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公开(公告)号：US20050131111A1
公开(公告)日：2005-06-16
申请号：US10497949
申请日：2002-08-06
IPC分类号： B01D19/04 , C07C20060101 , C07C69/22 , C07C69/28 , C07C69/52 , C07C319/20 , C07C319/26 , C07C323/58 , C07C391/00 , C08L1/00
CPC分类号： C07C319/20 , C07C319/26 , C07C319/28 , C07C323/58
摘要： The invention relates to a process for the preparation of methionine of high bulk density, in which a mixture which comprises a compound which has a foaming action and a compound which influences the crystallization is added to the hydrolysis solution, and to the mixture itself.
摘要翻译： 本发明涉及一种制备高堆积密度的甲硫氨酸的方法，其中将包含具有发泡作用的化合物和影响结晶的化合物的混合物加入到水解溶液中，以及混合物本身。
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公开(公告)号：US09464045B2
公开(公告)日：2016-10-11
申请号：US14850207
申请日：2015-09-10
申请人： Martin Koerfer , Hans Joachim Hasselbach , Stefan Reichert , Harald Jakob , Christoph Weckbecker , Klaus Huthmacher , Horst Krull , Bernd Drapal , Rainer Peter
发明人： Martin Koerfer , Hans Joachim Hasselbach , Stefan Reichert , Harald Jakob , Christoph Weckbecker , Klaus Huthmacher , Horst Krull , Bernd Drapal , Rainer Peter
IPC分类号： C07C319/28 , C07C319/20 , C07C319/26 , C07C319/12 , C07C323/52
CPC分类号： C07C319/28 , C07C319/12 , C07C319/20 , C07C319/26 , C07C323/52 , Y02P20/142 , C07C323/58
摘要： This disclosure relates to a process for preparing D,L-methionine by feeding carbon dioxide to an aqueous potassium methioninate solution obtained by hydrolysis of 5-(2-methylmercaptoethyl)hydantoin, in order to precipitate out crude methionine, which is separated off and purified. In this process an aqueous solution of the separated-off crude methionine is purified by recrystallization from a solution containing potassium ions and also a crystallization additive. The crystallization additive is a nonionic or anionic surfactant, or a mixture of different nonionic or anionic surfactants. The recrystallization occurs by introducing a 60 to 110° C.-hot methionine solution into a 35 to 80° C.-warm methionine suspension, a temperature of which is lower than that of the introduced solution, such that the temperature of the methionine suspension being maintained between 35 and 80° C. during the addition. The crystallization additive is a sorbitan fatty acid ester or a mixture of different sorbitan fatty acid esters.
摘要翻译： 本公开涉及通过将二氧化碳供给到通过水解5-（2-甲基巯基乙基）乙内酰脲获得的甲硫氨酸钾水溶液以便沉淀出粗蛋氨酸的方法来制备D，L-甲硫氨酸，其分离和纯化 。 在该方法中，分离的粗甲硫氨酸的水溶液通过从含有钾离子的溶液和结晶添加剂中重结晶来纯化。 结晶添加剂是非离子或阴离子表面活性剂，或不同的非离子或阴离子表面活性剂的混合物。 通过将60〜110℃的甲硫氨酸溶液导入35〜80℃的甲硫氨酸悬浮液中，其温度低于引入的溶液的温度，使得甲硫氨酸悬浮液的温度 在添加期间保持在35和80℃之间。 结晶添加剂是脱水山梨糖醇脂肪酸酯或不同脱水山梨糖醇脂肪酸酯的混合物。
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33.发明授权Mo containing catalyst, a preparation method and a method for preparing methyl mercaptan 有权含钼催化剂，制备方法和制备甲硫醇的方法公开(公告)号：US08883670B2
公开(公告)日：2014-11-11
申请号：US12439926
申请日：2007-05-25
申请人： Yiquan Yang , Aiping Chen , Qi Wang , Jan-Olaf Barth , Christoph Weckbecker , Klaus Huthmacher
发明人： Yiquan Yang , Aiping Chen , Qi Wang , Jan-Olaf Barth , Christoph Weckbecker , Klaus Huthmacher
IPC分类号： B01J27/057 , B01J21/04 , B01J21/08 , B01J39/14 , B01J23/28 , B01J37/02 , B01J23/887 , C07C319/02 , B01J35/00 , B01J37/20
CPC分类号： B01J23/28 , B01J21/08 , B01J23/8872 , B01J27/0576 , B01J35/002 , B01J37/0201 , B01J37/0203 , B01J37/0205 , B01J37/20 , C07C319/02 , C07C321/04
摘要： A method is described to prepare a Mo containing supported catalyst comprising TeO2 as active promoter and a process for preparing methanethiol in the presence of said catalyst.
