公开(公告)号：US20130210942A1

公开(公告)日：2013-08-15

申请号：US13396466

申请日：2012-02-14

Applicant: Charles Leonard Kibby ,  Robert James Saxton, JR. ,  Kandaswamy Jothimurugesan ,  Tapan Kumar Das ,  Howard Steven Lacheen ,  Michael Bartz ,  Alfred Has

Inventor： Charles Leonard Kibby ,  Robert James Saxton, JR. ,  Kandaswamy Jothimurugesan ,  Tapan Kumar Das ,  Howard Steven Lacheen ,  Michael Bartz ,  Alfred Has

IPC: B01J35/02 ,  B01J23/75 ,  C07C1/04 ,  B01J37/02

CPC classification number: B01J29/7669 ,  B01J23/8986 ,  B01J29/061 ,  B01J29/064 ,  B01J29/068 ,  B01J29/072 ,  B01J29/076 ,  B01J29/7469 ,  B01J29/7869 ,  B01J35/023 ,  B01J35/04 ,  B01J37/0036 ,  B01J37/0203 ,  B01J37/0225 ,  B01J37/0228 ,  B01J37/0244 ,  B01J37/0246 ,  B01J37/0248 ,  B01J2229/186 ,  B01J2229/42 ,  B01J2229/60 ,  C07C1/0435 ,  C07C2529/072 ,  C10G2/33 ,  Y10T428/31678

Abstract: Disclosed are hybrid synthesis gas conversion catalysts containing at least one Fischer-Tropsch component and at least one acidic component deposited on a monolith catalyst support for use in synthesis gas conversion processes and methods for preparing the catalysts. Also disclosed are synthesis gas conversion processes in which the hybrid synthesis gas conversion catalysts are contacted with synthesis gas to produce a hydrocarbon product containing at least 50 wt % C5+ hydrocarbons. Also disclosed are synthesis gas conversion processes in which at least one layer of Fischer-Tropsch component deposited onto a monolith support is alternated with at least one layer of acidic component in a fixed bed reactor.

Abstract translation: 公开了含有至少一种费 - 托组分和沉积在整体催化剂载体上的至少一种酸性组分的混合合成气转化催化剂，用于合成气转化方法和制备催化剂的方法。 还公开了合成气转化方法，其中混合合成气转化催化剂与合成气体接触以产生含有至少50重量％的C 5+烃的烃产物。 还公开了合成气转化方法，其中沉积在整料载体上的至少一层费 ​​- 托成分与固定床反应器中的至少一层酸性组分交替。

公开(公告)号：US08481601B2

公开(公告)日：2013-07-09

申请号：US12953042

申请日：2010-11-23

Applicant: Tapan Das ,  Kandaswamy Jothimurugesan ,  Charles L Kibby ,  Robert J. Saxton

Inventor： Tapan Das ,  Kandaswamy Jothimurugesan ,  Charles L Kibby ,  Robert J. Saxton

IPC: C07C27/00

CPC classification number: C10G2/332 ,  B01J21/04 ,  B01J23/462 ,  B01J23/6562 ,  B01J29/068 ,  B01J29/44 ,  B01J29/7415 ,  B01J35/0006 ,  B01J35/006 ,  B01J35/0066 ,  B01J35/1019 ,  B01J35/1038 ,  B01J37/04 ,  C10G2300/1022 ,  C10G2300/4006 ,  C10G2300/4012 ,  C10G2300/4018 ,  C10G2400/30

Abstract: The disclosure relates to a method of performing a synthesis gas conversion reaction in which synthesis gas contacts a catalyst system including a mixture of ruthenium loaded Fischer-Tropsch catalyst particles and at least one set of catalyst particles including an acidic component promoted with a noble metal, e.g., Pt or Pd. The reaction occurs at conditions resulting in a hydrocarbons product containing 1-15 weight % CH4, 1-15 weight % C2-C4, 70-95 weight % C5+, 0-5 weight % C21+ normal paraffins, and 0-10 weight % aromatic hydrocarbons.

