公开(公告)号：US20180002516A1

公开(公告)日：2018-01-04

申请号：US15538137

申请日：2015-12-28

Applicant: ExxonMobil Chemical Patents Inc.

Inventor： Jo Ann M. Canich ,  Rainer Kolb ,  Periagaram S. Ravishankar ,  Phillip T. Matsunaga ,  Peijun Jiang ,  Rhutesh K. Shah ,  Narayanaswami Dharmarajan

IPC: C08L23/16

CPC classification number: C08L23/16 ,  C08F4/65908 ,  C08F4/76 ,  C08F210/06 ,  C08F210/16 ,  C08F210/18 ,  C08F2500/09 ,  C08F2500/17 ,  C08L2205/02 ,  C08L2205/025 ,  C08L2205/06 ,  C08L2207/07 ,  C08L2312/04 ,  C08L2314/06 ,  C08F4/65927 ,  C08F4/65904 ,  C08F236/20 ,  C08F2500/04

Abstract: Provided herein are polymerization processes and polymer compositions including reactor blends formed by such polymerization processes. The polymerization processes include copolymerization using two metallocene catalyst systems: the first catalyst system capable of producing polymers having 60% or more vinyl terminations, the second catalyst system capable of producing high molecular weight polymers, preferably incorporating at least some of the polymers produced by the first catalyst system into the high molecular weight polymers. The reactor blends formed thereby therefore include first and second copolymer components, which may differ in monomer content and weight-average molecular weight (Mw). Furthermore, the reactor blends may exhibit advantageous rheological properties, at least some of which are consistent with long-chain branching. Preferred reactor blends comprise ethylene-propylene-diene (EPDM) terpolymers.

公开(公告)号：US20170327678A1

公开(公告)日：2017-11-16

申请号：US15527993

申请日：2015-11-18

Applicant: Borealis AG

Inventor： Jarmo Kela ,  Peter Niedersuss ,  Jari Aarila ,  Markku Vahteri ,  Floran Prades ,  John Jamieson ,  Willem Wever

IPC: C08L23/08 ,  C08J5/18

CPC classification number: C08L23/0815 ,  C08F210/16 ,  C08J5/18 ,  C08J2323/08 ,  C08J2423/08 ,  C08L2203/162 ,  C08L2205/025 ,  C08L2308/00 ,  C08L2314/06 ,  C08F4/65916 ,  C08F4/65912 ,  C08F4/6492 ,  C08F210/08 ,  C08F2500/12 ,  C08F210/14 ,  C08F4/65925

Abstract: The present invention relates to a polymer composition, to the use of the polymer composition in film applications and to a film comprising the polymer composition of the invention.

公开(公告)号：US20170267822A1

公开(公告)日：2017-09-21

申请号：US15609051

申请日：2017-05-31

Applicant: NOVA Chemicals (International) S.A.

Inventor： Celine Bellehumeur ,  Brian Molloy ,  Hamidreza Khakdaman ,  XiaoChuan Wang ,  Tieqi Li ,  Christopher Dobbin ,  Fazle Sibtain ,  Kenneth Taylor

IPC: C08J5/18 ,  B29C41/04 ,  B32B27/08 ,  B32B27/32 ,  B32B27/34 ,  B32B3/26 ,  B32B7/12 ,  C08F2/00 ,  C08F2/06 ,  C08F210/16 ,  C08F4/655 ,  C08F4/658 ,  C08F4/659 ,  C08F4/6592 ,  C08J5/00 ,  C08L23/08 ,  C08L23/20 ,  B29K105/00 ,  B29K23/00 ,  C08F210/14

