公开(公告)号：US20160023989A1

公开(公告)日：2016-01-28

申请号：US14873113

申请日：2015-10-01

Applicant: Stepan Company

Inventor： Dave R Allen ,  Randal J Bernhardt ,  Aaron Brown ,  Anatoliy A Dameshek ,  Brian Holland ,  Andrew D Malec ,  Ronald A Masters ,  Marshall J Nepras ,  Patti Skelton ,  Laura Lee Whitlock ,  Patrick Shane Wolfe

IPC: C07C219/08 ,  C11C3/08

CPC classification number: C07C219/08 ,  A01N25/02 ,  A01N25/04 ,  A01N25/30 ,  A01N33/12 ,  A01N37/18 ,  A01N37/44 ,  A01N41/04 ,  A61K8/416 ,  A61K8/42 ,  A61K8/44 ,  A61K8/466 ,  A61K8/92 ,  A61K8/922 ,  A61K2800/805 ,  A61Q5/02 ,  A61Q5/12 ,  A61Q19/10 ,  A62D1/0071 ,  B01F17/0028 ,  B01F17/0057 ,  C07C6/04 ,  C07C41/03 ,  C07C43/11 ,  C07C67/26 ,  C07C69/533 ,  C07C69/593 ,  C07C209/12 ,  C07C211/21 ,  C07C231/12 ,  C07C237/16 ,  C07C237/18 ,  C07C303/18 ,  C08G65/2615 ,  C08K5/01 ,  C08K5/20 ,  C09K8/00 ,  C09K15/28 ,  C11C3/00 ,  C11C3/08 ,  C11D1/002 ,  C11D1/04 ,  C11D1/28 ,  C11D1/62 ,  C11D1/652 ,  C11D1/74 ,  C11D1/83 ,  C11D1/90 ,  C11D1/92 ,  C11D1/94 ,  C11D3/48 ,  C07C211/63 ,  C07C211/64 ,  C07C233/38 ,  C07C309/14 ,  A01N33/18 ,  A01N39/04 ,  A01N43/653 ,  A01N51/00 ,  A01N57/20 ,  A01N43/40 ,  A01N43/56 ,  A01N53/00

Abstract: Esteramine compositions and their derivatives are disclosed. The esteramines comprise a reaction product of a metathesis-derived C10-C17 monounsaturated acid, octadecene-1,18-dioic acid, or their ester derivatives with a tertiary alkanolamine. Derivatives made by quaternizing, sulfonating, alkoxylating, sulfating, and/or sulfitating the esteramines are also disclosed. In one aspect, the ester derivative of the C10-C17 monounsaturated acid or octadecene-1,18-dioic acid is a lower alkyl ester. In other aspects, the ester derivative is a modified triglyceride made by self-metathesis of a natural oil or an unsaturated triglyceride made by cross-metathesis of a natural oil with an olefin. The esteramines and derivatives are valuable for a wide variety of end uses, including cleaners, fabric treatment, hair conditioning, personal care (liquid cleansing products, conditioning bars, oral care products), antimicrobial compositions, agricultural uses, and oil field applications.

公开(公告)号：US09708251B2

公开(公告)日：2017-07-18

申请号：US14395829

申请日：2013-03-13

Applicant: Stepan Company

Inventor： David R. Allen ,  Marcos Alonso ,  Mary Beddaoui ,  Randal J. Bernhardt ,  Aaron Brown ,  Xue Min Dong ,  Wilma Gorman ,  John Hutchison ,  Gary Luebke ,  Renee Luka ,  Franz Luxem ,  Andrew D. Malec ,  Ronald A Masters ,  Dennis S Murphy ,  Patti Skelton ,  Brian Sook ,  Chris Spaulding ,  Michael Wiester ,  Patrick Shane Wolfe