Abstract translation: 本发明涉及一种进行合成气转化反应的方法，其中合成气与包含钌负载的费 - 托催化剂颗粒和至少一组催化剂颗粒的催化剂体系接触，所述催化剂颗粒包括用贵金属促进的酸性组分， 例如Pt或Pd。 反应发生在产生含有1-15重量％CH 4，1-15重量％C 2 -C 4，70-95重量％C 5+，0-5重量％C 21+正构烷烃和0-10重量％芳族烃的烃产物的条件下 碳氢化合物。

公开(公告)号：US08445550B2

公开(公告)日：2013-05-21

申请号：US12953024

申请日：2010-11-23

Applicant: Kandaswamy Jothimurugesan ,  Tapan Das ,  Charles L. Kibby ,  Robert J. Saxton

Inventor： Kandaswamy Jothimurugesan ,  Tapan Das ,  Charles L. Kibby ,  Robert J. Saxton

IPC: C07C27/00

CPC classification number: B01J23/462 ,  B01J21/04 ,  B01J23/6562 ,  B01J29/068 ,  B01J29/076 ,  B01J29/48 ,  B01J29/7815 ,  B01J35/0006 ,  B01J35/002 ,  B01J35/006 ,  B01J35/1019 ,  B01J35/1038 ,  B01J35/108 ,  B01J37/0009 ,  B01J37/024 ,  B01J37/035 ,  C10G2/332 ,  C10G2/333 ,  C10G2300/1022 ,  C10G2300/304

Abstract: Disclosed is a method of forming a hybrid Fischer-Tropsch catalyst extrudate for use in synthesis gas conversion reactions. The method includes extruding a mixture of ruthenium loaded metal oxide support particles, particles of an acidic component and a binder sol to form an extrudate. The resulting extrudate contains from about 0.1 to about 15 weight percent ruthenium based on the weight of the extrudate. In a synthesis gas conversion reaction, the extrudate is contacted with a synthesis gas having a H2 to CO molar ratio of 0.5 to 3.0 at a reaction temperature of 160° C. to 300° C., a total pressure of 3 to 35 atmospheres, and an hourly space velocity of 5 to 10,000 v/v/hour, resulting in hydrocarbon products containing 1-15 weight % CH4; 1-15 weight % C2-C4; 70-95 weight % C5+; 0-5 weight % C21+ normal paraffins; and 0-10 weight % aromatic hydrocarbons.

Abstract translation: 公开了形成用于合成气转化反应的混合费 - 托催化剂挤出物的方法。 该方法包括挤出载有钌的金属氧化物载体颗粒，酸性组分的颗粒和粘合剂溶胶的混合物以形成挤出物。 所得挤出物含有基于挤出物重量的约0.1至约15重量％的钌。 在合成气转化反应中，将挤出物与H 2 CO 2摩尔比为0.5-3.0的合成气在160℃至300℃的反应温度，3至35大气压的总压力下接触， 和5至10,000v / v /小时的小时空间速度，得到含有1-15重量％CH 4的烃产物; 1-15重量％C2-C4; 70-95重量％C5 +; 0-5重量％C21 +正链烷烃; 和0-10重量％的芳烃。

公开(公告)号：US20120108682A1

公开(公告)日：2012-05-03

申请号：US13208195

申请日：2011-08-11

Applicant: Robert J. Saxton ,  Charles L. Kibby ,  Kandaswamy Jothimurugesan ,  Tapan Das

Inventor： Robert J. Saxton ,  Charles L. Kibby ,  Kandaswamy Jothimurugesan ,  Tapan Das

IPC: C07C1/04

CPC classification number: B01J37/0244 ,  B01J23/8913 ,  B01J29/42 ,  B01J29/74 ,  B01J37/024 ,  B01J37/04 ,  C10G2/32 ,  C10G2/333 ,  C10G2/341 ,  C10G45/58 ,  C10G45/64 ,  C10G47/00 ,  C10G47/14 ,  C10G65/12 ,  C10G2300/1022 ,  C10G2300/304 ,  C10G2400/02

Abstract: Disclosed is a process for converting synthesis gas to liquid hydrocarbon mixtures useful in the production of fuels and petrochemicals. The synthesis gas is contacted with at least two layers of synthesis gas conversion catalyst wherein each synthesis gas conversion catalyst layer is followed by a layer of hydrocracking catalyst and hydroisomerization catalyst or separate layers of hydrocracking and hydroisomerization catalysts. The process can occur within a single reactor, at an essentially common reactor temperature and an essentially common reactor pressure. The process provides a high yield of naphtha range liquid hydrocarbons and a low yield of wax.

