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    Metal oxide layer having oxygen deficit tilting structure
    71.
    发明申请
    Metal oxide layer having oxygen deficit tilting structure 有权
    具有缺氧倾斜结构的金属氧化物层

    公开(公告)号：US20020055005A1

    公开(公告)日：2002-05-09

    申请号：US09951180

    申请日：2001-09-13

    申请人： FUJI KIHAN CO., LTD.

    发明人： Yoshio Miyasaka

    IPC分类号： B32B015/04 ,  B32B018/00

    CPC分类号： B01J35/002 ,  B01J21/06 ,  B01J21/063 ,  B01J23/14 ,  B01J35/004 ,  C21D7/06 ,  C23C24/04

    摘要： To obtain metal oxide layer having a reactiveness to electromagnetic wave whose wave length is longer than that of ultraviolet rays, for example, visible radiation or the like. A metal oxide layer is a layer of a stable metal oxide, for example. TiO2, ZnO, WO3, SnO2, ZrO2 or the like obtained by melting and adhering metal powder for forming a layer of titanium (Ti), zinc (Zn), wolfram (W), stannum (Sn) and zirconium (Zr) or the like on a surface of a product to be treated comprising of a metal, ceramics or a mixture of them by injecting the metal powder with high speed by dint of using a compressed air and has oxygen deficit tilting structure wherein bonding quantity of oxygen is decreased as goes from the surface to the inside gradually.

    摘要翻译： 为了获得对波长比紫外线长的电磁波具有反应性的金属氧化物层，例如可见光等。 金属氧化物层例如是稳定的金属氧化物层。 通过将形成钛（Ti），锌（Zn），钨（W），锡（Sn）和锆（Zr）的层的金属粉末熔融和附着而得到的TiO 2，ZnO，WO 3，SnO 2，ZrO 2等 像通过使用压缩空气高速注入金属粉末的金属，陶瓷或它们的混合物在待处理产品的表面上，并且具有氧缺陷倾斜结构，其中氧的键合量减少为 逐渐从表面到内部。

    Ammoxidation catalysts for fluidized/moving bed reactors
    74.
    发明授权
    Ammoxidation catalysts for fluidized/moving bed reactors 失效
    用于流化/移动床反应器的氨氧化催化剂

    公开(公告)号：US06200926B1

    公开(公告)日：2001-03-13

    申请号：US08769446

    申请日：1996-12-19

    申请人： Gilbert Blanchard ,  Paolo Burattin ,  Fabrizio Cavani ,  Stéfano Masetti ,  Ferruccio Trifiro

    发明人： Gilbert Blanchard ,  Paolo Burattin ,  Fabrizio Cavani ,  Stéfano Masetti ,  Ferruccio Trifiro

    IPC分类号： B01J2300

    CPC分类号： B01J37/0203 ,  B01J23/002 ,  B01J23/14 ,  B01J23/18 ,  B01J23/22 ,  B01J23/8472 ,  B01J37/0205 ,  B01J37/08 ,  B01J2523/00 ,  B01J2523/43 ,  B01J2523/53 ,  B01J2523/55

    摘要： Solid catalysts suited for the fluidized/moving bed catalytic ammoxidation of alkanes comprise an active catalytic phase having the empirical formula (I): VSbaSnbTicFedEeOx  (I) in which E is an element which provides an oxide of rutile structure or an element which, in combination with V, Sb, Sn, Ti, Fe and/or with another element E, provides a phase of rutile or trirutile structure, or a solid solution of rutile structure, a is a whole or fractional number equal to or greater than 0.5, b, c, d and e, independently, are each a whole or fractional number ranging from 0 to 100, and x is a whole or fractional number determined by the oxidation state of the other elements, such active catalytic phase being deposited onto/into particulates of a solid and porous oxidic support therefor, and are produced by (a) impregnating the solid and porous oxidic support with a solution, in at least one saturated alcohol, of compounds of vanadium and antimony and, optionally, compounds of tin and/or titanium and/or of iron and/or of element E, (b) contacting the solid and porous oxidic support thus impregnated with an aqueous buffer solution having a pH ranging from about 6 to 8, (c) separating the solids from such aqueous buffer solution and drying same, and (d) calcining the dried solids in two stages.

