公开(公告)号：US20090326290A1

公开(公告)日：2009-12-31

申请号：US12490647

申请日：2009-06-24

申请人： Christophe Bouchy ,  Antoine Daudin ,  Emmanuelle Guillon ,  Nathalie Dupassieux ,  Thierry Chapus

发明人： Christophe Bouchy ,  Antoine Daudin ,  Emmanuelle Guillon ,  Nathalie Dupassieux ,  Thierry Chapus

IPC分类号： C07C5/13

CPC分类号： C10G65/043 ,  C10G3/46 ,  C10G3/50 ,  C10G3/54 ,  C10G45/02 ,  C10G45/08 ,  C10G45/64 ,  C10G2300/1014 ,  C10G2300/1018 ,  C10G2300/202 ,  C10G2300/4006 ,  C10G2300/4012 ,  C10G2300/4018 ,  Y02P30/20

摘要： The invention relates to a method of treating feedstocks from renewable sources without intermediate gas-liquid separation in order to produce diesel fuel bases of excellent quality. The feedstocks used can be raw vegetable oils or such oils that have been previously subjected to a prerefining stage, animal fats, or mixtures of such feedstocks. The invention relates to a method allowing high diesel fuel base yields to be obtained from such feedstocks.

摘要翻译： 本发明涉及一种从可再生能源处理原料而不进行中间气液分离的方法，以生产质量优良的柴油燃料基料。 所使用的原料可以是先前经受预精制阶段，动物脂肪或这些原料的混合物的生植物油或这种油。 本发明涉及允许从这些原料获得高柴油燃料碱产率的方法。

公开(公告)号：US07544347B2

公开(公告)日：2009-06-09

申请号：US11337080

申请日：2006-01-23

申请人： Gaëlle Hastoy ,  Johan Martens ,  Emmanuelle Guillon

发明人： Gaëlle Hastoy ,  Johan Martens ,  Emmanuelle Guillon

IPC分类号： C01B39/04 ,  B01J29/70 ,  B01J29/06 ,  B01J29/04

CPC分类号： C01B39/48 ,  B01J29/70

摘要： The invention concerns a process for the synthesis of solid zeolitic ZBM-30, comprising: i) a mixing step, during which a mixture comprising at least one source of a tetravalent metal, at least one source of a trivalent metal, water and at least two amine compounds is prepared, resulting in the production of a gel; and ii) a crystallization step, during which said gel is maintained under conditions allowing the formation of a crystalline solid. The invention also concerns the zeolite ZBM-30 obtained by said process.

摘要翻译： 本发明涉及一种合成固体沸石ZBM-30的方法，包括：i）混合步骤，在此期间，将包含至少一种四价金属源，至少一种三价金属源，水和至少 制备两种胺化合物，产生凝胶; 和ii）结晶步骤，其中所述凝胶保持在允许形成结晶固体的条件下。 本发明还涉及通过所述方法获得的沸石ZBM-30。

公开(公告)号：US20060292070A1

公开(公告)日：2006-12-28

申请号：US11337080

申请日：2006-01-23

申请人： Gaelle Hastoy ,  Johan Martens ,  Emmanuelle Guillon

发明人： Gaelle Hastoy ,  Johan Martens ,  Emmanuelle Guillon

IPC分类号： C01B39/48 ,  C01B39/00 ,  C01B33/36

CPC分类号： C01B39/48 ,  B01J29/70

摘要： The invention concerns a process for the synthesis of solid zeolitic ZBM-30, comprising: i) a mixing step, during which a mixture comprising at least one source of a tetravalent metal, at least one source of a trivalent metal, water and at least two amine compounds is prepared, resulting in the production of a gel; and ii) a crystallization step, during which said gel is maintained under conditions allowing the formation of a crystalline solid. The invention also concerns the zeolite ZBM-30 obtained by said process.

摘要翻译： 本发明涉及一种合成固体沸石ZBM-30的方法，包括：i）混合步骤，在此期间，将包含至少一种四价金属源，至少一种三价金属源，水和至少 制备两种胺化合物，产生凝胶; 和ii）结晶步骤，其中所述凝胶保持在允许形成结晶固体的条件下。 本发明还涉及通过所述方法获得的沸石ZBM-30。

公开(公告)号：US20060100471A1

公开(公告)日：2006-05-11

申请号：US11269531

申请日：2005-11-09

申请人： Jose' Serra Alfaro ,  Avelino Corma ,  Emmanuelle Guillon

发明人： Jose' Serra Alfaro ,  Avelino Corma ,  Emmanuelle Guillon

IPC分类号： C07C15/12

CPC分类号： C07C6/126 ,  C07C2529/44 ,  C07C2529/80 ,  C07C15/08

摘要： A process for transalkylation of an alkyl-aromatic hydrocarbon feedstock that has at least 9 carbon atoms per molecule that comprises a) the introduction of said alkyl-aromatic hydrocarbon feedstock at the inlet of a first reaction zone where it is brought into contact with at least a first zeolitic catalyst, b) the introduction of at least a portion of the effluent that is obtained from stage a) and a feedstock that contains benzene and/or toluene at the inlet of a second reaction zone that contains at least a second zeolitic catalyst, and c) the separation of at least a portion of the effluent that is obtained from stage b) is described.

