公开(公告)号：US06987144B2

公开(公告)日：2006-01-17

申请号：US10456576

申请日：2003-06-09

申请人： Lawrence G. Anderson ,  Shawn A. De Saw ,  Marvis E. Hartman ,  Deborah E. Hayes ,  Thomas R. Hockswender ,  Kymarie L. Kuster ,  Michael Allen Mayo ,  Masayuki Nakajima ,  Kurt G. Olson ,  Richard J. Sadvary ,  Laura E. Schilling ,  Dennis A. Simpson ,  Shiryn Tyebjee ,  Truman F. Wilt

发明人： Lawrence G. Anderson ,  Shawn A. De Saw ,  Marvis E. Hartman ,  Deborah E. Hayes ,  Thomas R. Hockswender ,  Kymarie L. Kuster ,  Michael Allen Mayo ,  Masayuki Nakajima ,  Kurt G. Olson ,  Richard J. Sadvary ,  Laura E. Schilling ,  Dennis A. Simpson ,  Shiryn Tyebjee ,  Truman F. Wilt

IPC分类号： C08L83/04 ,  C08L83/06 ,  C08L83/08

CPC分类号： B82Y30/00 ,  C08J3/20 ,  C08K3/01 ,  C08K3/013 ,  C08K2201/011 ,  C09D7/00 ,  C09D7/61 ,  C09D7/62 ,  C09D7/69 ,  C09D183/04 ,  C08L2666/14 ,  C08L2666/54 ,  C08L2666/04 ,  C08L2666/28

摘要： Coating compositions are provided which include a polysiloxane comprising at least one reactive functional group and at least one material comprising at least one reactive functional group. Also provided are multi-layer composite coatings formed from a basecoat deposited from a pigmented coating composition and a topcoat applied over the basecoat, the topcoat deposited from the aforementioned coating composition. A method for improving the scratch resistance of a coated substrate, as well as coated substrates also are provided. The compositions of the invention provide highly scratch resistant coatings, particularly highly scratch resistant color-plus-clearcoatings.

公开(公告)号：US06387519B1

公开(公告)日：2002-05-14

申请号：US09629423

申请日：2000-07-31

申请人： Lawrence G. Anderson ,  Karen A. Barkac ,  Anthony M. Chasser ,  Shawn A. DeSaw ,  Marvis E. Hartman ,  Deborah E. Hayes ,  Thomas R. Hockswender ,  Kymarie L. Kuster ,  Robert A. Montague ,  Masayuki Nakajima ,  Kurt G. Olson ,  Jamel S. Richardson ,  Richard J. Sadvary ,  Dennis A. Simpson ,  Shiryn Tyebjee ,  Truman F. Wilt

发明人： Lawrence G. Anderson ,  Karen A. Barkac ,  Anthony M. Chasser ,  Shawn A. DeSaw ,  Marvis E. Hartman ,  Deborah E. Hayes ,  Thomas R. Hockswender ,  Kymarie L. Kuster ,  Robert A. Montague ,  Masayuki Nakajima ,  Kurt G. Olson ,  Jamel S. Richardson ,  Richard J. Sadvary ,  Dennis A. Simpson ,  Shiryn Tyebjee ,  Truman F. Wilt

IPC分类号： B32B516

CPC分类号： B82Y30/00 ,  C08J3/20 ,  C08K3/01 ,  C08K3/013 ,  C08K2201/011 ,  C09D7/00 ,  C09D7/62 ,  C09D7/67 ,  C09D7/68 ,  C09D7/69 ,  C09D183/04 ,  Y10T428/25 ,  Y10T428/259 ,  Y10T428/31 ,  Y10T428/31551 ,  Y10T428/31663 ,  C08L2666/54 ,  C08L2666/14 ,  C08L2666/04

摘要： Cured coatings having particles at a surface region of the cured coating are provided. Also provided are multi-component composite coatings which include a cured basecoat deposited from a pigmented coating composition and a cured topcoat deposited from a topcoating composition. The multi-component composite coatings of the invention provide highly scratch resistant color-plus-clearcoatings capable of retaining scratch resistance after weathering.

