Surface stabilized active alumina
    41.
    发明授权
    Surface stabilized active alumina 失效
    表面活性氧化铝

    公开(公告)号:US3879310A

    公开(公告)日:1975-04-22

    申请号:US34463073

    申请日:1973-03-26

    CPC classification number: B01J27/16 B01J20/08 B01J37/28 Y10S585/906

    Abstract: Surface stabilized active alumina having significantly increased thermal stability is made by incorporating 1-20%, preferably 218% by weight PO4-ion (calculated on the weight of the calcined composite) in alumina having an essentially pseudoboehmitic structure. The stabilized active alumina retains its surface area and consequently its activity for prolonged periods under high temperature exposure, for example at 900* C without material deterioration.

    Abstract translation: 具有显着增加的热稳定性的表面稳定的活性氧化铝是通过在具有基本上假伯氏体结构的氧化铝中加入1-20%,优选2-18%(重量)煅烧复合物的PO4-离子来制备的。 稳定的活性氧化铝保持其表面积,并因此在高温暴露下延长其活性,例如在900℃下没有物质劣化。

    Catalyst for the preparation of anthraquinone
    42.
    发明授权
    Catalyst for the preparation of anthraquinone 失效
    催化剂制备蒽醌

    公开(公告)号:US3870655A

    公开(公告)日:1975-03-11

    申请号:US32681473

    申请日:1973-01-26

    CPC classification number: B01J23/22

    Abstract: A catalyst for the preparation of anthraquinone by vapor phase oxidation of anthracene with a molecular oxygen-containing gas comprising a catalytic material supported on an inert carrier, said catalytic material comprising 100 parts by weight, calculated as titanium dioxide, of titanium, 1 to 45 parts by weight, calculated as vanadium pentoxide, of vanadium, 0.05 to 15 parts by weight, calculated as oxide thereof, of at least two metal oxides selected from the group consisting of Li2O, Na2O, K2O, Rb2O, Cs2O and Tl2O, 0 to 5 parts by weight, calculated as phosphorus pentoxide, of phosphorus and 0 to 5 parts by weight, calculated as niobium pentoxide, of niobium.

    Abstract translation: 一种催化剂,用于通过含有支撑在惰性载体上的催化材料的含分子氧气体气相氧化蒽来制备蒽醌,所述催化材料包含100重量份(以二氧化钛计)钛,1至45 按五氧化二钒计算的钒,以氧化物计0.05至15重量份的选自Li 2 O,Na 2 O,K 2 O,Rb 2 O,Cs 2 O和T 2 O 2中的至少两种金属氧化物,0至 5重量份,以五氧化二磷计算,为磷,0〜5重量份,以五氧化二铌计,为铌。

    Amorphous hydrocarbon conversion catalysts and process for preparing same
    43.
    发明授权
    Amorphous hydrocarbon conversion catalysts and process for preparing same 失效
    无定形烃转化催化剂及其制备方法

    公开(公告)号:US3867305A

    公开(公告)日:1975-02-18

    申请号:US38215173

    申请日:1973-07-24

    Abstract: Novel amorphous compositions possessing catalytic properties may be prepared by controlled calcination of synthetic crystalline precursor material structurally related to the mineral jarosite, said precursor material being prepared and crystallized from an aqueous reaction mixture having a composition expressed in terms of mole ratios of oxides as

    Abstract translation: 具有催化性质的新型无定形组合物可以通过对结构上与矿物黄钾铁矾相关的合成结晶前体材料的可控煅烧来制备,所述前体材料由具有以氧化物摩尔比表示的组成的水性反应混合物制成并结晶,如G 2 O 。 f Fe2O3。 g L2O3。 我XO4 j H 2 O,其中G表示NH 4 +,H +,Ag +或碱金属离子或其任何混合物,其中L 2 O 3代表选自Al 2 O 3,Cr 2 O 3,V 2 O 3,La 2 O 3和 Ce2O3; XO4表示选自PO4,MoO4,VO4,SiO4和T104中的至少一种氧化物; q具有0.5至6.0的值:f具有1.5至4.0的值; g的值为0到1.0; h的值为8.0〜10.0; 我具有从零到2.0的值:j具有从100到1,000的值:f + g的和具有不超过4.0的值。

    Oxidative dehydrogenation catalyst
    46.
    发明授权

    公开(公告)号:US3790501A

    公开(公告)日:1974-02-05

    申请号:US3790501D

    申请日:1971-05-06

    Inventor: WALKER D

    CPC classification number: B01J23/835 B01J23/84 Y10S585/906

    Abstract: ORGANIC COMPOUNDS ARE DEHYDROGENATED TO COMPOUNDS HAVING A HIGHER DEGREE IF UNSATURATION BY CONTACTING THE FEEDSTOCK IN THE VAPOR PHASE IN THE PRESENCE OF AN OXYGENCONTAINING GAS WITH A CATALYST COMPRISING AT LEAST ONE OF NICKEL, COBALT OR IRON IN ASSOCIATION WITH TIN, PHOSPHORUS AND AN ALKALI METAL. REPRESENTATIVE OF SUCH CONVERSIONS IS THE OXIDATIVE DEHYDROGENATION OF, E.G., BUTANE TO BUTENES AND BUTADIENE. THE CONVERSION PRODUCTS ARE VALUABLE COMPOUNDS PARTICULARLY USEFUL AS INTERMEDIATES FOR THE PREPARATION OF POLYMERIC MATERIALS SUCH AS SYNTHETIC RUBBERS AND THE LIKE.

    Hydrotreating catalyst
    49.
    发明授权
    Hydrotreating catalyst 失效
    氢化催化剂

    公开(公告)号:US3755196A

    公开(公告)日:1973-08-28

    申请号:US3755196D

    申请日:1971-04-01

    Applicant: UNION OIL CO

    Inventor: MICKELSON G

    CPC classification number: C10G49/04 B01J27/19

    Abstract: Highly active catalysts of molybdenum and Group VIII metals are prepared by impregnating a support with highly stable solutions of the active metal compounds and an acid of phosphorus having a P/MoO3 weight ratio of 0.1-0.25 and an initial pH of 1 to about 2.

    Abstract translation: 通过用活性金属化合物的高度稳定的溶液浸渍载体和P / MoO 3重量比为0.1-0.25,初始pH为1至约2的磷的酸制备钼和Ⅷ族金属的高活性催化剂。

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