公开(公告)号：US20090283442A1

公开(公告)日：2009-11-19

申请号：US12402078

申请日：2009-03-11

申请人： Michael J. McCall ,  Joseph A. Kocal ,  Alakananda Bhattacharyya ,  Tom N. Kalnes ,  Timothy A. Brandvold

发明人： Michael J. McCall ,  Joseph A. Kocal ,  Alakananda Bhattacharyya ,  Tom N. Kalnes ,  Timothy A. Brandvold

IPC分类号： C10G65/12 ,  C10L1/04

CPC分类号： C10G3/47 ,  C10G3/46 ,  C10G3/49 ,  C10G3/52 ,  C10G45/02 ,  C10G45/58 ,  C10G47/00 ,  C10G2300/1014 ,  C10G2300/1018 ,  C10G2300/1022 ,  C10G2300/1037 ,  C10G2300/4081 ,  C10G2300/80 ,  C10G2400/08 ,  Y02P30/20

摘要： A hydrocarbon product stream having hydrocarbons with boiling points in the aviation fuel range is produced from renewable feedstocks such as plant and animal oils. The process involves treating a renewable feedstock by hydrogenating, deoxygenating, isomerization, and selectively hydrocracking the feedstock to produce paraffinic hydrocarbons having from about 9 to about 16 carbon atoms and a high iso/normal ratio in a single reaction zone containing a multifunctional catalyst, or set of catalysts, having hydrogenation, deoxygenation, isomerization and selective hydrocracking functions.

摘要翻译： 在航空燃料范围内具有沸点的烃的烃产物流由可再生原料如植物油和动物油生产。 该方法包括通过氢化，脱氧，异构化和选择性加氢裂解原料来处理可再生原料，以在含有多官能催化剂的单个反应区中产生具有约9至约16个碳原子的链烷烃和高异/正常比例，或 具有氢化，脱氧，异构化和选择性加氢裂化功能的催化剂组。

公开(公告)号：US20080249198A1

公开(公告)日：2008-10-09

申请号：US11697780

申请日：2007-04-09

申请人： Wensheng Chen ,  Simon R. Bare ,  Maureen L. Bricker ,  Timothy A. Brandvold ,  Joseph A. Kocal

发明人： Wensheng Chen ,  Simon R. Bare ,  Maureen L. Bricker ,  Timothy A. Brandvold ,  Joseph A. Kocal

IPC分类号： C07C27/06

CPC分类号： C07C29/095 ,  C07C67/035 ,  C12C11/02 ,  C07C31/04 ,  C07C69/63

摘要： A process for the oxidation of methane to methanol has been developed. The process involves contacting a gas stream, comprising methane, a solvent and an oxidizing agent with a bimetallic catalyst at oxidation conditions to produce a methyl ester. Finally, the methyl ester is hydrolyzed to yield a methanol product stream. The bimetallic catalyst comprises at least two transition metal components. One example of the catalytic component is a combination of cobalt and manganese.

摘要翻译： 已经开发了将甲烷氧化成甲醇的方法。 该方法包括在氧化条件下使包含甲烷，溶剂和氧化剂的气流与双金属催化剂接触以产生甲酯。 最后，将甲酯水解，得到甲醇产物流。 双金属催化剂包含至少两种过渡金属组分。 催化组分的一个实例是钴和锰的组合。

公开(公告)号：US06555715B1

公开(公告)日：2003-04-29

申请号：US09975371

申请日：2001-10-11

申请人： Joseph A. Kocal ,  Robert R. Frame ,  Jeffery C. Bricker

发明人： Joseph A. Kocal ,  Robert R. Frame ,  Jeffery C. Bricker

IPC分类号： C07C4528

CPC分类号： C07C1/24 ,  C07C11/02 ,  C07C29/145 ,  C07C45/28 ,  C07C2521/04 ,  C07C2521/06 ,  C07C2521/08 ,  C07C2527/054 ,  C07C2527/173 ,  C07C2529/04 ,  C07C49/08 ,  C07C49/10 ,  C07C31/10 ,  C07C31/12

摘要： A process has been developed for oxygenating linear C2 to C6 alkanes to ketones or aldehydes. The process involves reacting the alkanes with oxygen in the presence of a catalyst comprising an imide promoter and a metal co-catalyst. An example of the imide is N-hydroxyphthalimide and an example of the co-catalyst is Co (acetylacetonate). The process is preferably carried out using an inert solvent, an example of which is acetic acid. Optionally, the oxygenated product can be hydrogenated to give the corresponding alcohol which can optionally in turn be dehydrated to provide the corresponding olefin.