CPC classification number: C08L23/0815 ,  B29C41/04 ,  B29C41/22 ,  B29K2023/08 ,  B29K2105/0058 ,  B29K2105/0085 ,  B29K2105/0094 ,  B29K2905/02 ,  B29K2995/0063 ,  B29K2995/0088 ,  B32B3/266 ,  B32B7/12 ,  B32B27/08 ,  B32B27/327 ,  B32B27/34 ,  B32B2307/7265 ,  B32B2439/40 ,  C08F2/001 ,  C08F2/06 ,  C08F4/6555 ,  C08F4/6583 ,  C08F4/6585 ,  C08F4/65904 ,  C08F4/65908 ,  C08F4/65912 ,  C08F4/6592 ,  C08F210/14 ,  C08F210/16 ,  C08F2420/01 ,  C08F2420/04 ,  C08F2500/03 ,  C08F2500/09 ,  C08F2500/11 ,  C08F2500/12 ,  C08F2500/13 ,  C08F2500/17 ,  C08F2500/18 ,  C08F2500/26 ,  C08J5/00 ,  C08J5/18 ,  C08J2323/06 ,  C08J2323/08 ,  C08J2323/20 ,  C08J2323/24 ,  C08J2423/08 ,  C08J2423/20 ,  C08J2423/24 ,  C08L23/08 ,  C08L23/14 ,  C08L23/20 ,  C08L2203/16 ,  C08L2205/025 ,  C08L2205/03 ,  C08L2205/06 ,  C08L2314/02 ,  C08L2314/06

Abstract: This disclosure relates to rotomolded articles, having a wall structure, where the wall structure contains at least one layer containing an ethylene interpolymer product, or a blend containing an ethylene interpolymer product and an ethylene polymer, where the ethylene interpolymer product has a Dilution Index (Yd) greater than 0 and improved Environmental Stress Crack Resistance (ESCR). The ethylene interpolymer product has a melt index from about 0.5 to about 15 dg/minute, a density from about 0.930 to about 0.955 g/cm3, a polydispersity (Mw/Mn) from about 2 to about 6 and a CDBI50 from about 50% to about 98%. Further, the ethylene interpolymer products are a blend of at least two ethylene interpolymers; where one ethylene interpolymer is produced with a single-site catalyst formulation and at least one ethylene interpolymer is produced with a heterogeneous catalyst formulation.

公开(公告)号：US20170260430A1

公开(公告)日：2017-09-14

申请号：US15609455

申请日：2017-05-31

Applicant: HENKEL AG & CO. KGAA

Inventor： Masahiro MORIGUCHI ,  Shigekazu SAITO

IPC: C09J123/12 ,  C08L23/08 ,  C09J123/08 ,  C09J7/02 ,  C09J11/06

CPC classification number: C09J123/12 ,  C08L23/0815 ,  C08L2314/06 ,  C09J7/35 ,  C09J11/06 ,  C09J123/08 ,  Y10T428/2826

Abstract: The present invention provides a hot melt adhesive for high-speed coating and spiral coating at low temperature. The hot melt adhesive has excellent adhesion to polyethylene and nonwoven fabric, and is suitable for disposable products. The hot melt adhesive comprises: (A) a propylene homopolymer having a melting point of 100° C. or lower which is obtainable by polymerizing propylene using a metallocene catalyst; and (B) an ethylene-based copolymer.

公开(公告)号：US09695341B2

公开(公告)日：2017-07-04

申请号：US14169353

申请日：2014-01-31

Applicant: HENKEL IP & HOLDING GMBH

Inventor： Jennifer Thatcher ,  Yuhong Hu ,  Darshak Desai

IPC: C09J123/20 ,  C08J5/12 ,  C09J123/10 ,  C09J7/02 ,  C09J5/00 ,  A61L15/58

CPC classification number: C09J123/20 ,  A61L15/58 ,  C08J5/125 ,  C08J2423/12 ,  C08J2423/20 ,  C08L23/14 ,  C08L23/22 ,  C08L2205/02 ,  C08L2314/02 ,  C08L2314/06 ,  C09J5/00 ,  C09J7/381 ,  C09J123/10 ,  C09J2201/61 ,  C09J2423/00 ,  Y10T428/2878

Abstract: Adhesives, methods to bond substrates together with the adhesives, and articles of manufacture comprising the adhesives are described. It has been discovered that an adhesive with a polymer content greater than 70 weight percent can be formulated with a blend of (i) a metallocene catalyzed polypropylene polymer that has a density range of about 0.70 to about 0.91 g/cm3 and a melt viscosity less than 50,000 cP at 190° C. and (ii) a Ziegler-Natta catalyzed amorphous polybutene and/or polypropylene copolymer. Such adhesives have high creep resistance making them particularly well suited for disposable personal care garments.