Abstract translation: 公开了将合成气转化成用于生产燃料和石化产品的液体烃混合物的方法。 合成气与至少两层合成气转化催化剂接触，其中每个合成气转化催化剂层之后是一层加氢裂化催化剂和加氢异构化催化剂或分开的加氢裂化和加氢异构化催化剂层。 该方法可以在单个反应器中，在基本上公认的反应器温度和基本上共同的反应器压力下进行。 该方法提供了高产量的石脑油范围液体烃和低产率的蜡。

公开(公告)号：US20110306686A1

公开(公告)日：2011-12-15

申请号：US12797439

申请日：2010-06-09

Applicant: Kandaswamy Jothimurugesan ,  Charles Leonard Kibby ,  Robert James Saxton

Inventor： Kandaswamy Jothimurugesan ,  Charles Leonard Kibby ,  Robert James Saxton

IPC: B01J29/068 ,  C07C1/12

CPC classification number: C10G2/333 ,  B01J29/068 ,  B01J29/076 ,  B01J29/44 ,  B01J29/46 ,  B01J29/7415 ,  B01J29/7815 ,  B01J35/002 ,  B01J35/1019 ,  B01J37/0009 ,  B01J37/12 ,  B01J37/18 ,  C10G2/334

Abstract: A method for forming a catalyst for synthesis gas conversion and a synthesis gas conversion process impregnating a zeolite support wherein the catalyst contains ruthenium on a zeolite support, such as ZSM-5, ZSM-12, SSZ-32 or beta zeolite, and the product stream has less than 1 weight % C21+.

Abstract translation: 形成合成气转化催化剂的方法和浸渍沸石载体的合成气转化方法，其中催化剂在沸石载体如ZSM-5，ZSM-12，SSZ-32或β沸石上含有钌，产物 流具有小于1重量％的C21 +。

公开(公告)号：US20110306685A1

公开(公告)日：2011-12-15

申请号：US12797773

申请日：2010-06-10

Applicant: Charles L. Kibby ,  Robert J. Saxton ,  Kandaswamy Jothimurugesan ,  Tapan K. Das

Inventor： Charles L. Kibby ,  Robert J. Saxton ,  Kandaswamy Jothimurugesan ,  Tapan K. Das

IPC: C07C27/00

CPC classification number: C10G2/32 ,  B01J23/44 ,  B01J29/74 ,  B01J29/7469 ,  B01J29/7669 ,  B01J35/0006 ,  B01J35/006 ,  B01J35/0066 ,  B01J35/1019 ,  B01J37/0009 ,  B01J37/0203 ,  B01J37/18 ,  B01J2229/42 ,  C10G2/332 ,  C10G2/333 ,  C10G2/334 ,  C10G45/00 ,  C10G2300/1022 ,  C10G2300/304

Abstract: A method is provided for converting synthesis gas to liquid hydrocarbon mixtures useful as distillate fuel and/or lube base oil containing no greater than about 25 wt % olefins and containing no greater than about 5 wt % C21+ normal paraffins. The synthesis gas is contacted with a synthesis gas conversion catalyst comprising a Fischer-Tropsch synthesis component and an acidic component in an upstream catalyst bed thereby producing a wax-free liquid containing a paraffin component and an olefin component. The olefin component is saturated by contacting the liquid with an olefin saturation catalyst in a downstream catalyst bed.

Abstract translation: 提供了一种用于将合成气转化成液体烃混合物的方法，该液体烃混合物可用作不大于约25重量％的烯烃并且不超过约5重量％的C21 +正构链烷烃的馏出物燃料和/或润滑油基础油。 使合成气与上游催化剂床中的包含费 - 托合成成分和酸性成分的合成气转化催化剂接触，由此生成含有石蜡成分和烯烃成分的无蜡液体。 通过在下游催化剂​​床中使液体与烯烃饱和催化剂接触来使烯烃组分饱和。

公开(公告)号：US07825164B1

公开(公告)日：2010-11-02

申请号：US12621385

申请日：2009-11-18

Applicant: Charles L. Kibby ,  Kandaswamy Jothimurugesan ,  Tapan K. Das ,  Robert J. Saxton ,  Allen W. Burton

Inventor： Charles L. Kibby ,  Kandaswamy Jothimurugesan ,  Tapan K. Das ,  Robert J. Saxton ,  Allen W. Burton

