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    POLYMERIC COMPOSITIONS AND FOAMS, METHODS OF MAKING THE SAME, AND ARTICLES PREPARED FROM THE SAME
    62.
    发明申请
    POLYMERIC COMPOSITIONS AND FOAMS, METHODS OF MAKING THE SAME, AND ARTICLES PREPARED FROM THE SAME 有权
    聚合物组合物及其制备方法及其制备方法

    公开(公告)号：US20110160323A1

    公开(公告)日：2011-06-30

    申请号：US13062241

    申请日：2009-09-16

    Applicant: Wenbin Liang ,  Brian W. Walther ,  Gary Marchand

    Inventor： Wenbin Liang ,  Brian W. Walther ,  Gary Marchand

    IPC: C08J9/00 ,  C08F236/20 ,  C08F232/08 ,  C08L47/00 ,  C08F8/36 ,  C08F8/06

    CPC classification number: C08J3/24 ,  C08J9/04 ,  C08J2201/024 ,  C08J2203/04 ,  C08J2323/16 ,  C08L23/16 ,  C08L91/00 ,  C08L2666/02

    Abstract: The invention provides a composition comprising an ethylene/α-olefin/non-conjugated diene interpolymer, which has the following properties: an Mz(abs)/Mz(Conv) value greater than 1.35; an Mz(BB)/Mw(abs) value greater than 1.6; and a non-conjugated diene content less than 10 weight percent, based on the total weight of the interpolymer. The invention also provides a process for forming a crosslinked composition, said process comprising: (a) forming a polymeric admixture comprising at least the following: (A) an ethylene/α-olefin/non-conjugated diene copolymer rubber (B) which has the following properties: an Mz(abs)/Mz(Conv) value less than 1.3; an Mz(BB)/Mw(abs) value greater than 1.6, but less than 2.5; and an Mw(abs) value less than 350,000 g/mole; and (B) a coupling amount of (i) at least one poly(sulfonyl azide) or (ii) at least one peroxide; and (b) heating the resulting admixture to a temperature at least the decomposition temperature of the crosslinking agent. The invention also provides a process for forming a shaped article, said process comprising: (a) forming a polymeric admixture comprise of at least one ethylene/α-olefin/non-conjugated diene interpolymer, at least one sulfur-based curative or organic peroxide-based crosslinking agent, and, optionally, a process oil, carbon blacks, additional inorganic fillers, organic fillers, cure accelerators, and/or foaming agents; (b) shaping the resulting admixture; (c) heating the resulting admixture to a temperature at least the decomposition temperature of the sulfur-based cure agent or the peroxide crosslinking agent.

    Abstract translation: 本发明提供一种包含乙烯/α-烯烃/非共轭二烯互聚物的组合物，其具有以下性质：Mz（abs）/ Mz（Conv）值大于1.35; Mb（BB）/ Mw（abs）值大于1.6; 和非共轭二烯含量小于10重量％，基于互聚物的总重量。 本发明还提供一种形成交联组合物的方法，所述方法包括：（a）形成至少包含以下物质的聚合物混合物：（A）乙烯/α-烯烃/非共轭二烯共聚物橡胶（B），其具有 以下性质：Mz（abs）/ Mz（Conv）值小于1.3; Mb（BB）/ Mw（abs）值大于1.6，但小于2.5; 和Mw（abs）值小于350,000g / mol; 和（B）偶联量的（i）至少一种聚（磺酰基叠氮化物）或（ii）至少一种过氧化物; 和（b）将得到的混合物加热至至少交联剂的分解温度的温度。 本发明还提供了一种形成成型制品的方法，所述方法包括：（a）形成包含至少一种乙烯/α-烯烃/非共轭二烯互聚物的至少一种硫基固化剂或有机过氧化物的聚合物混合物 的交联剂和任选的工艺油，炭黑，另外的无机填料，有机填料，固化促进剂和/或发泡剂; （b）成型所得混合物; （c）将得到的混合物加热至至少硫基固化剂或过氧化物交联剂的分解温度的温度。

    FORMING POROUS SCAFFOLD FROM CELLULOSE DERIVATIVES
    63.
    发明申请
    FORMING POROUS SCAFFOLD FROM CELLULOSE DERIVATIVES 有权
    从纤维素衍生物形成多孔的SCAFF

    公开(公告)号：US20110159272A1

    公开(公告)日：2011-06-30

    申请号：US12824105

    申请日：2010-06-25

    Applicant: Zhilian Yue ,  Feng Wen ,  Hanry Yu

    Inventor： Zhilian Yue ,  Feng Wen ,  Hanry Yu

    IPC: B32B3/26 ,  C08B15/10

    CPC classification number: B32B3/26 ,  A61L27/20 ,  A61L27/56 ,  C08B11/20 ,  C08J9/28 ,  C08J2201/024 ,  C08J2201/026 ,  C08J2201/0484 ,  C08J2201/0524 ,  C08J2205/044 ,  C08J2207/10 ,  C08J2301/28 ,  C08L1/14 ,  Y10T428/249921 ,  Y10T428/249978 ,  Y10T428/249979 ,  C08L1/28