公开(公告)号：US09580533B2

公开(公告)日：2017-02-28

申请号：US13623242

申请日：2012-09-20

Applicant: ExxonMobil Chemical Patents Inc.

Inventor： Peijun Jiang ,  Kevin R. Squire ,  Jianya Cheng ,  Pradeep P. Shirodkar ,  Johannes M. Soulages ,  Keith E. Jolibois ,  Ronald R. Thackston ,  Andrew G. Narvaez, Jr.

IPC: C08F210/18 ,  C08F236/20 ,  C08J5/18 ,  C08L23/08 ,  C08F210/02

CPC classification number: C08F236/20 ,  C08F210/02 ,  C08F210/18 ,  C08F2500/09 ,  C08J5/18 ,  C08L23/0815 ,  C08L23/083 ,  C08L2203/16 ,  C08L2205/025 ,  C08L2207/07 ,  C08L2314/06 ,  C08F210/14 ,  C08F2500/12 ,  C08F2500/17 ,  C08F2500/19

Abstract: The present invention relates to a branched modifier and a composition comprising more than 25 wt % (based on the weight of the composition) of one or more linear ethylene polymers having a g′vis of 0.97 or more and an Mw of 20,000 g/mol or more and at least 0.1 wt % of a branched modifier where the modifier has a g′vis of less than 0.97, wherein the ethylene polymer has a g′vis of at least 0.01 units higher than the g′vis of the branched modifier.

Abstract translation: 支链改性剂和组合物，其包含超过25重量％（基于组合物的重量）的一种或多种线性乙烯聚合物，其具有0.97以上的Mw和20,000g / mol的Mw， 更多且至少0.1重量％的支化改性剂，其中改性剂的含量小于0.97，其中乙烯聚合物具有比分支改性剂的g'vis高至少0.01单位的氨基酸。

公开(公告)号：US09570642B2

公开(公告)日：2017-02-14

申请号：US14362695

申请日：2012-12-03

Applicant: Dai Nippon Printing Co., Ltd.

Inventor： Hideki Matsui ,  Kosuke Saeki ,  Yasushi Shirahige ,  Noritoshi Akazawa ,  Toshio Yoshihara

IPC: H01L31/04 ,  C09D123/08 ,  H01L31/048

CPC classification number: H01L31/0481 ,  B32B17/10018 ,  B32B2323/046 ,  C08L2203/204 ,  C08L2205/025 ,  C08L2207/06 ,  C08L2312/08 ,  C08L2314/06 ,  C09D123/0815 ,  Y02E10/50

Abstract: Provided is a sealing material sheet for solar cell modules, which is obtained by irradiating a polyethylene resin with ionizing radiation and has high transparency, heat resistance and adhesion at the same time. This sealing material sheet for solar cell modules contains a low density polyethylene having a density of 0.900 g/cm3 or less, while having a gel fraction of from 0% to 40% (inclusive) and a degree of dispersity (Mw/Mn), which is the ratio of the weight average molecular weight (Mw) to the number average molecular weight (Mn) in terms of polystyrene, of from 2.5 to 3.5 (inclusive).

Abstract translation: 本发明提供一种太阳能电池模块用密封材料片，其通过用电离辐射照射聚乙烯树脂并同时具有高透明性，耐热性和粘合性而获得。 该太阳能电池模块用密封材料片含有密度为0.900g / cm 3以下的低密度聚乙烯，凝胶分数为0〜40％（Mw），分散度Mw / Mn， 其是以聚苯乙烯换算的重均分子量（Mw）与数均分子量（Mn）之比为2.5〜3.5（含）的比例。

