料，其特征通常以直链烷烃和烯烃的混合物形式。

    Process for preparing multimetallic reforming catalysts
    26.
    发明授权
    Process for preparing multimetallic reforming catalysts 失效
    制备多金属重整催化剂的方法

    公开(公告)号：US4302359A

    公开(公告)日：1981-11-24

    申请号：US152669

    申请日：1980-05-23

    申请人： Charles H. Mauldin ,  William C. Baird, Jr.

    发明人： Charles H. Mauldin ,  William C. Baird, Jr.

    IPC分类号： B01J23/656 ,  B01J23/89 ,  C10G35/09 ,  B01J21/04 ,  B01J23/64 ,  B01J23/72

    CPC分类号： B01J23/8986 ,  B01J23/6567 ,  C10G35/09

    摘要： A process for the synthesis of catalysts by pre-forming a porous refractory inorganic oxide support, or carrier from a coarse particulate solid, preferably an alumina extrudate, contacting said preformed support with an acid solution, and then treating, contacting and neutralizing said preformed acid treated support with a base prior to the impregnation of said neutralized support with a metal, or metals, hydrogenation-dehyrdogenation component. The preformed solid support ranges at least about 1/32 inch diameter, and preferably at least about 1/16 inch diameter, and larger.

    摘要翻译： 一种通过从粗颗粒固体，优选氧化铝挤出物预先形成多孔耐火无机氧化物载体或载体来合成催化剂的方法，使所述预制载体与酸溶液接触，然后处理，接触和中和所述预成型的酸 在用金属或金属氢化脱硫成分浸渍所述中和的载体之前，用碱处理的载体。 预制的固体支持体的直径至少约为1/32英寸，优选至少约1/16英寸直径，并且更大。