Iron oxide magnetic nanoparticle, its preparation and its use in desulfurization
    47.
    发明授权
    Iron oxide magnetic nanoparticle, its preparation and its use in desulfurization 有权
    氧化铁磁性纳米颗粒,其制备及其在脱硫中的应用

    公开(公告)号:US09034174B2

    公开(公告)日:2015-05-19

    申请号:US13672298

    申请日:2012-11-08

    摘要: The present invention provides a method of preparing an iron oxide magnetic nanoparticle, comprising the steps of: i) reacting a water-soluble ferrous salt with a water-soluble ferric salt in a mole ratio of 1:2 in the presence of a base and a citrate to give an iron oxide particle surface-coated with the citrate (c-MNP); ii) reacting the c-MNP obtained in step (i) with a thiophilic compound to give a thiophilic compound-bounded iron oxide particle surface-coated with the citrate (thiophilic-c-MNP); and iii) modifying the thiophilic-c-MNP obtained in step (ii) using a surfactant for phase transfer of the thiophilic-c-MNP from aqueous phase to organic phase. The present invention also relates to the iron oxide magnetic nanoparticle prepared by the above-mentioned method and the use of the nanoparticle in desulfurization. The iron oxide magnetic nanoparticle of the present invention is capable of effective deep desulfurization.

    摘要翻译: 本发明提供一种制备氧化铁磁性纳米颗粒的方法,包括以下步骤:i)在碱存在下使水溶性亚铁盐与摩尔比为1:2的水溶性铁盐与水溶性铁盐反应, 柠檬酸盐,得到表面涂覆有柠檬酸盐(c-MNP)的氧化铁颗粒; ii)使步骤(i)中获得的c-MNP与亲硫化合物反应,得到表面涂覆有柠檬酸(thiophilic-c-MNP)的硫醇化合物结合的氧化铁颗粒; 和iii)使用表面活性剂修饰在步骤(ii)中获得的嗜硫菌素c-MNP,所述表面活性剂将嗜硫菌c-MNP从水相相转移到有机相。 本发明还涉及通过上述方法制备的氧化铁磁性纳米颗粒和在脱硫中使用纳米颗粒。 本发明的氧化铁磁性纳米粒子能够进行有效的深度脱硫。

    Feed mixtures for extraction process to produce rubber processing oil
    48.
    发明授权
    Feed mixtures for extraction process to produce rubber processing oil 有权
    进料混合物用于萃取工艺生产橡胶加工油

    公开(公告)号:US08864981B2

    公开(公告)日:2014-10-21

    申请号:US13007581

    申请日:2011-01-14

    摘要: Deasphalted residual oil (DAO) and the aromatics-rich extract that is derived from DAO have low polycyclic aromatics contents, relatively low aniline points, and high flash points. They form blending stocks that improve properties of mixed feedstocks to consistently produce environmentally qualified rubber processing oil (RPO) by extraction under low solvent-to-oil ratios and moderate extraction temperatures. Distilling a petroleum crude oil under atmospheric pressure generates a bottom residual oil which is then subject to vacuum distillation to yield a bottom residual oil. DAO is produced by removing the asphalt from the vacuum bottom residual oil through extraction with light paraffinic solvent. The extract of DAO is a co-product in the production of the bright stock of the lubricating oil through extraction. The feedstock is mixed with the extract from a petroleum fraction boiling in lube oil range. Liquid-liquid counter-current extraction yields a raffinate stream; removal of solvent therefrom produces the RPO.

    摘要翻译: 脱气残油(DAO)和来自DAO的富含芳烃的提取物具有低多环芳烃含量,苯胺点相对较低,闪点高。 它们形成混合原料,以改善混合原料的性能,以通过在低溶剂/油比和中等萃取温度下萃取来一致地生产环保合格的橡胶加工油(RPO)。 在大气压下蒸馏石油原油产生底部残余油,然后进行真空蒸馏以产生底部残余油。 DAO是通过用轻链烷烃溶剂萃取从真空底渣中除去沥青而制得的。 DAO的提取物是通过萃取生产润滑油的亮油的共同产品。 原料与在润滑油范围沸腾的石油馏分的提取物混合。 液 - 液逆流萃取产生萃余液流; 除去溶剂产生RPO。

    Process oil, process for production of deasphalted oil, process for production of extract, and process for production of process oil
    49.
    发明授权
    Process oil, process for production of deasphalted oil, process for production of extract, and process for production of process oil 失效
    加工油,脱沥青油的生产工艺,生产提取物的方法以及生产工艺油的方法

