POLYURETHANE RESIN POWDER COMPOSITION FOR SLUSH MOLDING
    37.
    发明申请
    POLYURETHANE RESIN POWDER COMPOSITION FOR SLUSH MOLDING 审中-公开
    聚氨酯树脂粉末组合物

    公开(公告)号:US20130261240A1

    公开(公告)日:2013-10-03

    申请号:US13793179

    申请日:2013-03-11

    IPC分类号: C08L33/12 C08L75/04

    摘要: Provided is a polyurethane resin powder composition for slush molding from which an outer skin for an instrument panel can be produced, the outer skin not interfering with deployment of an airbag. More specifically, provided is a polyurethane resin powder composition (D) for slush molding comprising perfectly spherical thermoplastic polyurethane resin particles (A) obtained by reacting a polyester diol component (J) and a diisocyanate component (F), a plasticizer (B), and a vinyl-type copolymer fine particles (C) having a crosslinked structure, wherein the polyester diol component (J) comprises a polyester diol (J1) comprising an aromatic dicarboxylic acid (E) and ethylene glycol as essential constituent units, a ratio of volume average particle sizes of (A) and (C), (A):(C), is 200:1 to 2000:1, and an extent of surface coverage of a surface of (A) with (C) {Equation (1)} is 20 to 80%. [Expression 1] Extent of surface coverage (%)=[number of particles of (C)]×[average cross section area of one particle of (C)]/surface area of (A)×100   (1)

    摘要翻译: 本发明提供一种用于搪塑的聚氨酯树脂粉末组合物,由此可以制造用于仪表板的外皮,外皮不会妨碍气囊的展开。 更具体地说,提供了一种用于搪塑的聚氨酯树脂粉末组合物(D),包括通过使聚酯二醇组分(J)和二异氰酸酯组分(F)反应获得的完全球形的热塑性聚氨酯树脂颗粒(A),增塑剂(B), 和具有交联结构的乙烯基型共聚物微粒(C),其中所述聚酯二醇组分(J)包含包含芳族二羧酸(E)和乙二醇作为必要组分单元的聚酯二醇(J1),其比例为 (A)和(C),(A):( C)的体积平均粒径为200:1〜2000:1,(A)表面的覆盖程度为(C){式 1)}为20〜80%。 [表达式1]表面覆盖度(%)= [(C)的颗粒数]×((C)的一个粒子的平均截面积)/(A)×100(1)

    URETHANE RESIN PARTICLES
    38.
    发明申请
    URETHANE RESIN PARTICLES 有权
    URETHANE树脂颗粒

    公开(公告)号:US20130237664A1

    公开(公告)日:2013-09-12

    申请号:US13884771

    申请日:2011-11-09

    IPC分类号: C08G18/83 C08K5/04 C08L75/12

    摘要: Provided is a slush molding material which exhibits excellent low-temperature meltability and heat resistance and which can yield a molded product having excellent tensile strength and elongation. The present invention is urethane resin particles (D1) comprising a urethane or urethane-urea resin (U1) that has residues (j) bonded thereto covalently, said residues (j) being residues derived from an at least trivalent aromatic polycarboxylic acid by removing hydroxyl groups, or urethane resin particles (D2) comprising a urethane resin composition (S2) which comprises both a urethane or urethane-urea resin (U2) and a compound (E) that has a residue (j) derived from an at least trivalent aromatic polycarboxylic acid by removing hydroxyl groups, said compound (E) being represented by general formula (1), wherein the residues (j) are linked respectively to urethane or urea groups (u) of the resin (U1) or (U2) by hydrogen bonds.

    摘要翻译: 提供一种具有优异的低温熔融性和耐热性的搪塑成型材料,并且可以得到具有优异的拉伸强度和伸长率的成型体。 本发明是包含具有共价键合的残基(j)的氨基甲酸酯或氨基甲酸酯 - 尿素树脂(U1)的聚氨酯树脂颗粒(D1),所述残基(j)是通过除去羟基从至少三价芳族多元羧酸衍生的残基 基团或聚氨酯树脂颗粒(D2),其包含氨基甲酸酯或氨基甲酸酯 - 脲树脂(U2)和具有衍生自至少三价芳族化合物的残基(j)的化合物(E)的聚氨酯树脂组合物(S2) 通过除去羟基的多元羧酸,所述化合物(E)由通式(1)表示,其中残基(j)分别通过氢气与树脂(U1)或(U2)的氨基甲酸酯基或脲基(u)连接 债券。

    Rod sealing system
    40.
    发明授权
    Rod sealing system 有权
    杆密封系统

    公开(公告)号:US08056903B2

    公开(公告)日:2011-11-15

    申请号:US12086211

    申请日:2006-12-05

    IPC分类号: F16J15/16

    摘要: In a rod sealing system, which comprises a buffer ring, a rod seal, and a dust seal, provided successively in this order from a fluid hydraulic side toward the outside in an annular clearance between two members in reciprocating motion, the buffer ring is made up of a thermoplastic polyurethane molding product obtained by subjecting a thermoplastic polyurethane molding product prepared by reaction of (A) a high molecular weight polycarbonatediol having a number average molecular weight Mn of 500-6,000, (B) an aromatic diisocyanate, and (C) a low molecular weight diol as a chain elongation agent in an NCO/OH ratio of 0.95-1.20, to heat treatment under conditions that a glass transition point (Tg) of hard phases becomes 170° C. or higher, preferably 170-230° C., and an endothermic peak area (ΔH) at Tg becomes 5 J/g or more, by differential scanning calorimetry. The buffer ring made up of the thermoplastic polyurethane molding product has a distinguished heat resistance capable of withstanding the service environmental temperature, particularly maximum 120° C., compression set characteristics, follow-up to eccentricity, etc.

    摘要翻译: 在包括缓冲环,杆密封和防尘密封的杆密封系统中,以往复运动中的两个构件之间的环形间隙从液压侧朝向外部依次提供缓冲环,制成缓冲环 (A)数均分子量Mn为500〜6000的高分子量聚碳酸酯二醇,(B)芳香族二异氰酸酯和(C)的反应制得的热塑性聚氨酯成型体, 作为NCO / OH比为0.95-1.20的链延长剂的低分子量二醇,在硬相的玻璃化转变温度(Tg)为170℃以上,优选为170〜230℃的条件下进行热处理 通过差示扫描量热法测定Tg的吸热峰面积(&Dgr; H)为5J / g以上。 由热塑性聚氨酯成型制品制成的缓冲环具有耐受使用环境温度,特别是最大120℃,压缩永久变形特性,偏心率等特性的耐热性。