IPC: C07C27/00

CPC classification number: C10G2/333 ,  B01J23/75 ,  B01J23/894 ,  B01J29/068 ,  B01J29/44 ,  B01J29/74 ,  B01J35/0006

Abstract: A process is disclosed for converting a feed comprising synthesis gas to liquid hydrocarbons within a single reactor at essentially common reaction conditions. The synthesis gas contacts a catalyst bed comprising a mixture of a synthesis gas conversion catalyst on a support containing an acidic component and a dual functionality catalyst including a hydrogenation component and a solid acid component. The hydrocarbons produced are liquid at about 0° C., contain at least 25% by volume C10+ and are substantially free of solid wax.

Abstract translation: 公开了用于在基本上常见的反应条件下将包含合成气的进料转化为单个反应器内的液体烃的方法。 合成气在包含酸性组分的载体和包含氢化组分和固体酸组分的双官能催化剂的催化剂床上接触合成气转化催化剂的混合物。 生产的烃在约0℃是液体的，含有至少25体积％的C 10+，并且基本上不含固体蜡。

公开(公告)号：US20060011512A1

公开(公告)日：2006-01-19

申请号：US11180089

申请日：2005-07-13

Applicant: Rafael Espinoza ,  Keith Lawson ,  Kandaswamy Jothimurugesan

Inventor： Rafael Espinoza ,  Keith Lawson ,  Kandaswamy Jothimurugesan

IPC: C10G47/02

CPC classification number: B01J37/036 ,  B01J21/12 ,  B01J23/24 ,  B01J23/40 ,  B01J23/42 ,  B01J23/652 ,  B01J23/85 ,  B01J23/89 ,  B01J35/0006 ,  B01J35/002 ,  B01J35/0066 ,  B01J35/1019 ,  B01J35/1023 ,  B01J35/1042 ,  B01J35/1047 ,  B01J35/1061 ,  B01J37/04 ,  C10G2/32 ,  C10G47/02 ,  C10G47/04 ,  C10G47/12 ,  C10G47/14

Abstract: An amorphous support, methods for making the same and methods of using, particularly in hydrocracking. A method of making may comprise mixing a first amorphous material and a second amorphous material of different acidities to form a mixture, and treating by either separately treating the first and second amorphous materials before mixing or treating the mixture, so as to form an amorphous catalyst support. Treating preferably includes calcining. The acidity of the amorphous support may be modified by the different acidities of the precursor amorphous materials, their proportions in the mixture, and/or the order of the mixing and treating steps. A method of use may comprise reacting a hydrocarbon fraction with hydrogen over a hydrocracking catalyst comprising the amorphous catalyst support to form a hydrocracked product. Further embodiments include the first and second amorphous materials comprising silica-alumina, and/or differing in Brönsted acidity, Lewis acidity, or acidity index.

Abstract translation: 无定形支撑物，制备方法和使用方法，特别是在加氢裂化中。 制备方法可以包括混合不同酸度的第一无定形材料和第二无定形材料以形成混合物，并且在混合或处理混合物之前单独处理第一和第二非晶材料进行处理，以形成无定形催化剂 支持。 处理优选包括煅烧。 无定形载体的酸度可以通过前体无定形材料的不同酸度，它们在混合物中的比例和/或混合和处理步骤的顺序来改变。 使用的方法可以包括使烃馏分与氢气在包含无定形催化剂载体的加氢裂化催化剂上反应以形成加氢裂化产物。 另外的实施方案包括包含二氧化硅 - 氧化铝的第一和第二无定形材料和/或布朗斯台德酸度，路易斯酸度或酸度指数不同。

公开(公告)号：US20050119116A1

公开(公告)日：2005-06-02

申请号：US10962702

申请日：2004-10-12

Applicant: Rafael Espinoza ,  Kandaswamy Jothimurugesan ,  Kevin Coy ,  James Ortego ,  Nithya Srinivasan ,  Olga Ionkina

Inventor： Rafael Espinoza ,  Kandaswamy Jothimurugesan ,  Kevin Coy ,  James Ortego ,  Nithya Srinivasan ,  Olga Ionkina