    Abstract: Scaffold comprises a polymer defining macropores and comprising hydroxypropylcellulose partially substituted by a substituent comprising a self-crosslinkable group, which is crosslinked through the self-crosslinkable group. The macropores have an average pore size larger than 50 microns and are at least partially interconnected. In one method, bicontinuous emulsion comprising a continuous aqueous phase and a continuous polymer phase is formed. The polymer phase comprises hydroxypropylcellulose partially substituted by a substituent comprising a self-crosslinkable group, and is crosslinked through the self-crosslinkable group to form a polymer defining at least partially interconnected pores. In another method, phase separation is induced in a solution comprising a polymer precursor and water to form a bicontinuous emulsion comprising a continuous polymer phase and a continuous aqueous phase. The polymer precursor comprises a self-crosslinkable group and is crosslinked through the self-crosslinkable group in the emulsion to form a polymer defining at least partially interconnected macropores.

    Abstract translation: 脚手架包含限定大孔的聚合物，并且包含部分由包含自交联基团的取代基取代的羟丙基纤维素，所述取代基通过自交联基团交联。 大孔具有大于50微米的平均孔径并且至少部分互连。 在一种方法中，形成包含连续水相和连续聚合物相的双连续乳液。 聚合物相包含部分由包含自交联基团的取代基取代的羟丙基纤维素，并且通过自交联基团交联以形成限定至少部分互连的孔的聚合物。 在另一种方法中，在包含聚合物前体和水的溶液中诱导相分离以形成包含连续聚合物相和连续水相的双连续乳液。 聚合物前体包含自交联基团，并且通过乳液中的自交联基团交联以形成限定至少部分互连的大孔的聚合物。

    BIODEGRADABLE ALIPHATIC POLYESTER-BASED FOAMED PARTICLE AND MOLDED PRODUCT OF THE SAME
    66.
    发明申请
    BIODEGRADABLE ALIPHATIC POLYESTER-BASED FOAMED PARTICLE AND MOLDED PRODUCT OF THE SAME 审中-公开
    可生物降解的基于聚酯的泡沫颗粒及其模塑产品

    公开(公告)号：US20100184877A1

    公开(公告)日：2010-07-22

    申请号：US12666756

    申请日：2008-06-18

    Applicant: Toshio Miyagawa ,  Tomonori Furukawa

    Inventor： Toshio Miyagawa ,  Tomonori Furukawa

    IPC: C08J9/16 ,  B29C39/00

    CPC classification number: C08G18/4283 ,  C08G18/0895 ,  C08G18/7664 ,  C08G2101/00 ,  C08G2230/00 ,  C08G2350/00 ,  C08J9/0061 ,  C08J9/18 ,  C08J2201/024 ,  C08J2203/14 ,  C08J2367/04 ,  C08J2467/00 ,  C08K5/29 ,  C08L67/04 ,  C08L2205/02 ,  C08L2666/18

    Abstract: Biodegradable aliphatic polyester-based resin foamed particles that are excellent in environmental suitability and are produced using a source material derived from a plant, and a molded product of the same are provided. Thus, biodegradable aliphatic polyester-based resin foamed particles retaining high rigidity even when foamed at a high degree and having heat resistance, and a molded product are provided. Biodegradable aliphatic polyester-based resin foamed particles produced by foaming a resin composition obtained by melting and kneading a base resin constituted with a polymer (poly(3-hydroxyalkanoate)) having one or more recurring unit represented by the formula: [—O—CHR—CH2—CO—] (wherein, R is an alkyl group represented by CnH2n+1; and n is an integer of 1 to 15) and a polylactic acid-based resin, and an isocyanate compound. A molded product is produced by filling the resin foamed particles into a die, followed by heating and molding.

    Abstract translation: 提供环境适应性优异且使用源自植物的源材料制造的生物降解性脂肪族聚酯类树脂发泡粒子及其成型品。 因此，即使在高度发泡并具有耐热性的情况下也能够提供保持高刚性的生物降解性的脂肪族聚酯类树脂发泡体和成型体。 通过使具有一个或多个由下式表示的重复单元的聚合物（聚（3-羟基链烷酸酯））构成的基础树脂熔融和捏合而获得的树脂组合物发泡制备的可生物降解的脂肪族聚酯类树脂发泡颗粒：[-O-CHR -CH 2 -CO-]（其中，R为由C n H 2n + 1表示的烷基，n为1〜15的整数），聚乳酸系树脂和异氰酸酯化合物。 通过将树脂发泡颗粒填充到模具中，然后进行加热和模塑来制造模制产品。

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