摘要翻译： 已经开发了将线性C2至C6烷烃氧化成酮或醛的方法。 该方法包括在包含酰亚胺助催化剂和金属助催化剂的催化剂存在下使烷烃与氧反应。 酰亚胺的实例是N-羟基邻苯二甲酰亚胺，助催化剂的实例是Co（乙酰丙酮化物）。 该方法优选使用惰性溶剂进行，惰性溶剂的实例是乙酸。 任选地，氧化产物可以被氢化得到相应的醇，其可以任选地依次脱水以提供相应的烯烃。

公开(公告)号：US06512144B1

公开(公告)日：2003-01-28

申请号：US09728536

申请日：2000-12-01

申请人： Gregory J. Lewis ,  Paula L. Bogdan ,  Feng Xu ,  Joseph A. Kocal

发明人： Gregory J. Lewis ,  Paula L. Bogdan ,  Feng Xu ,  Joseph A. Kocal

IPC分类号： C07C4500

CPC分类号： B01J27/187 ,  B01J29/82 ,  C01B25/377 ,  C07C45/33 ,  C07C315/02

摘要： Processes for oxidizing hydrocarbons using a new family of crystalline manganese phosphate compositions have been developed. These compositions have an extended network which network can be a one-, two-, or three-dimensional network. The composition has an empirical formula of: (Aa+)v(Mnb+)(Mc+)xPyOz where A is a structure directing agent such as an alkali metal, M is a metal such as Al, Fe3+ and “b” is the average manganese oxidation state and varies from greater than 2.0 to a maximum of 3.0. Specific oxidation processes are oxidative dehydrodimerization and oxidative dehydrogenation.

摘要翻译： 已经开发了使用新的结晶磷酸锰组合物来氧化烃的方法。 这些组合物具有扩展网络，其网络可以是一维，二维或三维网络。 该组合物具有以下经验式：其中A是结构导向剂如碱金属，M是金属如Al，Fe 3+，“b”是平均锰氧化态，并且从大于2.0变化到最大值 3.0。 具体的氧化过程是氧化脱氢二聚化和氧化脱氢。

公开(公告)号：US06368495B1

公开(公告)日：2002-04-09

申请号：US09689550

申请日：2000-10-12

申请人： Joseph A. Kocal ,  Timothy A. Brandvold

发明人： Joseph A. Kocal ,  Timothy A. Brandvold

IPC分类号： C10G2922

CPC分类号： C10G27/04

摘要： A novel process effective for the removal of organic sulfur compounds from liquid hydrocarbons is disclosed. The process more specifically addresses the removal of thiophenes and thiophene derivatives from a number of petroleum fractions, including gasoline, diesel fuel, and kerosene. In the first step of the process, the liquid hydrocarbon is subjected to oxidation conditions in order to oxidize at least some of the thiophene compounds to sulfones. Then, these sulfones can be catalytically decomposed to hydrocarbons (e.g. hydroxybiphenyl) and volatile sulfur compounds (e.g. sulfur dioxide). The hydrocarbon decomposition products remain in the treated liquid as valuable blending components, while the volatile sulfur compounds are easily separable from the treated liquid using well-known techniques such as flash vaporization or distillation.