IPC: B01J20060101 ,  B01J20/00 ,  B01J21/00 ,  B01J21/02 ,  B01J21/08 ,  B01J21/12 ,  B01J21/14 ,  B01J23/00 ,  B01J23/08 ,  B01J23/40 ,  B01J23/42 ,  B01J23/44 ,  B01J23/56 ,  B01J23/58 ,  B01J23/70 ,  B01J23/74 ,  B01J23/75 ,  B01J23/89 ,  B01J25/00 ,  B01J25/02 ,  B01J25/04 ,  B01J27/053 ,  B01J35/10 ,  B01J37/03 ,  C07C1/02 ,  C10G2/00 ,  C10K1/02

CPC classification number: B01J21/12 ,  B01J21/08 ,  B01J23/75 ,  B01J23/89 ,  B01J23/8913 ,  B01J35/0053 ,  B01J35/006 ,  B01J35/0066 ,  B01J35/023 ,  B01J35/1014 ,  B01J35/1019 ,  B01J35/1023 ,  B01J35/1042 ,  B01J35/1047 ,  B01J35/1061 ,  B01J37/036 ,  C10G2/33 ,  C10G2/332 ,  C10G2/333

Abstract: This invention relates to catalysts comprising a catalytic metal deposited on a composite support with well-dispersed chemical “anchor” species acting as nucleation centers for catalytic metal crystallites growth. The catalysts have the advantage that the average catalytic metal crystallite size can be controlled by the molar ratio of catalytic metal to chemical “anchor,” and is not limited by the porous structure of the support. A preferred embodiment comprises a cobalt-based catalyst on a silica-alumina support made by a co-gel method, wherein its average pore size can be controlled by the pH. The alumina species in the support most likely serve as chemical “anchors” to control the dispersion of cobalt species, such that the average cobalt crystallite size can be greater than the average pore size.

Abstract translation: 本发明涉及包含沉积在复合载体上的催化金属的催化剂，其具有充分分散的作为催化金属微晶生长的成核中心的化学“锚”物质。 催化剂的优点在于，催化金属的平均催化金属粒度可以通过催化金属与化学“锚”的摩尔比来控制，并不受支持体的多孔结构的限制。 优选的实施方案包括在通过共凝胶法制备的二氧化硅 - 氧化铝载体上的钴基催化剂，其中其平均孔径可以由pH控制。 载体中的氧化铝物质最有可能用作化学“锚”以控制钴物质的分散体，使得平均钴微晶尺寸可以大于平均孔径。

公开(公告)号：US20050107479A1

公开(公告)日：2005-05-19

申请号：US10964988

申请日：2004-10-14

Applicant: Rafael Espinoza ,  Kandaswamy Jothimurugesan ,  Kevin Coy

Inventor： Rafael Espinoza ,  Kandaswamy Jothimurugesan ,  Kevin Coy

IPC: B01J21/04 ,  B01J21/08 ,  B01J21/12 ,  B01J23/46 ,  B01J23/656 ,  B01J23/745 ,  B01J23/75 ,  B01J23/78 ,  B01J23/889 ,  B01J23/89 ,  B01J29/06 ,  B01J35/10 ,  B01J37/03 ,  B01J37/04 ,  C07C27/00 ,  C07C27/06 ,  C10G2/00

CPC classification number: C10G2/33 ,  B01J21/12 ,  B01J23/462 ,  B01J23/6567 ,  B01J23/745 ,  B01J23/75 ,  B01J23/78 ,  B01J23/8896 ,  B01J23/8906 ,  B01J23/8913 ,  B01J35/1019 ,  B01J35/1042 ,  B01J35/1061 ,  B01J35/109 ,  B01J37/036 ,  B01J37/04

Abstract: An effective catalyst includes an amorphous silica-alumina support having a bimodal pore size-distribution. The support may be prepared by a method that includes the physical mixing of two silica-alumina gels prepared so as to have two different average pore sizes. The catalyst has the advantage that both metal dispersion on the support and product diffusion in the pores are optimized. Further, the catalyst has improved performance in the production of hydrocarbons from synthesis gas.

Abstract translation: 有效的催化剂包括具有双峰孔径分布的无定形二氧化硅 - 氧化铝载体。 载体可以通过包括物理混合制备成具有两种不同平均孔径的二氧化硅 - 氧化铝凝胶的方法来制备。 催化剂具有以下优点：金属分散在载体上和产物在孔中的扩散被优化。 此外，催化剂在从合成气生产碳氢化合物方面具有改进的性能。