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    TERMINAL UNSATURATED, GLYCIDOL-BASED MACROMONOMERS, POLYMERS OBTAINABLE THEREFROM, PREPARATION AND USE
    76.
    发明申请
    TERMINAL UNSATURATED, GLYCIDOL-BASED MACROMONOMERS, POLYMERS OBTAINABLE THEREFROM, PREPARATION AND USE 有权
    端基不饱和，基于甘氨酸的麦芽糖，可获得的聚合物，制备和使用

    公开(公告)号：US20120165414A1

    公开(公告)日：2012-06-28

    申请号：US13379303

    申请日：2010-06-04

    申请人： Wojciech Jaunky ,  Albert Frank ,  Alfred Bubat ,  Jürgen Omeis

    发明人： Wojciech Jaunky ,  Albert Frank ,  Alfred Bubat ,  Jürgen Omeis

    IPC分类号： A61K8/81 ,  C07C231/12 ,  C07C43/178 ,  C09D125/08 ,  C08F220/58 ,  C08F216/14 ,  C09D133/26 ,  C07C41/03 ,  C07C233/20

    CPC分类号： C08G65/2609 ,  C08G65/00 ,  C08G65/22 ,  C08G65/2612

    摘要： Process for preparing a macromonomer, in which a starting compound H2C═CR1—C6H4-s(R4)s—R3—OH or H2C═CR2—CO—NH—R3—OH, where R1 and R2 are each H or a linear or branched alkyl radical having from 1 to 4 carbon atoms, R3 is a linear or branched alkylene, aralkylene radical which has from 1 to 20 carbon atoms and can contain one or more hydroxy groups and the radicals R4 are each, independently of one another, a linear or branched alkyl, aralkyl, alkoxy or aralkoxy radical having from 1 to 20 carbon atoms and s=0-4, is, after partial deprotonation, reacted with at least one hydroxy-functional oxirane compound in the presence of an inhibitor of free-radical polymerization with opening of the oxirane ring, where the molar ratio of the molar amounts used n(starting compound):n(oxirane compound) is in the range from 1:100 to 1:1.Macromonomers which can be obtained by the process, polymers which can be obtained therefrom and their use as additives in coating compositions, plastics and cosmetics.

    摘要翻译： 制备大分子单体的方法，其中起始化合物H2C = CR1-C6H4-s（R4）s-R3-OH或H2C = CR2-CO-NH-R3-OH，其中R1和R2各自为H或直链或 具有1至4个碳原子的支链烷基，R3是具有1至20个碳原子并且可以含有一个或多个羟基的基团的直链或支链亚烷基，亚芳基，并且基团R 4各自彼此独立地为 具有1至20个碳原子且s = 0-4的直链或支链烷基，芳烷基，烷氧基或芳烷氧基是在部分去质子化后与至少一种羟基官能的环氧乙烷化合物在游离 - 使用n（起始化合物）:n（环氧乙烷化合物）的摩尔量的摩尔比为1：100〜1：1的环氧乙烷环的开环自由基聚合。 可以通过该方法获得的大分子单体，可从其获得的聚合物及其作为涂料组合物，塑料和化妆品中的添加剂的用途。