Hydrogen Generator and Method of Controlling Reaction
    41.
    发明申请
    Hydrogen Generator and Method of Controlling Reaction 审中-公开
    氢发生器和控制反应的方法

    公开(公告)号:US20130344407A1

    公开(公告)日:2013-12-26

    申请号:US13532005

    申请日:2012-06-25

    Applicant: Alvin R. Mick

    Inventor: Alvin R. Mick

    Abstract: A hydrogen generator is provided for generating hydrogen gas for a fuel cell stack. The hydrogen generator includes a reaction area and a reactant storage area for storing a reactant composition for reacting to generate hydrogen gas. The hydrogen generator also includes a high pH solution contained within a solution storage area. Hydrogen gas is discharged through an outlet that passes through a filter to supply gas to the fuel cell. A predetermined quantity of high pH solution is injected into the reaction area to stop the reaction when electrical power is no longer demanded.

    Abstract translation: 提供氢气发生器用于产生用于燃料电池堆的氢气。 氢发生器包括反应区域和反应物储存区域,用于储存用于反应生成氢气的反应物组合物。 氢气发生器还包括溶液储存区域内所含的高pH值溶液。 氢气通过通过过滤器的出口排出以向燃料电池供应气体。 当不再需要电力时,将预定量的高pH值溶液注入反应区域以停止反应。

    Permeation method and apparatus for preparing fluids containing high purity chlorine dioxide
    42.
    发明授权
    Permeation method and apparatus for preparing fluids containing high purity chlorine dioxide 有权
    用于制备含有高纯度二氧化氯的流体的渗透方法和装置

    公开(公告)号:US08512671B2

    公开(公告)日:2013-08-20

    申请号:US12441941

    申请日:2007-09-21

    Abstract: Method to prepare fluids (liquids and gases) containing pure chlorine dioxide which is not contaminated by the starting materials or the byproducts of the chlorine dioxide synthesis or to deliver pure chlorine dioxide into any medium capable of dissolving chlorine dioxide, wherein the chlorine dioxide generated in the process is transported across a pore free polymeric membrane via selective permeation into the target medium. Apparatus to realize the said method, wherein the generation of chlorine dioxide is carried out in such a reactor where some or all walls comprising the reactor, or the walls of a permeator unit attached to the reactor, are made of the said pore free polymer, characteristically some kind of silicone rubber, which is highly permeable to chlorine dioxide, but which is practically impermeable for the acidic and corrosive reagents used for the chlorine dioxide synthesis, its permeability being at least 3 orders of magnitude lower for these contaminating components compared to that of chlorine dioxide. The invention can be realized both by batch and by continuous reactors.

    Abstract translation: 制备含有纯二氧化氯的流体(液体和气体)的方法,其不被二氧化氯合成的原料或副产物污染,或将纯二氧化氯输送到任何能够溶解二氧化氯的介质中,其中二氧化氯 该过程通过选择性渗透到目标介质中而通过无孔的聚合物膜传送。 实现所述方法的装置,其中二氧化氯的产生在这样的反应器中进行,其中包括反应器的一些或所有壁或连接到反应器的渗透器单元的壁由所述无孔聚合物制成, 特点是某种硅氧烷,其对二氧化氯是高度可渗透的,但对于用于二氧化氯合成的酸性和腐蚀性试剂实际上是不可渗透的,与其相比,这些污染成分的渗透性低至少3个数量级 的二氧化氯。 本发明可以通过批量和连续反应器实现。

    MEMBRANE STRUCTURES SUITABLE FOR GAS SEPARATION, AND RELATED PROCESSES
    43.
    发明申请
    MEMBRANE STRUCTURES SUITABLE FOR GAS SEPARATION, AND RELATED PROCESSES 审中-公开
    适用于气体分离的膜结构及相关工艺

    公开(公告)号:US20130022510A1

    公开(公告)日:2013-01-24

    申请号:US13630807

    申请日:2012-09-28

    Abstract: A method for fabricating a high-density zeolite membrane structure is described. The method includes the step of combining (i) a mineral zeolite material; (ii) at least one cement precursor; and (iii) an organic binder, with an aqueous component, to form an aqueous composite zeolite composition. The zeolite composition is then applied on a surface of a scaffold formed from a porous, metal oxide material. The zeolite composition is dried, and then heated under conditions to form a metal oxide-zeolite composite layer. This layer is exposed to a phosphate composition, under conditions sufficient to reduce the porosity to a level no greater than about 10%. A high-density zeolite cement composite membrane structure results. Related methods for separating hydrogen from a fluid stream, using the membrane structure, are also disclosed.

