摘要:
The polymerization process is carried out starting from a monomer that is introduced via pipe (1) and a comonomer that is introduced via pipe (2); the comonomer that is used, which is an alpha-olefin, is introduced into polymerization reactor P in the form of an approximately pure compound. The polymerization effluent is then separated in separator S1 into two fractions: a heavy fraction that is evacuated via pipe (5) and that contains at least one polymer, and a light fraction that is evacuated via pipe (4) and that comprises the monomer that has not reacted, the comonomer that has not reacted, as well as isomers of this comonomer. At least a portion of the light fraction is then treated during an ethenolysis stage E in the presence of an addition of fresh ethylene that is introduced via line (9). The effluent that is produced in the ethenolysis stage is subjected to at least two separations in separation train S2. After the fraction that contains the light olefins and the fraction that contains the heavy compounds have been separated, the fraction that comprises the comonomer is recycled via pipe (10) toward polymerization zone P.
摘要:
The present invention relates to a process for the production of olefins from a hydrocarbon cut, comprising a step for separating at least one paraffin contained in the hydrocarbon cut, a step for dehydrogenating the paraffin and a step for purifying the hydrogen produced during dehydrogenation, at least a part of that hydrogen being recycled to the dehydrogenation step. The invention is of particular application to the preparation of olefins containing 3 to 5 carbon atoms per molecule from a C.sub.3 to C.sub.5 hydrocarbon cut containing at least one paraffin.
摘要:
The simultaneous production of an olefin-free, tert.amyl alkyl, ether-rich fraction an n-pentane-rich paraffin fraction, wherein a charge based on isopentenes is hydrogenated (1) under appropriate conditions to bring about a distribution of the methyl butenes close to thermodynamic equilibrium and then the hydrogenation effluent is treated in an etherification zone (2).
摘要:
A reaction-distillation apparatus is provided comprising at least one reaction-distillation zone including at least one bed of solid elements disposed on a fluid-permeable perforated support having perforations small enough to retain the elements wherein the bed of solid elements includes loose solid catalytic particles and at least one receptacle, containing at least one distillation packing body, the external jacket of which is permeable to fluids and the impermeable to the solid catalytic particles and packing body. The apparatus can be used for carrying out chemical reaction and concomitant fractionation of the reaction mixture, for example, to synthesize ethers from olefins and alcohols.
摘要:
Manufacture of catalysts containing at least three essential metals consisting of copper, zinc and aluminum.The process for manufacturing the catalyst comprises the formation of homogeneous amorphous precipitate of the above-mentioned metals, followed with a washing in two steps, first with water, then with an acid solution.These catalysts are used in balanced reactions involving alcohols and synthesis gas, particularly in methanol synthesis.
摘要:
Process for manufacturing chlorolactones by reacting, within an ahydrous organic solvent, a metal N-chlorosulfonamidate of the formula ##STR1## wherein R is a hydrogen or halogen atom or an alkyl radical, Ar is a mono- or polycyclic divalent aromatic radical and M is an alkali metal, with a substantially stoichiometrical proportion of an aliphatic or alicyclic carboxylic acid having at least one double bond separated from the COOH group by at least 2 carbon atoms, in the presence of a substantially stoichiometrical amount of a strong acid whose conjugate base is weakly nucleophilic.
摘要:
An improved catalytic composition for oligomerization, in particular dimerization, of monoolefins comprises the product resulting from bringing the following three constituents into contact in any order: a) at least one divalent nickel compound; b) at least one hydrocarbylaluminium dihalide, optionally enriched with an aluminum trihalide; and c) at least one organic Bronsted acid; the catalytic composition being pre-conditioned in a solvent before using it for oligomerization.
摘要:
The invention concerns a process for preparing a hybrid organic-inorganic material (HOIM) with phosphorus-containing bridges between the surface of an inorganic substrate containing an element M and one or more organic groups of the covalent M-O-P-R type, said process using, as a precursor for said organic group or groups, at least one organophosphorus acid halide with formula RxP(O)Xy in which x=1 or 2, y=3−x, X being a halogen and R designating at least one organic alkyl, aryl or aryl-alkyl group.Non-exhaustive applications for the hybrid organic-inorganic material obtained by the process of the invention are in the fields of anti-corrosion, lubrication, microelectronics, nanotechnologies, composite materials, heterogeneous catalysis, supported catalysis, depollution and biomedical applications.
摘要:
Process for desulfurization of an effluent for cracking or steam-cracking hydrocarbons, more particularly a gasoline for example for catalytic cracking that comprises the elimination of thiophenic compounds by alkylation of these compounds, followed by a distillation, a hydrocracking of said alkyl-thiophenic compounds, then a hydrodesulfurization of the effluent that is obtained from the hydrocracking zone. In a preferred embodiment, this process comprises a preliminary stage for separating the cracking or steam-cracking effluent into three fractions, and proposes sending to the alkylation stage only the intermediate fraction that is low in heavy basic nitrogen-containing compounds that are initially present in the effluents that are to be alkylated.
摘要:
An improved catalytic composition for oligomerization, in particular dimerization, of monoolefins comprises the product resulting from bringing the following three constituents into contact in any order: a) at least one divalent nickel compound; b) at least one hydrocarbylaluminium dihalide, optionally enriched with an aluminium trihalide; and c) at least one organic Bronsted acid; the catalytic composition being pre-conditioned in a solvent before using it for oligomerization.