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公开(公告)号:US20210179437A1
公开(公告)日:2021-06-17
申请号:US17263189
申请日:2019-07-29
发明人: Young-Eun Cheon , Yeon-Ho Kim , Chang-Q Lee
摘要: The present invention pertains to a mordenite zeolite having excellent particle uniformity, and a method for preparing same, the method including a step for providing an aqueous solution in which a silica precursor is dissolved; a step for providing an aqueous solution in which a structure-inducing substance and an alumina precursor are dissolved; a step for providing an aqueous solution in which a surfactant is dissolved; a step for preparing a silica-alumina aqueous solution by mixing and stirring the basic silica suspension and the alumina aqueous solution; a step for preparing a zeolite synthesis composition by adding the surfactant aqueous solution to the silica-alumina aqueous solution; a step for gelling the zeolite synthesis composition; and a step for crystallizing the gelled zeolite synthesis composition.
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公开(公告)号:US20200239323A1
公开(公告)日:2020-07-30
申请号:US16852169
申请日:2020-04-17
发明人: Kunhao Li , Javier Garcia-Martinez
IPC分类号: C01B39/06 , C01B39/20 , C01B39/26 , C01B39/40 , C01B39/32 , C01B39/02 , C01B39/38 , C01B39/48 , C01B39/46
摘要: Compositions and methods for preparing mesoporous and/or mesostructured materials from low SAR zeolites are provided herewith. In particular, methods are provided that involve: (a) providing a low SAR zeolite, (b) optionally subjecting the low SAR zeolite to an acid framework modification, and (c) subjecting the framework-modified zeolite to a mesopore formation treatment. The resulting mesoporous zeolites can have bi-modal mesoporosity and higher aluminum contents relative to existing mesoporous zeolites.
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公开(公告)号:US10669157B2
公开(公告)日:2020-06-02
申请号:US15492318
申请日:2017-04-20
IPC分类号: C01B39/02 , C01B39/36 , C01B39/42 , C01B39/46 , B01J29/70 , C01B39/26 , C01B39/38 , C30B5/00 , C30B29/34
摘要: Disclosed is a method for readily and inexpensively producing zeolite without using an organic structure-directing agent (organic SDA). Specifically disclosed is a method whereby a gel containing a silica source, an alumina source, an alkaline source and water is reacted with zeolite seed crystals, to produce a zeolite with the same kind of skeletal structure as the zeolite. The gel used is a gel of a composition whereby, when a zeolite is synthesized from this gel only, the synthesized zeolite comprises at least one of the kinds of composite building units of the target zeolite.
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34.
公开(公告)号:US20190284057A1
公开(公告)日:2019-09-19
申请号:US16299704
申请日:2019-03-12
发明人: Raed Hasan Abudawoud , Avelino Corma Canos , M. Teresa Portilla Ovejero , Vicente J. Margarit Benavent , M. Teresa Navarro Villalba , M. Cristina Martinez Sanchez , Ibrahim M. Al-Zahrani
IPC分类号: C01B39/04 , C01B39/38 , C01B39/26 , B01J37/04 , B01J37/08 , B01J37/02 , B01J29/48 , B01J29/26 , C07C4/18 , C07C6/12
摘要: A method of forming composite zeolite catalyst particles includes combining a silicon source, an aqueous organic structure directing agent having a polyquaternary ammonium compound, water and an aluminum source to form a catalyst gel. The method also includes heating the catalyst gel to form the composite zeolite catalyst particle having an intergrowth region with a mixture of both Mordenite crystals and ZSM-5 crystals. An associated method of making xylene includes feeding heavy reformate to a reactor, the reactor containing the composite zeolite catalyst particles, and producing xylene by simultaneously performing dealkylation and transalkylation of the heavy reformate in the reactor, where each composite zeolite catalyst particle is able to catalyze both the dealkylation and transalkylation reactions.
