Abstract:
The present invention relates to a process for preparing substituted indole derivatives. More particularly, the invention refers to a new method to synthesize indole-derivatives by oxidative C—H-functionalization.
Abstract:
The present invention relates to the use of mesoporous graphitic particles having a loading of sintering-stable metal nanoparticles for fuel cells and further electrochemical applications, for example as constituent of layers in electrodes of fuel cells and batteries.
Abstract:
The invention relates to chiral imidodiphosphates and derivatives thereof having the general formula I, The compounds are suitable as chiral Brønsted acid catalysts, phase-transfer catalysts, chiral anions for organic salts, metal salts or metal complexes for catalysis.
Abstract:
A series of mono, bi and tricarbocyclic compounds, most of which have olefinic unsaturation in the ring, which may or may not have substituents thereon. While the bi and tricyclic rings may be unsubstituted, these compounds which have olefinic unsaturation, particularly multiple olefinic unsaturation, are polymerizable and copolymerizable in known polymerization systems. They are particularly good crosslinking agents. These compounds are further useful in the sense that they can be cleaved oxidatively, to corresponding carboxylic acids, aldehydes and/or alcohols which have known utility in the plasticizer and detergent arts. The compounds which do not have olefinic unsaturation can also be oxidatively cleaved to produce oxygenated, e.g., acid, alcohol or aldehyde, compounds having known utility.
Abstract:
Process of extracting cocoa butter from sources thereof by use of supercritical gases which are solvents therefor, especially carbon dioxide.
Abstract:
A polymerization catalyst for polymerizing olefins, such as ethylene and its homologs, in the form of the reaction product obtained by mixing a titanium trihalide such as titanium trichloride with an organo-metallic compound which has a reducing action on the valence of the titanium trihalide. Examples of organo-metallic compounds include organo-aluminum and -magnesium compounds such as the metal alkyls and metal alkyl halides.
Abstract:
PROCESS OF PRODUCING NICKEL ALCOHOLATES BY REACTING $-ALLYL NICKEL COMPOUNDS WITH CARBONLY COMPOUNDS. THE NICKEL ALCOHOLATES SO PRODUCED CAN BE HYDROLYZED TO THEIR CORRESPONDING ALCOHOLS AND THESE ALCOHOLS CAN IN PART BE DEHYDRATED TO THEIR CORRESPONDING OLEFINS. THE NICKEL ALCOHOLATE PRODUCTS ARE USEFUL FOR THE PRODUCTION OF THEIR CORRESPONDING ALCOHOLS AND THESE ALCOHOLS ARE USEFUL FOR THE PRODUCTION OF THEIR CORRESPONDING OLEFINS.
Abstract:
A process for obtaining caffein from green coffee by withdrawing the caffein by means of recirculating moist carbon dioxide in supercritical state, which comprises removing the caffein from the caffein-loaded carbon dioxide by repeated treatment with water and recovering the caffein and the water from the resultant dilute aqueous caffein solution by recycling a stream of air or nitrogen under a superatmospheric pressure at about 1 to 5 atmospheres through the heated caffein solution and a heat exchanger, separating the caffein and the condensed water and recycling after admixture of cold caffein solution the gas through the heat exchanger in countercurrent flow relation and meeting the heat requirement by supplying heat to the hot caffein solution.
Abstract:
A PROCESS FOR THE SEPARATION OF MIXTURES OF ALUMINUM TRIALKYLS HAVING ALKYL GROUPS OF DIFFERENT CHAIN LENGTHS TO PRODUCE A FRACTION HAVING ALKYL GROUPS OR MORE UNIFORM CHAIN LENGTH WHICH COMPRISES CONTACTING THE MIXTURE WITH AN INERT GAS WHICH IS UNDER SUPER-CRITICAL CONDITIONS OF TEMPERATURE AND PRESSURE AND INERT TO ALUMINUM TRIALKYLS UNDER THE PROCESS CONDITIONS THEREBY TAKING UP AT LEAST PART OF THE MIXTURE IN THE SUPERCRITICAL GAS AND RECOVERING FROM THE GAS ALUMINUM TRIALKYL TAKEN UP THEREBY.