    摘要翻译： 适用于流化/移动床的固体催化剂催化氨基氧化烷烃包括具有经验式（I）的活性催化相：其中E是提供金红石结构的氧化物的元素或与V，Sb ，Sn，Ti，Fe和/或另一元素E提供金红石或三元结构的相或金红石结构的固溶体，a是等于或大于0.5的整数或分数，b，c，d 和e独立地分别为0至100的整数或分数，x为由其它元素的氧化态确定的整数或分数，该活性催化相沉积在固体颗粒中， 通过（a）在至少一种饱和醇中的溶液中浸渍固体和多孔氧化载体来制备，其中钒和锑的化合物以及任选的锡和/或钛和/或 的铁和 /或元素E，（b）使由此浸渍的固体和多孔氧化物载体与pH范围为约6至8的水性缓冲溶液接触，（c）将该固体与该缓冲溶液分离并干燥，和 d）分两步焙烧干固体。

    Esterification process using a catalyst consisting of sand, stannous tin and aluminate
    78.
    发明授权
    Esterification process using a catalyst consisting of sand, stannous tin and aluminate 失效
    使用由沙子，锡和锡酸铝组成的催化剂进行酯化处理

    公开(公告)号：US5571938A

    公开(公告)日：1996-11-05

    申请号：US509609

    申请日：1995-07-31

    申请人： Stan Jakubowycz

    发明人： Stan Jakubowycz

    IPC分类号： B01J23/14 ,  B01J31/04 ,  B01J31/12 ,  C07C67/08 ,  C07C67/00

    CPC分类号： B01J23/14 ,  B01J31/2234 ,  B01J31/26 ,  C07C67/08 ,  B01J2531/42 ,  B01J31/04

    摘要： The present invention provides for an esterification process comprising a catalyst source of stannous tin and an alkali metal aluminate. In one preferred embodiment the catalyst comprises about 92 parts sand, about 5 parts stannous oxalate, and about 3 parts of a sodium aluminate, by weight, dry basis. This catalyst is particularly useful in making phthalates, adipates, sebacates and azelates which esters are chiefly used plasticizers.

    摘要翻译： 本发明提供了一种酯化方法，其包括锡锡的催化剂源和碱金属铝酸盐。 在一个优选的实施方案中，催化剂包含约92份砂，约5份草酸亚锡和约3份以干基计重量的铝酸钠。 该催化剂特别可用于制造邻苯二甲酸酯，己二酸酯，癸二酸酯和壬二酸酯，其中酯主要用于增塑剂。

    Lower alkane conversion
    80.
    发明授权
    Lower alkane conversion 失效
    降低烷烃转化率

    公开(公告)号：US5053578A

    公开(公告)日：1991-10-01

    申请号：US477318

    申请日：1990-02-08

    申请人： Glenn O. Michaels ,  Michael J. Spangler

    发明人： Glenn O. Michaels ,  Michael J. Spangler

    IPC分类号： B01J23/04 ,  B01J23/06 ,  B01J23/14 ,  B01J37/03 ,  C07C2/84

    CPC分类号： B01J37/03 ,  B01J23/04 ,  B01J23/06 ,  B01J23/14 ,  C07C2/84 ,  C07C2521/04 ,  C07C2521/10 ,  C07C2523/02 ,  Y10S585/943

    摘要： A method for converting a feedstock alkane containing from 1 to 3 carbon atoms to a higher molecular weight hydrocarbon comprising contacting a feedstock with an oxygen-containing gas in the presence of a catalytic composition is disclosed. The catalytic composition includes a Group IA metal, a Group IIA metal and a third component, the precursor of which is a sol such as an aqueous suspension of a metal such as aluminum, silicon, titanium, zinc, zirconium, cadmium or tin with which the other components of the composition are thoroughly dispersed.

    摘要翻译： 公开了一种将含有1至3个碳原子的原料烷烃转化为较高分子量烃的方法，包括在催化组合物存在下使原料与含氧气体接触。 催化剂组合物包括IA族金属，IIA族金属和第三组分，其前体是诸如铝，硅，钛，锌，锆，镉或锡的金属的水性悬浮液的溶胶，其中 组合物的其它组分被彻底分散。