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公开(公告)号:US20190092644A1
公开(公告)日:2019-03-28
申请号:US15745375
申请日:2016-07-15
IPC分类号: C01B39/02 , C01B39/54 , C01B39/20 , C01B39/26 , C01B39/14 , C01B39/46 , C01B37/02 , C01F7/00
摘要: Core @ layered double hydroxide shell materials of the invention have the formula: Tp@{[Mz+(1−x)M′xy+(OH)2]a+(Xn−)a/n·bH2O·c(AMO-solvent)}q wherein T is a solid, porous, inorganic oxide-containing framework material, Mz+ is a metal cation of charge z or a mixture of two or more metal cations each independently having the charge z; M′y+ is a metal cation of charge y or a mixture of two or more metal cations each independently having the charge y; z=1 or 2; y=3 or 4; 0 0; q>0; Xn− is an anion; with n>0; a=z(1−x)+xy−2; and AMO-solvent is an organic solvent which is completely miscible with water.Also disclosed are the products obtained by calcining the core @ layered double hydroxide shell materials which calcination products are core @ mixed metal oxide materials having the formula Tp@[{Mz+1−xM′y+xOw]pŸ] wherein T is a solid, porous, inorganic oxide-containing framework material, Mz+1−xM′y+xOw is a mixed metal oxide, or mixture of mixed metal oxides, which may be crystalline or non-crystalline, wherein Mz+ and M′y+ are different charged metal cations; Mz+ is a metal cation of charge z or a mixture of two or more metal cations each independently having the charge z; M′y+ is a metal cation of charge y or a mixture of two or more metal cations each independently having the charge y; z is 1 or 2; y is 3 or 4; 0 0; p>0 and q>0; Ÿ is the residue of an Xn− anion in which n>0.
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公开(公告)号:US10058854B2
公开(公告)日:2018-08-28
申请号:US15714204
申请日:2017-09-25
IPC分类号: B01J29/06 , B01J29/80 , C07C15/06 , B01J29/46 , B01J29/44 , B01J29/24 , B01J29/22 , B01J35/10 , B01J29/76 , C01B39/26 , B01J35/02 , B01J35/00 , B01J29/74 , B01J29/68 , B01J29/67 , B01J37/18 , C07C4/18 , C07C6/12 , B01J8/04 , B01J37/30 , B01J37/02
CPC分类号: B01J29/80 , B01J8/04 , B01J29/22 , B01J29/24 , B01J29/44 , B01J29/46 , B01J29/67 , B01J29/68 , B01J29/74 , B01J29/7446 , B01J29/7453 , B01J29/7461 , B01J29/7476 , B01J29/7484 , B01J29/7492 , B01J29/76 , B01J29/7646 , B01J29/7653 , B01J29/7661 , B01J29/7676 , B01J29/7684 , B01J29/7692 , B01J35/002 , B01J35/023 , B01J35/1014 , B01J35/1019 , B01J35/1023 , B01J35/1033 , B01J35/1052 , B01J35/108 , B01J37/0201 , B01J37/18 , B01J37/30 , B01J2208/027 , B01J2229/186 , B01J2229/42 , C01B39/265 , C07C4/18 , C07C6/126 , C07C15/06 , C07C2521/04 , C07C2529/18 , C07C2529/22 , C07C2529/24 , C07C2529/26 , C07C2529/40 , C07C2529/44 , C07C2529/46 , C07C2529/80 , C07C2529/87 , C10G45/62 , C10G45/64 , C10G45/70 , C10G2300/1096 , C10G2300/70 , C10G2400/30 , Y02P20/52
摘要: Disclosed are a catalyst system and its use in a process for the conversion of a feedstock containing C8+ aromatic hydrocarbons to produce light aromatic products, comprising benzene, toluene and xylene. The catalyst system comprises (a) a first catalyst bed comprising a first catalyst composition, said first catalyst composition comprising a zeolite having a constraint index of 3 to 12 combined (i) optionally with at least one first metal of Group 10 of the IUPAC Periodic Table, and (ii) optionally with at least one second metal of Group 11 to 15 of the IUPAC Periodic Table; and (b) a second catalyst bed comprising a second catalyst composition, said second catalyst composition comprising (i) a meso-mordenite zeolite, combined (ii) optionally with at least one first metal of Group 10 of the IUPAC Periodic Table, and (iii) optionally with at least one second metal of Group 11 to 15 of the IUPAC Periodic Table, wherein said meso-mordenite zeolite is synthesized from TEA or MTEA and having a mesopore surface area of greater than 30 m2/g and said meso-mordenite zeolite comprises agglomerates composed of primary crystallites, wherein said primary crystallites have an average primary crystal size as measured by TEM of less than 80 nm and an aspect ratio of less than 2.
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37.