IPC: A61K47/00 ,  C07C309/10 ,  C11D1/14 ,  C11D1/29 ,  A01N25/30 ,  A61K8/46 ,  B01F17/00 ,  C04B38/10 ,  C07C29/147 ,  C07C303/14 ,  C07C303/32 ,  C07C309/08 ,  C11D1/37 ,  C07C41/06 ,  C09D7/12 ,  C11D1/66 ,  C07C41/03

CPC classification number: C07C309/10 ,  A01N25/30 ,  A61K8/463 ,  A61K8/466 ,  A61K2800/10 ,  B01F17/0057 ,  B01F17/0092 ,  C04B38/10 ,  C07C29/147 ,  C07C41/03 ,  C07C41/06 ,  C07C303/14 ,  C07C303/32 ,  C07C309/08 ,  C09D7/63 ,  C11D1/143 ,  C11D1/146 ,  C11D1/29 ,  C11D1/37 ,  C11D1/66 ,  A01N37/34 ,  A01N43/40 ,  A01N43/56 ,  A01N43/653 ,  A01N43/70 ,  A01N47/30 ,  A01N51/00 ,  C07C43/1785 ,  C07C33/025

Abstract: Unsaturated fatty alcohol alkoxylates, processes for making them, and methods of using them are disclosed. In one aspect, a monounsaturated fatty alcohol alkoxylate is made by reducing a metathesis-derived monounsaturated alkyl ester, followed by alkoxylation of the resulting monounsaturated alcohol. Microscopy reveals that the monounsaturated alkoxylates have isotropic and lamellar phases over a wider range of actives levels compared with their saturated analogs. This attribute expands formulating latitude for many end-use applications. The unsaturated fatty alcohol alkoxylates are valuable in, for example, agricultural solvents, nonionic emulsifiers for agricultural compositions, hard surface cleaners, laundry detergents, specialty foams, additives or surfactants for paints or coatings, and surfactant compositions for enhanced oil recovery.

公开(公告)号：US09573884B2

公开(公告)日：2017-02-21

申请号：US14847041

申请日：2015-09-08

Applicant: Stepan Company

Inventor： Dave R Allen ,  Marcos Alonso ,  Randal J Bernhardt ,  Aaron Brown ,  Kelly Buchek ,  Sangeeta Ganguly-Mink ,  Brian Holland ,  Gary Luebke ,  Renee Luka ,  Andrew D. Malec ,  Ronald A Masters ,  Dennis S Murphy ,  Irene Shapiro ,  Patti Skelton ,  Brian Sook ,  Michael R Terry ,  Gregory Wallace ,  Laura Lee Whitlock ,  Michael Wiester ,  Patrick Shane Wolfe ,  Lena Titievsky

IPC: C11D3/32 ,  C07C233/09 ,  A01N25/02 ,  A01N25/04 ,  A01N25/30 ,  A01N33/12 ,  A01N37/18 ,  A01N37/44 ,  A01N41/04 ,  A61K8/41 ,  A61K8/42 ,  A61K8/44 ,  A61K8/46 ,  A61K8/92 ,  A61Q5/12 ,  A61Q19/10 ,  A62D1/02 ,  B01F17/00 ,  C07C69/533 ,  C07C69/593 ,  C07C209/12 ,  C07C211/21 ,  C07C219/08 ,  C07C231/12 ,  C07C237/16 ,  C07C303/18 ,  C08G65/26 ,  C08K5/01 ,  C08K5/20 ,  C09K8/00 ,  C09K15/28 ,  C11C3/00 ,  C11C3/08 ,  C11D1/00 ,  C11D1/04 ,  C11D1/28 ,  C11D1/62 ,  C11D1/65 ,  C11D1/74 ,  C11D1/83 ,  C11D1/90 ,  C11D1/92 ,  C11D1/94 ,  C11D3/48 ,  A61Q5/02 ,  C07C233/20 ,  C07C233/38 ,  C07C309/15 ,  C07D233/24 ,  C09D7/02 ,  C09K8/54 ,  C11D1/66