摘要翻译： 提供了在固化涂层的表面区域具有颗粒的固化涂层。 还提供了多组分复合涂层，其包括由着色涂料组合物沉积的固化底涂层和从表面涂层组合物沉积的固化顶涂层。 本发明的多组分复合涂层提供了耐刮擦后能够保持耐划伤性的高耐划伤性的彩色 - 透明涂层。

公开(公告)号：US06225434B1

公开(公告)日：2001-05-01

申请号：US09364524

申请日：1999-07-30

申请人： Richard J. Sadvary ,  Lawrence G. Anderson ,  Dennis A. Simpson ,  Thomas R. Hockswender ,  Masayuki Nakajima ,  Truman F. Wilt

发明人： Richard J. Sadvary ,  Lawrence G. Anderson ,  Dennis A. Simpson ,  Thomas R. Hockswender ,  Masayuki Nakajima ,  Truman F. Wilt

IPC分类号： C08G7716

CPC分类号： C09D183/08 ,  C08G77/388 ,  C08L63/00 ,  C08L67/02 ,  C08L83/04 ,  C09D5/448 ,  C09D133/066 ,  C09D183/06 ,  Y10T428/31663 ,  C08L2666/14 ,  C08L2666/04 ,  C08L2666/36 ,  C08L2666/34

摘要： Multi-component composite coating compositions are provided which comprise a base coat deposited from a pigmented film-forming composition and a transparent top coat applied over the base coat in which the transparent top coat is deposited from a film-forming composition comprising one or more ungelled chain-extended organic polysiloxanes having reactive functional groups, and one or more curing agents having functional groups reactive with the functional groups of the polysiloxane. Additionally provided is a process for applying the multi-component composite coatings described above to a substrate. Substrates coated with the above-described multi-component composite coating compositions are also provided.

摘要翻译： 提供了多组分复合涂料组合物，其包含由着色成膜组合物沉积的底涂层和涂覆在底涂层上的透明顶涂层，其中透明顶涂层由成膜组合物沉积，所述成膜组合物包含一种或多种未凝胶化 具有反应性官能团的链延伸的有机聚硅氧烷，以及具有与聚硅氧烷的官能团反应的官能团的一种或多种固化剂。 另外提供了将上述多组分复合涂层应用于基材的方法。 还提供了涂覆有上述多组分复合涂料组合物的基材。

公开(公告)号：US4409376A

公开(公告)日：1983-10-11

申请号：US448168

申请日：1982-12-10

申请人： Rostyslaw Dowbenko ,  Marvis E. Hartman ,  Thomas R. Hockswender

发明人： Rostyslaw Dowbenko ,  Marvis E. Hartman ,  Thomas R. Hockswender

IPC分类号： C08G75/04 ,  C09D4/00 ,  C09D123/00 ,  C08G8/28 ,  C08L61/32

CPC分类号： C07C323/00 ,  C08G75/045 ,  C09D4/00

摘要： There are herein provided reaction products of a compound containing an ethylenically unsaturated group and a compound containing at least two reactive groups of varying reactivity. One of the reactive groups such as a mercapto group reacts through the ethylenically unsaturated group. The resulting products are useful as reactive diluents or as film-formers.

摘要翻译： 本文提供了含有烯属不饱和基团的化合物和含有至少两个不同反应活性基团的化合物的反应产物。 反应性基团之一如巯基通过烯属不饱和基团反应。 所得产物可用作反应性稀释剂或成膜剂。

公开(公告)号：US4335829A

公开(公告)日：1982-06-22

申请号：US964549

申请日：1978-11-29

申请人： Roger M. Christenson ,  Rudolf Maska ,  Rostyslaw Dowbenko ,  Thomas R. Hockswender

发明人： Roger M. Christenson ,  Rudolf Maska ,  Rostyslaw Dowbenko ,  Thomas R. Hockswender

IPC分类号： B65D8/04 ,  C08L63/00 ,  C09D133/02 ,  C09D133/26 ,  C09D157/10 ,  C09D157/12 ,  B65D8/00 ,  B05D3/02 ,  B32B15/08 ,  B32B27/38

CPC分类号： C09D157/10 ,  C09D133/02 ,  C09D133/26 ,  C09D157/12 ,  C08L63/00 ,  Y10T428/1355 ,  Y10T428/31529 ,  Y10T428/31692

摘要： An aqueous resinous dispersion and a method of coating employing the aqueous resinous dispersion are disclosed. The aqueous resinous dispersions are solubilized with base and comprise an acrylic polymer containing N-ethoxymethylacrylamide or methacrylamide moieties and an epoxy resin. The dispersion is useful for coating metal containers particularly as a coating for the interior of containers which are used for alcoholic beverages, for example, beer cans.

