Light-sensitive composition consisting essentially of, in admixture a
nonionic aromatic diazo compound and a cationic dye/borate anion complex
    81.
    发明授权
    Light-sensitive composition consisting essentially of, in admixture a nonionic aromatic diazo compound and a cationic dye/borate anion complex 失效
    基本上由非离子芳族重氮化合物和阳离子染料/硼酸盐阴离子络合物的混合物组成的感光组合物

    公开(公告)号:US5200292A

    公开(公告)日:1993-04-06

    申请号:US466548

    申请日:1990-01-17

    摘要: A light-sensitive composition is provided comprising (a) an aromatic diazo compound and (b) a cationic dye/borate anion complex.In a preferred embodiment, the cationic dye/anionic borate dye complex is represented by the general formula (I): ##STR1## wherein D.sup.+ represents a cationic dye; and R.sub.1, R.sub.2, R.sub.3 and R.sub.4, which may be the same or different, each represents an unsubstituted or substituted alkyl group, an unsubstituted or substituted aryl group, an unsubstituted or substituted aralkyl group, an unsubstituted or substituted alkenyl group, an unsubstituted or substituted alkynyl group, an unsubstituted or substituted alicyclic group, or an unsubstituted or substituted heterocyclic group.The aromatic diazo compound can be a nonionic diazo compound.The light-sensitive compound can further comprise a radical-polymerizable unsaturated compound.

    摘要翻译: 提供了一种感光组合物,其包含(a)芳族重氮化合物和(b)阳离子染料/硼酸盐阴离子络合物。 在优选的实施方案中,阳离子染料/阴离子硼酸盐染料络合物由通式(I)表示:其中D +表示阳离子染料; 可以相同或不同的R 1,R 2,R 3和R 4各自表示未取代或取代的烷基,未取代或取代的芳基,未取代或取代的芳烷基,未取代或取代的烯基,未取代或未取代的 取代的炔基,未取代或取代的脂环基,或未取代或取代的杂环基。 芳族重氮化合物可以是非离子重氮化合物。 感光性化合物还可以含有自由基聚合性不饱和化合物。

    Method of producing polychromatic colored image
    82.
    发明授权
    Method of producing polychromatic colored image 失效
    生产多色彩色图像的方法

    公开(公告)号:US5155005A

    公开(公告)日:1992-10-13

    申请号:US675825

    申请日:1991-03-27

    摘要: A method of producing a polychromatic colored image with clear fine patterns, comprising the steps of:(a) contacting a light-sensitive colored resin layer, provided on a temporary support transmissive of ultraviolet rays with an adhesive layer provided on a permanent support;(b) imagewise exposing the light-sensitive colored resin layer to a pattern through the temporary support;(c) peeling the temporary support from the imagewise exposed resin layer;(d) developing the imagewise exposed colored resin layer to form a colored resin pattern on the adhesive layer;(e) embedding the colored resin pattern into the surface of the adhesive layer by applying pressure through a material having a surface energy lower than that of both the colored resin pattern and the adhesive layer;(f) contacting a light-sensitive resin layer of another image-forming material colored in a tint different from resin layers previously formed on the adhesive layer with the adhesive layer; and(g) repeating the exposure, development and embedding steps as described above; and(h) repeating these processes until the desired number of colored patterns are formed and embedded in the adhesive layer.

    摘要翻译: 一种制造具有清晰精细图案的多色彩色图像的方法,包括以下步骤:(a)将设置在透射紫外线的临时支架上的感光着色树脂层与设置在永久支撑体上的粘合剂层接触; (b)通过临时支撑将感光着色树脂层成像曝光到图案; (c)从成像暴露的树脂层剥离临时支撑体; (d)显影图像曝光的着色树脂层,以在粘合剂层上形成着色树脂图案; (e)通过施加压力通过表面能低于着色树脂图案和粘合剂层的表面能的材料将着色树脂图案嵌入粘合剂层的表面; (f)将预先形成在粘合剂层上的树脂层的着色着色的另一图像形成材料的感光树脂层与粘合剂层接触; 和(g)重复上述的曝光,开发和嵌入步骤; 和(h)重复这些过程直到形成所需数量的着色图案并嵌入粘合剂层中。

