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    Polyester macromers containing 1,1-dicarbonyl-substituted 1 alkenes
    42.
    发明授权
    Polyester macromers containing 1,1-dicarbonyl-substituted 1 alkenes 有权

    公开(公告)号：US10087283B2

    公开(公告)日：2018-10-02

    申请号：US15472379

    申请日：2017-03-29

    Applicant: SIRRUS, INC.

    Inventor： Aniruddha Palsule ,  Jeffrey M. Sullivan ,  Kshitij K. Parab ,  Elliott King ,  William Barrett

    IPC: C08G63/60 ,  C08G64/42 ,  C07C69/593 ,  C12P7/62

    Abstract: Disclosed are compositions comprising polyester macromers containing in one or more chains the residue of one or more diols and one or more diesters wherein the residue of the one or more diols and the one or more diesters alternate along the chain and a portion of the diesters are 1,1-diester-1-alkenes, and optionally one or more dihydrocarbyl dicarboxylates, and at least one terminal end comprises the residue of one of the 1,1-diester-1 alkenes and wherein one or more terminal ends may comprise the residue of one or more diols. The chains may contain the residue of the one or more diols and one or more diesters comprising one or more diesters 1,1-diester-1 alkenes and optionally one or more dihydrocarbyl dicarboxylates randomly disposed along the chains. Disclosed are methods of preparing the polyester macromers and incorporating them in a variety of polyester containing compositions such as coatings and films.

    METHOD TO OBTAIN METHYLENE MALONATE VIA BIS(HYDROXYMETHYL) MALONATE PATHWAY
    48.
    发明申请
    METHOD TO OBTAIN METHYLENE MALONATE VIA BIS(HYDROXYMETHYL) MALONATE PATHWAY 审中-公开
    通过双（羟甲基）马来酸酐路线获得亚甲基马来酸盐的方法

    公开(公告)号：US20170050167A1

    公开(公告)日：2017-02-23

    申请号：US15345976

    申请日：2016-11-08

    Applicant: SIRRUS, INC.

    Inventor： Bernard Miles Malofsky ,  Adam Gregg Malofsky ,  Jeffrey M. Sullivan ,  Philip B. Kisanga ,  John Joseph Anderson ,  Michael Charles Milner Cockrem ,  Philip Jay Carlberg

    IPC: B01J19/24 ,  B01J29/40 ,  B01J8/06

    CPC classification number: B01J19/245 ,  B01J8/067 ,  B01J29/40 ,  B01J2208/00168 ,  B01J2208/065 ,  B01J2219/00033 ,  B01J2219/0004 ,  B01J2219/00087 ,  B01J2219/00177 ,  B01J2219/24 ,  C07C67/31 ,  C07C67/327 ,  C07C67/333 ,  C07C67/56 ,  C07C69/593 ,  C08F222/14 ,  C09D4/00 ,  C09J4/00

    Abstract: Method to obtain methylene malonate and related monomers following a bis(hydroxymethyl) malonate pathway. A bis(hydroxymethyl) malonate intermediary is subsequently reacted (i.e., subjected to thermolysis) to provide a methylene malonate monomer species. A source of formaldehyde (e.g., formalin) is provided in the presence of a basic catalyst (e.g., calcium hydroxide), to which a malonate (e.g., diethyl malonate) is added under suitable reaction conditions to obtain the desired intermediary (e.g., dialkyl bis(hydroxymethyl) malonate). The intermediary is reacted (i.e., subjected to thermolysis) under suitable conditions in the presence of a suitable catalyst (e.g., a zeolite) to obtain a methylene malonate monomer. In an exemplary embodiment, the thermolysis reaction includes the addition of the bis(hydroxymethyl) malonate intermediary onto a heated catalyst. The reaction product is collected and purified. The disclosed methods may be performed in a continuous operation. Discrete steps may be performed by using modular units within a plant.

    Abstract translation: 获得二（羟甲基）丙二酸酯途径后亚甲基丙二酸酯和相关单体的方法。 随后将双（羟甲基）丙二酸酯中间体反应（即进行热解）以提供亚甲基丙二酸酯单体种类。 在碱性催化剂（如氢氧化钙）的存在下提供甲醛源（如福尔马林），在合适的反应条件下加入丙二酸酯（如丙二酸二乙酯），得到所需的中间体（如二烷基 双（羟甲基）丙二酸酯）。 在合适的条件下，在合适的催化剂（例如沸石）的存在下，使中间体反应（即进行热解），得到亚甲基丙二酸酯单体。 在一个示例性实施方案中，热解反应包括在加热的催化剂上加入双（羟甲基）丙二酸酯中间体。 收集并纯化反应产物。 所公开的方法可以在连续操作中执行。 离散步骤可以通过使用工厂内的模块化单元来执行。

    High purity 1,1-dicarbonyl substituted-1-alkenes and methods for their preparation
    49.
    发明授权
    High purity 1,1-dicarbonyl substituted-1-alkenes and methods for their preparation 有权
    高纯度1,1-二羰基取代-1-烯烃及其制备方法

    公开(公告)号：US09518001B1

    公开(公告)日：2016-12-13

    申请号：US15159185

    申请日：2016-05-19

    Applicant: SIRRUS, INC.

    Inventor： Jeffrey M. Sullivan ,  Kevin Powers ,  William Barrett

    IPC: C07C67/327 ,  B01J29/06 ,  C07C67/333 ,  C07C57/13 ,  C08G63/00

    CPC classification number: C07C67/333 ,  C07C51/377 ,  C07C57/13 ,  C07C67/343 ,  C07C69/593 ,  C07C69/675

    Abstract: A composition comprising about 97 mole percent or greater of one or more 1,1-dicarbonyl substituted-1-ethylenes and about 3 mole percent or less of one or more 1,1-dicarbonyl substituted-methanes. A process comprising: contacting in a fluid state one or more 1,1-dicarbonyl substituted-1,1 hydroxymethyl-methanes and greater than 200 ppm to about 1000 ppm of one or more strong acids based on the weight of the one or more 1,1-dicarbonyl substituted-1,1 hydroxymethyl-methanes with a zeolite catalyst at a temperature of about 180° C. to about 220° C. for a sufficient time to convert about 96 percent or greater of the one or more 1,1-dicarbonyl substituted-1,1 hydroxymethyl-methanes to one or more 1,1-dicarbonyl substituted-1-ethylenes.

    Abstract translation: 包含约97摩尔％或更多的一种或多种1,1-二羰基取代的-1-乙烯和约3摩尔％或更少的一种或多种1,1-二羰基取代的甲烷的组合物。 一种方法，其包括：以一种或多种1,1-二羰基取代的-1.1羟甲基 - 甲烷和大于200ppm至约1000ppm的一种或多种强酸的流体状态接触一种或多种强酸， ，1-二羰基取代的-1.1羟甲基 - 甲烷与沸石催化剂在约180℃至约220℃的温度下反应足够的时间以转化约96％或更大的一种或多种1,1 - 二羰基取代的-1.1羟甲基 - 甲烷与一个或多个1,1-二羰基取代的-1-乙烯。

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