CPC classification number: C07C233/09 ,  A01N25/02 ,  A01N25/04 ,  A01N25/30 ,  A01N33/12 ,  A01N37/18 ,  A01N37/44 ,  A01N41/04 ,  A61K8/416 ,  A61K8/42 ,  A61K8/44 ,  A61K8/466 ,  A61K8/92 ,  A61Q5/02 ,  A61Q5/12 ,  A61Q17/005 ,  A61Q19/10 ,  A62D1/0071 ,  B01F17/0028 ,  B01F17/0057 ,  C07C69/533 ,  C07C69/593 ,  C07C209/12 ,  C07C211/21 ,  C07C219/08 ,  C07C231/12 ,  C07C233/20 ,  C07C233/38 ,  C07C237/16 ,  C07C303/18 ,  C07C309/15 ,  C07C309/70 ,  C07D233/24 ,  C08G65/2615 ,  C08K5/01 ,  C08K5/20 ,  C08K5/42 ,  C09D7/45 ,  C09D7/63 ,  C09K8/00 ,  C09K8/524 ,  C09K8/54 ,  C09K15/28 ,  C11C3/00 ,  C11C3/08 ,  C11D1/002 ,  C11D1/04 ,  C11D1/28 ,  C11D1/62 ,  C11D1/652 ,  C11D1/66 ,  C11D1/74 ,  C11D1/83 ,  C11D1/90 ,  C11D1/92 ,  C11D1/94 ,  C11D3/48 ,  C11D11/0017 ,  C07C211/63 ,  C07C211/64 ,  C07C309/14 ,  A01N33/18 ,  A01N39/04 ,  A01N43/653 ,  A01N51/00 ,  A01N57/20 ,  A01N43/40 ,  A01N43/56 ,  A01N53/00

Abstract: Fatty amide compositions and their derivatives are disclosed. The fatty amides comprise a reaction product of a metathesis-derived C10-C17 monounsaturated acid, octadecene-1,18-dioic acid, or their ester derivatives with a primary or secondary amine. Derivatives made by reducing, quaternizing, sulfonating, alkoxylating, sulfating, and sulfitating the fatty amide are also included. The amine reactant can be diethylenetriamine or (2-aminoethyl)ethanolamine, which provide imidazoline amides or esters, respectively. In one aspect, the ester derivative of the C10-C17 monounsaturated acid or octadecene-1,18-dioic acid is a lower alkyl ester. In other aspects, the ester derivative is a modified triglyceride made by self-metathesis of a natural oil or an unsaturated triglyceride made by cross-metathesis of a natural oil with an olefin. The compositions are valuable for cleaners, fabric treatment, hair conditioning, personal care, antimicrobial compositions, agricultural uses, and oil field applications.

Abstract translation: 公开了脂肪酰胺组合物及其衍生物。 脂肪酰胺包含由复分解衍生的C10-C17单不饱和酸，十八碳烯-1,18-二酸或其酯衍生物与伯胺或仲胺的反应产物。 还包括通过还原，季铵化，磺化，烷氧基化，硫酸化和硫酸化而制得的衍生物。 胺反应物可以是二亚乙基三胺或（2-氨基乙基）乙醇胺，其分别提供咪唑啉酰胺或酯。 一方面，C10-C17单不饱和酸或十八碳烯-1,18-二酸的酯衍生物是低级烷基酯。 在其它方面，酯衍生物是通过天然油或不饱和甘油三酸酯通过天然油与烯烃的交叉复分解而制备的改性甘油三酸酯。 组合物对于清洁剂，织物处理，头发调理，个人护理，抗微生物组合物，农业用途和油田应用是有价值的。

公开(公告)号：US20150376118A1

公开(公告)日：2015-12-31

申请号：US14847041

申请日：2015-09-08

Applicant: Stepan Company

Inventor： Dave R Allen ,  Marcos Alonso ,  Randal J Bernhardt ,  Aaron Brown ,  Kelly Buchek ,  Sangeeta Ganguly-Mink ,  Brian Holland ,  Gary Luebke ,  Renee Luka ,  Andrew D. Malec ,  Ronald A Masters ,  Dennis S Murphy ,  Irene Shapiro ,  Patti Skelton ,  Brian Sook ,  Michael R Terry ,  Gregory Wallace ,  Laura Lee Whitlock ,  Michael Wiester ,  Patrick Shane Wolfe ,  Lena Titievsky