公开(公告)号:US20180194635A1
公开(公告)日:2018-07-12
申请号:US15323112
申请日:2015-07-08
IPC分类号: C01B39/02 , C01B39/24 , C01B39/38 , C01B39/26 , C01B39/46 , B01J20/18 , B01J20/30 , B01J29/08 , B01J29/40 , B01J29/18 , B01J29/70 , B01J37/30 , B01J37/06
CPC分类号: C01B39/026 , B01J20/186 , B01J20/3071 , B01J20/3085 , B01J29/084 , B01J29/18 , B01J29/40 , B01J29/70 , B01J37/06 , B01J37/30 , B01J2229/126 , B01J2229/38 , C01B39/24 , C01B39/26 , C01B39/38 , C01B39/46
摘要: The present invention relates to a method for the preparation of a synthetic crystalline zeolite material, to said synthetic crystalline zeolite material, and to the uses of said method and said synthetic crystalline zeolite material in various applications.
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公开(公告)号:US10017394B2
公开(公告)日:2018-07-10
申请号:US15002809
申请日:2016-01-21
发明人: Wenyih F. Lai , Nicholas S. Rollman , Guang Cao
IPC分类号: C01B39/26 , B01J29/18 , B01J20/18 , B01J20/28 , B01J20/30 , B01J29/22 , B01J29/24 , C07C6/12 , B01J29/40 , B01J29/70 , B01J29/80 , B01J35/00 , B01J35/02 , B01J35/10
CPC分类号: C01B39/265 , B01J20/18 , B01J20/183 , B01J20/28007 , B01J20/2803 , B01J20/28059 , B01J20/28061 , B01J20/28083 , B01J20/3078 , B01J29/18 , B01J29/22 , B01J29/24 , B01J29/40 , B01J29/70 , B01J29/80 , B01J35/002 , B01J35/023 , B01J35/1057 , B01J35/1061 , B01J35/108 , B01J2229/16 , B01J2229/18 , B01J2229/62 , C01B39/26 , C01P2002/01 , C01P2002/70 , C01P2004/54 , C01P2004/64 , C01P2006/12 , C07C6/12 , C07C2529/18 , C07C15/02
摘要: The present invention provides a mordenite zeolite having a mesopore surface area of greater than 30 m2/g and an average primary crystal size as measured by TEM of less than 80 nm, and methods of making the mordenite zeolite.
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公开(公告)号:US09845249B2
公开(公告)日:2017-12-19
申请号:US14902423
申请日:2013-12-02
发明人: Haiyan Liu , Xinyan Sun , Xiaojun Bao , Gang Shi
IPC分类号: C01B39/26
CPC分类号: C01B39/265 , C01B39/26
摘要: The present invention provides a method for preparing a mordenite, which is a method for preparing the mordenite through a hydrothermal crystallization by using natural aluminosilicate minerals as total silicon sources and total aluminum sources, comprising the steps of: subjecting the natural aluminosilicate minerals to activation treatment which is an activation by sub-molten salt and an activation by thermal treatment; selecting and mixing the activated natural aluminosilicate minerals according to the silicon-to-aluminum ratio of the targeted mordenite, adding thereto deionized water, sodium hydroxide, crystal seed, a templating agent to obtain a reaction mixture; adjusting the reaction mixture by using an inorganic acid to have a pH of 10-13, and then aging it at 40-80° C. for 6-24 hours; and subjecting the aged reaction mixture to hydrothermal crystallization, and then filtering, washing, drying and calcinating the crystallized product to obtain the mordenite. The method for preparing a mordenite provided in the present invention enlarges the sources of raw materials for a molecular sieve, has a low cost and a simple process route, and can largely reduce the cost for synthesizing a molecular sieve.
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公开(公告)号:US09663378B2
公开(公告)日:2017-05-30
申请号:US13520142
申请日:2010-12-27
IPC分类号: C01B39/26 , H01F10/28 , C01B39/02 , B01D19/00 , B01J20/02 , B01J20/06 , B01J20/08 , B01J20/18 , B01J20/28 , B01J20/32 , B01J29/06 , B01J35/00 , C02F1/68 , H01F1/01 , B01D3/02 , C02F1/48 , C02F101/32
CPC分类号: C01B39/026 , B01D3/02 , B01D19/0036 , B01J20/0229 , B01J20/06 , B01J20/08 , B01J20/186 , B01J20/28009 , B01J20/3204 , B01J20/3236 , B01J29/06 , B01J35/0033 , C02F1/488 , C02F1/681 , C02F2101/32 , H01F1/01
摘要: Procedure for the magnetization of different inorganic surfaces, whether natural or synthetic, such as aluminosilicates, both synthetic and natural (natural zeolites, synthetic zeolites, alumina, allophane, among others) that give magnetic properties to those surfaces. Objectives of the present application are also the above mentioned surfaces, magnetized, and their different uses.
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