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公开(公告)号:US20170210077A1
公开(公告)日:2017-07-27
申请号:US15328203
申请日:2015-08-12
Applicant: Carbon, Inc.
Inventor: Alexander Ermoshkin , David Shirvanyants , Joseph M. DeSimone , Nordstrom Kirk Phelps , Jason P. Rolland
Abstract: A method of forming a three-dimensional object (17) includes: providing a carrier (18) and an optically transparent member (15) having a build surface, the carrier (18) and the build surface defining a build region therebetween; filling the build region with a polymerizable liquid (16); irradiating the build region with light (12) through the optically transparent member (15) to form a solid polymer from the polymerizable liquid; and advancing the carrier (18) away from the build surface to form the three-dimensional object (17) from the solid polymer. The carrier (18) includes at least one retain and release (34) feature that is configured to: i) retain the three-dimensional object (17) formed from the solid polymer on the carrier (18) in a first state; and ii) facilitate release of the three-dimensional object (17) formed from the solid polymer from the carrier (18) in a second state.
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公开(公告)号:US12134227B2
公开(公告)日:2024-11-05
申请号:US17860466
申请日:2022-07-08
Applicant: Carbon, Inc.
Inventor: Joseph M. DeSimone , Alexander Ermoshkin , Edward T. Samulski , Jason P. Rolland
IPC: B29C64/124 , B29C64/112 , B29C64/129 , B29C64/245 , B33Y10/00 , B33Y30/00 , B33Y80/00
Abstract: A method of forming a three-dimensional object includes: providing a carrier and an optically transparent member having a build surface, the carrier and the build surface defining a build region therebetween; filling the build region with a polymerizable liquid, irradiating the build region with light through the optically transparent member to form a solid polymer from the polymerizable liquid, and advancing said carrier away from said build surface to form said three-dimensional object from said solid polymer. The irradiating step includes projecting focused light at the build region, and the advancing step is carried out at a rate that is dependent on an average light intensity of the focused light.
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公开(公告)号:US20240336010A1
公开(公告)日:2024-10-10
申请号:US18746539
申请日:2024-06-18
Applicant: Carbon, Inc.
Inventor: Mu San Zhang , Kai Chen , Jason P. Rolland , Justin Poelma
CPC classification number: B29C64/357 , B29B17/0026 , B29B17/04 , B33Y40/00 , B33Y40/20 , B33Y70/00 , C08G18/7843 , C08L75/04 , B29B2017/0416
Abstract: Provided herein are methods of recycling additively manufactured objects (e.g., stereolithographically produced objects), the additively manufactured objects comprising linear polyurethane, branched polyurethane, linear polyurea, branched polyurea, a copolymer thereof, or a combination thereof. Compositions comprising the same and methods of use thereof are also provided.
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公开(公告)号:US11905423B2
公开(公告)日:2024-02-20
申请号:US16947914
申请日:2020-08-24
Applicant: Carbon, Inc.
Inventor: Jessica D. Drazba , Kai Chen , Jason P. Rolland
IPC: C09D11/101 , C09D11/102 , C09D11/037 , C08G18/10 , C08G18/63 , C08G18/77 , B33Y70/00 , G03F7/075 , G03F7/037 , B29C64/124 , G03F7/027 , B29C64/188 , B33Y40/20 , C09D4/00 , B33Y10/00 , B29C64/135 , B29K75/00 , B29K83/00 , B29K96/04 , B29K105/00 , B29C35/08 , B33Y70/10
CPC classification number: C09D11/101 , B29C64/124 , B29C64/188 , B33Y40/20 , B33Y70/00 , C08G18/10 , C08G18/638 , C08G18/778 , C09D4/00 , C09D11/037 , C09D11/102 , G03F7/027 , G03F7/037 , G03F7/0755 , G03F7/0757 , B29C64/135 , B29C2035/0855 , B29K2075/00 , B29K2083/00 , B29K2096/04 , B29K2105/0002 , B29K2105/0085 , B33Y10/00 , B33Y70/10
Abstract: A polymerizable liquid useful for the production of a three-dimensional object comprised of silicone, or a copolymer thereof, which includes at least one constituent selected from the group consisting of (i) a blocked or reactive blocked siloxane-containing prepolymer, (ii) a blocked or reactive blocked siloxane-containing polyisocyanate, and (iii) a blocked or reactive blocked siloxane-containing polyisocyanate chain extender. Methods of using the same in additive manufacturing processes such as continuous liquid interface production are also described.
