Photo radical generator, photo sensitive resin composition and article
    31.
    发明授权
    Photo radical generator, photo sensitive resin composition and article 失效
    光自由基发生器,感光树脂组合物及制品

    公开(公告)号:US07141354B2

    公开(公告)日:2006-11-28

    申请号:US10946782

    申请日:2004-09-22

    申请人: Katsuya Sakayori

    发明人: Katsuya Sakayori

    CPC分类号: C07C225/22

    摘要: The invention provides a radical generator, although being a self-cleavage type initiator, which is capable of suppressing volatilization of low molecular weight decomposition materials at the time of light radiation and post-baking, and leaving no low molecular weight decomposition materials in the final product, a photosensitive resin composition and an article using the radical generator. The photoradical generator provided according to the invention contains a compound (a) having one or more self-cleavage type radical-generating parts and one or more ethylenic unsaturated groups in one molecule.

    摘要翻译: 本发明提供了一种自由基发生剂,虽然它是一种自裂解型引发剂,它能够在光辐射和后烘烤时抑制低分子量分解物质的挥发,并且在最终的条件下不留下低分子量的分解物质 产品,光敏树脂组合物和使用自由基发生剂的制品。 根据本发明提供的光电发生器包含在一个分子中具有一个或多个自裂解型自由基产生部分和一个或多个烯属不饱和基团的化合物(a)。

    Laminate for electronic circuit
    32.
    发明申请
    Laminate for electronic circuit 有权
    电子电路层压板

    公开(公告)号:US20050031879A1

    公开(公告)日:2005-02-10

    申请号:US10762334

    申请日:2004-01-23

    申请人: Katsuya Sakayori

    发明人: Katsuya Sakayori

    摘要: The present invention is directed to a laminate having a layer construction of metal-insulating layer-metal or a layer construction of metal-insulating layer, which laminate meets conditions for developing large adhesive strength between the insulating layer and the metal, as well as to an insulating film and an electronic circuit using the laminate. The laminate has a layer construction of first metal layer/insulating layer/second metal layer or a layer construction of metal layer/insulating layer. The insulating layer 1 has a multilayer structure of two or more layers. The layers on the side of the adhesive interface with each metal layer (a copper foil 3 and an SUS foil 4), out of the layers constituting the insulating layer 1, each are a thermoplastic resin layer 2. The minimum value of the storage modulus at a temperature at or above Tg of the thermoplastic resin layer 2 is not more than 106 Pa.

    摘要翻译: 本发明涉及具有金属绝缘层金属的层结构或金属绝缘层的层结构的层压体,其层压体满足在绝缘层和金属之间形成大的粘合强度的条件,以及 绝缘膜和使用该层压体的电子电路。 层压体具有第一金属层/绝缘层/第二金属层的层结构或金属层/绝缘层的层结构。 绝缘层1具有两层以上的多层结构。 与构成绝缘层1的层中的每个金属层(铜箔3和SUS箔4)的粘合剂界面侧的层各自为热塑性树脂层2.储能模量的最小值 在热塑性树脂层2的Tg以上的温度下,为10Pa以下。

    Photoradical polymerization initiator, radical generator, photosensitive compound and photosensitive resin composition containing these materials and product or its accessory portions using the composition
    35.
    发明授权
    Photoradical polymerization initiator, radical generator, photosensitive compound and photosensitive resin composition containing these materials and product or its accessory portions using the composition 失效
    光自由基聚合引发剂,自由基发生剂,感光性化合物和含有这些材料的感光性树脂组合物和使用该组合物的产品或其附件部分

    公开(公告)号:US08211613B2

    公开(公告)日:2012-07-03

    申请号:US12166449

    申请日:2008-07-02

    申请人: Katsuya Sakayori

    发明人: Katsuya Sakayori

    摘要: The present invention provides a radical generator having a naphthalimide structure or a crosslinking agent and a photosensitive compound having a function as a radical generator. A photoradical polymerization initiator of the present invention comprises a compound (a) having only one naphthalimide structure-containing group in one molecule. The radial generator of the present invention comprises a compound (c) having two or more naphthalimide structure-containing groups in one molecule and also functions as a crosslinking agent. A first photosensitive compound of the present invention comprises a compound (d) having a naphthalimide structure-containing group and an ethylenic unsaturated group in one molecule. A second photosensitive compound of the present invention comprises a polymer (e) of one or more radical polymerizable compounds containing the compound (d). A photosensitive resin composition according to the present invention contains, as an essential component, the above compound (a), compound (c), compound (d) or polymer (e).

