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    Process for the acylation of aromatic ethers
    52.
    发明授权
    Process for the acylation of aromatic ethers 失效
    芳香醚酰化的方法

    公开(公告)号：US6013840A

    公开(公告)日：2000-01-11

    申请号：US765533

    申请日：1997-01-09

    申请人： Michel Spagnol ,  Laurent Gilbert ,  Eric Benazzi ,  Christian Marcilly

    发明人： Michel Spagnol ,  Laurent Gilbert ,  Eric Benazzi ,  Christian Marcilly

    IPC分类号： B01J29/08 ,  C07C45/46 ,  C07C49/84 ,  C07C205/04 ,  C07C211/09 ,  C07C231/12 ,  C07C235/32 ,  C07C253/30 ,  C07C255/40 ,  C07C45/00

    CPC分类号： B01J29/084 ,  C07C45/46

    摘要： The present invention concerns a process for the acylation of an aromatic ether.Preferably the invention relates to a process for the acylation of a substituted aromatic ether, in particular veratrol.The acylation process of the invention consists of reacting the ether with an acylation agent in the presence of a zeolitic catalyst, and is characterized in that the acylation reaction is carried out in the presence of an effective quantity of a catalyst comprising a faujasite type zeolite or a Y zeolite with the following physico-chemical characteristics:an atomic ratio denoted "global Si/Me.sup.1 " between the number of atoms of the element silicon and the number of atoms of every trivalent element Me.sup.1 contained in the zeolite in the range 2.4 to 90, preferably in the range 2.4 to 75, and more preferably in the range 2.4 to 60;an Me.sup.2 alkali metal content such that the atomic ratio Me.sup.2 /Me.sup.1(IV) between the number of atoms of alkali metal Me.sup.2 and the number of atoms of every trivalent element Me.sup.1(IV) included in the zeolitic network is less than 0.2, preferably less than 0.1, and more preferably less than 0.05.

    摘要翻译： PCT No.PCT / FR96 / 00716 Sec。 371日期1997年1月9日 102（e）日期1997年1月9日PCT提交1996年5月10日PCT公布。 出版物WO96 / 35655 日期：1996年11月14日本发明涉及一种酰化芳族醚的方法。 优选地，本发明涉及酰化取代的芳族醚，特别是藜芦醇的方法。 本发明的酰化方法包括在沸石催化剂存在下使醚与酰化剂反应，其特征在于酰化反应在有效量的含有八面沸石型沸石的催化剂或 具有以下物理化学特性的Y沸石：在元素硅的原子数与沸石中所含的每个三价元素Me1的原子数在2.4至90之间的原子比表示为“全局Si / Me1” ，优选在2.4至75范围内，更优选在2.4至60范围内; Me2碱金属含量使得碱金属Me2的原子数与沸石网络中包含的每个三价元素Me1（IV）的原子数之间的原子比Me2 / Me1（IV）小于0.2，优选较少 小于0.1，更优选小于0.05。

    Catalyst comprising a trioctahedral 2:1 phyllosilicate prepared in a fluoride medium and a process for the hydroconversion of petroleum feeds
    54.
    发明授权
    Catalyst comprising a trioctahedral 2:1 phyllosilicate prepared in a fluoride medium and a process for the hydroconversion of petroleum feeds 失效
    包含在氟化物介质中制备的三八面体2:1页硅酸盐和用于石油进料加氢转化的方法的催化剂

    公开(公告)号：US5961816A

    公开(公告)日：1999-10-05

    申请号：US813587

    申请日：1997-03-07

    申请人： Eric Benazzi ,  Samuel Mignard

    发明人： Eric Benazzi ,  Samuel Mignard

    IPC分类号： B01J29/08 ,  C10G47/12 ,  C10G47/18 ,  B01J21/16

    CPC分类号： B01J29/084 ,  C10G47/12 ,  B01J2229/42

    摘要： A catalyst comprising at least one catalytic element, and a support comprising 20-99% by weight of at least one matrix, 1-80% by weight of at least one 2:1 trioctahedral phyllosilicate containing fluorine and 0-30% by weight of at least one Y zeolite, in which the catalytic element is from groups VI and/or VIII, and phosphorous can be present, as well as a process for the hydroconversion of petroleum with said catalyst.