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公开(公告)号:US20240009921A1
公开(公告)日:2024-01-11
申请号:US18474433
申请日:2023-09-26
Applicant: Carbon, Inc.
Inventor: Jason P. Rolland
IPC: B29C64/118 , B29C64/209 , B33Y70/00 , B33Y10/00 , B33Y30/00
CPC classification number: B29C64/118 , B29C64/209 , B33Y70/00 , B33Y10/00 , B33Y30/00 , B29K2083/00
Abstract: Apparatus for, and associated method of, making a three-dimensional object from a light polymerizable resin by inkjet additive manufacturing are described. The methods and apparatus employ dual precursor resins, including but not limited to dual cure resins having a first component photopolymerizable and a second component polymerizable by a mechanism different from the first component.
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公开(公告)号:US11518096B2
公开(公告)日:2022-12-06
申请号:US17150102
申请日:2021-01-15
Applicant: Carbon, Inc.
Inventor: David Moore , John R. Tumbleston , Edward T. Samulski , Alexander Ermoshkin , Jason P. Rolland , Ariel M. Herrmann , Bob E. Feller
IPC: B29C64/245 , B29C64/20 , B29C64/124 , B33Y30/00 , B29C35/08 , G03F7/20
Abstract: A build plate for a three-dimensional printer includes: a rigid, optically transparent, gas-impermeable planar base having an upper surface and a lower surface; and a flexible, optically transparent, gas-permeable sheet having an upper and lower surface, the sheet upper surface comprising a build surface for forming a three-dimensional object, the sheet lower surface positioned on the base upper surface. The build plate includes a gas flow enhancing feature configured to increase gas flow to the build surface.
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公开(公告)号:US11458673B2
公开(公告)日:2022-10-04
申请号:US16616101
申请日:2018-06-20
Applicant: Carbon, Inc.
Inventor: Jason P. Rolland , Courtney F. Converse , Oshin Nazarian , Matthew Panzer
IPC: B29C64/124 , B29C64/314 , B29C64/321 , B29C64/364 , B29C64/245 , B29C64/255 , B29C64/393 , B29C64/35 , B29C64/205 , B33Y10/00 , B33Y30/00 , B33Y50/02 , B33Y40/20 , B29K63/00 , B29K75/00 , B29K83/00
Abstract: A method of making a three-dimensional object by additive manufacturing from a blended resin (e.g., a blended dual cure resin), the blended resin including (i) at least one light polymerizable first component and, (ii) optionally but preferably, at least one, or a plurality of, second solidifiable components that are different from said first component, the method including one or more of the steps of: (a) providing a first resin and a second resin, where the resins produce three-dimensional objects having different mechanical properties from one another when all are produced under the same process conditions; (b) mixing the first and second resins with one another to produce the blended resin, the blended resin producing a three-dimensional object having mechanical properties intermediate between that of objects produced by the first and second resins when all are produced under the same process conditions; and (c) dispensing the blended resin to the build region of an additive manufacturing apparatus; and then (d) optionally but preferably producing a three-dimensional object from the blended resin in the apparatus.
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公开(公告)号:US11440244B2
公开(公告)日:2022-09-13
申请号:US16432352
申请日:2019-06-05
Applicant: Carbon, Inc.
