公开(公告)号：US20140235755A1

公开(公告)日：2014-08-21

申请号：US14168383

申请日：2014-01-30

Applicant: Wisconsin Alumni Research Foundation

Inventor： Padma Gopalan ,  Daniel P. Sweat ,  Myungwoong Kim

IPC: C09D163/00

CPC classification number: C08F293/005 ,  B05D3/007 ,  B81C2201/0149 ,  B81C2201/0156 ,  C08F12/16 ,  C08F14/16 ,  C08F20/22 ,  C08F20/32 ,  C08F214/16 ,  C08F220/22 ,  C08F220/32 ,  C08F2438/01 ,  C08F2438/03 ,  C08J3/24 ,  C08J5/18 ,  C08J2327/10 ,  C08J2333/14 ,  C08L2312/00 ,  C09D127/10 ,  C09D133/08 ,  C09D133/14 ,  C09D133/16

Abstract: Crosslinkable random copolymers comprising atom transfer radical polymerization (ATRP) initiators and crosslinked copolymer films formed from the copolymers are provided. The random copolymers, which are polymerized from one or more alkyl halide functional inimers and one or more monomers having a crosslinkable functionality, are characterized by pendant ATRP initiating groups and pendant crosslinkable groups.

Abstract translation: 提供包含原子转移自由基聚合（ATRP）引发剂和由共聚物形成的交联共聚物膜的可交联无规共聚物。 由一种或多种烷基卤化物官能异构体和一种或多种具有可交联官能团的单体聚合的无规共聚物的特征在于侧链ATRP引发基团和侧链可交联基团。

公开(公告)号：US20130059130A1

公开(公告)日：2013-03-07

申请号：US13659824

申请日：2012-10-24

Applicant: Wisconsin Alumni Research Foundation

Inventor： Padma Gopalan ,  Eungnak Han

IPC: B32B3/10 ,  B32B33/00 ,  B05D3/06 ,  B32B27/08

CPC classification number: G03F7/09 ,  C08F293/005 ,  C08F2438/02 ,  C08J3/24 ,  C08J7/04 ,  C08J7/12 ,  C08L33/068 ,  C08L2312/00 ,  C09D125/14 ,  C09D133/068 ,  C09D153/00 ,  G03F7/038 ,  G03F7/0388 ,  G03F7/165 ,  G03F7/26 ,  Y10T428/24174 ,  Y10T428/24802 ,  C08L33/062

Abstract: The present invention provides structures including a substrate, a crosslinked polymer film disposed over the substrate, and a patterned diblock copolymer film disposed over the crosslinked polymer film. The crosslinked polymer comprises a random copolymer polymerized from a first monomer, a second monomer, and a photo-crosslinkable and/or thermally crosslinkable third monomer, including epoxy-functional or acrylyol-functional monomers. Also disclosed are methods for forming the structures.

Abstract translation: 本发明提供了包括基材，设置在基材上的交联聚合物膜以及设置在交联聚合物膜上的图案化二嵌段共聚物膜的结构。 交联聚合物包含由第一单体，第二单体和可光交联和/或可热交联的第三单体（包括环氧官能或丙烯酰基官能单体）聚合的无规共聚物。 还公开了用于形成结构的方法。

公开(公告)号：US20230159435A1

公开(公告)日：2023-05-25

申请号：US18149345

申请日：2023-01-03

Applicant: Wisconsin Alumni Research Foundation

Inventor： Padma Gopalan ,  Balamurugan Ayyakkalai ,  Ri Chen

IPC: C07C225/16 ,  C08F12/26 ,  C07C225/14

CPC classification number: C07C225/16 ,  C08F12/26 ,  C07C225/14 ,  C07C2602/42

Abstract: Formamide group-containing monomers and polymers made by polymerizing the monomers are provided. Also provided are methods of polymerizing the monomers and methods of synthesizing functionalized polymers by pre- and/or post-polymerization functionalization. The monomers are non-toxic and can generate highly reactive isocyanate and isonitrile precursors in a one-pot synthesis that enables the incorporation of complex functionalities into the side-chain of the polymers that are synthesized from the monomers.

公开(公告)号：US20230028346A1

公开(公告)日：2023-01-26

申请号：US17376295

申请日：2021-07-15

Applicant: Wisconsin Alumni Research Foundation

Inventor： Michael Scott Arnold ,  Katherine Rose Jinkins ,  Padma Gopalan

IPC: H01L51/00 ,  H01L51/05

Abstract: Methods of forming films of aligned carbon nanotubes on a substrate surface are provided. The films are deposited from carbon nanotubes that have been concentrated and confined at a two-dimensional liquid/liquid interface. The liquid/liquid interface is formed by a dispersion of organic material-coated carbon nanotubes that flows over the surface of an immiscible liquid within a flow channel. Within the interface, the carbon nanotubes self-organize via liquid crystal phenomena and globally align along the liquid flow direction. By translating the interface across the substrate, large-area, wafer-scale films of aligned carbon nanotubes can be deposited on the surface of the substrate in a continuous and scalable process.