公开(公告)号：US09567351B2

公开(公告)日：2017-02-14

申请号：US14131549

申请日：2012-07-06

Applicant: Norbert Hafner ,  Luigi Resconi ,  Markus Gahleitner ,  Jimgbo Wang ,  Pascal Castro ,  Pavel Sergeevich Kulyabin ,  Vyatcheslav Izmer ,  Alexander Voskoboynikov ,  Dmitry Kononovich ,  Ville Virkkunen

Inventor： Norbert Hafner ,  Luigi Resconi ,  Markus Gahleitner ,  Jimgbo Wang ,  Pascal Castro ,  Pavel Sergeevich Kulyabin ,  Vyatcheslav Izmer ,  Alexander Voskoboynikov ,  Dmitry Kononovich ,  Ville Virkkunen

IPC: C08L23/00 ,  C07F7/08 ,  C07C13/465 ,  C07F17/00 ,  C08L23/12 ,  C08F4/6592 ,  C08F10/06 ,  C08F110/06 ,  C08F210/06 ,  C08F4/659

CPC classification number: C07F7/081 ,  C07C13/36 ,  C07C13/38 ,  C07C13/465 ,  C07C41/01 ,  C07F17/00 ,  C08F4/65912 ,  C08F4/65916 ,  C08F4/65927 ,  C08F10/06 ,  C08F110/06 ,  C08F210/06 ,  C08L23/12 ,  C08L2207/02 ,  C08L2314/06 ,  C08L23/16 ,  C08F2500/03 ,  C08F2500/12 ,  C08F210/16

Abstract: A heterophasic polypropylene resin comprising a polypropylene homopolymer matrix phase (A) and an ethylene-propylene copolymer phase (B) dispersed within the matrix, wherein the xylene soluble fraction of the heterophasic polypropylene resin is in the range 20 to less than 50 wt %; the heterophasic polypropylene resin has an MFR2 of 0.01 to 50 g/10 min; the ethylene content of the xylene soluble fraction of the heterophasic polypropylene resin is in the range of at least 20 wt % to less than 50 wt %; the heterophasic polypropylene resin has a notched charpy impact strength at −20 C of at least 25 kJ/m2, preferably at least 50 kJ/m2; and wherein the MFR2 (Matrix)/MFR2(XS)≧5, preferably ≧10.

Abstract translation: 包含分散在基质内的聚丙烯均聚物基质相（A）和乙烯 - 丙烯共聚物相（B）的多相聚丙烯树脂，其中所述多相聚丙烯树脂的二甲苯可溶部分在20至小于50重量％的范围内; 多相聚丙烯树脂的MFR 2为0.01〜50g / 10分钟; 多相聚丙烯树脂的二甲苯可溶级分的乙烯含量在至少20重量％至小于50重量％的范围内; 多相聚丙烯树脂在-20℃下具有至少25kJ / m 2，优选至少50kJ / m 2的缺口夏比冲击强度; 并且其中MFR 2（Matrix）/ MFR 2（XS）≥5，优选≥10。

公开(公告)号：US09540155B2

公开(公告)日：2017-01-10

申请号：US13511094

申请日：2009-11-20

Applicant: Christiane Poel ,  Georg Schlenk ,  Rüdiger Wittenberg

Inventor： Christiane Poel ,  Georg Schlenk ,  Rüdiger Wittenberg

IPC: B65D53/04 ,  B21D51/46 ,  C08L23/08 ,  C08L53/00 ,  B65D53/00

CPC classification number: B65D53/04 ,  B21D51/46 ,  B65D53/00 ,  C08L23/0815 ,  C08L53/00 ,  C08L2205/02 ,  C08L2314/06 ,  C08L2666/06

Abstract: The invention relates to a polymer compound for a sealing insert for a container closure, in particular for fat-containing filling materials, which has a composition such that the migration of constituents of the compound into the filling material is reduced, characterized in that the Shore A hardness of the polymer compound is between 45 and 95 and in the compressive deformation test analogous to ASTM D395-97 Method B at 70 DEG C the polymer compound exhibits a compression set of 30-90%.

