公开(公告)号：US5186818A

公开(公告)日：1993-02-16

申请号：US743957

申请日：1991-08-12

Applicant: Michel Daage ,  Russell R. Chianelli

Inventor： Michel Daage ,  Russell R. Chianelli

IPC: B01J27/02 ,  C10G45/02 ,  C10G45/04 ,  C10G45/72

CPC classification number: C10G45/72 ,  C10G45/02

Abstract: The hydrotreating of petroleum feedstock is improved by using a layered transition metal catalyst, a mixture of such catalysts or a stocked bed of transition metal catalysts that has a selected ratio of edge to rim sites sufficient to provide a product having a predetermined sulfur and nitrogen content.In another aspect of the present invention, there is provided a method for selecting a transition metal catalyst system for use in hydrotreating nitrogen and sulfur containing feedstocks to provide a hydrotreated product having a predetermined nitrogen and sulfur content and at a predetermined reaction residence time, which method comprises: selecting the amount of sulfur and nitrogen to be removed from a given feedstock by hydrotreating to obtain a product having a predetermined nitrogen and sulfur content; determining the variation in the reaction kinetics for sulfur and nitrogen removal of the given feedstock by hydrotreating with a transition metal catalyst of varying edge to rim ratios; selecting, for a predetermined reaction residence time, that ratio from the varying edge to rim ratios of the transition metal catalyst that provides the requisite sulfur and nitrogen removal to provide the product of predetermined sulfur and nitrogen content.

公开(公告)号：US10017705B2

公开(公告)日：2018-07-10

申请号：US14918746

申请日：2015-10-21

Applicant: Richard Charles Dougherty ,  William J. Novak ,  Stuart S. Shih ,  Stephen John McCarthy ,  Michel Daage

Inventor： Richard Charles Dougherty ,  William J. Novak ,  Stuart S. Shih ,  Stephen John McCarthy ,  Michel Daage

IPC: C10L1/08 ,  C10G45/64 ,  C10G65/10 ,  C10G65/12 ,  C10G69/10 ,  C10G47/00 ,  C10G65/18 ,  C10L10/12

CPC classification number: C10L1/08 ,  C10G45/64 ,  C10G47/00 ,  C10G65/10 ,  C10G65/12 ,  C10G65/18 ,  C10G69/10 ,  C10G2300/1055 ,  C10G2300/1059 ,  C10G2300/1074 ,  C10G2300/301 ,  C10G2300/304 ,  C10G2300/305 ,  C10G2300/307 ,  C10G2400/02 ,  C10G2400/04 ,  C10L10/12 ,  C10L2200/0446 ,  C10L2270/026

Abstract: This invention relates to a process involving hydrocracking and dewaxing of a feedstream in which a converted fraction can correspond to a majority of the product from the reaction system, while an unconverted fraction can exhibit improved properties. In this hydrocracking process, it can be advantageous for the yield of unconverted fraction for gasoline fuel application to be controlled to maintain desirable cold flow properties for the unconverted fraction. Catalysts and conditions can be chosen to assist in attaining, or to optimize, desirable product yields and/or properties.

公开(公告)号：US09498738B2

公开(公告)日：2016-11-22

申请号：US14334836

申请日：2014-07-18

Applicant: Amar S. Wanni ,  Lei Zhang ,  Jason M. McMullan ,  Gregory J. DeMartin ,  Michel Daage

Inventor： Amar S. Wanni ,  Lei Zhang ,  Jason M. McMullan ,  Gregory J. DeMartin ,  Michel Daage

IPC: B01D17/00

CPC classification number: B01D17/005

Abstract: Systems and methods are provided for performing field enhanced separations on a feed, such as a petroleum feed, a refinery feed, or another type of hydrocarbonaceous feed. The system can allow for increased throughput of feed per volume of the separation device or system while performing a desired amount of field enhanced separation. The field enhanced separation can include separation by thermal diffusion, optionally enhanced by the presence of an electric field in the channel for performing the separation by thermal diffusion.