    公开(公告)号:US08758595B2

    公开(公告)日:2014-06-24

    申请号:US13095936

    申请日:2011-04-28

    IPC分类号: C10G21/00 C10M105/06

    摘要: The present invention is related to a process oil using as a raw material a deasphalted oil obtained by deasphalting a vacuum residual oil of a crude oil and a manufacturing method of the process oil, the process oil having properties of: (a) a polycyclic aromatics (PCA) content of less than 3 mass %; (b) a viscosity (100° C.) of 40 to 70 mm2/s; (c) an aniline point of 85 to 100° C.; (d) a flash point of 250° C. or higher; (e) an aromatic hydrocarbon content of 40 to 55 mass %; and (f) a polar substance content of 10 to 15 mass %. The present invention is also related to a process oil and a manufacturing method of the process oil, the process oil obtained by mixing: an extract obtained by deasphalting and solvent-extracting a vacuum residual oil of a crude oil; and a lubricant base oil having a polycyclic aromatics (PCA) content of less than 3 mass %, and having properties of: (a) a polycyclic aromatics (PCA) content of less than 3 mass %; (i) a viscosity (100° C.) of 30 to 80 mm2/s; (j) an aniline point of 90° C. or lower; (k) a flash point of 240° C. or higher; (l) a benzo(a)pyrene content of 1 mass ppm or less; (m) a specified aromatic compound content of 10 mass ppm or less; and (n) a polar substance content of 10 to 30 mass %.

    摘要翻译: 本发明涉及一种以原油为原料,通过脱油原油的真空残油获得的脱油油和工艺油的制造方法,该工艺油具有以下性质:(a)多环芳烃 (PCA)含量小于3质量%; (b)40至70mm 2 / s的粘度(100℃); (c)苯胺点为85〜100℃。 (d)闪点为250℃以上; (e)40〜55质量%的芳烃含量; 和(f)极性物质含量为10〜15质量%。 本发明还涉及工艺油和工艺油的制造方法,该工艺油通过混合:通过脱沥青获得的提取物和溶剂萃取原油的真空残油; 以及多环芳烃(PCA)含量小于3质量%的润滑油基础油,具有以下性质:(a)多环芳烃(PCA)含量小于3质量%; (i)粘度(100℃)为30〜80mm 2 / s; (j)90℃以下的苯胺点; (k)240℃或更高的闪点; (1)1质量ppm以下的苯并(a)芘含量; (m)10质量ppm以下的规定的芳香族化合物含量; 和(n)极性物质含量为10〜30质量%。

    IRON OXIDE MAGNETIC NANOPARTICLE, ITS PREPARATION AND ITS USE IN DESULFURIZATION
    50.
    发明申请
    IRON OXIDE MAGNETIC NANOPARTICLE, ITS PREPARATION AND ITS USE IN DESULFURIZATION 有权
    氧化铁磁纳米颗粒,其制备及其在脱硫中的应用

    公开(公告)号:US20130126394A1

    公开(公告)日:2013-05-23

    申请号:US13672298

    申请日:2012-11-08

    IPC分类号: B01J20/32 C10G32/02 B01J20/22

    摘要: The present invention provides a method of preparing an iron oxide magnetic nanoparticle, comprising the steps of: i) reacting a water-soluble ferrous salt with a water-soluble ferric salt in a mole ratio of 1:2 in the presence of a base and a citrate to give an iron oxide particle surface-coated with the citrate (c-MNP); ii) reacting the c-MNP obtained in step (i) with a thiophilic compound to give a thiophilic compound-bounded iron oxide particle surface-coated with the citrate (thiophilic-c-MNP); and iii) modifying the thiophilic-c-MNP obtained in step (ii) using a surfactant for phase transfer of the thiophilic-c-MNP from aqueous phase to organic phase. The present invention also relates to the iron oxide magnetic nanoparticle prepared by the above-mentioned method and the use of the nanoparticle in desulfurization. The iron oxide magnetic nanoparticle of the present invention is capable of effective deep desulfurization.

    摘要翻译: 本发明提供一种制备氧化铁磁性纳米颗粒的方法,包括以下步骤:i)在碱存在下使水溶性亚铁盐与摩尔比为1:2的水溶性铁盐与水溶性铁盐反应, 柠檬酸盐,得到表面涂覆有柠檬酸盐(c-MNP)的氧化铁颗粒; ii)使步骤(i)中获得的c-MNP与亲硫化合物反应,得到表面涂覆有柠檬酸(thiophilic-c-MNP)的硫醇化合物结合的氧化铁颗粒; 和iii)使用表面活性剂修饰在步骤(ii)中获得的嗜硫菌素c-MNP,所述表面活性剂将嗜硫菌c-MNP从水相相转移到有机相。 本发明还涉及通过上述方法制备的氧化铁磁性纳米颗粒和在脱硫中使用纳米颗粒。 本发明的氧化铁磁性纳米粒子能够进行有效的深度脱硫。