摘要:
Provided is a copolymer of a conjugated diene compound and a non-conjugated olefin, the copolymer being a block copolymer, the conjugated diene compound unit having 1,2 adduct (including 3,4 adduct) content of 5% or less or the conjugated diene compound unit having a cis-1,4 bond content of more than 92%, in which preferred examples of the conjugated diene compound include 1,3-butadiene and isoprene, and preferred examples of the non-conjugated olefin include ethylene, propylene, and 1-butene.
摘要:
The instant invention is a high-density polyethylene composition, method of producing the same, closure devices made therefrom, and method of making such closure devices. The high-density polyethylene composition according to the present invention comprises (a) a first component comprising a high molecular weight ethylene alpha-olefin copolymer having a density in the range of 0.927 to 0.938 g/cm3, and a melt flow rate (I21) in the range of 4 to 10 g/10 minutes, and (b) a second component comprising a low molecular weight ethylene polymer having a density in the range of 0.960 to 0.975 g/cm3, and a melt index (I2) in the range of 100 to 1200 g/10 minutes; and wherein the high-density polyethylene composition has a melt index (I2) in the range of from 2 to 10 g/10 minutes, a density in the range of from 0.950 to 0.960 g/cm3, and a flow direction shrinkage to cross flow direction shrinkage ratio in the range of from 2 to 3.2, and an environmental stress crack resistance (ESCR) (F50) according to ASTM D-1693, condition B at 50° C., and using 10 percent Branched Octylphenoxy Poly(Ethyleneoxy) Ethanol, in the range of equal to or greater than 50 hours.
摘要翻译:本发明是高密度聚乙烯组合物,其制造方法,由其制成的封闭装置,以及制造这种闭合装置的方法。 根据本发明的高密度聚乙烯组合物包含(a)包含密度在0.927至0.938g / cm 3范围内的高分子量乙烯α-烯烃共聚物和熔体流动速率(I21)的第一组分, 在4至10g / 10分钟的范围内,和(b)包含密度在0.960至0.975g / cm 3范围内的低分子量乙烯聚合物的第二组分和在该范围内的熔体指数(I 2) 为100〜1200g / 10分钟; 并且其中所述高密度聚乙烯组合物具有在2至10g / 10分钟范围内的熔体指数(I 2),在0.950至0.960g / cm 3范围内的密度和横向流动方向收缩 方向收缩率在2至3.2范围内,以及根据ASTM D-1693,条件B在50℃下的环境应力开裂抗力(ESCR)(F50),并使用10%支链辛基苯氧基聚(乙烯氧基)乙醇 在等于或大于50小时的范围内。
摘要:
The present invention provides a method for controlling the chain structure of a copolymer. The disclosed method is capable of controlling the arrangement of monomeric units in a copolymer, and of selectively forming a random copolymer, tapered copolymer, multiblock copolymer and block copolymer. In the method for controlling the chain structure of a copolymer of a conjugated diene compound and a non-conjugated olefin, the introduction of the conjugated diene compound is controlled in the presence of the non-conjugated olefin so as to control the chain structure of the copolymer.
摘要:
Improved reaction processes comprise reacting a mixture to form a product comprising a metal alkyl, metal oxide, or mixture thereof and then passing said product to a post-reactor heat exchanger. The improvement comprises one or more of the following: (1) reacting said metal alkyl compound with an acid to produce a soluble metal ester; or (2) adding an ionic surfactant; or (3) adding a mixture comprising an antioxidant to the product under conditions sufficient to avoid formation of significant amounts of insoluble metal or metal compounds derived from said metal alkyl compound; or (4) purging said post-reactor heat exchanger with an inert gas under conditions to remove metal oxide from the post-reactor heat exchanger.
摘要:
Disclosed herein is a polymeric composition. The polymeric composition includes: (A) a propylene/a-olefin interpolymer; (B) an ethylene-based polymer; (C) a block composite comprising: i) a propylene-based crystalline polymer; ii) an ethylene/a-olefin polymer; and iii) a block copolymer comprising a propylene-based crystalline block and an ethylene/a-olefin block. The polymeric composition provides improved heat seals when formed into film, film layer, or flexible containers such as a retort pouch.
摘要:
This invention relates to a process for polymerizing olefins in which the amount of trimethylaluminum in a methylalumoxane solution is adjusted to be from 1 to 25 mol %, prior to use as an activator, where the mol % trimethylaluminum is determined by 1H NMR of the solution prior to combination with any support. This invention also relates to a process for polymerizing olefins in which the amount of an unknown species present in a methylalumoxane solution is adjusted to be from 0.10 to 0.65 integration units prior to use as an activator, where the amount of the unknown species is determined by the 1H NMR spectra of the solution performed prior to combination with any support. Preferably, the methylalumoxane solution is present in a catalyst system also comprising a metallocene transition metal compound.
摘要:
The present invention relates to a thermoplastic polyolefin elastomer composition in powder form comprising (i) an olefin block copolymer or (ii) a substantially linear ethylene polymer and/or a linear ethylene polymer and propylene polymer blend. Said composition demonstrates good pulverizing and flow characteristics at ambient temperature. In another aspect, this invention relates to a process for preparing said thermoplastic polyolefin elastomer powder and applications for using said powder. In a further aspect, this invention relates to paper transfer molding said thermoplastic polyolefin elastomer composition into artificial leather, particularly for skins for automotive interior applications such as instrument panels.
摘要:
Polyolefin composition, comprising in percent by weight: 1) 75-85% of a copolymer of propylene, said copolymer containing up to 15% by weight, of ethylene and/or C4-C10 α-olefin(s) and having a fraction soluble in Xilene at room temperature lower than 6% by weight, and 2) 15-25% of a copolymer of ethylene with one or more C4-C10 α-olefin(s) containing from 10 to 25% by weight of said C4-C10 α-olefin(s); said composition having the value of MFR, measured at 230° C., 2.16 kg, of less than 2.5 g/10 min, the total content of ethylene of from 14 to 22% by weight, the total content of C4-C10 α-olefin(s) of less than 4.5% by weight, the ratio of the total content of ethylene to the total content of C4-C10 α-olefin(s) equal to or higher than 4, the value of the intrinsic viscosity of the total fraction soluble in xylene at room temperature equal to or less than 1.5 dl/g, and the ratio of the amount of component 2) and the amount of C4-C10 α-olefin(s) in component 2) equal to or higher than 0.80.
摘要:
Disclosed are processes for producing polypropylene resin compositions including two or three sorts of propylene-based polymeric materials, the processes including a first step of melt-kneading at least a propylene-α-olefin block copolymer containing a polymer portion composed mainly of propylene and a propylene-α-olefin copolymer portion having a relatively high intrinsic viscosity and a second step of melt-kneading the product of the first step with a propylene-ethylene block copolymer containing a polymer portion composed mainly of propylene and a propylene-ethylene copolymer portion having a relatively low intrinsic viscosity or a polymer portion composed mainly of propylene having a relatively low intrinsic viscosity. In the composition produced by these processes, no or substantially no fish eyes develop.
摘要:
Disclosed is a propylene block copolymer having excellent flexibility and impact resistance and showing a good polymer powder form. Also disclosed is a process for producing the copolymer. More specifically, the copolymer is a novel propylene block copolymer which satisfies a specific requirement and is produced by a process comprising continuously performing a multi-step polymerization composed of a former step in which a propylene homopolymer component or a specific propylene copolymer component is produced in the presence of a metallocene catalyst carried on a support and a latter step in which propylene and a specific copolymer component are produced by gas phase polymerization.