Abstract translation: 提供了系统和方法用于在进料上进行现场强化分离，例如石油进料，炼油厂进料或另一种类型的烃类进料。 该系统可以在执行期望量的场增强分离时允许分离装置或系统的体积的进料的增加的吞吐量。 场增强分离可以包括通过热扩散分离，任选地通过在通道中存在用于通过热扩散进行分离的电场而增强。

公开(公告)号：US09200218B2

公开(公告)日：2015-12-01

申请号：US13432098

申请日：2012-03-28

Applicant: Richard Dougherty ,  William J. Novak ,  Stuart S. Shih ,  Stephen J. McCarthy ,  Michel Daage

Inventor： Richard Dougherty ,  William J. Novak ,  Stuart S. Shih ,  Stephen J. McCarthy ,  Michel Daage

IPC: C10G65/12 ,  C10G45/64 ,  C10G65/10 ,  C10G69/10

CPC classification number: C10L1/08 ,  C10G45/64 ,  C10G47/00 ,  C10G65/10 ,  C10G65/12 ,  C10G65/18 ,  C10G69/10 ,  C10G2300/1055 ,  C10G2300/1059 ,  C10G2300/1074 ,  C10G2300/301 ,  C10G2300/304 ,  C10G2300/305 ,  C10G2300/307 ,  C10G2400/02 ,  C10G2400/04 ,  C10L10/12 ,  C10L2200/0446 ,  C10L2270/026

Abstract: This invention relates to a process involving hydrocracking and dewaxing of a feedstream in which a converted fraction can correspond to a majority of the product from the reaction system, while an unconverted fraction can exhibit improved properties. In this hydrocracking process, it can be advantageous for the yield of unconverted fraction for gasoline fuel application to be controlled to maintain desirable cold flow properties for the unconverted fraction. Catalysts and conditions can be chosen to assist in attaining, or to optimize, desirable product yields and/or properties.

Abstract translation: 本发明涉及一种包含进料流的加氢裂化和脱蜡的方法，其中转化的馏分可以对应于来自反应体系的大部分产物，而未转化的馏分可以表现出改进的性能。 在该加氢裂化过程中，可以有利地控制汽油燃料应用的未转化馏分的产率，以保持未转化馏分的期望的冷流动性能。 可以选择催化剂和条件以帮助实现或优化所需的产物产率和/或性能。

公开(公告)号：US20150315491A1

公开(公告)日：2015-11-05

申请号：US14691980

申请日：2015-04-21

Applicant: Patrick Loring Hanks ,  Michel Daage ,  Thomas Francis Degnan, JR.

Inventor： Patrick Loring Hanks ,  Michel Daage ,  Thomas Francis Degnan, JR.

IPC: C10G55/02

CPC classification number: C10G31/06 ,  C10G31/08 ,  C10G53/02 ,  C10G2300/4012

Abstract: New methods and systems for crude oil desalting are provided that utilize hydrodynamic cavitation to crack molecules that have a tendency to form emulsions, thereby allowing increased desalter throughput, reduced desalter operating temperatures, and/or reduced or eliminated need for diluent oil or emulsifier.

Abstract translation: 提供了用于原油脱盐的新方法和系统，其利用水动力空化来裂解具有形成乳液趋势的分子，从而允许增加脱盐剂生产量，降低脱盐器操作温度，和/或减少或消除稀释油或乳化剂的需要。

公开(公告)号：US20150175898A1

公开(公告)日：2015-06-25

申请号：US14560129

申请日：2014-12-04

Applicant: Stephen J. McCarthy ,  Rohit VIJAY ,  Michael Francis RATERMAN ,  Brian PETERSON ,  Karlton J. HICKEY ,  Michel DAAGE ,  Brett LOVELESS ,  Ramesh GUPTA ,  Patricia A. BIELENBERG

Inventor： Stephen J. McCarthy ,  Rohit VIJAY ,  Michael Francis RATERMAN ,  Brian PETERSON ,  Karlton J. HICKEY ,  Michel DAAGE ,  Brett LOVELESS ,  Ramesh GUPTA ,  Patricia A. BIELENBERG

IPC: C10G3/00 ,  C10L1/06

CPC classification number: B01J29/405 ,  B01J21/04 ,  B01J23/06 ,  B01J27/14 ,  B01J29/061 ,  B01J29/40 ,  B01J29/7049 ,  B01J29/7057 ,  B01J29/90 ,  B01J35/10 ,  B01J35/1014 ,  B01J35/1019 ,  B01J35/1023 ,  B01J35/1038 ,  B01J35/1042 ,  B01J35/1057 ,  B01J35/108 ,  B01J35/109 ,  B01J37/0009 ,  B01J37/0201 ,  B01J37/28 ,  B01J38/02 ,  B01J38/12 ,  B01J2229/186 ,  B01J2229/20 ,  B01J2229/42 ,  C07C1/20 ,  C07C1/22 ,  C07C2523/06 ,  C07C2529/06 ,  C07C2529/40 ,  C07C2529/70 ,  C10G3/45 ,  C10G3/49 ,  C10G3/55 ,  C10L1/06 ,  C10L2200/0423 ,  C10L2200/0469 ,  C10L2270/023 ,  Y02P20/584 ,  Y02P30/20 ,  Y02P30/42 ,  C07C11/02 ,  C07C15/02

Abstract: Methods for organic compound conversion are disclosed. Particular methods include providing a first mixture comprising ≧10.0 wt % of at least one oxygenate, based on the weight of the first mixture; contacting said first mixture in at least a first moving bed reactor with a catalyst under conditions effective to covert at least a portion of the first mixture to a product stream comprising water, hydrogen, and one or more hydrocarbons; and separating from said product stream (i) at least one light stream and ii) at least one heavy stream, wherein the method is characterized by a recycle ratio of ≦5.0.

