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    Method for the catalytic production of hydrocodone and hydromorphone
    21.
    发明申请
    Method for the catalytic production of hydrocodone and hydromorphone 有权
    氢可酮和氢吗啡酮的催化生产方法

    公开(公告)号：US20050124811A1

    公开(公告)日：2005-06-09

    申请号：US10973031

    申请日：2004-10-25

    申请人： Peter Wang ,  Carl White

    发明人： Peter Wang ,  Carl White

    IPC分类号： C07D489/02 ,  C07D489/08

    CPC分类号： B01J31/2404 ,  B01J31/1658 ,  B01J2231/76 ,  B01J2531/821 ,  B01J2531/822 ,  B01J2531/827 ,  C07D489/02

    摘要： A method for the catalytic conversion of codeine, morphine or analogs thereof into hydrocodone, hydromorphone or analogs thereof utilizing a transition metal catalyst of the formula [M(PR3R4R5)nXm]p; wherein R1 is H, alkyl, aryl or acyl; M is a Group VIII transition metal; R3, R4 and R5 are selected from the group consisting of alkyl, aryl, alkoxyl, phenoxyl and combinations thereof; X is a halide or an anion; n is 1, 2, 3 or 4; m is 1 or 2; and p is at least 1.

    摘要翻译： 利用过渡金属催化剂将式可待因，吗啡或其类似物催化转化为氢可酮，氢吗啡酮或其类似物的方法，其用式[M（PR 3 其中R 1是H，烷基，芳基或酰基; M是第VIII族过渡金属; R 3，R 4和R 5选自烷基，芳基，烷氧基，苯氧基及其组合; X是卤素或阴离子; n为1,2,3或4; m为1或2; p至少为1。

    Triphos polymer compounds and acylation agent useful in their preparation
    28.
    发明授权
    Triphos polymer compounds and acylation agent useful in their preparation 有权
    Triphos聚合物化合物和酰化剂可用于其制备

    公开(公告)号：US06441230B1

    公开(公告)日：2002-08-27

    申请号：US09781356

    申请日：2001-02-12

    申请人： Niels Christian Schiødt ,  Finn Joensen

    发明人： Niels Christian Schiødt ,  Finn Joensen

    IPC分类号： C07C30900

    CPC分类号： B01J31/1658 ,  B01J31/06 ,  B01J31/20 ,  B01J31/2404 ,  B01J2231/321 ,  B01J2531/0247 ,  B01J2531/821 ,  B01J2531/822 ,  B01J2531/824 ,  B01J2531/828 ,  C07C7/163 ,  C07C45/50 ,  C07C45/68 ,  C07C309/65 ,  C07C381/00 ,  C07C2531/24 ,  C07C49/80 ,  C07C47/02

    摘要： Material and process of preparing such material, of the formula where R1 is a linker and C(R2P(R3)2)3 group is a triphos moiety; and wherein R1 is selected from branched and linear alkyl group and alkyl carbonyl group optionally substituted with functional groups comprising carbonyl, alkoxy, hydroxy, amino, nitro, carboxylic or sulfonic acid and esters or amides thereof; R2 are methylene (CH2) or substituted methylene groups; R3 are linear or branched alkyl or phenyl or substituted phenyl groups; polymer is any polymer containing aromatic groups, comprising polystyrene, poly-vinyl pyridine, poly pyrrole, poly pyrrolidone or derivatives thereof. The material impregnated with a transition metal has catalytic properties. The preparation of the material involves the use of an acylating agent having the formula CF3SO3C(O)C(H2X)3 or an anhydride thereof, where X is a halogen.

    摘要翻译： 制备这种材料的材料和方法，其中R1是连接基，C（R2P（R3）2）3基团是三磷键部分; 并且其中R 1选自支链和直链烷基，和任选被包括羰基，烷氧基，羟基，氨基，硝基，羧酸或磺酸的官能团取代的烷基羰基和其酯或酰胺; R2是亚甲基（CH2）或取代亚甲基; R3是直链或支链烷基或苯基或取代的苯基; 聚合物是含有芳族基团的任何聚合物，包括聚苯乙烯，聚乙烯基吡啶，聚吡咯，聚吡咯烷酮或其衍生物。 用过渡金属浸渍的材料具有催化性能。 该材料的制备涉及使用具有式CF 3 SO 3 C（O）C（H 2 X）3的酰化剂或其酸酐，其中X为卤素。

    Polymeric phosphite composition and hydrocyanation of unsaturated organic compounds and the isomerization of unsaturated nitriles
    30.
    发明申请
    Polymeric phosphite composition and hydrocyanation of unsaturated organic compounds and the isomerization of unsaturated nitriles 失效
    聚合亚磷酸酯组合物和不饱和有机化合物的氢氰化和不饱和腈的异构化

    公开(公告)号：US20010049431A1

    公开(公告)日：2001-12-06

    申请号：US09865942

    申请日：2001-05-25

    发明人： Wilson Tam ,  Sigridur Soley Kristjansdottir ,  Robin Nikolas Greene

    IPC分类号： C08G079/02

    CPC分类号： C08G79/04 ,  B01J31/06 ,  B01J31/1658 ,  B01J31/1845 ,  B01J31/185 ,  B01J31/28 ,  B01J2231/323 ,  B01J2231/52 ,  B01J2531/824 ,  B01J2531/845 ,  B01J2531/847 ,  C08G63/6924 ,  C08G69/42 ,  C08G69/48

    摘要： A polymeric composition, a process for producing the composition, and a process for using the composition in, for example, hydrocyanation or isomerization are disclosed. The composition comprises repeat units derived from (1) a carbonyl compound, a monomer, and phosphorochloridite; (2) phosphorus trichloride, a polyhydric alcohol, and an aromatic diol; or (3) combinations of (1) and (2) in which the monomer can be a polyhydric alcohol, an amine, combinations thereof. The composition can further comprise a Group VIII metal and optionally a Lewis acid. The composition can be produced by (1) contacting a carbonyl compound with the monomer to produce an intermediate and contacting the intermediate with phosphorochloridite; (2) contacting phosphorus trichloride with a second polyhydric alcohol under a condition sufficient to produce a phosphorus-containing polymer and contacting the phosphorus-containing polymer with an aromatic diol; or (3) contacting an N,N-dialkyl dichlorophosphoramidite with a second polyhydric alcohol to produce a polymer phosphoramidite, contacting the polymer phosphoramidite with an acid such as HCl to produce the phospphorus-containing polymer, which is then contacted with an aromatic diol. The composition can be used as catalyst, for example, for converting an unsaturated organic compound to a nitrile and isomerizing a nitrile.

    摘要翻译： 公开了一种聚合物组合物，用于生产该组合物的方法以及该组合物在例如氢氰化或异构化中的使用方法。 该组合物包含衍生自（1）羰基化合物，单体和磷酰氯的重复单元; （2）三氯化磷，多元醇和芳族二醇; 或（3）（1）和（2）的组合，其中所述单体可以是多元醇，胺及其组合。 组合物还可以包含VIII族金属和任选的路易斯酸。 组合物可以通过（1）使羰基化合物与单体接触以制备中间体并使中间体与磷酰氯接触而制备; （2）在足以产生含磷聚合物并使含磷聚合物与芳族二醇接触的条件下，使三氯化磷与第二多元醇接触; 或（3）使N，N-二烷基二氯亚磷酰胺与第二多元醇接触以产生聚合亚磷酰胺，使聚亚磷酰胺与酸如HCl接触以制备含磷基聚合物，然后与芳族二醇接触。 该组合物可用作催化剂，例如用于将不饱和有机化合物转化为腈并使腈异构化。