公开(公告)号：US20050177017A1

公开(公告)日：2005-08-11

申请号：US10981740

申请日：2004-11-05

申请人： Patrick Euzen ,  Emmanuelle Guillon

发明人： Patrick Euzen ,  Emmanuelle Guillon

IPC分类号： B01J21/12 ,  B01J23/42 ,  B01J35/00 ,  B01J35/10 ,  B01J37/00 ,  C07C2/66 ,  C07C5/00 ,  C07C2/68

CPC分类号： B01J21/12 ,  B01J23/42 ,  B01J35/002 ,  B01J35/1019 ,  B01J35/1038 ,  B01J35/1061 ,  B01J35/108 ,  B01J37/0009 ,  C07C2/66 ,  C07C15/107

摘要： The invention relates to a process for the production of at least one compound that is selected from among the 2-, 3-, 4-, 5-, and 6-phenylalkanes by alkylation of an aromatic compound by means of at least one olefin that comprises at least 9 carbon atoms per molecule, in the presence of a catalyst that comprises at least one non-zeolitic substrate with a silicated alumina base that contains an amount of more than 6% by weight and less than or equal to 50% by weight of silica (SiO2) and that exhibits particular characteristics, whereby said process is carried out at a temperature of between 30 and 400° C., a pressure of between 0.1 and 10 MPa, an hourly volumetric flow rate of 0.50 to 200 h−1, and an aromatic compound/olefin molar ratio of between 1:1 and 50:1.

摘要翻译： 本发明涉及一种通过至少一种烯烃将芳族化合物烷基化制备至少一种选自2-，3-，4-，5-和6-苯基烷烃的化合物的方法， 在每个分子中包含至少9个碳原子的催化剂存在下，所述催化剂包含至少一种非沸石基质，其中硅烷氧化铝基质含量超过6重量％且小于或等于50重量％ 的二氧化硅（SiO 2），并且其表现出特定的特性，由此所述方法在30至400℃的温度下进行，压力为0.1至10MPa，小时体积流速为0.50至200h -1 ，芳香族化合物/烯烃的摩尔比为1：1〜50：1。

公开(公告)号：US09475999B2

公开(公告)日：2016-10-25

申请号：US13102283

申请日：2011-05-06

申请人： Emmanuelle Guillon ,  Nicolas Cadran ,  Natacha Touchais ,  Laurent Bournay

发明人： Emmanuelle Guillon ,  Nicolas Cadran ,  Natacha Touchais ,  Laurent Bournay

IPC分类号： C07C1/24 ,  C10G3/00 ,  C10G50/00

CPC分类号： C10G50/00 ,  C10G3/49 ,  C10G3/62 ,  C10G2300/1014 ,  C10G2300/301 ,  C10G2300/4018 ,  C10G2300/4081 ,  C10G2400/04 ,  C10G2400/08 ,  C10G2400/20 ,  C10G2400/22 ,  C10G2400/28 ,  Y02E50/13 ,  Y02P30/20

摘要： The invention describes a process for the production of middle distillate hydrocarbon bases from an ethanol feedstock that is produced from a renewable source that is obtained from biomass, whereby said process comprises a stage for purification of said feedstock, a stage for transformation of said purified feedstock into a light olefinic effluent that comprises at least 30% by weight of olefins that have between four to six carbon atoms relative to the total mass of the formed hydrocarbon compounds, whereby said stage works in the presence of a catalyst that comprises at least one zeolite that is selected from among the zeolites that have a structural type that appears in the following list: CHA, ERI, MTF, AEI, AEL, FER, EUO, MEL, MFS, TON, MTT and the zeolites ZBM-30, ZSM-48, IM-5 and IZM-2, taken by themselves or in a mixture, a stage for separation of the olefinic effluent that is obtained from stage b) in such a way as to eliminate at least a portion of the water that is formed during stage b) to produce at least one hydrocarbon gaseous effluent that for the most part has three or fewer carbon atoms and at least one olefinic hydrocarbon liquid effluent that for the most part has more than four carbon atoms, and a stage for oligomerization of at least a portion of the hydrocarbon effluents that are obtained from stage c) in the presence of an amorphous or zeolitic catalyst that has at least pore openings that contain 10 or 12 oxygen atoms, producing middle distillate hydrocarbon bases.