    摘要翻译： 包含至少一种催化元素的催化剂和包含20-99重量％的至少一种基质，1-80重量％至少一种含氟的三氧八面体页硅酸盐的含量为1-30重量％的载体和0-30重量％ 至少一种Y沸石，其中催化元素来自基团VI和/或VIII，并且可以存在磷，以及用所述催化剂加氢转化石油的方法。

    Process for skeletal isomerization of linear olefins using a pretreated molecular sieve, and a catalyst containing a pretreated sieve
    55.
    发明授权
    Process for skeletal isomerization of linear olefins using a pretreated molecular sieve, and a catalyst containing a pretreated sieve 失效
    使用预处理分子筛的线性烯烃的骨架异构化方法和含有预处理筛的催化剂的方法

    公开(公告)号：US5817907A

    公开(公告)日：1998-10-06

    申请号：US642191

    申请日：1996-05-06

    申请人： Eric Benazzi ,  Michel Guisnet ,  Christine Travers ,  Ngi Suor Gnep ,  Patricia Andy

    发明人： Eric Benazzi ,  Michel Guisnet ,  Christine Travers ,  Ngi Suor Gnep ,  Patricia Andy

    IPC分类号： B01J29/06 ,  B01J29/70 ,  B01J29/85 ,  B01J37/08 ,  C07B61/00 ,  C07C5/27 ,  C07C11/02

    CPC分类号： B01J29/65 ,  B01J29/7046 ,  B01J29/85 ,  C07C5/2775 ,  B01J2229/12 ,  B01J2229/34 ,  B01J37/084 ,  C07C2529/18 ,  C07C2529/65 ,  C07C2529/70 ,  C07C2529/85

    摘要： The invention concerns a process for skeletal isomerization of linear olefins using a catalyst containing at least one pre-treated molecular sieve selected from the group formed by SAPO-31, SAPO-11, Theta-1, EU-1, omega zeolite, mordenite, Nu-10, Nu-86, Nu-87, ferrierite, ZSM-12 and ZSM-23. The pre-treatment process consists in bringing the molecular sieve, which has a pore size of 0.4 to 0.8 nm, into contact with at least one hydrocarbon molecule containing 4 to 20 carbon atoms, at a space velocity of 0.1-45 h.sup.-1, a temperature of 300.degree.-550.degree. C. and at a pressure of 0.1-1 MPa, for 0.5-48 h, to deposit coke in the pores. The process is of particular application to one-dimensional sieves. It is preferably carried out outside the reaction zone. The invention also concerns a catalyst containing a pre-treated sieve, the sieve being selected from SAPO-31, SAPO-11, Theta-1, EU-1, omega zeolite, mordenite, ferrierite, Nu-10, Nu-86 and Nu-87.

    摘要翻译： 本发明涉及一种使用含有至少一种选自SAPO-31，SAPO-11，Theta-1，EU-1，ω-沸石，丝光沸石形成的组的预处理分子筛的催化剂的线性烯烃骨架异构化方法。 Nu-10，Nu-86，Nu-87，镁碱沸石，ZSM-12和ZSM-23。 预处理过程包括使孔径为0.4至0.8nm的分子筛与至少一种含有4-20个碳原子的烃分子以0.1-45h -1的空间速度接触， 温度为300〜-550℃，压力为0.1〜1MPa，时间为0.5〜48h，将焦炭沉积在孔中。 该过程特别适用于一维筛。 优选在反应区外进行。 本发明还涉及含有预处理筛的催化剂，该筛选自SAPO-31，SAPO-11，Theta-1，EU-1，ω-沸石，丝光沸石，镁碱沸石，Nu-10，Nu-86和Nu -87。

    Process for the acylation of aromatic ethers
    56.
    发明授权
    Process for the acylation of aromatic ethers 失效
    芳香醚酰化的方法

    公开(公告)号：US5817878A

    公开(公告)日：1998-10-06

    申请号：US765537

    申请日：1997-01-09

    申请人： Michel Spagnol ,  Laurent Gilbert ,  Eric Benazzi ,  Christian Marcilly

    发明人： Michel Spagnol ,  Laurent Gilbert ,  Eric Benazzi ,  Christian Marcilly

    IPC分类号： B01J29/70 ,  B01J29/04 ,  C07C45/46 ,  C07C49/84 ,  C07C205/04 ,  C07C211/09 ,  C07C231/12 ,  C07C235/32 ,  C07C253/30 ,  C07C255/40 ,  C07C45/45

