Mordenite Zeolite Having Excellent Particle Uniformity and Method for Preparing Same

    公开(公告)号:US20210179437A1

    公开(公告)日:2021-06-17

    申请号:US17263189

    申请日:2019-07-29

    摘要: The present invention pertains to a mordenite zeolite having excellent particle uniformity, and a method for preparing same, the method including a step for providing an aqueous solution in which a silica precursor is dissolved; a step for providing an aqueous solution in which a structure-inducing substance and an alumina precursor are dissolved; a step for providing an aqueous solution in which a surfactant is dissolved; a step for preparing a silica-alumina aqueous solution by mixing and stirring the basic silica suspension and the alumina aqueous solution; a step for preparing a zeolite synthesis composition by adding the surfactant aqueous solution to the silica-alumina aqueous solution; a step for gelling the zeolite synthesis composition; and a step for crystallizing the gelled zeolite synthesis composition.

    INORGANIC POROUS FRAMEWORKLAYERED DOUBLE HYDROXIDE CORESHELL MATERIALS

    公开(公告)号:US20190092644A1

    公开(公告)日:2019-03-28

    申请号:US15745375

    申请日:2016-07-15

    摘要: Core @ layered double hydroxide shell materials of the invention have the formula: Tp@{[Mz+(1−x)M′xy+(OH)2]a+(Xn−)a/n·bH2O·c(AMO-solvent)}q wherein T is a solid, porous, inorganic oxide-containing framework material, Mz+ is a metal cation of charge z or a mixture of two or more metal cations each independently having the charge z; M′y+ is a metal cation of charge y or a mixture of two or more metal cations each independently having the charge y; z=1 or 2; y=3 or 4; 0 0; q>0; Xn− is an anion; with n>0; a=z(1−x)+xy−2; and AMO-solvent is an organic solvent which is completely miscible with water.Also disclosed are the products obtained by calcining the core @ layered double hydroxide shell materials which calcination products are core @ mixed metal oxide materials having the formula Tp@[{Mz+1−xM′y+xOw]pŸ] wherein T is a solid, porous, inorganic oxide-containing framework material, Mz+1−xM′y+xOw is a mixed metal oxide, or mixture of mixed metal oxides, which may be crystalline or non-crystalline, wherein Mz+ and M′y+ are different charged metal cations; Mz+ is a metal cation of charge z or a mixture of two or more metal cations each independently having the charge z; M′y+ is a metal cation of charge y or a mixture of two or more metal cations each independently having the charge y; z is 1 or 2; y is 3 or 4; 0 0; p>0 and q>0; Ÿ is the residue of an Xn− anion in which n>0.

    Method for preparation of mordenite

    公开(公告)号:US09845249B2

    公开(公告)日:2017-12-19

    申请号:US14902423

    申请日:2013-12-02

    IPC分类号: C01B39/26

    CPC分类号: C01B39/265 C01B39/26

    摘要: The present invention provides a method for preparing a mordenite, which is a method for preparing the mordenite through a hydrothermal crystallization by using natural aluminosilicate minerals as total silicon sources and total aluminum sources, comprising the steps of: subjecting the natural aluminosilicate minerals to activation treatment which is an activation by sub-molten salt and an activation by thermal treatment; selecting and mixing the activated natural aluminosilicate minerals according to the silicon-to-aluminum ratio of the targeted mordenite, adding thereto deionized water, sodium hydroxide, crystal seed, a templating agent to obtain a reaction mixture; adjusting the reaction mixture by using an inorganic acid to have a pH of 10-13, and then aging it at 40-80° C. for 6-24 hours; and subjecting the aged reaction mixture to hydrothermal crystallization, and then filtering, washing, drying and calcinating the crystallized product to obtain the mordenite. The method for preparing a mordenite provided in the present invention enlarges the sources of raw materials for a molecular sieve, has a low cost and a simple process route, and can largely reduce the cost for synthesizing a molecular sieve.