摘要翻译： 公开了一种水性树脂分散体和使用该水性树脂分散体的涂布方法。 水性树脂分散体用碱溶解并且包含含有N-乙氧基甲基丙烯酰胺或甲基丙烯酰胺部分的丙烯酸聚合物和环氧树脂。 该分散体可用于涂覆金属容器，特别是用作用于酒精饮料（例如啤酒罐）的容器内部的涂层。

公开(公告)号：US4153586A

公开(公告)日：1979-05-08

申请号：US885935

申请日：1978-03-13

申请人： Thomas R. Hockswender ,  Marvis E. Hartman

发明人： Thomas R. Hockswender ,  Marvis E. Hartman

IPC分类号： C08G59/66 ,  C09D5/44 ,  C08L91/00

CPC分类号： C08G59/66 ,  C09D5/4446

摘要： A process of making modified epoxy resins wherein a polyepoxide resin is reacted with a mercaptan compound of the formula HS--R--(COOX).sub.m wherein R is an organic radical having from 1 to 10 carbon atoms, X is hydrogen or a moiety formed by reacting the carboxyl group with a basic compound to form its salt and m is an integer of from 1 to 5. The compounds are reacted in the presence of a tin catalyst to produce resins of the structureB [--S--R--(COOX).sub.m ].sub.nwherein B is the residue from the ring opening reaction of an epoxide group on the polyepoxide resin molecule and the sulfhydryl hydrogen, R, X and m are as defined previously and n is at least 1. The aforementioned resins are produced without the need of a hydrolysis step.The modified epoxy resins are useful in formulating coating compositions having excellent physical and chemical properties. The resins can be dissolved or dispersed in water to form aqueous coating compositions.

摘要翻译： 一种制备改性环氧树脂的方法，其中聚环氧化物树脂与式HS-R-（COOX）m的硫醇化合物反应，其中R是具有1至10个碳原子的有机基团，X是氢或由 使羧基与碱性化合物反应形成其盐，m为1至5的整数。化合物在锡催化剂存在下反应生成结构B [-SR-（COOX）m]的树脂， 其中B是来自多环氧树脂分子和巯基氢环上的环氧基的开环反应的残基，R，X和m如前定义，n至少为1.上述树脂是在不需要 水解步骤。

公开(公告)号：US08822594B2

公开(公告)日：2014-09-02

申请号：US12426411

申请日：2009-04-20

申请人： George Yakulis ,  Calum H. Munro ,  Edward R. Millero, Jr. ,  John Furar ,  Barry A. Russell ,  Howard L. Senkfor ,  Debra L. Singer ,  Steven V. Barancyk ,  Thomas R. Hockswender

发明人： George Yakulis ,  Calum H. Munro ,  Edward R. Millero, Jr. ,  John Furar ,  Barry A. Russell ,  Howard L. Senkfor ,  Debra L. Singer ,  Steven V. Barancyk ,  Thomas R. Hockswender

IPC分类号： C08G18/08 ,  C08L75/00 ,  C08G18/28 ,  C08G18/22 ,  C08G18/00 ,  C08G18/18 ,  C08G18/10 ,  C08G18/32 ,  C08G79/02 ,  C08G18/38 ,  C08G18/78 ,  C08G18/66 ,  C08L75/02 ,  C08G18/50

CPC分类号： C09D175/02 ,  A43B1/00 ,  C08G18/3234 ,  C08G18/3821 ,  C08G18/3885 ,  C08G18/5024 ,  C08G18/6685 ,  C08G18/7837 ,  C08G2410/00 ,  C08L75/02

摘要： Coating compositions comprising a polyurea formed from a reaction mixture comprising: (a) a first component comprising an isocyanate, the first component having a viscosity of ≦2000 centipoise at a temperature ≧7° C.; and (b) a second component comprising an amine. Substrates coated at least in part with such a composition are also disclosed. Footwear coated at least in part with polyurea are also disclosed.

摘要翻译： 包含由反应混合物形成的聚脲的涂料组合物包括：（a）包含异氰酸酯的第一组分，第一组分在≥7℃的温度下具有2000℃的粘度; 和（b）包含胺的第二组分。 还公开了至少部分涂覆有这种组合物的底物。 还公开了至少部分用聚脲涂覆的鞋。

公开(公告)号：US07722958B2

公开(公告)日：2010-05-25

申请号：US11754694

申请日：2007-05-29

申请人： Charles M. Kania ,  Roxalana L. Martin ,  Carolyn A. K. Novak ,  Thomas R. Hockswender ,  Mark A. Tucker ,  Mary Beth Grolemund ,  Deirdre Ragan ,  Alicia Williams

发明人： Charles M. Kania ,  Roxalana L. Martin ,  Carolyn A. K. Novak ,  Thomas R. Hockswender ,  Mark A. Tucker ,  Mary Beth Grolemund ,  Deirdre Ragan ,  Alicia Williams

IPC分类号： B32B5/16 ,  B32B9/04

CPC分类号： C08F212/08 ,  C08F212/14 ,  Y10T428/25 ,  Y10T428/256 ,  Y10T428/257 ,  Y10T428/259 ,  Y10T428/26 ,  Y10T428/31663

摘要： Provided is a film-forming composition substantially free of organic solvent which includes an aqueous dispersion of polymeric microparticles prepared by emulsion polymerization of a monomeric composition containing (1) at least 10 percent by weight of one or more vinyl aromatic compounds; (2) 0.1 to 10 percent by weight of one or more carboxylic acid functional polymerizable, ethylenically unsaturated monomers; (3) 0 to 10 percent by weight of one or more polymerizable monomers having one or more functional groups capable of reacting to form crosslinks; and (4) one or more polymerizable ethylenically unsaturated monomers. Each of (1), (2), (3) and (4) are different one from the other and at least one of (3) and (4) is present in the monomeric composition. Multi-layer composite coatings and coated substrates also are provided.

