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    SELF-ACTIVATING HYDROPROCESSING CATALYST AND PROCESS FOR TREATING HEAVY HYDROCARBON FEEDSTOCKS
    25.
    发明申请
    SELF-ACTIVATING HYDROPROCESSING CATALYST AND PROCESS FOR TREATING HEAVY HYDROCARBON FEEDSTOCKS 有权
    自激活氢化催化剂和处理重油烃进料的方法

    公开(公告)号：US20140116924A1

    公开(公告)日：2014-05-01

    申请号：US13660879

    申请日：2012-10-25

    Applicant: SHELL OIL COMPANY

    Inventor： Opinder Kishan BHAN

    IPC: B01J23/883 ,  C10G45/08

    CPC classification number: B01J23/883 ,  B01J27/19 ,  B01J35/0006 ,  B01J35/002 ,  B01J35/026 ,  B01J35/1042 ,  B01J35/1061 ,  B01J35/108 ,  B01J37/0009 ,  B01J37/0201 ,  B01J37/04 ,  B01J37/08 ,  B01J37/28 ,  B01J38/68 ,  B01J38/72 ,  C10G45/08 ,  C10G2300/107 ,  C10G2300/1077 ,  C10G2300/202 ,  C10G2300/205 ,  C10G2300/206

    Abstract: A self activating catalyst for treating heavy hydrocarbon feedstocks that comprises a calcined particle comprising a co-mulled mixture made by co-mulling inorganic oxide powder, molybdenum trioxide powder, and a nickel compound and then forming the co-mulled mixture into a particle that is calcined to thereby provide the calcined particle. The calcined particle comprises from 1 to 10 weight percent molybdenum and nickel that is present in an amount such that the weight ratio of said nickel-to-molybdenum is less than 0.4. The calcined particle has a pore size distribution that contributes to the unique properties of the catalyst. The calcined particle and catalyst also exhibits a unique Raman spectrum. The self activating catalyst is activated when contacted under suitable process conditions with a heavy residue feedstock having high nickel, vanadium and sulfur concentrations.

    Abstract translation: 一种用于处理重烃原料的自活化催化剂，其包含煅烧颗粒，该煅烧颗粒包含通过共研磨无机氧化物粉末，三氧化钼粉末和镍化合物制成的共研磨混合物，然后将共研磨混合物形成为 煅烧，从而提供煅烧颗粒。 煅烧颗粒包含1至10重量％的钼和镍，其存在量使得所述镍 - 钼的重量比小于0.4。 煅烧颗粒具有有助于催化剂独特性质的孔径分布。 煅烧颗粒和催化剂也表现出独特的拉曼光谱。 当在合适的工艺条件下与具有高镍，钒和硫浓度的重残余原料接触时，自活化催化剂被活化。

    CATALYST SUPPORT MATERIALS, CATALYSTS, METHODS OF MAKING THEM AND USES THEREOF
    26.
    发明申请
    CATALYST SUPPORT MATERIALS, CATALYSTS, METHODS OF MAKING THEM AND USES THEREOF 有权
    催化剂支持材料，催化剂，制备方法及其用途

    公开(公告)号：US20140056793A1

    公开(公告)日：2014-02-27

    申请号：US13975073

    申请日：2013-08-23

    Applicant: CRISTAL USA INC.

    Inventor： Steve M. Augustine ,  David M. Chapman ,  Dennis F. Clark

    IPC: B01J27/199 ,  B01D53/56 ,  B01J23/28

    CPC classification number: B01J23/28 ,  B01D53/565 ,  B01D53/9418 ,  B01D2255/20707 ,  B01D2255/20769 ,  B01D2255/30 ,  B01J21/063 ,  B01J23/22 ,  B01J27/051 ,  B01J27/19 ,  B01J27/199 ,  B01J35/1014 ,  B01J37/00 ,  B01J37/0201 ,  B01J2523/00 ,  B01J2523/41 ,  B01J2523/47 ,  B01J2523/68