Inventor: Jason P. Rolland , Julia D. Cushen
IPC: B29C64/129 , B29C64/124 , G03F7/00 , B29C64/135 , G03F7/16 , B33Y70/00 , C08L63/00 , B33Y10/00
Abstract: A method of forming a dual cure three-dimensional object by additive manufacturing may be carried out by mixing a first precursor liquid and a second precursor liquid to produce a polymerizable liquid comprising a mixture of (i) a light polymerizable liquid first component, and (ii) a second solidifiable component (e.g., a second reactive component) that is different from the first component (e.g., that does not contain a cationic photoinitiator, or is further solidified by a different physical mechanism, or further reacted, polymerized or chain extended by a different chemical reaction). In the foregoing: (i′) at least one reactant of the second solidifiable component is contained in the first precursor liquid, and (ii′) at least one reactant or catalyst of the second solidifiable component is contained in the second precursor liquid. Once mixed, the three-dimensional object may be formed from the resin by a dual cure additive manufacturing process.
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49.
公开(公告)号:US11358342B2
公开(公告)日:2022-06-14
申请号:US16556404
申请日:2019-08-30
Applicant: Carbon, Inc.
Inventor: Jason P. Rolland , Kai Chen , Justin Poelma , James Goodrich , Robert Pinschmidt , Joseph M. DeSimone , Lloyd M. Robeson
IPC: B29C64/40 , B29C64/129 , C08K3/013 , C08K3/01 , G03F7/00 , G03F7/027 , G03F7/038 , G03F7/075 , G03F7/38 , B29C64/124 , B29C64/135 , B29C64/386 , C08G18/81 , C08G18/10 , C08G18/76 , C08F220/34 , C08G18/42 , C08F290/06 , C08G18/73 , C08G18/48 , C08G18/24 , C08G18/69 , C08G18/75 , C08F283/00 , C08G18/40 , B29C71/00 , B33Y10/00 , B33Y70/00 , B29D11/00 , B29C35/08 , C08K5/00 , C08L75/04 , B33Y80/00 , C09D135/02 , C09D175/04 , C09D175/08 , B29C64/255 , B29C64/106 , B29C64/165 , B33Y30/00 , C08J5/00 , C08L75/14 , B33Y50/02 , B29C33/00 , B29K75/00 , B29K105/04 , B29L11/00 , B29L31/10 , B29K105/00 , B29K105/16 , B29K509/00 , B29L31/00
Abstract: A method of forming a three-dimensional object is carried out by: (a) providing a carrier and an optically transparent member having a build surface, the carrier and the build surface defining a build region therebetween; (b) filling the build region with a polymerizable liquid, the polymerizable liquid including a mixture of (i) a light polymerizable liquid first component, and (ii) a second solidifiable component that is different from the first component; (c) irradiating the build region with light through the optically transparent member to form a solid polymer scaffold from the first component and also advancing the carrier away from the build surface to form a three-dimensional intermediate having the same shape as, or a shape to be imparted to, the three-dimensional object, and containing the second solidifiable component carried in the scaffold in unsolidified and/or uncured form; and (d) concurrently with or subsequent to the irradiating step, solidifying and/or curing the second solidifiable component in the three-dimensional intermediate to form the three-dimensional object.
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公开(公告)号:US11207835B2
公开(公告)日:2021-12-28
申请号:US17048667
申请日:2019-04-10
Applicant: Carbon, Inc.
Inventor: Jason P. Rolland , Matthew S. Menyo , Joseph M. Desimone
IPC: B29C64/30 , B29C64/307 , B29C64/124 , B29C64/188 , B29C71/02 , B29C64/194 , B33Y10/00 , B33Y40/00 , B33Y70/00
Abstract: Provided is a method of making a cured object having a surface coating bonded thereto, which may include: providing an intermediate object produced in an additive manufacturing process such as stereolithography by light polymerization of a dual cure resin, the resin comprising a mixture of (i) a light polymerizable first component, and (ii) a second component that is different from the first component; applying a first reactive coating composition to a surface portion of the object to form a first coating thereon; optionally, but in some embodiments preferably, applying a second reactive coating composition to the first coating to form a second coating thereon; and heating the object at (and for) a time and to a temperature sufficient to bond the first coating to the surface portion, and bond the second coating when present to the first coating, and form the cured object having a surface coating bonded thereto.
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