Abstract translation: 本发明涉及一种用于容器封闭件的密封插入物的高分子化合物，特别是用于含脂肪的填充材料，其具有使化合物的成分向填充材料的迁移减少的组成，其特征在于肖氏 聚合物化合物的硬度在45和95之间，在压缩变形试验类似于ASTM D395-97方法B在70℃下，聚合物化合物表现出30-90％的压缩永久变形。

公开(公告)号：US09512283B2

公开(公告)日：2016-12-06

申请号：US14918964

申请日：2015-10-21

Applicant: NOVA Chemicals (International) S.A.

Inventor： XiaoChuan Wang ,  Tieqi Li ,  Christopher John Brooke Dobbin ,  Fazle Sibtain ,  Kenneth Edward Taylor ,  Hamidreza Khakdaman

IPC: C08L23/20 ,  C08J5/00 ,  B32B3/26 ,  B32B27/32 ,  C08J5/18 ,  C08L23/08

CPC classification number: C08L23/0815 ,  B29C41/04 ,  B29C41/22 ,  B29K2023/08 ,  B29K2105/0058 ,  B29K2105/0085 ,  B29K2105/0094 ,  B29K2905/02 ,  B29K2995/0063 ,  B29K2995/0088 ,  B32B3/266 ,  B32B7/12 ,  B32B27/08 ,  B32B27/327 ,  B32B27/34 ,  B32B2307/7265 ,  B32B2439/40 ,  C08F2/001 ,  C08F2/06 ,  C08F4/6555 ,  C08F4/6583 ,  C08F4/6585 ,  C08F4/65904 ,  C08F4/65908 ,  C08F4/65912 ,  C08F4/6592 ,  C08F210/14 ,  C08F210/16 ,  C08F2420/01 ,  C08F2420/04 ,  C08F2500/03 ,  C08F2500/09 ,  C08F2500/11 ,  C08F2500/12 ,  C08F2500/13 ,  C08F2500/17 ,  C08F2500/18 ,  C08F2500/26 ,  C08J5/00 ,  C08J5/18 ,  C08J2323/06 ,  C08J2323/08 ,  C08J2323/20 ,  C08J2323/24 ,  C08J2423/08 ,  C08J2423/20 ,  C08J2423/24 ,  C08L23/08 ,  C08L23/14 ,  C08L23/20 ,  C08L2203/16 ,  C08L2205/025 ,  C08L2205/03 ,  C08L2205/06 ,  C08L2314/02 ,  C08L2314/06

Abstract: This disclosure relates to rotomolded articles, having a wall structure, where the wall structure contains at least one layer containing an ethylene interpolymer product, or a blend containing an ethylene interpolymer product, where the ethylene interpolymer product has: a Dilution Index (Yd) greater than 0; total catalytic metal ≧3.0 ppm; ≧0.03 terminal vinyl unsaturations per 100 carbon atoms, and; optionally a Dimensionless Modulus (Xd) greater than 0. The ethylene interpolymer products have a melt index from about 0.4 to about 100 dg/minute, a density from about 0.950 to about 0.970 g/cm3, a polydispersity (Mw/Mn) from about 2 to about 25 and a CDBI50 from about 55% to about 97%. Further, the ethylene interpolymer products are a blend of at least two ethylene interpolymers; where one ethylene interpolymer is produced with a single-site catalyst formulation and at least one ethylene interpolymer is produced with a heterogeneous catalyst formulation.

Abstract translation: 本公开涉及具有壁结构的滚塑制品，其中壁结构包含至少一层含有乙烯互聚物产物的层或含有乙烯互聚物产物的共混物，其中乙烯互聚物产物具有：稀释指数（Yd）更大 比0; 总催化金属≥3.0ppm; ≧0.03个末端乙烯基不饱和/ 100个碳原子， 任选的大于0的无量纲模量（Xd）。乙烯互聚物产物的熔体指数为约0.4至约100dg /分钟，密度为约0.950至约0.970g / cm 3，多分散性（Mw / Mn）为约 2至约25，CDBI50为约55％至约97％。 此外，乙烯互聚物产物是至少两种乙烯互聚物的共混物; 其中一个乙烯互聚物用单中心催化剂制剂生产，并且用非均相催化剂制剂生产至少一种乙烯互聚物。