    摘要翻译: 本发明提供具有萘酰亚胺结构或交联剂的自由基发生剂和具有作为自由基发生剂的功能的光敏化合物。 本发明的光自由基聚合引发剂包括在一个分子中仅具有一个含萘酰亚胺结构的基团的化合物(a)。 本发明的径向发生器包括在一个分子中具有两个或更多个含萘酰亚胺结构的基团的化合物(c),并且还用作交联剂。 本发明的第一感光性化合物在一个分子中含有具有含萘酰亚胺结构的基团和烯属不饱和基团的化合物(d)。 本发明的第二光敏性化合物包含含有化合物(d)的一种或多种可自由基聚合的化合物的聚合物(e)。 本发明的感光性树脂组合物含有上述化合物(a),化合物(c),化合物(d)或聚合物(e)作为必要成分。

    Photo radical generator, photo sensitive resin composition and article
    36.
    发明授权
    Photo radical generator, photo sensitive resin composition and article 有权
    光自由基发生器,感光树脂组合物及制品

    公开(公告)号:US07528205B2

    公开(公告)日:2009-05-05

    申请号:US10945697

    申请日:2004-09-21

    申请人: Katsuya Sakayori

    发明人: Katsuya Sakayori

    IPC分类号: C08F2/48 C08F2/46

    摘要: A photoradical generator which produces no low-molecular decomposition material but a radical during a photoradical generating process, does not generate a radical during a heating process, exists in a chemically stable state in a resulting product of a radical reaction such as a cured coating layer or the like, has high heat resistance, stability and preserving ability, and is excellent in compatibility or solubility is provided. The photoradical generator is comprised of a compound (a) having a seven-membered ring imide structure-containing group represented by the following formula (1), wherein, R1 to R8 respectively represent a hydrogen atom or a substituent and may be a cyclic structure in which they are bonded to each other.

    摘要翻译: 在光自由基产生过程中不产生低分子分解物质而不产生自由基的光自发生成器在加热过程中不产生自由基,在所得到的自由基反应产物如固化涂层中以化学稳定的状态存在 具有高的耐热性,稳定性和保存能力,并且具有优异的相容性或溶解性。 光自由基发生器由具有由下式(1)表示的含有7元环酰亚胺结构的基团的化合物(a)组成,其中,R 1〜R 8分别表示氢原子或取代基,可以是环状结构 其中它们彼此结合。

    Photoradical polymerization initiator, radical generator, photosensitive compound and photosensitive resin composition containing these materials and product or its accessory portions using the composition
    37.
    发明授权
    Photoradical polymerization initiator, radical generator, photosensitive compound and photosensitive resin composition containing these materials and product or its accessory portions using the composition 有权
    光自由基聚合引发剂,自由基发生剂,感光性化合物和含有这些材料的感光性树脂组合物和使用该组合物的产品或其附件部分

    公开(公告)号:US07410746B2

    公开(公告)日:2008-08-12

    申请号:US10396206

    申请日:2003-03-25

    申请人: Katsuya Sakayori

    发明人: Katsuya Sakayori

    IPC分类号: G03F7/004 G03F7/30 C07D221/14

    摘要: The present invention provides a radical generator having a naphthalimide structure or a crosslinking agent and a photosensitive compound having a function as a radical generator. A photoradical polymerization initiator of the present invention comprises a compound (a) having only one naphthalimide structure-containing group in one molecule. The radial generator of the present invention comprises a compound (c) having two or more naphthalimide structure-containing groups in one molecule and also functions as a crosslinking agent. A first photosensitive compound of the present invention comprises a compound (d) having a naphthalimide structure-containing group and an ethylenic unsaturated group in one molecule. A second photosensitive compound of the present invention comprises a polymer (e) of one or more radical polymerizable compounds containing the compound (d). A photosensitive resin composition according to the present invention contains, as an essential component, the above compound (a), compound (c), compound (d) or polymer (e).