摘要翻译： 公开了一种有效从液态烃中除去有机硫化合物的新方法。 该方法更具体地涉及从许多石油馏分（包括汽油，柴油燃料和煤油）中除去噻吩和噻吩衍生物。 在该方法的第一步中，液态烃经受氧化条件以使至少一些噻吩化合物氧化成砜。 然后，这些砜可以催化分解成烃类（如羟基联苯）和挥发性硫化合物（如二氧化硫）。 烃分解产物保留在经处理的液体中作为有价值的共混组分，而使用众所周知的技术，例如闪蒸或蒸馏，挥发性硫化合物容易与处理液体分离。

公开(公告)号：US5763728A

公开(公告)日：1998-06-09

申请号：US533038

申请日：1995-09-25

申请人： Joseph A. Kocal ,  Harold U. Hammershaimb ,  Robert J. Cornish ,  Terry L. Marker ,  James F. Himes

发明人： Joseph A. Kocal ,  Harold U. Hammershaimb ,  Robert J. Cornish ,  Terry L. Marker ,  James F. Himes

IPC分类号： B01J27/32 ,  C07C2/54 ,  C07C2/58 ,  C07C2/56 ,  C07C7/00

CPC分类号： C07C2/54 ,  B01J27/32 ,  C07C2527/1206 ,  C07C2531/02 ,  Y02P20/584

摘要： An HF-agent complex, such as HF-pyridine complex where the complexing agent is pyridine, is recovered and recycled from a by-product containing stream in an alkylation process using the complex by (a) selectively removing a portion of the HF from the by-product stream to produce an HF-depleted stream having a molar ratio of HF per Lewis base site of the complexing agent of 3:1 to 5:1, (b) separating the resulting HF-depleted stream into a hydrocarbon phase enriched in ASO and an acid phase depleted in ASO and containing a substantial portion of the complex, and (c) recycling the acid phase to the hydrocarbon alkylation step.

摘要翻译： 通过（a）从（a）选择性地除去HF的一部分HF，从烷基化方法中回收含有副产物的流的HF-试剂络合物，例如络合剂为吡啶的HF-吡啶络合物 副产物流以产生具有3:1至5:1络合剂的每个路易斯碱位点的HF的摩尔比的HF贫化物流，（b）将所得的HF贫化物流分离成富集的烃相 ASO和在ASO中耗尽的酸相，并含有大部分复合物，和（c）将酸相再循环到烃烷基化步骤。

公开(公告)号：US5391527A

公开(公告)日：1995-02-21

申请号：US172960

申请日：1993-12-27

申请人： Masami Kojima ,  Joseph A. Kocal

发明人： Masami Kojima ,  Joseph A. Kocal

IPC分类号： B01J23/96 ,  B01J38/10 ,  C07C2/60 ,  B01J27/32 ,  B01J38/58

CPC分类号： B01J23/96 ,  B01J38/10 ,  C07C2/60 ,  C07C2523/42 ,  C07C2523/44 ,  C07C2523/46 ,  C07C2523/755 ,  C07C2527/08 ,  C07C2527/125 ,  C07C2527/133 ,  C07C2527/135 ,  C07C2527/14 ,  Y02P20/584

摘要： Catalytic composites of the reaction product of a metal halide having Friedel-Crafts activity with the bound surface hydroxyl group of inorganic oxides and containing a zerovalent metal with hydrogenation activity, often are effective catalysts in motor fuel alkylation which, however, undergo rapid deactivation. Deactivated catalysts are readily regenerable by treating the composite from which alkylate feedstock has been removed with hydrogen at temperatures in the range of 10.degree. to 300.degree. C. Multiple regenerations are possible without appreciable activity loss.