    Abstract translation: 描述了一种制造高密度沸石膜结构的方法。 该方法包括以下步骤:(i)矿物沸石材料; (ii)至少一种水泥前体; 和(iii)具有水性组分的有机粘合剂,以形成水性复合沸石组合物。 然后将沸石组合物施加在由多孔金属氧化物材料形成的支架的表面上。 将沸石组合物干燥,然后在条件下加热以形成金属氧化物 - 沸石复合层。 在足以将孔隙率降低到不超过约10%的水平的条件下,将该层暴露于磷酸盐组合物。 高密度沸石水泥复合膜结构的结果。 还公开了使用膜结构从流体流分离氢的相关方法。

    HYDROGEN GENERATING DEVICE
    45.
    发明申请
    HYDROGEN GENERATING DEVICE 有权
    氢气发生装置

    公开(公告)号:US20120141335A1

    公开(公告)日:2012-06-07

    申请号:US13187531

    申请日:2011-07-21

    Abstract: A hydrogen generating device is adapted for a fuel cell. The hydrogen generating device includes a casing, a button, a solid reactant, a bag-shaped body, and at least one flexible element. The casing has a containing space and an opening. The button is integrally formed and connected to the casing to seal the opening. The solid reactant is disposed in the casing. The bag-shaped body is disposed in the casing and contains a liquid reactant. The flexible element is connected to the casing and is located in the containing space. The flexible element includes a bending end, wherein the flexible element is aligned to the button and is located between the button and the bag-shaped body. When the button is pressed, the button pushes the flexible element so the bending end pierces the bag-shaped body, and the liquid reactant flows out and reacts with the solid reactant to generate hydrogen.

    Abstract translation: 氢气发生装置适用于燃料电池。 氢生成装置包括壳体,按钮,固体反应物,袋状体以及至少一个柔性元件。 壳体具有容纳空间和开口。 按钮整体形成并连接到壳体以密封开口。 固体反应物设置在壳体中。 袋形体设置在壳体中并含有液体反应物。 柔性元件连接到壳体并且位于容纳空间中。 柔性元件包括弯曲端,其中柔性元件与按钮对准并且位于按钮和袋状体之间。 当按钮被按下时,按钮推动柔性元件,使得弯曲端刺穿袋状体,并且液体反应物流出并与固体反应物反应产生氢气。

    DESTRUCTION OF AMMONIUM IONS
    46.
    发明申请
    DESTRUCTION OF AMMONIUM IONS 审中-公开
    破坏氨离子

    公开(公告)号:US20120128569A1

    公开(公告)日:2012-05-24

    申请号:US13122573

    申请日:2009-10-07

    CPC classification number: C01B21/02 C01B21/1418

    Abstract: The invention relates to a process for converting ammonium formed in a hydroxylamine phosphate oxime process into molecular nitrogen in an ammonium destruction zone, comprising—preparing a vapour stream comprising nitrogen oxide from ammonia, in an ammonia combustion zone;—bringing into contact by feeding to the ammonium destruction zone, individually and/or as pre-mixed combinations, at least part of said vapour stream, and a first liquid stream, comprising ammonium formed in the hydroxylamine phosphate oxime process, and a second liquid stream, comprising at least one acid selected from nitric acid and nitrous acid in a total nitric+nitrous acid concentration of at least 30 wt. %, thereby forming in the ammonium destruction zone a fluid mixture; and—reacting ammonium ions in the fluid mixture with nitrogen oxide under formation of molecular nitrogen, in the ammonium destruction zone. The invention further relates to an installation for converting ammonium formed in a hydroxylamine phosphate oxime process.

    Abstract translation: 本发明涉及将在磷酸羟胺肟工艺中形成的铵转化为铵破坏区中的分子氮的方法,其包括:在氨燃烧区中由氨制备包含氮氧化物的蒸气流; - 通过进料至 所述铵破坏区,单独地和/或作为预混合组合,至少部分所述蒸气流,以及包含在磷酸羟胺肟方法中形成的铵的第一液体流,和包含至少一种酸 选自硝酸和亚硝酸,总硝酸+亚硝酸浓度至少为30wt。 %,从而在铵破坏区中形成流体混合物; 在铵破坏区中,在分子氮形成下,将流体混合物中的铵离子与氮氧化物反应。 本发明还涉及一种用于转化在磷酸羟胺肟工艺中形成的铵的装置。

    LIQUID-GAS PHASE REACTOR SYSTEM
    50.
    发明申请
    LIQUID-GAS PHASE REACTOR SYSTEM 审中-公开
    液相气相反应器系统

    公开(公告)号:US20110144384A1

    公开(公告)日:2011-06-16

    申请号:US12442117

    申请日:2007-09-20

    Abstract: A liquid-gas phase reactor system including a slinger located in an upper section (headspace region) of a reaction vessel. The slinger comprises an upper horizontal surface including a plurality of vertically raised vanes extending radially outward along a curved path which effectively distribute liquid about the reactor vessel. A method for conducting an oxidation reaction using a liquid-gas phase reactor system is also disclosed. The disclosed reactor system and method have a broad range of applications but are particularly suited for the production of terephthalic acid.

    Abstract translation: 一种液 - 气相反应器系统,包括位于反应容器的上部(顶部空间区域)中的抛油环。 抛油环包括上水平表面,其包括沿着弯曲路径径向向外延伸的多个垂直凸起的叶片,其有效地分布在反应器容器周围的液体。 还公开了使用液 - 气相反应器系统进行氧化反应的方法。 所公开的反应器系统和方法具有广泛的应用,但特别适合于生产对苯二甲酸。

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