    Abstract: Catalyst support materials, catalysts, methods of making such and uses thereof are described. Methods of making catalyst support material include combining anatase titania slurry with i) a low molecular weight form of silica; and ii) a source of Mo to form a TiO2—MoO3—SiO2 mixture. Catalyst support material include from about 86% to about 94% weight anatase titanium dioxide; from about 0.1% to about 10% weight MoO3; and from about 0.1% to about 10% weight SiO2. Low molecular weight forms of silica include forms of silica having a volume weighted median size of less than 4 nm and average molecular weight of less than 44,000, either individually or in a combination of two or more thereof. Catalyst include such catalyst support material with from about 0.1 to about 3% weight of V2O5 and optionally from about 0.01% to about 2.5% weight P.

    Abstract translation: 描述了催化剂载体材料，催化剂，制备方法和用途。 制备催化剂载体材料的方法包括将锐钛型二氧化钛浆料与i）低分子量形式的二氧化硅组合; 和ii）Mo的源以形成TiO 2 -MoO 3 -SiO 2混合物。 催化剂载体材料包括约86％至约94％重量的锐钛矿型二氧化钛; 约0.1重量％至约10重量％的MoO 3; 和约0.1％至约10％重量的SiO 2。 二氧化硅的低分子量形式包括体积加权中值大小小于4nm，平均分子量小于44,000的二氧化硅的形式，单独地或两种或更多种的组合。 催化剂包括这样的催化剂载体材料，其具有约0.1至约3重量％的V 2 O 5和任选的约0.01重量％至约2.5重量％的P.

    Condensation of glycols to produce biofuels
    28.
    发明授权
    Condensation of glycols to produce biofuels 有权
    二醇缩合生产生物燃料

    公开(公告)号：US08617262B2

    公开(公告)日：2013-12-31

    申请号：US13308041

    申请日：2011-11-30

    Applicant: Matthew J. Truitt

    Inventor： Matthew J. Truitt

    IPC: C10L1/185

    CPC classification number: C10L1/02 ,  B01J21/066 ,  B01J21/08 ,  B01J23/6527 ,  B01J27/19 ,  B01J29/08 ,  B01J29/084 ,  B01J29/18 ,  B01J29/40 ,  B01J37/0201

    Abstract: The present disclosure relates to methods for converting light glycol streams of biological origin into products suitable for use as oxygenated fuel additives. These methods involve the acidic condensation of light glycols to form larger products, termed low molecular weight poly-glycols. The remaining hydroxyl functional groups of the poly-glycol products are then modified to decrease the overall polarity of the products, and improve their suitability for use as an oxygenated fuel additive.

    Abstract translation: 本公开涉及将生物来源的轻二醇流转化成适合用作氧化燃料添加剂的产物的方法。 这些方法涉及轻二元醇的酸性缩合形成较大的产物，称为低分子量聚二醇。 然后对聚乙二醇产物的剩余羟基官能团进行改性以降低产物的总体极性，并改善其作为氧化燃料添加剂的适用性。

    A CATALYST AND PROCESS FOR THE MANUFACTURE OF ULTRA-LOW SULFUR DISTILLATE PRODUCT
    29.
    发明申请
    A CATALYST AND PROCESS FOR THE MANUFACTURE OF ULTRA-LOW SULFUR DISTILLATE PRODUCT 有权
    超低硫蒸馏物生产的催化剂和工艺

    公开(公告)号：US20130296163A1

    公开(公告)日：2013-11-07

    申请号：US13932471

    申请日：2013-07-01

    Applicant: Shell Oil Company

    Inventor： Opinder Kishan BHAN

    IPC: C10G45/12 ,  C10G45/08 ,  B01J27/19

    CPC classification number: C10G45/12 ,  B01J23/882 ,  B01J23/883 ,  B01J27/1853 ,  B01J27/19 ,  B01J35/1019 ,  B01J35/1061 ,  B01J35/1066 ,  B01J37/0009 ,  B01J37/04 ,  C01G45/08 ,  C10G45/08 ,  C10G2300/1037 ,  C10G2300/202 ,  C10G2300/4018