摘要翻译： 描述了一种制备包含TeO 2作为活性促进剂的Mo载体催化剂的方法和在所述催化剂存在下制备甲硫醇的方法。
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公开(公告)号：US08299293B2
公开(公告)日：2012-10-30
申请号：US12169683
申请日：2008-07-09
申请人： Christoph Kobler , Martin Hateley , Philipp Roth , Barbara Jaeger , Christoph Weckbecker , Klaus Huthmacher
发明人： Christoph Kobler , Martin Hateley , Philipp Roth , Barbara Jaeger , Christoph Weckbecker , Klaus Huthmacher
IPC分类号： C07C323/22 , C07C69/66 , C07C67/36 , C07C69/73 , C07C59/00
CPC分类号： C07C319/20 , C07B41/06 , C07B41/08 , C07C51/373 , C07C67/313 , C07C319/14 , C07C323/52 , C07D317/32 , C07D493/08 , C07C62/18 , C07C69/716 , C07C321/14
摘要： A method for preparing α-keto acids, especially α-ketomethionine, and/or derivatives thereof, whereby an aldehyde is reacted with thiols to give a corresponding dithioacetal, the dithioacetal formed, is reacted with an electrophile in the presence of a strong base, and the resulting α,α-(dithio)carboxylic acid is solvolyzed with acid-catalysis to release thiol and give the α-keto acid or a derivative thereof. Umpolung of aliphatic or aromatic aldehydes is effected by reaction with thiols.
摘要翻译： 一种制备α-酮酸，特别是α-酮基甲硫氨酸和/或其衍生物的方法，其中醛与硫醇反应，得到相应的二硫缩醛，形成的二硫缩醛与亲电子试剂在强碱存在下反应， 所得的α，α-（二硫代）羧酸用酸催化溶剂分解，释放硫醇，得到α-酮酸或其衍生物。 通过与硫醇反应来实现脂族或芳族醛的沸腾。
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35.发明授权Polynucleotides which code for cyanide-tolerant nitrile hydratase and compositions thereof 有权编码氰化物耐受性腈水合酶的多核苷酸及其组合物公开(公告)号：US07943359B2
公开(公告)日：2011-05-17
申请号：US12539804
申请日：2009-08-12
申请人： Steffen Osswald , Christoph Weckbecker , Klaus Huthmacher , Tatijana Gerasimova , Andrey Novikov , Ludmila Ryabchenko , Alexander Yanenko , Ksenia Egorova
发明人： Steffen Osswald , Christoph Weckbecker , Klaus Huthmacher , Tatijana Gerasimova , Andrey Novikov , Ludmila Ryabchenko , Alexander Yanenko , Ksenia Egorova
摘要： Disclosed herein are cyanide-tolerant nitrile hydratases especially from Pseudomonas putida or Pseudomonas marginalis strains which exhibit increased cyanide tolerance. Also disclosed are methods of preparing amides from nitriles in the presence of cyanides and polynucleotide sequences coding for cyanide-tolerant nitrile hydratases.
摘要翻译： 本文公开的是氰化物耐受性腈水合酶，特别是恶臭假单胞菌（Pseudomonas putida）或边缘假单胞菌（Pseudomonas marginalis）的菌株，其表现出增加的氰化物耐受性。 还公开了在氰化物和编码氰化物耐受性腈水合酶的多核苷酸序列存在下由腈制备酰胺的方法。
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公开(公告)号：US07846861B2
公开(公告)日：2010-12-07
申请号：US12017911
申请日：2008-01-22
IPC分类号： B01J38/46
CPC分类号： B01J21/16 , B01J21/20 , B01J23/30 , B01J23/6527 , B01J23/888 , B01J23/92 , B01J23/94 , B01J23/96 , B01J29/076 , B01J35/002 , B01J37/0201 , B01J37/04 , C07C45/52 , Y02P20/584 , Y10S502/514 , Y10S502/515 , C07C47/22
摘要： A process for regenerating a catalyst used in the preparation of acrolein from glycerol, which comprises tungsten compounds and has acidic properties and at least one promoter.
摘要翻译： 用于从甘油制备丙烯醛中使用的催化剂的方法，其包含钨化合物并具有酸性和至少一种助催化剂。
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公开(公告)号：US20100261250A1
公开(公告)日：2010-10-14
申请号：US12539804
申请日：2009-08-12
申请人： Steffen Osswald , Christoph Weckbecker , Klaus Huthmacher , Tatijana Gerasimova , Andrey Novikov , Ludmila Ryabchenko , Alexander Yanenko , Ksenia Egorova
发明人： Steffen Osswald , Christoph Weckbecker , Klaus Huthmacher , Tatijana Gerasimova , Andrey Novikov , Ludmila Ryabchenko , Alexander Yanenko , Ksenia Egorova
摘要： Disclosed herein are cyanide-tolerant nitrile hydratases especially from Pseudomonas putida or Pseudomonas marginalis strains which exhibit increased cyanide tolerance. Also disclosed are methods of preparing amides from nitriles in the presence of cyanides and polynucleotide sequences coding for cyanide-tolerant nitrile hydratases.