Abstract translation: 公开了有机化合物转化方法。 具体方法包括提供基于第一混合物的重量的包含≥10.0wt％的至少一种含氧化合物的第一混合物; 在有效地将至少一部分第一混合物转化成包含水，氢和一种或多种烃的产物流的条件下，使至少第一移动床反应器中的第一混合物与催化剂接触; 和从所述产物流（i）分离至少一种轻质物流和ii）至少一种重质流，其中所述方法的特征在于再循环比为＆lt;

公开(公告)号：US09034595B2

公开(公告)日：2015-05-19

申请号：US13325988

申请日：2011-12-14

Applicant: Paul D. Oldenburg ,  Michel Daage ,  Virginia M. Roberts ,  Paul J. Berlowitz ,  David C. Long ,  James R. Bielenberg

Inventor： Paul D. Oldenburg ,  Michel Daage ,  Virginia M. Roberts ,  Paul J. Berlowitz ,  David C. Long ,  James R. Bielenberg

IPC: C12P7/10 ,  C12P7/24 ,  C12P7/54 ,  C12P7/62 ,  C12P7/64 ,  C12P7/04 ,  C12P7/16 ,  C12N1/12 ,  C12P7/06

CPC classification number: C12P7/6436 ,  C12N1/12 ,  C12P7/04 ,  C12P7/065 ,  C12P7/10 ,  C12P7/16 ,  Y02E50/10 ,  Y02E50/16 ,  Y02E50/17 ,  Y02P20/125 ,  Y02P20/582

Abstract: Systems and methods are provided for enhancing the integration of processes for recovering products from algae-derived biomass. The enhanced process integration allows for increased use of input streams and other reagents that are derived from renewable sources. This increases the overall renewable character of the products extracted from the algae-derived biomass. The process integration can include exchange of input streams or energy between an algae processing system and a system for processing non-algal biomass. One example of improving process integration is using oxygenates that are generated in a renewable manner as a reagent for enhancing the algae processing system.

Abstract translation: 提供了系统和方法，用于增强从藻类衍生的生物质中回收产物的方法的整合。 增强的过程集成允许更多地使用从可再生来源获得的输入流和其他试剂。 这增加了从藻类来源的生物质提取的产品的整体可再生性。 过程集成可以包括在藻类处理系统和用于处理非藻类生物质的系统之间的输入流或能量的交换。 改进过程整合的一个实例是使用以可再生方式产生的含氧化合物作为增强藻类处理系统的试剂。

公开(公告)号：US08864975B2

公开(公告)日：2014-10-21

申请号：US12157968

申请日：2008-06-13

Applicant: Darden Sinclair ,  Michel Daage ,  Charles J. Mart ,  Louis Burns ,  Timothy L. Hilbert

Inventor： Darden Sinclair ,  Michel Daage ,  Charles J. Mart ,  Louis Burns ,  Timothy L. Hilbert

IPC: C10G73/02 ,  C10G45/62 ,  C10G65/08 ,  B01J29/74 ,  B01J29/03 ,  B01J29/04 ,  C10G65/04 ,  B01J35/00 ,  B01J21/06 ,  B01J37/00 ,  B01J23/44

CPC classification number: C10G65/043 ,  B01J21/063 ,  B01J23/44 ,  B01J29/0325 ,  B01J29/043 ,  B01J29/7461 ,  B01J35/0026 ,  B01J37/0009 ,  B01J2229/20 ,  B01J2229/42 ,  C10G45/62 ,  C10G65/08 ,  C10G73/02 ,  C10G2300/301 ,  C10G2300/302 ,  C10G2300/304 ,  C10G2300/4018 ,  C10G2400/10

Abstract: Integrated hydroprocessing methods using high activity, low density catalysts are provided. The high activity catalysts allow for lower temperature operation, which reduces catalyst degradation, while the low density of the catalysts means a corresponding reduction in the amount of metal needed to fill a reactor volume. The methods allow for flexible processing of feedstocks with a variety of wax contents.