摘要翻译： 本发明提供一种基本上不含有机溶剂的成膜组合物，其包括通过含有（1）至少10重量％的一种或多种乙烯基芳族化合物的单体组合物的乳液聚合制备的聚合物微粒的水性分散体; （2）0.1至10重量％的一种或多种羧酸官能可聚合的烯属不饱和单体; （3）0〜10重量％的一种或多种具有一个或多个能够反应形成交联的官能团的可聚合单体; 和（4）一种或多种可聚合的烯属不饱和单体。 （1），（2），（3）和（4）中的每一个彼此不同，并且（3）和（4）中的至少一个存在于单体组合物中。 还提供多层复合涂层和涂覆的基底。

公开(公告)号：US20100076143A1

公开(公告)日：2010-03-25

申请号：US12426411

申请日：2009-04-20

申请人： George Yakulis ,  Calum H. Munro ,  Edward R. Millero, JR. ,  John Furar ,  Barry A. Russell ,  Howard L. Senkfor ,  Debra L. Singer ,  Steven V. Barancyk ,  Thomas R. Hockswender

发明人： George Yakulis ,  Calum H. Munro ,  Edward R. Millero, JR. ,  John Furar ,  Barry A. Russell ,  Howard L. Senkfor ,  Debra L. Singer ,  Steven V. Barancyk ,  Thomas R. Hockswender

IPC分类号： C08L75/02 ,  C08G71/02 ,  C08L75/04

CPC分类号： C09D175/02 ,  A43B1/00 ,  C08G18/3234 ,  C08G18/3821 ,  C08G18/3885 ,  C08G18/5024 ,  C08G18/6685 ,  C08G18/7837 ,  C08G2410/00 ,  C08L75/02

摘要： Coating compositions comprising a polyurea formed from a reaction mixture comprising: (a) a first component comprising an isocyanate, the first component having a viscosity of ≦2000 centipoise at a temperature ≧7° C.; and (b) a second component comprising an amine. Substrates coated at least in part with such a composition are also disclosed. Footwear coated at least in part with polyurea are also disclosed.

摘要翻译： 包含由反应混合物形成的聚脲的涂料组合物包括：（a）包含异氰酸酯的第一组分，第一组分在≥7℃的温度下具有2000℃的粘度; 和（b）包含胺的第二组分。 还公开了至少部分涂覆有这种组合物的底物。 还公开了至少部分用聚脲涂覆的鞋。

公开(公告)号：US07611772B2

公开(公告)日：2009-11-03

申请号：US11211188

申请日：2005-08-25

申请人： Steven V. Barancyk ,  Dan M. Brayts, Sr. ,  Joseph DiMario ,  Thomas R. Hockswender ,  Jonathan T. Martz ,  Joseph Morales ,  Howard L. Senkfor ,  Jose C. Trindade

发明人： Steven V. Barancyk ,  Dan M. Brayts, Sr. ,  Joseph DiMario ,  Thomas R. Hockswender ,  Jonathan T. Martz ,  Joseph Morales ,  Howard L. Senkfor ,  Jose C. Trindade

IPC分类号： B32B27/40 ,  C08G18/00

CPC分类号： C08G18/798 ,  C08G18/0885 ,  C08G18/12 ,  C08G18/3821 ,  C08G18/4854 ,  C08G18/5024 ,  C08G18/725 ,  C08J7/047 ,  C08J2475/00 ,  C09D175/02 ,  Y10T428/31551 ,  C08G18/6685

摘要： A polyurea composition, a multi-component composite coating and articles formed therefrom, and methods of forming the same are disclosed. The coating composition is formed from a reaction mixture comprising an isocyanate-functional component and an amine-functional component. The ratio of equivalents of isocyanate groups to equivalents of amine groups is greater than 1 while the volume mixing ratio of the isocyanate-functional component to the amine-functional component is capable of being applied to a substrate at 1:1.

摘要翻译： 公开了聚脲组合物，多组分复合涂层和由其形成的制品及其形成方法。 涂料组合物由包含异氰酸酯官能组分和胺官能组分的反应混合物形成。 异氰酸酯基的当量与胺基的当量的比例大于1，而异氰酸酯官能组分与胺官能组分的体积混合比能够以1:1的比例施加到基材上。