IPC: C07C233/09 ,  A61K8/42 ,  A61Q5/12 ,  A61Q19/10 ,  A61Q5/02 ,  C07C233/20 ,  C07D233/24 ,  C07C233/38 ,  C07C309/15 ,  A01N25/30 ,  C11D1/00 ,  C11D1/66 ,  C09K8/54 ,  C09K8/00 ,  C09D7/02 ,  A01N37/18

CPC classification number: C07C233/09 ,  A01N25/02 ,  A01N25/04 ,  A01N25/30 ,  A01N33/12 ,  A01N37/18 ,  A01N37/44 ,  A01N41/04 ,  A61K8/416 ,  A61K8/42 ,  A61K8/44 ,  A61K8/466 ,  A61K8/92 ,  A61Q5/02 ,  A61Q5/12 ,  A61Q17/005 ,  A61Q19/10 ,  A62D1/0071 ,  B01F17/0028 ,  B01F17/0057 ,  C07C69/533 ,  C07C69/593 ,  C07C209/12 ,  C07C211/21 ,  C07C219/08 ,  C07C231/12 ,  C07C233/20 ,  C07C233/38 ,  C07C237/16 ,  C07C303/18 ,  C07C309/15 ,  C07C309/70 ,  C07D233/24 ,  C08G65/2615 ,  C08K5/01 ,  C08K5/20 ,  C08K5/42 ,  C09D7/45 ,  C09D7/63 ,  C09K8/00 ,  C09K8/524 ,  C09K8/54 ,  C09K15/28 ,  C11C3/00 ,  C11C3/08 ,  C11D1/002 ,  C11D1/04 ,  C11D1/28 ,  C11D1/62 ,  C11D1/652 ,  C11D1/66 ,  C11D1/74 ,  C11D1/83 ,  C11D1/90 ,  C11D1/92 ,  C11D1/94 ,  C11D3/48 ,  C11D11/0017 ,  C07C211/63 ,  C07C211/64 ,  C07C309/14 ,  A01N33/18 ,  A01N39/04 ,  A01N43/653 ,  A01N51/00 ,  A01N57/20 ,  A01N43/40 ,  A01N43/56 ,  A01N53/00

Abstract: Fatty amide compositions and their derivatives are disclosed. The fatty amides comprise a reaction product of a metathesis-derived C10-C17 monounsaturated acid, octadecene-1,18-dioic acid, or their ester derivatives with a primary or secondary amine. Derivatives made by reducing, quaternizing, sulfonating, alkoxylating, sulfating, and sulfitating the fatty amide are also included. The amine reactant can be diethylenetriamine or (2-aminoethyl)ethanolamine, which provide imidazoline amides or esters, respectively. In one aspect, the ester derivative of the C10-C17 monounsaturated acid or octadecene-1,18-dioic acid is a lower alkyl ester. In other aspects, the ester derivative is a modified triglyceride made by self-metathesis of a natural oil or an unsaturated triglyceride made by cross-metathesis of a natural oil with an olefin. The compositions are valuable for cleaners, fabric treatment, hair conditioning, personal care, antimicrobial compositions, agricultural uses, and oil field applications.