摘要翻译： 本发明描述了从由生物质获得的可再生来源生产的乙醇原料生产中间馏分烃碱的方法，其中所述方法包括纯化所述原料的阶段，用于转化所述纯化原料的阶段 包含至少30重量％的具有4-6个碳原子的烯烃相对于形成的烃化合物的总质量的轻质烯烃流出物，其中所述阶段在包含至少一种沸石 选自具有下列结构类型的沸石：CHA，ERI，MTF，AEI，AEL，FER，EUO，MEL，MFS，TON，MTT和沸石ZBM-30，ZSM-48 ，IM-5和IZM-2，它们本身或在混合物中，分离从阶段b）获得的烯烃流出物的阶段，以消除形成的至少一部分水 环状阶段b）以产生至少一种大多数具有三个或更少碳原子的烃气态流出物和至少一种大多数具有四个以上碳原子的烯烃液体流出物， 至少一部分烃阶段c）在无定形或沸石催化剂存在下得到的烃流出物至少具有含有10或12个氧原子的孔隙，产生中间馏分烃基。

公开(公告)号：US08629073B2

公开(公告)日：2014-01-14

申请号：US13057812

申请日：2009-07-21

申请人： Emmanuelle Guillon ,  Nicolas Cadran ,  Sylvie Maury ,  Amandine Cabiac

发明人： Emmanuelle Guillon ,  Nicolas Cadran ,  Sylvie Maury ,  Amandine Cabiac

IPC分类号： B01J29/06 ,  C07C1/20 ,  C07C1/24 ,  C07C2/12 ,  C07C5/22 ,  C07C5/00

CPC分类号： B01J29/72 ,  B01J29/74 ,  B01J29/76 ,  B01J29/78 ,  B01J37/0009 ,  B01J2229/18 ,  B01J2229/42 ,  C01B39/48 ,  C07C1/24 ,  C07C2/12 ,  C07C5/2708 ,  C07C5/2775 ,  C07C6/126 ,  C07C11/02 ,  C07C2529/74 ,  C07C2529/76 ,  C07C2529/78 ,  C10G45/62 ,  C10G45/64 ,  C10G2300/1096 ,  C10G2300/70 ,  C10G2400/20 ,  C10G2400/22 ,  C10G2400/30 ,  Y02P20/52 ,  C07C15/08 ,  C07C9/16

摘要： A catalyst is described which comprises at least one IZM-2 zeolite, at least one matrix and at least one metal selected from metals from groups VIII, VIB and VIIB, said zeolite having a chemical composition expressed as the anhydrous base in terms of moles of oxides by the following general formula: XO2:aY2O3:bM2/nO, in which X represents at least one tetravalent element, Y represents at least one trivalent element and M is at least one alkali metal and/or alkaline-earth metal with valency n, a and b respectively representing the number of moles of Y2O3 and M2/nO; and a is in the range 0.001 to 0.5 and b is in the range 0 to 1.

摘要翻译： 描述了一种催化剂，其包含至少一种IZM-2沸石，至少一种基质和至少一种选自VIII，VIB和VIIB族金属的金属，所述沸石具有以无水碱的摩尔数表示的化学组成 氧化物由以下通式表示：XO2：aY2O3：bM2 / nO，其中X表示至少一种四价元素，Y表示至少一种三价元素，M为至少一种碱金属和/或碱土金属，价态为n ，a和b分别代表Y2O3和M2 / nO的摩尔数; a在0.001〜0.5的范围内，b在0〜1的范围内。

公开(公告)号：US20130281741A1

公开(公告)日：2013-10-24

申请号：US13995518

申请日：2011-12-16

申请人： Flora Chambon ,  Nadine Essayem ,  Franck Rataboul ,  Catherine Pinel ,  Amandine Cabiac ,  Emmanuelle Guillon

发明人： Flora Chambon ,  Nadine Essayem ,  Franck Rataboul ,  Catherine Pinel ,  Amandine Cabiac ,  Emmanuelle Guillon

IPC分类号： C07C45/60

CPC分类号： C07C45/60 ,  C07C29/132 ,  C07C31/20 ,  C07C49/17

摘要： The invention relates to a process for transformation of lignocellulosic biomass or cellulose using heterogeneous catalysts that are based on tin oxide and/or antimony oxide, dispersed on a substrate and containing at least one element in the particular metal state. The use of these catalysts makes it possible to obtain directly upgradable products, in particular hydroxyacetone and propylene glycol with high selectivity.

