摘要:
NOVEL THERMOSETTING RESIN POWDERS WHICH CAN BE MOLDED TO FORM UNIQUE, URETHANE-CROSSLINKED, ELASTOMERCOMPRISING PRODUCTS ARE PREPARED BY REACTING HYDROXYFUNCTIONAL, GRADED, ACYRLIC, RUBBER-LIKE PARTICLES WITH A MONOBLOCKED DIISOCYANATE. THESE POWDERS ARE MOLDED BY CONVENTIONAL MOLDING TEHCNIQUES TO FORM UNIQUE THERMOSET PRODUCTS.
摘要:
The invention relates to a powdery composition for use in the layer by layer manufacturing of three-dimensional molded bodies. The composition comprises at least one powder made of an aliphatic thermoplastic polyurethane (TPU) and is characterized in that the TPU powder has a melting temperature of less than 135° C. and a melting viscosity at 150° C. of at most 800 Pa·s.
摘要:
Methods for making compositions for making thermoplastic aliphatic urethane/urea elastomers, which are in turn used to make molding compositions used in forming molded articles, particularly, shells for automotive applications. The molding compositions comprise an aliphatic thermoplastic urethane/urea elastomer and a polyolefin-based modifier. These compositions may be used to form a powder, pellets, microspheres or minibeads which may then be cast to form air bag door and instrument panel cover skins which may meet automotive deployment and weathering requirements.
摘要:
Provided is a vinyl chloride resin composition that can provide a molded product having superior flexibility at low temperatures. The vinyl chloride resin composition includes (a) a vinyl chloride resin and (b) a dodecanedioic acid diester. Moreover, (a) the vinyl chloride resin includes (x) a base vinyl chloride resin in an amount of from 70 mass % to 100 mass % and (y) vinyl chloride resin fine particles in an amount of from 0 mass % to 30 mass %.
摘要:
Provided is a polyurethane resin powder composition for slush molding from which an outer skin for an instrument panel can be produced, the outer skin not interfering with deployment of an airbag. More specifically, provided is a polyurethane resin powder composition (D) for slush molding comprising perfectly spherical thermoplastic polyurethane resin particles (A) obtained by reacting a polyester diol component (J) and a diisocyanate component (F), a plasticizer (B), and a vinyl-type copolymer fine particles (C) having a crosslinked structure, wherein the polyester diol component (J) comprises a polyester diol (J1) comprising an aromatic dicarboxylic acid (E) and ethylene glycol as essential constituent units, a ratio of volume average particle sizes of (A) and (C), (A):(C), is 200:1 to 2000:1, and an extent of surface coverage of a surface of (A) with (C) {Equation (1)} is 20 to 80%. [Expression 1] Extent of surface coverage (%)=[number of particles of (C)]×[average cross section area of one particle of (C)]/surface area of (A)×100 (1)
摘要:
Provided is a slush molding material which exhibits excellent low-temperature meltability and heat resistance and which can yield a molded product having excellent tensile strength and elongation. The present invention is urethane resin particles (D1) comprising a urethane or urethane-urea resin (U1) that has residues (j) bonded thereto covalently, said residues (j) being residues derived from an at least trivalent aromatic polycarboxylic acid by removing hydroxyl groups, or urethane resin particles (D2) comprising a urethane resin composition (S2) which comprises both a urethane or urethane-urea resin (U2) and a compound (E) that has a residue (j) derived from an at least trivalent aromatic polycarboxylic acid by removing hydroxyl groups, said compound (E) being represented by general formula (1), wherein the residues (j) are linked respectively to urethane or urea groups (u) of the resin (U1) or (U2) by hydrogen bonds.
摘要:
The present invention provides a resin powder composition for slush molding which can give slush molded articles with more excellent hydrolysis resistance. The present invention relates to a resin powder composition for slush molding which is characterized by comprising as the main component a thermoplastic polyurethane resin powder, preferably a thermoplastic polyurethane elastomer powder, and containing a polycarbodiimide prepared by polymerizing tetramethylxylylene diisocyanate, alkoxy terminated one having a number average molecular weight of 500 to 30,000.
摘要:
In a rod sealing system, which comprises a buffer ring, a rod seal, and a dust seal, provided successively in this order from a fluid hydraulic side toward the outside in an annular clearance between two members in reciprocating motion, the buffer ring is made up of a thermoplastic polyurethane molding product obtained by subjecting a thermoplastic polyurethane molding product prepared by reaction of (A) a high molecular weight polycarbonatediol having a number average molecular weight Mn of 500-6,000, (B) an aromatic diisocyanate, and (C) a low molecular weight diol as a chain elongation agent in an NCO/OH ratio of 0.95-1.20, to heat treatment under conditions that a glass transition point (Tg) of hard phases becomes 170° C. or higher, preferably 170-230° C., and an endothermic peak area (ΔH) at Tg becomes 5 J/g or more, by differential scanning calorimetry. The buffer ring made up of the thermoplastic polyurethane molding product has a distinguished heat resistance capable of withstanding the service environmental temperature, particularly maximum 120° C., compression set characteristics, follow-up to eccentricity, etc.