    Abstract: Described is a catalyst and process useful in the hydrodesulfurization of a distillate feedstock to manufacture a low-sulfur distillate product. The catalyst comprises a calcined mixture of inorganic oxide material, a high concentration of a molybdenum component, and a high concentration of a Group VIII metal component. The mixture that is calcined to form the calcined mixture comprises molybdenum trioxide in the form of finely divided particles, a Group VIII metal compound, and an inorganic oxide material. The catalyst is made by mixing the aforementioned starting materials and forming therefrom an agglomerate that is calcined to yield the calcined mixture that may be used as the catalyst or catalyst precursor.

    Abstract translation: 描述了可用于馏出物原料的加氢脱硫以制备低硫馏出物产物的催化剂和方法。 催化剂包括无机氧化物材料，高浓度的钼组分和高浓度的VIII族金属组分的煅烧混合物。 被煅烧以形成煅烧混合物的混合物包括细碎颗粒形式的三氧化钼，第Ⅷ族金属化合物和无机氧化物材料。 催化剂是通过混合上述起始原料并由其形成的聚集体，其被煅烧以产生可用作催化剂或催化剂前体的煅烧混合物。

    Method of Gas Purification, Coal Gasification Plant, and Shift Catalyst
    30.
    发明申请
    Method of Gas Purification, Coal Gasification Plant, and Shift Catalyst 审中-公开
    气体净化方法，煤气化装置和换档催化剂

    公开(公告)号：US20130255153A1

    公开(公告)日：2013-10-03

    申请号：US13771456

    申请日：2013-02-20

    Applicant: HITACHI, LTD.

    Inventor： Takashi SASAKI ,  Tomoko AKIYAMA

    IPC: B01J27/19 ,  C10J3/82

    CPC classification number: B01J27/19 ,  B01J21/063 ,  B01J21/066 ,  B01J23/28 ,  B01J23/755 ,  B01J37/0027 ,  B01J37/04 ,  B01J37/20 ,  B01J37/28 ,  C10J3/82 ,  C10J2300/093 ,  C10J2300/1653 ,  C10J2300/1807 ,  C10J2300/1884 ,  C10K1/005 ,  C10K1/06 ,  C10K3/04 ,  Y02E20/16 ,  Y02E20/18 ,  Y02P20/52

    Abstract: Disclosed is a method of gas purification, a coal gasification plant, and a shift catalyst, each of which enables an inexpensive treatment of condensed water derived from steam used in a CO shift reaction. A CO shift reaction is performed using a shift catalyst less causing side reactions (e.g., a P—Mo—Ni-supported shift catalyst), and condensed water derived from steam used in the CO shift reaction is reused or treated. The method includes a cleaning step of removing water-soluble substances from a gasified gas containing CO and H2S; a CO shift step of allowing CO in a gas after the cleaning step to react with steam by the catalysis of the shift catalyst to convert CO into CO2 and H2; and a recovery step of removing CO2 and H2S from a gas after the CO shift step, in which post-shift condensed water formed after the CO shift step is recycled.

    Abstract translation: 本发明公开了一种气体净化方法，煤气化装置和变换催化剂，其能够廉价地处理来自CO转化反应中使用的蒸汽的冷凝水。 使用较少引起副反应的转移催化剂（例如，P-Mo-Ni负载型变换催化剂）进行CO转化反应，并且再利用或处理由CO转化反应中使用的蒸汽得到的冷凝水。 该方法包括从含有CO和H 2 S的气化气体中除去水溶性物质的清洗步骤; CO漂移步骤，其通过催化转化催化剂将CO转化为CO 2和H 2后，使清洗步骤中的气体中的CO与蒸汽反应; 以及在CO转移步骤之后的气体中除去CO 2和H 2 S的回收步骤，其中在CO转移步骤之后形成的变换后冷凝水被再循环。

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