    Light sensitive alkali developable photoresist material with fluorine
surfactant containing color layer
    84.
    发明授权
    Light sensitive alkali developable photoresist material with fluorine surfactant containing color layer 失效
    光敏碱显影光刻胶材料,含氟表面活性剂含色层

    公开(公告)号:US4803145A

    公开(公告)日:1989-02-07

    申请号:US31737

    申请日:1987-03-30

    CPC分类号: G03F1/56

    摘要: A light-sensitive image-forming material which has on a support a coloring layer comprising a coloring agent and an alkali soluble organic macromolecular binder, and a photopolymer layer, in the order listed, with the coloring layer further containing a particular fluorine-containing surface active agent, whereby uniform film thickness is ensured to the coloring layer even when drying is carried out in a short time using simple equipment. The fluorine-containing surface active agent is a copolymer comprising as repeating units (1) an acrylate or a methacrylate which has a fluorinated alphatic group containing from 3 to 20 carbon atoms and not less than 40 wt % of fluorine atoms, with the aliphatic group having a terminal moiety containing at least 3 fluorinated carbon atoms, and (2) a poly(oxyalkylene)acrylate or a poly(oxyalkylene)methacrylate. In addition, the portion of the fluorinated aliphatic group-containing acrylate or methacrylate repeating unit is from 10 to 70% by weight.

    摘要翻译: 一种感光成像材料,其具有在载体上包含着色剂和碱溶性有机高分子粘合剂的着色层和光聚合物层,其中所述着色层还包含特定的含氟表面 即使使用简单的设备在短时间内进行干燥,也可以确保着色层的均匀膜厚。 含氟表面活性剂是包含作为重复单元的共聚物(1)具有含有3〜20个碳原子且40重量%以上的氟原子的氟化脂肪族基团的丙烯酸酯或甲基丙烯酸酯与脂肪族基团 具有含有至少3个氟化碳原子的末端部分,和(2)聚(氧化烯)丙烯酸酯或聚(氧化烯)甲基丙烯酸酯。 此外,含氟脂肪族基团的丙烯酸酯或甲基丙烯酸酯重复单元的部分为10〜70重量%。

    Heat-sensitive recording material
    86.
    发明授权
    Heat-sensitive recording material 失效
    热敏记录材料

    公开(公告)号:US4650740A

    公开(公告)日:1987-03-17

    申请号:US650143

    申请日:1984-09-13

    摘要: A heat-sensitive recording material is described, comprising a support having provided thereon a recording layer comprising a binder containing a diazonium compound and a coupling component, said diazonium compound being a diazonium salt represented by formula (I)ArN.sub.2.sup.+ X.sup.- (I)wherein Ar represents a substituted or unsubstituted aromatic moiety; and X.sup.- represents an acid anion containing an alkyl group having three or more fluorine atoms.

    摘要翻译: 描述了一种热敏记录材料,其包括其上设置有包含含有重氮化合物和偶联组分的粘合剂的记录层的载体,所述重氮化合物是由式(I)表示的重氮盐ArN2 + X-(I) 其中Ar表示取代或未取代的芳族部分; X表示含有具有3个以上氟原子的烷基的酸性阴离子。

    Photopolymerizable composition containing heterocyclic additives
    87.
    发明授权
    Photopolymerizable composition containing heterocyclic additives 失效
    含有杂环添加剂的光聚合组合物

    公开(公告)号:US4543318A

    公开(公告)日:1985-09-24

    申请号:US626950

    申请日:1984-07-02

    IPC分类号: G03F7/085 H05K3/00 G03C1/68

    摘要: A photopolymerizable composition is described, comprising (1) a non-gaseous ethylenically unsaturated compound which has at least two ethylenically unsaturated terminal groups and is capable of forming a polymer, (2) a thermoplastic polymeric binder, (3) a photopolymerization initiator which is activated by actinic radiation, and (4) at least one of certain heterocyclic compounds. The composition is useful as a photoresist for producing printed circuit boards, printing plates, etc., by etching or plating, and the photoresist has superior adhesion with respect to the base.

