摘要:
A graft copolymer for use as an adhesive for drug delivery patches or dressings that is resistant to dissolution in the presence of skin penetration enhancers comprises copolymerized acrylic and, optionally, vinyl monomers, to form a backbone polymer, to which are grafted polymeric moieties that do not absorb greater than 3% by weight of a skin-penetration enhancer under thermodynamic equilibrium at 25.degree. C. if independently introduced into an excess of the enhancer. Preferably, the grafted polymers are selected from the classes of polybutylene, polysaccharide, poly(ethyleneoxide/propyleneoxide), and polyamide polymers, and specific grafted polymers will depend on the specific enhancers used in a particular drug delivery system.
摘要:
The present invention relates to antistatic and adherent compositions based on polyamide, which can be employed especially for the manufacture of composite materials and articles, such as multilayer pipes and/or conduits for conveying and/or storing hydrocarbons. The compositions contain carbon black and are employed for the production of pipes, containers and drums including:an inner layer in contact with the hydrocarbons, based on the said antistatic and adherent composition,a middle layer made of fluoropolymer, preferably of polyvinylidene fluoride, andan outer layer of polyamide,these layers being bonded to each other respectively by layers of adhesive binder. The invention also relates to a process for preparing these items.
摘要:
A multi-cycle refastenable contact responsive non-tacky fastener system and method of use with a field of a contact responsive fastening layer having essentially no surface tack. The fastening layer is multiply releasable and refastenable against a non-tacky target surface, and has substantially constant 90.degree. peel strength of less than about 5 kN/m when in contact with the target surface. A mounting layer comprises a field of a pressure sensitive adhesive onto which the field of the contact responsive layer is directly attached.
摘要:
A polymeric composition in pellet form comprising a tacky hot melt composition, comprising a) from about 5% by weight to about 90% by weight of a thermoplastic polymer, b) from about 0% by weight to about 65% by weight of a tackifying resin, c) from about 0% to about 50% by weight of a plasticizer, d) up to about 2% by weight of an antioxidant, and a pelletizing aid, wherein the tacky hot melt composition has some minimum amount of tackifier or plasticizer and is a pressure sensitive adhesive having a storage modulus, G', at about 25.degree. C., of less than about 5.times.10.sup.6 dynes/cm.sup.2, and each pellet has a substantially tack-free surface.This invention further discloses a polymeric composition in pellet form suitable for molding articles. The composition comprises a tacky hot melt composition comprising at least one high molecular weight triblock copolymer of the general configuration A-B-A and a plasticizer and a pelletizing aid. The pelletizing aid substantially surrounds the tacky composition such that the molded articles are substantially free from surface tack.A method of forming the pellets is also disclosed.
摘要:
An adhesive for bonding together a first substrate made of vinylidene fluoride resin and a second substrate comprises an elastic fluorohydrocarbon resin, a polyisocyanate, and an organic solvent. This elastic fluorohydrocarbon resin is obtained by graft copolymerization of a fluorine-containing copolymer with a vinylidene fluoride monomer. This copolymer is prepared by copolymerizing at least one first fluorine-containing monomer with at least one unsaturated monomer that has peroxy bond. The adhesive itself is superior in durability, and bond strength between the first and second substrates is also superior.
摘要:
The invention concerns a dispersion powder composition which is redispersible in water and is made from water-insoluble homopolymers or copolymers of preferably ethylenically unsaturated monomers and one or more organosilicon compounds plus, optionally, other additives such as protective colloids and anti-blocking agents. The composition is obtained by: a) polymerizing one or more monomers in the presence of 0.1 to 30% by wt., relative to the total weight of the monomers, of one or more silicon compounds which are dispersible in water and which have a boiling point at normal pressure of >160.degree. C., selected from the group comprising the silanes, polysilanes, oligosiloxanes, polysiloxanes, carbosilanes, polycarbosilanes, carbosiloxanes, polycarbosiloxanes and polysilylenedisiloxanes and: b) spray-drying the product thus obtained, either before or after addition of the additives mentioned.
摘要:
An aqueous polymer emulsion is obtained by polymerizing first a monomer composition 1 in a first polymerization stage and then a monomer composition 2 in a polymerization stage 2, in each case by the free radical aqueous emulsion polymerization method, one of the two monomer compositions essentially comprising hard monomers and the other monomer composition essentially comprising soft monomers, and, in addition to the monomer compositions 1 and 2, nitrogen-containing adhesion-promoting monomers being polymerized, at least 20 mol % of the total amount of the adhesion-promoting monomers being polymerized in polymerization stage 1.
摘要:
The invention relates to an aqueous resin composition characterized by comprising 80 to 10 parts by weight of modified polyolefin with weight average molecular weight of 1000 to 100000, modified by copolymerizing polypropylene, polyethylene, copolymer of propylene or ethylene with .alpha.-olefin or degradation products of these under heat or with oxidizing agent, radical-generating agent or the like, with 0.1 to 20% by weight of one kind or not less than two kinds of acid anhydride, carboxylic acid or alcohol with radically polymerizable double bond, and 20 to 90 parts by weight of one kind or a mixture of two or more kinds of acrylic or methacrylic monomers, mixed or dissolved and polymerized in water in the presence of surfactant and polymerization initiator. And, the aqueous resin composition of the invention not only shows excellent adhesion to polyolefin, but also has adherence to other organic substrates and inorganic substrates. In addition, because of little organic solvent contained, it is excellent in the aspects of safety and hygiene and environmental pollution.
摘要:
The invention relates to core/shell copolymer dispersions whose shell comprises hydrolyzable organosilicon comonomers, the shell consisting of a copolymer comprising, a) from 70 to 95% by weight of acrylic and/or methacrylic C.sub.1 to C.sub.10 alkyl esters of which from 20 to 80% by weight, based on the overall weight of a), have a water-solubility of not more than 2 g/l and from 80 to 20% by weight, based on the overall weight of a), have a water-solubility of at least 10 g/l, b) from 5 to 25% by weight of one or more ethylenically unsaturated, functional and water-soluble monomers including a proportion of from 25 to 100% by weight, based on the overall weight of b), of unsaturated carboxylic acids, and c) from 0.01 to 10% by weight of one or more olefinically unsaturated, hydrolyzable silicon compounds of the general formula R.sup.1 --Si(OR.sup.2).sub.3, and whose core, making up a proportion of from 75 to 98% by weight of the overall weight of the core/shell copolymer, consists of a polymer comprising d) one or more comonomers from the group consisting of vinyl esters, acrylic and/or methacrylic esters, vinyl chloride, vinylaromatic compounds and ethylene.
摘要:
A novel high performance pressure sensitive adhesive composition is provided comprised of a phase separated graft copolymer comprised of a polymerized acrylic or methacrylic acid ester backbone having grafted thereon pendant polymeric moieties such as polystyrene or poly-alpha-methylstyrene. The composition is non-corrosive and has a low volatile content.