SELECTIVITY OF BORON HARD MASKS USING ION IMPLANT

    公开(公告)号:US20250140566A1

    公开(公告)日:2025-05-01

    申请号:US18495493

    申请日:2023-10-26

    Abstract: Thicker hardmasks are typically needed for etching deeper capacitor holes in a DRAM structure. Instead of increasing the hardmask thickness, hardmasks may instead be formed with an increased etch selectivity relative to the underlying semiconductor structure. For example, boron-based hardmasks may be formed that include a relatively high percentage of boron (e.g., greater than 90%). The etch selectivity of the hardmask may be improved by performing an ion implant process using different types of ions. The ion implant may take place before or after opening the hardmask with the pattern for the DRAM capacitor holes. Some designs may also tilt the semiconductor substrate relative to the ion implant process and rotate the substrate to provide greater ion penetration throughout a depth of the openings in the hardmask.

    BORON CONCENTRATION TUNABILITY IN BORON-SILICON FILMS

    公开(公告)号:US20250112046A1

    公开(公告)日:2025-04-03

    申请号:US18980163

    申请日:2024-12-13

    Abstract: Exemplary semiconductor processing methods may include flowing a silicon-containing precursor into a substrate processing region of a semiconductor processing chamber. The methods may include flowing a boron-containing precursor into the substrate processing region of the semiconductor processing chamber. The methods may include depositing a boron-and-silicon-containing layer on a substrate in the substrate processing region of the semiconductor processing chamber. The boron-and-silicon-containing layer may be characterized by an increasing ratio of boron-to-silicon from a first surface in contact with the substrate to a second surface of the boron-and-silicon-containing layer opposite the first surface. A flow rate of the boron-containing precursor may be increased during the deposition of the boron-and-silicon-containing layer.

    RF PULSING ASSISTED TUNGSTEN-CONTAINING FILM DEPOSITION

    公开(公告)号:US20240332003A1

    公开(公告)日:2024-10-03

    申请号:US18128049

    申请日:2023-03-29

    Abstract: Exemplary semiconductor processing methods may include providing one or more deposition precursors to a processing region of a semiconductor processing chamber, the deposition precursors may be or include a tungsten-containing precursor. A substrate may be disposed within the processing region of the semiconductor processing chamber. The methods may include forming a plasma of the one or more deposition precursors in the processing region. The plasma may be at least partially formed by an RF power operating at less than or about 3,000 W and at a pulsing frequency less than or about 100,000 Hz. The methods may include forming a layer of material on the substrate. The layer of material may be or include a tungsten-containing material.

    Metal-doped boron films
    55.
    发明授权

    公开(公告)号:US12077852B2

    公开(公告)日:2024-09-03

    申请号:US17240395

    申请日:2021-04-26

    CPC classification number: C23C16/042 C23C16/18 C23C16/402 C23C22/77 C23C22/82

    Abstract: Exemplary deposition methods may include delivering a boron-containing precursor to a processing region of a semiconductor processing chamber. The methods may include delivering a dopant-containing precursor with the boron-containing precursor. The dopant-containing precursor may include a metal. The methods may include forming a plasma of all precursors within the processing region of the semiconductor processing chamber. The methods may include depositing a doped-boron material on a substrate disposed within the processing region of the semiconductor processing chamber. The doped-boron material may include greater than or about 80 at. % of boron in the doped-boron material.

    Processes for depositing sib films
    56.
    发明授权

    公开(公告)号:US12033848B2

    公开(公告)日:2024-07-09

    申请号:US17352039

    申请日:2021-06-18

    CPC classification number: H01L21/02123 H01L21/02211 H01L21/02271

    Abstract: Embodiments of the present disclosure generally relate to processes for forming silicon- and boron-containing films for use in, e.g., spacer-defined patterning applications. In an embodiment, a spacer-defined patterning process is provided. The process includes disposing a substrate in a processing volume of a processing chamber, the substrate having patterned features formed thereon, and flowing a first process gas into the processing volume, the first process gas comprising a silicon-containing species, the silicon-containing species having a higher molecular weight than SiH4. The process further includes flowing a second process gas into the processing volume, the second process gas comprising a boron-containing species, and depositing, under deposition conditions, a conformal film on the patterned features, the conformal film comprising silicon and boron.

    Plasma enhanced deposition of silicon-containing films at low temperature

    公开(公告)号:US11640905B2

    公开(公告)日:2023-05-02

    申请号:US17125349

    申请日:2020-12-17

    Abstract: Exemplary deposition methods may include flowing a silicon-containing precursor into a processing region of a semiconductor processing chamber. The method may include striking a plasma in the processing region between a faceplate and a pedestal of the semiconductor processing chamber. The pedestal may support a substrate including a patterned photoresist. The method may include maintaining a temperature of the substrate less than or about 200° C. The method may also include depositing a silicon-containing film along the patterned photoresist.

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