Abstract translation: 公开了脂肪酰胺组合物及其衍生物。 脂肪酰胺包含由复分解衍生的C10-C17单不饱和酸，十八碳烯-1,18-二酸或其酯衍生物与伯胺或仲胺的反应产物。 还包括通过还原，季铵化，磺化，烷氧基化，硫酸化和硫酸化而制得的衍生物。 胺反应物可以是二亚乙基三胺或（2-氨基乙基）乙醇胺，其分别提供咪唑啉酰胺或酯。 一方面，C10-C17单不饱和酸或十八碳烯-1,18-二酸的酯衍生物是低级烷基酯。 在其它方面，酯衍生物是通过天然油或不饱和甘油三酸酯通过天然油与烯烃的交叉复分解而制备的改性甘油三酸酯。 组合物对于清洁剂，织物处理，头发调理，个人护理，抗微生物组合物，农业用途和油田应用是有价值的。

公开(公告)号：US09796662B2

公开(公告)日：2017-10-24

申请号：US14873113

申请日：2015-10-01

Applicant: Stepan Company

Inventor： Dave R Allen ,  Randal J Bernhardt ,  Aaron Brown ,  Anatoliy A Dameshek ,  Brian Holland ,  Andrew D Malec ,  Ronald A Masters ,  Marshall J Nepras ,  Patti Skelton ,  Laura Lee Whitlock ,  Patrick Shane Wolfe

IPC: C07C209/12 ,  C07C211/21 ,  C07C219/08 ,  C07C237/12 ,  C07C237/16 ,  C07C303/18 ,  C07C41/03 ,  C07C43/11 ,  C07C6/04 ,  C07C67/26 ,  C07C69/533 ,  C07C69/593 ,  A01N25/02 ,  A01N25/04 ,  A01N25/30 ,  A01N33/12 ,  A01N37/18 ,  A01N37/44 ,  A01N41/04 ,  A61K8/41 ,  A61K8/42 ,  A61K8/44 ,  A61K8/46 ,  A61K8/92 ,  A61Q5/12 ,  A61Q19/10 ,  A62D1/02 ,  B01F17/00 ,  C07C231/12 ,  C07C237/18 ,  C08G65/26 ,  C08K5/01 ,  C08K5/20 ,  C09K15/28 ,  C11C3/00 ,  C11C3/08 ,  C11D1/00 ,  C11D1/04 ,  C11D1/28 ,  C11D1/62 ,  C11D1/65 ,  C11D1/74 ,  C11D1/83 ,  C11D1/90 ,  C11D1/92 ,  C11D1/94 ,  C11D3/48 ,  A61Q5/02 ,  C09K8/00

CPC classification number: C07C219/08 ,  A01N25/02 ,  A01N25/04 ,  A01N25/30 ,  A01N33/12 ,  A01N37/18 ,  A01N37/44 ,  A01N41/04 ,  A61K8/416 ,  A61K8/42 ,  A61K8/44 ,  A61K8/466 ,  A61K8/92 ,  A61K8/922 ,  A61K2800/805 ,  A61Q5/02 ,  A61Q5/12 ,  A61Q19/10 ,  A62D1/0071 ,  B01F17/0028 ,  B01F17/0057 ,  C07C6/04 ,  C07C41/03 ,  C07C43/11 ,  C07C67/26 ,  C07C69/533 ,  C07C69/593 ,  C07C209/12 ,  C07C211/21 ,  C07C231/12 ,  C07C237/16 ,  C07C237/18 ,  C07C303/18 ,  C08G65/2615 ,  C08K5/01 ,  C08K5/20 ,  C09K8/00 ,  C09K15/28 ,  C11C3/00 ,  C11C3/08 ,  C11D1/002 ,  C11D1/04 ,  C11D1/28 ,  C11D1/62 ,  C11D1/652 ,  C11D1/74 ,  C11D1/83 ,  C11D1/90 ,  C11D1/92 ,  C11D1/94 ,  C11D3/48 ,  C07C211/63 ,  C07C211/64 ,  C07C233/38 ,  C07C309/14 ,  A01N33/18 ,  A01N39/04 ,  A01N43/653 ,  A01N51/00 ,  A01N57/20 ,  A01N43/40 ,  A01N43/56 ,  A01N53/00