Abstract translation: 提供了使用高活性，低密度催化剂的综合加氢处理方法。 高活性催化剂允许较低的温度操作，这降低催化剂降解，而催化剂的低密度意味着填充反应器体积所需的金属量的相应减少。 这些方法允许用各种蜡含量对原料进行灵活处理。

公开(公告)号：US08704020B2

公开(公告)日：2014-04-22

申请号：US13285787

申请日：2011-10-31

Applicant: Virginia M. Roberts ,  Michel Daage ,  James R. Bielenberg ,  Paul J. Berlowitz ,  Paul D. Oldenburg ,  David C. Long ,  Halou Oumar-Mahamat

Inventor： Virginia M. Roberts ,  Michel Daage ,  James R. Bielenberg ,  Paul J. Berlowitz ,  Paul D. Oldenburg ,  David C. Long ,  Halou Oumar-Mahamat

IPC: C07C1/00

CPC classification number: C10G3/50 ,  C10G3/42 ,  C10G3/44 ,  C10G3/45 ,  C10G3/52 ,  C10G3/62 ,  C10G45/08 ,  C10G45/26 ,  C10G45/50 ,  C10G47/06 ,  C10G65/12 ,  C10G2300/1011 ,  C10G2300/1014 ,  C10G2300/1018 ,  C10G2300/201 ,  C10G2300/202 ,  C10G2300/205 ,  C10G2300/4081 ,  C10G2300/44 ,  C10G2300/70 ,  C10G2300/805 ,  C10G2400/02 ,  C10G2400/04 ,  C10G2400/10 ,  Y02P30/20

Abstract: Biomass based feeds are processed under hydrothermal treatment conditions, e.g., to produce a hydrocarbon liquid product and a solids portion. The hydrothermal treatment is performed in the presence of a dissolved catalyst or catalyst precursor. The presence of the dissolved catalyst or catalyst precursor can modify the nature of the hydrocarbon products produced from the hydrothermal treatment.

Abstract translation: 基于生物质的饲料在水热处理条件下进行处理，例如产生烃液体产物和固体部分。 在溶解的催化剂或催化剂前体的存在下进行水热处理。 溶解的催化剂或催化剂前体的存在可以改变由水热处理产生的烃产物的性质。

公开(公告)号：US20140024869A1

公开(公告)日：2014-01-23

申请号：US13917743

申请日：2013-06-14

Applicant: Virginia M. Roberts ,  Michel Daage ,  Paul D. Oldenburg ,  Suzzy C. Ho ,  Kun Wang ,  Bradley R. Fingland

Inventor： Virginia M. Roberts ,  Michel Daage ,  Paul D. Oldenburg ,  Suzzy C. Ho ,  Kun Wang ,  Bradley R. Fingland

IPC: C07C1/207

CPC classification number: C07C1/2076 ,  B01J21/12 ,  B01J23/02 ,  B01J23/10 ,  C10G3/44 ,  C10G3/50 ,  C10G29/22 ,  C10G2300/1014 ,  C10G2300/1018 ,  C10G2400/10 ,  C11C3/00 ,  Y02E50/13 ,  Y02P30/20

Abstract: Methods are provided for processing glycerides to form lubricant boiling range molecules in a single reactor and/or a single reaction zone. The glycerides are exposed to catalysts that are stable under the conditions present in the reaction zones during conversion of glycerides to fatty ketones via a coupling reaction in the presence of a first catalyst, and the subsequent deoxygenation and isomerization of the ketones in the presence of a second dewaxing catalyst. The glyceride-containing feedstock can further include free fatty acids or fatty acid derivatives that can also be used for formation of ketones and subsequent deoxygenation and isomerization. In some configuration, the processing can occur in a single reaction zone containing mixed beds of the first and second catalyst. Such configurations can be used to control the ratio of diesel boiling range molecules versus lubricant boiling range molecules generated by the methods.

Abstract translation: 提供了用于处理甘油酯以在单个反应器和/或单个反应区中形成润滑剂沸程分子的方法。 将甘油酯暴露于在第一催化剂存在下通过偶联反应将甘油酯转化成脂肪酮的反应区中存在的条件下稳定的催化剂，以及随后在存在下的酮的脱氧和异构化 第二脱蜡催化剂。 含甘油酯的原料还可以包括游离脂肪酸或脂肪酸衍生物，其还可用于形成酮和随后的脱氧和异构化。 在一些配置中，处理可以发生在包含第一和第二催化剂的混合床的单个反应区中。 这种配置可用于控制柴油沸程分子与通过该方法产生的润滑剂沸程分子的比例。