摘要翻译： 本文公开的是氰化物耐受性腈水合酶，特别是恶臭假单胞菌（Pseudomonas putida）或边缘假单胞菌（Pseudomonas marginalis）的菌株，其表现出增加的氰化物耐受性。 还公开了在氰化物和编码氰化物耐受性腈水合酶的多核苷酸序列存在下由腈制备酰胺的方法。
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公开(公告)号：US07790934B2
公开(公告)日：2010-09-07
申请号：US12687909
申请日：2010-01-15
IPC分类号： C07C45/66 , C07C323/52
CPC分类号： B01J23/30 , B01J23/6527 , B01J23/888 , B01J23/92 , B01J23/94 , B01J23/96 , B01J29/076 , B01J35/002 , B01J37/0009 , B01J37/0201 , B01J37/04 , C07C45/52 , C07C319/18 , Y02P20/584 , C07C47/22 , C07C323/22
摘要： A process for preparing acrolein from glycerol using an acidic solid-state catalyst which comprises tungsten compounds and further promoters.
摘要翻译： 使用包含钨化合物和进一步促进剂的酸性固体催化剂由甘油制备丙烯醛的方法。
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公开(公告)号：US07723261B2
公开(公告)日：2010-05-25
申请号：US12102505
申请日：2008-04-14
申请人： Jan-Olaf Barth , Hubert Redlingshöfer , Christoph Weckbecker , Klaus Huthmacher , Horst-Werner Zanthoff , Ralf Mayer
发明人： Jan-Olaf Barth , Hubert Redlingshöfer , Christoph Weckbecker , Klaus Huthmacher , Horst-Werner Zanthoff , Ralf Mayer
CPC分类号： B01J23/36 , B01J21/063 , B01J23/34 , B01J37/0201 , B01J37/0205 , B01J37/20 , C07C319/02 , C07C321/04
摘要： The present invention refers to a catalyst for the manufacture of methyl mercaptan from carbon oxides comprising Mo and K compounds and oxides or sulfides of metals chosen from the manganese group. The improvement of the present process consists of the fact that carbon dioxide can be converted with higher conversions and selectivities to methyl mercaptan as compared to state-of-the-art technologies, with only minor amounts of carbon monoxide being formed as side product. Simultaneously, carbon monoxide can be easily converted into carbon dioxide and hydrogen by reaction with water using established water-gas-shift-technologies thus increasing the overall selectivity to methyl mercaptan.
摘要翻译： 本发明涉及用于从包含Mo和K化合物的碳氧化物和选自锰基的金属的氧化物或硫化物制备甲硫醇的催化剂。 本方法的改进包括以下事实：与现有技术相比，二氧化碳可以以较高的转化率和选择性转化成甲硫醇，只有少量的一氧化碳作为副产物形成。 同时，一氧化碳可以通过使用已建立的水煤气变换技术与水反应而容易地转化成二氧化碳和氢，从而增加了对甲硫醇的总体选择性。
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公开(公告)号：US07592165B2
公开(公告)日：2009-09-22
申请号：US10598873
申请日：2005-03-14
申请人： Steffen Osswald , Christoph Weckbecker , Klaus Huthmacher , Tatijana Gerasimova , Andrey Novikov , Ludmila Ryabchenko , Alexander Yanenko , Ksenia Egorova
发明人： Steffen Osswald , Christoph Weckbecker , Klaus Huthmacher , Tatijana Gerasimova , Andrey Novikov , Ludmila Ryabchenko , Alexander Yanenko , Ksenia Egorova
摘要： Disclosed herein are cyanide-tolerant nitrile hydratases especially from Pseudomonas putida or Pseudomonas marginalis strains which exhibit increased cyanide tolerance. Also disclosed are methods of preparing amides from nitriles in the presence of cyanides and polynucleotide sequences coding for cyanide-tolerant nitrile hydratases.
摘要翻译： 本文公开的是氰化物耐受性腈水合酶，特别是恶臭假单胞菌（Pseudomonas putida）或边缘假单胞菌（Pseudomonas marginalis）的菌株，其表现出增加的氰化物耐受性。 还公开了在氰化物和编码耐受氰化腈水合酶的多核苷酸序列存在下由腈制备酰胺的方法。
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