摘要翻译： 具有Friedel-Crafts活性的金属卤化物与无机氧化物的结合表面羟基并含有具有氢化活性的零价金属的反应产物的催化复合物通常是马达燃料烷基化中的有效催化剂，然而，其经历快速失活。 去活化的催化剂可以容易地再生，通过处理在10至300℃的温度范围内用氢气除去烷基化物原料的复合物。多次再生可能没有明显的活性损失。

公开(公告)号：US5034564A

公开(公告)日：1991-07-23

申请号：US507812

申请日：1990-04-12

申请人： Joseph A. Kocal

发明人： Joseph A. Kocal

IPC分类号： B01J21/16 ,  B01J29/04 ,  B01J37/00 ,  C07C20060101 ,  C07C2/66 ,  C07C2/86 ,  C07C15/02

CPC分类号： B01J29/049 ,  B01J37/0009 ,  C07C2/66 ,  C07C2/861 ,  C07C2/864 ,  C07C2529/05 ,  Y02P20/582

摘要： Alkyl aromatic compounds may be prepared by reacting an aromatic compound such as benzene with an alkylating agent such as an olefin, alkyl halide or alkyl alcohol in the presence of an alkylation catalyst. The alkylation catalyst of the present invention comprises a pillared clay and a binder which has been prepared by dispersing a clay in a metallic pillaring agent sol, separating the resultant pillared clay, washing and drying said pillared clay, forming a dough of said pillared clay and a binder compound, extruding said dough extudate. By utilizing this catalytic composite it is possible to obtain improved selectivity of the desired alkyl aromatic compound which may then be used in the preparation of biodegradable detergents.

摘要翻译： 烷基芳族化合物可以通过芳族化合物如苯与烷基化剂如烯烃，烷基卤或烷基醇在烷基化催化剂的存在下反应来制备。 本发明的烷基化催化剂包括柱状粘土和粘合剂，其通过将粘土分散在金属柱状溶胶中，分离所得柱状粘土，洗涤和干燥所述柱状粘土，形成所述柱状粘土的生面团和 一种粘合剂化合物，挤出所述的面团。 通过利用该催化复合物，可以获得所需的烷基芳族化合物的改进的选择性，然后可以将其用于制备可生物降解的洗涤剂。

公开(公告)号：US4835333A

公开(公告)日：1989-05-30

申请号：US223310

申请日：1988-07-25

申请人： Joseph A. Kocal

发明人： Joseph A. Kocal

IPC分类号： B01J27/12 ,  B01J31/02 ,  B01J31/40 ,  C07C2/62

CPC分类号： B01J31/40 ,  B01J27/12 ,  B01J31/0215 ,  B01J31/0227 ,  B01J31/0258 ,  B01J31/0271 ,  C07C2/62 ,  B01J2231/323 ,  C07C2527/1206 ,  C07C2531/02 ,  Y02P20/584

摘要： A novel hydrofluoric acid-catalyzed motor fuel alkylation process and catalyst is disclosed which incorporates from 0.5 to 5 vol. % of a cationic or anionic surfactant component in an HF containing acid alkylation catalyst to enable the process to be operated at an olefin-to-acid volumetric feed ratio greater than 1.0 while producing a motor alkylate product with a good octane number.

公开(公告)号：US4795728A

公开(公告)日：1989-01-03

申请号：US68513

申请日：1987-07-01

申请人： Joseph A. Kocal

发明人： Joseph A. Kocal

IPC分类号： B01J31/02 ,  B01J31/40 ,  C07C2/62

CPC分类号： B01J31/0258 ,  B01J31/0225 ,  B01J31/0259 ,  B01J31/0268 ,  B01J31/0271 ,  B01J31/40 ,  C07C2/62 ,  B01J2231/323 ,  C07C2527/1206 ,  C07C2531/02 ,  Y02P20/584

摘要： A novel hydrofluoric acid-catalyzed motor fuel alkylation process and catalyst is disclosed which incorporates from 0.5 to 5 vol. % of a cationic or anionic surfactant component in an HF containing acid alkylation catalyst to enable the process to be operated at an olefin-to-acid volumetric feed ratio greater than 1.0 while producing a motor alkylate product with a good octane number.

摘要翻译： 公开了一种新的氢氟酸催化的汽油燃料烷基化方法和催化剂，其结合0.5至5体积％ ％的阳离子或阴离子表面活性剂组分在含HF的酸性烷基化催化剂中，使得该方法能够以大于1.0的烯烃 - 酸体积进料比操作，同时产生具有良好辛烷值的马来烷烷基化产物。