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    Olefin oxidation catalyst system
    42.
    发明授权
    Olefin oxidation catalyst system 失效
    烯烃氧化催化剂体系

    公开(公告)号：US4853357A

    公开(公告)日：1989-08-01

    申请号：US103442

    申请日：1987-09-30

    申请人： Janis Vasilevskis ,  Jacques C. De Deken ,  Robert J. Saxton ,  Paul R. Wentrcek ,  Jere D. Fellmann ,  Lyubov S. Kipnis

    发明人： Janis Vasilevskis ,  Jacques C. De Deken ,  Robert J. Saxton ,  Paul R. Wentrcek ,  Jere D. Fellmann ,  Lyubov S. Kipnis

    IPC分类号： B01J31/16 ,  B01J31/18 ,  C07C45/34 ,  C07C45/35

    CPC分类号： C07C45/35 ,  B01J31/1805 ,  B01J31/4038 ,  C07C45/34 ,  B01J2231/70 ,  B01J2531/824 ,  Y02P20/584

    摘要： The additional of redox-active metal components and ligands, alternatively or simultaneously, results in increased conversion and selectivity in the palladium-catalyzed oxidation of olefins to carbonyl products in the presence of polyoxoanions. In preferred modes, heteropolyoxoanions and Isopolyoxoanions containing tungsten, molybdenum and vanadium, individually or in combination, are described. The use of copper as the redox-active metal component shows reduced allylic reactivity. The elimination of chloride from the catalyst system provides substantial engineering advantages over the prior art, particularly, the reduction of corrosion and chloro-organic by-product formation. The use of redox-active metal components and/or ligands makes the palladium-polyoxoanion catalyst system industrially practicable.

    摘要翻译： 备选或同时添加氧化还原活性金属组分和配体导致在聚氧乙烯存在下，将钯催化的烯烃氧化成羰基产物的转化率和选择性提高。 在优选的模式中，描述了单独或组合地含有钨，钼和钒的杂多氧阴离子和异聚氧阴离子。 使用铜作为氧化还原活性金属组分显示出降低的烯丙基反应性。 与现有技术相比，从催化剂体系中除去氯化物提供了显着的工程优点，特别是减少腐蚀和氯 - 有机副产物形成。 使用氧化还原活性金属组分和/或配体使得钯 - 聚氧阴离子催化剂体系在工业上是可行的。

    METHODS FOR PREPARING INTEGRAL CATALYSTS WHILE MAINTAINING ZEOLITE ACIDITY AND CATALYSTS MADE THEREBY
    44.
    发明申请
    METHODS FOR PREPARING INTEGRAL CATALYSTS WHILE MAINTAINING ZEOLITE ACIDITY AND CATALYSTS MADE THEREBY 审中-公开
    在保持沸石酸性和催化剂的情况下制备集成催化剂的方法

    公开(公告)号：US20130157841A1

    公开(公告)日：2013-06-20

    申请号：US13327233

    申请日：2011-12-15

    申请人： Howard S. Lacheen ,  Robert J. Saxton

    发明人： Howard S. Lacheen ,  Robert J. Saxton

    IPC分类号： B01J37/30 ,  B01J35/02

    CPC分类号： B01J37/0009 ,  B01J29/043 ,  B01J29/044 ,  B01J29/045 ,  B01J29/46 ,  B01J37/12 ,  B01J37/16 ,  B01J37/18 ,  B01J2229/186 ,  B01J2229/40 ,  C10G2/332 ,  C10G2/333

    摘要： Methods for preparing catalysts including a transition metal component and a zeolite component are disclosed. In some embodiments, the transition metal is deposited in a precursor solution onto a zeolite extrudate to form an intermediate integral catalyst wherein prior to the deposition, the zeolite has been subjected to an initial ion exchange with protecting cations which exchange with the protons of the zeolite. The intermediate integral catalyst is heated to decompose the transition metal, and the catalyst is subsequently subjected to a secondary ion exchange with an ionic ammonium complex which exchanges with the protecting cations. The resulting ammonium treated catalyst is heated to a temperature sufficient to decompose the ammonium complex to form ammonia and H+ ions. The transition metal in the resulting catalyst is in the form of reduced crystallites located outside the zeolite channels. No appreciable ion exchange of the transition metal occurs within the zeolite channels.

    摘要翻译： 公开了制备包括过渡金属组分和沸石组分的催化剂的方法。 在一些实施方案中，将过渡金属沉积在前体溶液中以形成沸石挤出物以形成中间体一体催化剂，其中在沉积之前，沸石已经与保护阳离子进行初始离子交换，所述阳离子与沸石的质子交换 。 加热中间整体催化剂以分解过渡金属，然后将催化剂与与保护性阳离子交换的离子铵络合物进行二次离子交换。 将得到的经铵处理的催化剂加热到足以分解铵络合物以形成氨和H +离子的温度。 所得催化剂中的过渡金属是位于沸石通道外部的微晶形式。 在沸石通道内不发生明显的过渡金属离子交换。

    PROCESS OF SYNTHESIS GAS CONVERSION TO LIQUID HYDROCARBON MIXTURES USING SYNTHESIS GAS CONVERSION CATALYST AND HYDROISOMERIZATION CATALYST
    50.
    发明申请
    PROCESS OF SYNTHESIS GAS CONVERSION TO LIQUID HYDROCARBON MIXTURES USING SYNTHESIS GAS CONVERSION CATALYST AND HYDROISOMERIZATION CATALYST 审中-公开
    使用合成气转化催化剂和氢化催化剂合成气体混合物的合成方法

    公开(公告)号：US20110160315A1

    公开(公告)日：2011-06-30

    申请号：US12780672

    申请日：2010-05-14

    申请人： Charles L. Kibby ,  Robert J. Saxton ,  Kandaswamy Jothimurugesan ,  Tapan K. Das

    发明人： Charles L. Kibby ,  Robert J. Saxton ,  Kandaswamy Jothimurugesan ,  Tapan K. Das

    IPC分类号： C07C1/04

    CPC分类号： C07C9/22 ,  C07C1/0435 ,  C07C5/222 ,  C07C9/16 ,  C07C2529/72

    摘要： A process is disclosed for converting synthesis gas to a liquid hydrocarbon mixture useful as distillate fuel and/or lube base oil which is substantially free of solid wax. A synthesis gas feed is contacted with a synthesis gas conversion catalyst in an upstream bed and a hydroisomerization catalyst containing a metal promoter and an acidic component in a downstream bed within a single reactor at essentially common reaction conditions. A Fischer-Tropsch wax is formed over the synthesis gas conversion catalyst and said wax is subsequently hydroisomerized over the hydroisomerization catalyst, thereby resulting in a liquid hydrocarbon mixture having a desirable product distribution.

    摘要翻译： 公开了一种将合成气转化为可用作基本上不含固体蜡的馏出物燃料和/或润滑油基础油的液体烃混合物的方法。 合成气进料在上游床中与合成气转化催化剂和含有金属助催化剂和酸性组分的加氢异构化催化剂在基本上常见的反应条件下在单个反应器内的下游床中接触。 在合成气转化催化剂上形成费托蜡，然后所述蜡在加氢异构化催化剂上加氢异构化，从而得到具有所需产物分布的液态烃混合物。