公开(公告)号：US10913873B2

公开(公告)日：2021-02-09

申请号：US15404775

申请日：2017-01-12

Applicant: Wisconsin Alumni Research Foundation

Inventor： Padma Gopalan ,  Daniel Patrick Sweat ,  Xiang Yu ,  Myungwoong Kim

IPC: C09D153/00 ,  C08F297/02 ,  C08F12/22 ,  C08F12/32 ,  G03F7/00 ,  C08F297/04 ,  C09D153/02

Abstract: Block copolymers for use in block copolymer lithography, self-assembled films of the block copolymers and methods for polymerizing the block copolymers are provided. The block copolymers are characterized by high Flory-Huggins interaction parameters (χ). The block copolymers can be polymerized from protected hydroxystyrene monomers or from tert-butyl styrene and 2-vinylpyridine monomers.

公开(公告)号：US10557054B2

公开(公告)日：2020-02-11

申请号：US15665831

申请日：2017-08-01

Applicant: Wisconsin Alumni Research Foundation

Inventor： Padma Gopalan ,  William L. Murphy ,  Samantha Kelly Schmitt

IPC: C09D133/14 ,  C08F220/28 ,  C12N5/00

Abstract: Random copolymers, crosslinked thin films of the random copolymers and cell culture substrates comprising the crosslinked thin films are provided. Also provided are methods of making and using the copolymers, thin films and substrates. The copolymers are polymerized from glycidyl methacrylate monomers and vinyl azlactone monomers. The crosslinked thin films are substrate independent, in that they need not be covalently bound to a substrate to form a stable film on the substrate surface.

公开(公告)号：US10252914B2

公开(公告)日：2019-04-09

申请号：US15184036

申请日：2016-06-16

Applicant: Wisconsin Alumni Research Foundation

Inventor： Michael Scott Arnold ,  Padma Gopalan ,  Nathaniel S. Safron ,  Myungwoong Kim

IPC: C01B32/182 ,  B82Y30/00 ,  B82Y40/00 ,  C01B32/186 ,  C01B32/194

Abstract: Methods of producing layers of patterned graphene with smooth edges are provided. The methods comprise the steps of fabricating a layer of crystalline graphene on a surface, wherein the layer of crystalline graphene has a crystallographically disordered edge, and decreasing the crystallographic disorder of the edge of the layer of crystalline graphene by heating the layer of crystalline graphene on the surface at an elevated temperature in a catalytic environment comprising carbon-containing molecules.

公开(公告)号：US10100163B2

公开(公告)日：2018-10-16

申请号：US14724104

申请日：2015-05-28

Applicant: Wisconsin Alumni Research Foundation

Inventor： Padma Gopalan

IPC: C08J5/18 ,  C08J7/18 ,  C08J5/12 ,  C40B40/04 ,  C40B50/18

Abstract: The present invention provides crosslinked epoxy-functional copolymer films and microarrays built from the crosslinked epoxy-functional copolymer films. Microarrays incorporating the copolymers include a substrate on which a film of the crosslinked epoxy-functional copolymer is disposed and target molecules bound to the copolymer film. The crosslinked polymer films are well-suited for use as scaffolds for target molecules in microarrays because they provide a high density of binding sites for the target molecules, are mechanically stable, and may be coated onto a wide range of substrates.

公开(公告)号：US20180261772A1

公开(公告)日：2018-09-13

申请号：US15455587

申请日：2017-03-10

Applicant: Wisconsin Alumni Research Foundation

Inventor： Michael Scott Arnold ,  Katherine Rose Jinkins ,  Gerald Joseph Brady ,  Padma Gopalan

IPC: H01L51/00 ,  H01L51/05 ,  B82Y30/00 ,  B82Y40/00

CPC classification number: H01L51/0003 ,  B82Y10/00 ,  B82Y30/00 ,  B82Y40/00 ,  C01B32/168 ,  C01B32/172 ,  C01B2202/08 ,  H01L51/0012 ,  H01L51/0048 ,  H01L51/0558 ,  Y10S977/746 ,  Y10S977/847 ,  Y10S977/891

Abstract: Methods for forming carbon nanotube arrays are provided. Also provided are the arrays formed by the methods and electronic devices that incorporate the array as active layers. The arrays are formed by flowing a fluid suspension of carbon nanotubes through a confined channel under conditions that create a velocity gradient across the flowing suspension.

公开(公告)号：US09938149B1

公开(公告)日：2018-04-10

申请号：US15291508

申请日：2016-10-12

Applicant: Wisconsin Alumni Research Foundation

Inventor： Padma Gopalan ,  Michael Scott Arnold ,  Catherine Kanimozhi Kansiusarulsamy ,  Gerald Joseph Brady ,  Matthew John Shea

IPC: C01B31/02 ,  C08G73/06 ,  H01L51/00

CPC classification number: C01B32/17 ,  C01B31/026 ,  C01B32/172 ,  C01B2202/02 ,  C01B2202/22 ,  C08G73/0627 ,  H01L51/0039 ,  H01L51/0048 ,  H01L51/0558

Abstract: Conjugated polymers composed of bi-pyridine units linked to 9,9-dialkyl fluorenyl-2,7-diyl units via imine linkages along the polymer backbone are provided. Also provided are semiconducting single-walled carbon nanotubes coated with the conjugated polymers and methods of sorting and separating s-SWCNTs from a sample comprising a mixture of s-SWCNTs and metallic single-walled carbon nanotubes using the conjugated polymers.