    摘要翻译: 本发明提供具有萘酰亚胺结构或交联剂的自由基发生剂和具有作为自由基发生剂的功能的光敏化合物。 本发明的光自由基聚合引发剂包括在一个分子中仅具有一个含萘酰亚胺结构的基团的化合物(a)。 本发明的径向发生器包括在一个分子中具有两个或更多个含萘酰亚胺结构的基团的化合物(c),并且还用作交联剂。 本发明的第一感光性化合物在一个分子中含有具有含萘酰亚胺结构的基团和烯属不饱和基团的化合物(d)。 本发明的第二光敏性化合物包含含有化合物(d)的一种或多种可自由基聚合的化合物的聚合物(e)。 本发明的感光性树脂组合物含有上述化合物(a),化合物(c),化合物(d)或聚合物(e)作为必要成分。

    Polymer compound, highly transparent polyimide, resin composition and article
    38.
    发明申请
    Polymer compound, highly transparent polyimide, resin composition and article 审中-公开
    高分子化合物,高透明聚酰亚胺,树脂组合物和制品

    公开(公告)号:US20050256295A1

    公开(公告)日:2005-11-17

    申请号:US11093783

    申请日:2005-03-30

    申请人: Katsuya Sakayori

    发明人: Katsuya Sakayori

    IPC分类号: C08G69/08

    CPC分类号: C08G73/10 C08L79/08

    摘要: A polymer compound, wherein a transparency of a polymer compound which is easily colored due to the formation of a conjugated state is improved by a new method different from conventional ones, is provided. More preferably, polyimide having high transparency and original properties such as heat resistance or the like at the same time is provided. A polymer compound comprising a part which sequences an unsaturated bond containing a n electron orbit and a single bond alternately, wherein at least a part of a conjugated state formed by the n electron orbit in a molecule is shortened or weakened due to a three-dimensional structure of the molecule, thereby a transmittance is improved, is provided. Further, as one embodiment thereof, highly transparent polyimide having a repeating unit represented by the following formula (1) is provided: wherein, each of R1 to R6 is independently a hydrogen atom or a monovalent organic group, and which may be bonded each other; R7 is a divalent organic group.

    摘要翻译: 提供了通过与常规方法不同的新方法,提高了由于形成共轭状态而容易着色的高分子化合物的透明性的高分子化合物。 更优选提供同时具有高透明性和原始性能如耐热性等的聚酰亚胺。 一种高分子化合物,其包含交替含有电子轨道和单键的不饱和键的部分,其中由分子中的n电子轨道形成的共轭态的至少一部分由于三维结构而缩短或变弱 ,从而提高透射率。 此外,作为其一个实施方案,提供了具有由下式(1)表示的重复单元的高度透明的聚酰亚胺:其中R 1至R 6中的每一个独立地为 氢原子或一价有机基团,并且可以彼此键合; R 7是二价有机基团。

    Photo radical generator, photo sensitive resin composition and article
    39.
    发明申请
    Photo radical generator, photo sensitive resin composition and article 有权
    光自由基发生器,感光树脂组合物及制品

    公开(公告)号:US20050119432A1

    公开(公告)日:2005-06-02

    申请号:US10945697

    申请日:2004-09-21

    申请人: Katsuya Sakayori

    发明人: Katsuya Sakayori

    摘要: A photoradical generator which produces no low-molecular decomposition material but a radical during a photoradical generating process, does not generate a radical during a heating process, exists in a chemically stable state in a resulting product of a radical reaction such as a cured coating layer or the like, has high heat resistance, stability and preserving ability, and is excellent in compatibility or solubility is provided. The photoradical generator is comprised of a compound (a) having a seven-membered ring imide structure-containing group represented by the following formula (1), wherein, R1 to R8 respectively represent a hydrogen atom or a substituent and may be a cyclic structure in which they are bonded to each other.

    摘要翻译: 在光自由基产生过程中不产生低分子分解物质而不产生自由基的光自发生成器在加热过程中不产生自由基,在所得到的自由基反应产物如固化涂层中以化学稳定的状态存在 具有高的耐热性,稳定性和保存能力,并且具有优异的相容性或溶解性。 光自由基发生器由具有由下式(1)表示的含有七元环酰亚胺结构的基团的化合物(a)组成,其中R 1至R 8, SUP>分别表示氢原子或取代基,可以是它们彼此结合的环状结构。