摘要翻译： 本发明涉及一种使用基于氧化锡和/或氧化锑的非均相催化剂转化木质纤维素生物质或纤维素的方法，其分散在基材上并含有至少一种特定金属状态的元素。 使用这些催化剂使得可以以高选择性获得直接可升级的产物，特别是羟基丙酮和丙二醇。

公开(公告)号：US20130184496A1

公开(公告)日：2013-07-18

申请号：US13812921

申请日：2011-07-19

申请人： Flora Chambon ,  Nadine Essayem ,  Franck Rataboul ,  Catherine Pinel ,  Amandine Cabiac ,  Emmanuelle Guillon

发明人： Flora Chambon ,  Nadine Essayem ,  Franck Rataboul ,  Catherine Pinel ,  Amandine Cabiac ,  Emmanuelle Guillon

IPC分类号： C07C45/51

CPC分类号： C07C45/51 ,  B01J23/6527 ,  B01J37/0201 ,  B01J37/0209 ,  B01J37/086 ,  B01J37/30 ,  C07C29/00 ,  C07C45/60 ,  C07C31/205 ,  C07C47/19

摘要： The invention relates to a process for transformation of lignoceliulosic biomass or cellulose that uses tungsten-oxide-based heterogeneous catalysts that are dispersed on an oxide-based substrate, preferably with a base of oxide(s) of aluminum and/or zirconium and/or titanium and/or niobium and containing an element in the particular metallic state. The use of these catalysts makes it possible to obtain directly upgradable products containing three carbon atoms, in particular hydroxyacetone and propylene glycol with high selectivity.

摘要翻译： 本发明涉及一种转化木质素生物质或纤维素的方法，其使用分散在基于氧化物的基质上，优选以铝和/或锆的氧化物和/或碱的氧化物为基础的非均相催化剂和/或 钛和/或铌，并含有特定金属状态的元素。 使用这些催化剂使得可以以高选择性获得含有三个碳原子的直接可升级产物，特别是羟基丙酮和丙二醇。

公开(公告)号：US20120205286A1

公开(公告)日：2012-08-16

申请号：US13345041

申请日：2012-01-06

申请人： Jeremy FRANCIS ,  Laurent Simon ,  Emmanuelle Guillon ,  Nicolas Bats ,  Avelino Corma ,  Christophe Pichon

发明人： Jeremy FRANCIS ,  Laurent Simon ,  Emmanuelle Guillon ,  Nicolas Bats ,  Avelino Corma ,  Christophe Pichon

IPC分类号： C10G65/12 ,  B01J29/04 ,  C10G47/06

CPC分类号： B01J29/146 ,  B01J29/166 ,  B01J35/002 ,  B01J35/0066 ,  B01J35/109 ,  B01J37/0009 ,  B01J37/0205 ,  B01J37/20 ,  B01J2229/14 ,  B01J2229/16 ,  B01J2229/186 ,  B01J2229/20 ,  B01J2229/36 ,  B01J2229/37 ,  B01J2229/38 ,  B01J2229/42 ,  C10G49/08 ,  C10G2300/301 ,  C10G2300/4018

摘要： Process for hydrocracking and/or hydrotreatment of hydrocarbon feeds utilizing a catalyst comprising at least one hydro-dehydrogenating element of group VIB and of non-precious group VIII used alone or mixed, and a support comprising at least one porous mineral matrix and at least one dealuminated USY zeolite having an overall silicon-to-aluminium atomic ratio comprised between 2.5 and 10, a fraction by weight of extra-network aluminium atom greater than 10% relative to the total mass of the aluminium present in the zeolite, a mesopore volume measured by nitrogen porosimetry greater than 0.07 ml.g−1, and a crystal parameter a0 of the elemental mesh greater than 24.28 Å, in which a quantity of the element nickel comprised between 0.5 and 3% by weight relative to the total mass of the zeolite is deposited on said USY zeolite and in which said catalyst is in the sulphide form.

摘要翻译： 使用包含至少一种单独或混合使用的VIB族和非贵重族VIII的加氢脱氢元素的催化剂，以及包含至少一种多孔矿物基质和至少一种多孔矿物基质的载体来加氢裂化和/或加氢处理烃进料的方法 具有2.5至10的整体硅 - 铝原子比的脱铝USY沸石，相对于存在于沸石中的铝的总质量大于10％的网络外铝原子的重量百分比，测量的中孔体积 通过氮气孔隙度法大于0.07ml.g-1，并且元素网的晶体参数a0大于24.28，其中元素镍的量相对于沸石的总质量为0.5-3重量％ 沉积在所述USY沸石上，其中所述催化剂为硫化物形式。