    CPC分类号： B01J29/04 ,  C07C45/46

    摘要： The present invention concerns a process for the acylation of an aromatic ether. Preferably, the invention relates to a process for the acylation of an unsubstituted aromatic ether, in particular anisole. The acylation process of the invention consists of reacting the ether with an acylation agent in the presence of a zeolitic catalyst, and is characterized in that the acylation reaction is carried out in the presence of an effective quantity of a catalyst comprising a beta zeolite with an atomic ratio denoted "global Si/Me.sup.1 " between the number of atoms of the element silicon and the number of atoms of every trivalent element Me.sup.1 contained in the zeolite of no less than 15, preferably in the range 15 to 55, and more preferably in the range 18 to 35.

    摘要翻译： PCT No.PCT / FR96 / 00717 Sec。 371日期1997年1月9日 102（e）日期1997年1月9日PCT提交1996年5月10日PCT公布。 WO96 / 35656PC PCT出版物 日期：1996年11月14日本发明涉及一种酰化芳族醚的方法。 优选地，本发明涉及酰化未取代芳族醚，特别是苯甲醚的方法。 本发明的酰化方法包括在沸石催化剂存在下使醚与酰化剂反应，其特征在于酰化反应在有效量的包含β沸石的催化剂存在下进行， 原子比在元素硅的原子数与沸石中所含的每个三价元素Me1的原子数之间的“全局Si / Me1”表示为不小于15，优选在15至55的范围内，更优选在 范围18到35。

    Process for the synthesis of zeolites and mesoporous solids from a homogeneous solution in a semi-open system
    57.
    发明授权
    Process for the synthesis of zeolites and mesoporous solids from a homogeneous solution in a semi-open system 失效
    在半开放系统中从均相溶液合成沸石和介孔固体的方法

    公开(公告)号：US5695735A

    公开(公告)日：1997-12-09

    申请号：US565399

    申请日：1995-11-30

    申请人： Eric Benazzi ,  Pierre-Yves Legoff ,  Philippe Caullet ,  Jean-Louis Guth

    发明人： Eric Benazzi ,  Pierre-Yves Legoff ,  Philippe Caullet ,  Jean-Louis Guth

    IPC分类号： C01B37/02 ,  C01B39/02 ,  C01B39/04 ,  C01B39/24 ,  C01B39/30 ,  C01B39/38 ,  C01B39/40 ,  C01B39/48

    CPC分类号： C01B39/02 ,  C01B37/02 ,  C01B39/04 ,  C01B39/24 ,  C01B39/305 ,  C01B39/40 ,  C01B39/48 ,  Y10S423/21 ,  Y10S423/22 ,  Y10S423/27 ,  Y10S423/32 ,  Y10S423/38

    摘要： The invention concerns a process for the synthesis of zeolites based on element(s) T and mesoporous solids based on element(s) T, T being silicon and/or aluminium, comprising the following sequence of steps: i) synthesizing a reaction medium which is a homogeneous source of element(s) T containing: a) at least one source of element(s) T selected from the group formed by aqueous basic solutions of silica or silica and alumina and alcoholic solutions of alkyl tetraorthosilicate and trialkoxyaluminium; b) optionally, at least one structuring agent; c) optionally, seeds of the desired crystalline phase; ii) heating the reaction medium to a temperature in the range 20.degree. C. to 220.degree. C. for a period in the range several minutes and several days; iii) injecting at least one chemical agent at a controlled rate to generate polycondensable species in said medium.

    摘要翻译： 本发明涉及一种基于元素T和介孔固体的基于元素T，T为硅和/或铝的合成沸石的方法，其包括以下步骤顺序：i）合成反应介质，其中 是元素T的均匀源，其含有：a）选自由二氧化硅或二氧化硅和氧化铝的碱性水溶液形成的基团中的至少一种元素T，以及四原硅酸烷基酯和三烷氧基铝的烷基醇溶液; b）任选地，至少一种结构剂; c）任选地，所需结晶相的种子; ii）将反应介质加热至20℃至220℃的温度，持续数分钟和数天的时间; iii）以受控的速率注射至少一种化学试剂以在所述介质中产生可缩聚物质。