Abstract: Esteramine compositions and their derivatives are disclosed. The esteramines comprise a reaction product of a metathesis-derived C10-C17 monounsaturated acid, octadecene-1,18-dioic acid, or their ester derivatives with a tertiary alkanolamine. Derivatives made by quaternizing, sulfonating, alkoxylating, sulfating, and/or sulfitating the esteramines are also disclosed. In one aspect, the ester derivative of the C10-C17 monounsaturated acid or octadecene-1,18-dioic acid is a lower alkyl ester. In other aspects, the ester derivative is a modified triglyceride made by self-metathesis of a natural oil or an unsaturated triglyceride made by cross-metathesis of a natural oil with an olefin. The esteramines and derivatives are valuable for a wide variety of end uses, including cleaners, fabric treatment, hair conditioning, personal care (liquid cleansing products, conditioning bars, oral care products), antimicrobial compositions, agricultural uses, and oil field applications.

公开(公告)号：US20150087724A1

公开(公告)日：2015-03-26

申请号：US14395829

申请日：2013-03-13

Applicant: Stepan Company

Inventor： David R. Allen ,  Marcos Alonso ,  Mary Beddaoui ,  Randal J. Bernhardt ,  Aaron Brown ,  Xue Min Dong ,  Wilma Gorman ,  John Hutchison ,  Gary Luebke ,  Renee Luka ,  Franz Luxem ,  Andrew D. Malec ,  Ronald A Masters ,  Dennis S Murphy ,  Patti Skelton ,  Brian Sook ,  Chris Spaulding ,  Michael Wiester ,  Patrick Shane Wolfe

IPC: C07C29/147 ,  C09D7/12 ,  C11D1/66 ,  C07C41/06 ,  A01N25/30

CPC classification number: C07C309/10 ,  A01N25/30 ,  A61K8/463 ,  A61K8/466 ,  A61K2800/10 ,  B01F17/0057 ,  B01F17/0092 ,  C04B38/10 ,  C07C29/147 ,  C07C41/03 ,  C07C41/06 ,  C07C303/14 ,  C07C303/32 ,  C07C309/08 ,  C09D7/63 ,  C11D1/143 ,  C11D1/146 ,  C11D1/29 ,  C11D1/37 ,  C11D1/66 ,  A01N37/34 ,  A01N43/40 ,  A01N43/56 ,  A01N43/653 ,  A01N43/70 ,  A01N47/30 ,  A01N51/00 ,  C07C43/1785 ,  C07C33/025

Abstract: Unsaturated fatty alcohol alkoxylates, processes for making them, and methods of using them are disclosed. In one aspect, a monounsaturated fatty alcohol alkoxylate is made by reducing a metathesis-derived monounsaturated alkyl ester, followed by alkoxylation of the resulting monounsaturated alcohol. Microscopy reveals that the monounsaturated alkoxylates have isotropic and lamellar phases over a wider range of actives levels compared with their saturated analogs. This attribute expands formulating latitude for many end-use applications. The unsaturated fatty alcohol alkoxylates are valuable in, for example, agricultural solvents, nonionic emulsifiers for agricultural compositions, hard surface cleaners, laundry detergents, specialty foams, additives or surfactants for paints or coatings, and surfactant compositions for enhanced oil recovery.

Abstract translation: 公开了不饱和脂肪醇烷氧基化物，其制备方法及其使用方法。 在一个方面，单不饱和脂肪醇烷氧基化物是通过还原衍生的单不饱和烷基酯，然后将所得的单不饱和醇进行烷氧基化来制备的。 显微镜显示，与其饱和类似物相比，单不饱和烷氧基化物在更广泛的活性水平范围内具有各向同性和层状相。 该属性扩展了许多最终用途应用程序的自由度。 不饱和脂肪醇烷氧基化物在例如农用溶剂，用于农业组合物的非离子乳化剂，硬表面清洁剂，衣物洗涤剂，特种泡沫，用于油漆或涂料的添加剂或表面活性剂以及用于提高油采收率的表面活性剂组合物中是有价值的。