Method for the preparation of rhodium containing solutions
    51.
    发明申请
    Method for the preparation of rhodium containing solutions 审中-公开
    制备含铑溶液的方法

    公开(公告)号:US20010043895A1

    公开(公告)日:2001-11-22

    申请号:US09853911

    申请日:2001-05-11

    Inventor: Niels C. Schiodt

    CPC classification number: B01J38/48 B01J27/32 C07C51/12 Y02P20/584 C07C53/08

    Abstract: A method for generating a solution containing rhodium at a concentration of at least 0.01 M and preferably at least 0.20 M, comprising treating solid rhodium iodide or other solid source of rhodium with a reducing agent selected from a source of hydrazine, hydrazine hydrate, hydrazinium salts, organic derivatives of hydrazine, hypophosphorous acid and salts of hypophosphorous acid.

    Abstract translation: 一种产生浓度为至少0.01M,优选至少0.20M的铑的溶液的方法,包括用选自肼,水合肼,腙盐的还原剂处理固体碘化铑或其它固体铑源 ,肼的有机衍生物,次磷酸和次磷酸的盐。

    HIGH TAP DENSITY LITHIUM POSITIVE ELECTRODE ACTIVE MATERIAL, INTERMEDIATE AND PROCESS OF PREPARATION

    公开(公告)号:US20190006668A1

    公开(公告)日:2019-01-03

    申请号:US15753664

    申请日:2016-08-24

    Abstract: A lithium positive electrode active material intermediate comprising less than 80 wt % spinel phase and a net chemical composition of LixNiyMn2-yO4-δ wherein 0.9≤x≤1.1; 0.4≤y≤0.5; and 0.1≤δ; where the lithium positive electrode active material intermediate has been heat treated in a reducing atmosphere at a temperature of from 300° C. to 1200° C. A process for the preparation of a lithium positive electrode active material with high tap density for a high voltage secondary battery where the cathode is fully or partially operated above 4.4 V vs. Li/Li+, comprising the steps of a) heating a precursor in a reducing atmosphere at a temperature of from 300° C. to 1200° C. to obtain a lithium positive electrode active material intermediate; b) heating the product of step a. in a non-reducing atmosphere at a temperature of from 300° C. to 1200° C.

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