    摘要翻译: 描述了可光聚合组合物,其包含(1)具有至少两个烯属不饱和端基并能够形成聚合物的非气态烯属不饱和化合物,(2)热塑性聚合物粘合剂,(3)光聚合引发剂, 通过光化辐射活化,和(4)某些杂环化合物中的至少一种。 该组合物可用作通过蚀刻或电镀制造印刷电路板,印版等的光致抗蚀剂,并且光致抗蚀剂相对于基底具有优异的粘附性。

    Process for preparing a color proofing sheet
    89.
    发明授权
    Process for preparing a color proofing sheet 失效
    制备彩色打样片的方法

    公开(公告)号:US4482625A

    公开(公告)日:1984-11-13

    申请号:US555736

    申请日:1983-11-28

    CPC分类号: G03C5/00 G03F3/10

    摘要: A process for preparing a color proofing sheet is disclosed. The process comprises imagewise exposing a light-sensitive image-forming material comprising a transparent support having provided thereon a dye- or pigment-containing light-sensitive photoresist composition layer or both a dye- or pigment-containing colorant layer and a light-sensitive photoresist composition layer through a color separation mask, developing the material to form a color separation image, transferring the color separation image onto a photopolymerizable image-receiving layer, transferring in registration at least one more color separation image onto the same image-receiving layer to obtain a multicolored color proofing sheet on a single support, and totally exposing the image-receiving layer after the image transfer in an amount sufficient to induce photopolymerization thereof. A color proofing sheet realizing color reproduction essentially the same as actual print copies and has a good image strength and non-tackiness can be obtained by the process.

    摘要翻译: 公开了一种制备彩色打样片的方法。 该方法包括成像曝光包含透明支持​​物的感光成像材料,所述透明支持体上设置有含有染料或颜料的光敏光致抗蚀剂组合物层,或者含染料或颜料的着色剂层和光敏光致抗蚀剂 组成层,通过分色面罩显影,形成色分离图像,将分色图像转印到可光聚合图像接收层上,将至少一个以上的颜色分离图像配准转印到同一图像接收层上,得到 在单个支撑体上的多色彩色打样片,并且在图像转印之后,以足以引起其光聚合的量完全曝光图像接收层。 通过该处理可以获得实现与实际打印副本基本相同并且具有良好的图像强度和非粘性的色彩再现片。

    Light-sensitive material and image forming processes using the same
    90.
    发明授权
    Light-sensitive material and image forming processes using the same 失效
    感光材料和使用其的成像方法

    公开(公告)号:US4431725A

    公开(公告)日:1984-02-14

    申请号:US399583

    申请日:1982-07-19

    CPC分类号: G03F7/0226

    摘要: A light-sensitive material having on a support a light-sensitive layer containing an o-quinonediazide compound as a main component and, additionally, a particular compound represented by the following general formula (I): ##STR1## wherein Z represents the nonmetallic atoms forming a 5-membered ring; X represents S, O, ##STR2## or .dbd.N--R.sub.c (where R.sub.a, R.sub.b and R.sub.c are each a hydrogen atom or an organic group other than a carboxylic acid group); and Y is a hydrogen atom or an organic group other than a carboxylic acid group, is disclosed. This material can provide both positive and negative working images having high resolution and good adhesiveness to the support. A process for producing positive working images includes the steps of imagewise exposure and development processing, while a process for producing negative working images includes the steps of imagewise exposure, heating, uniform (overall) exposure and development processing. The same conditions regarding imagewise exposure and development processing, respectively, can be applied to both processes.

    摘要翻译: 一种感光材料,其在载体上具有含有邻醌二叠氮化合物作为主要成分的感光层,另外还包含由以下通式(I)表示的特定化合物:其中Z表示 形成5元环的非金属原子; X表示S,O,或= N-Rc(其中Ra,Rb和Rc各自为氢原子或除羧酸基团之外的有机基团); 并且Y是氢原子或除羧酸基以外的有机基团。 该材料可以提供具有高分辨率和对支持体的良好粘附性的正和负工作图像。 用于产生正面工作图像的方法包括成像曝光和显影处理的步骤,而用于产生负面工作图像的处理包括成像曝光,加热,均匀(总体)曝光和显影处理的步骤。 分别对成像曝光和显影处理的相同条件可以应用于两个处理。