Synergistic light stabilizer compositions for synthetic resins and resin
compositions containing the same

    公开(公告)号:US4396735A

    公开(公告)日:1983-08-02

    申请号:US193551

    申请日:1980-10-03

    CPC分类号: C08K5/3462 C08K5/3435

    摘要: Light stabilizers for synthetic resin compositions and synthetic resin compositions containing such stabilizers are provided, comprising(1) at least one hindered heterocyclic amine having the formula: ##STR1## wherein: X is a bivalent linking radical forming with the ring structure ##STR2## a nitrogen-containing heterocyclic ring having from five to seven ring atoms, preferably piperidine;R.sub.1 and R.sub.2 are each selected from the group consisting of lower alkyl, preferably methyl, and R.sub.1 and R.sub.2 taken together as pentylene (CH.sub.2).sub.5 ;R.sub.3 and R.sub.4 are each selected from the group consisting of lower alkyl, and R.sub.3 and R.sub.4 taken together as one of butylene--(CH.sub.2).sub.4, pentylene--(CH.sub.2).sub.5, and CH.sub.2 --C(CH.sub.3).sub.2 --NH--C(CH.sub.3).sub.2 --CH.sub.2 --;n is 1 or 2; andwhen n is 1, Y.sub.1 is selected from the group consisting of hydrogen, O.sup..cndot., OH, alkyl, alkenyl, alkynyl, aralkyl and acyl having from one to about thirty carbon atoms; andwhen n is 2, Y.sub.1 is selected from the group consisting of alkylene, alkenylene, alkynylene, cycloalkylene and aralkylene having from one to about thirty carbon atoms; together with(2) at least one heterocyclic acid hydrazide having the formula: ##STR3## wherein: R is selected from the group consisting of hydrogen, alkyl, aryl and such groups having hydroxyl, carboxylic acid ester, oxyether and carbonyl groups having from one to about thirty carbon atoms; ##STR4## is the residue of a dicarboxylic or tetracarboxylic acid, wherein Z is selected from the group consisting of alkylene, alkenylene, cycloalkylene, alkylcycloalkylene, arylene and alkylarylene having from one to about thirty carbon atoms, and such radicals bearing free carboxylic acid or carboxylic acid ester groups; andm is 1 or 2.In such combinations, the heterocyclic acid hydrazide, which alone is not a light-stabilizer, synergizes the stabilizing effectiveness of the hindered heterocyclic amine.

    Use of selected 1,2-dihydro-1,2,4,5-tetrazines as oxygen-scavenging
agents
    83.
    发明授权
    Use of selected 1,2-dihydro-1,2,4,5-tetrazines as oxygen-scavenging agents 失效
    使用选择的1,2-二氢-1,2,4,5-四嗪作为清除氧化剂

    公开(公告)号:US4389327A

    公开(公告)日:1983-06-21

    申请号:US387989

    申请日:1982-06-14

    摘要: Disclosed is a method for removing dissolved oxygen from a liquid (e.g., aqueous) system which comprisesadding to said liquid system an effective amount of an oxygen-scavenging chemical selected from 1,2-dihydro-1,2,4,5-tetrazines of the formula ##STR1## wherein R.sub.1 and R.sub.2 are individually selected from lower alkyl groups having 1 to 4 carbon atoms and phenyl.

    摘要翻译: 公开了一种从液体(例如水溶液)体系中除去溶解氧的方法,该方法包括向所述液体体系中加入有效量的选自1,2-二氢-1,2,4,5-四嗪的除氧化学化学品 其中R 1和R 2分别选自具有1至4个碳原子的低级烷基和苯基。

    Metal corrosion inhibitor
    85.
    发明授权
    Metal corrosion inhibitor 失效
    金属腐蚀抑制剂

    公开(公告)号:US4219433A

    公开(公告)日:1980-08-26

    申请号:US943795

    申请日:1978-09-19

    CPC分类号: C23F11/08

    摘要: Metal corrosion inhibitor comprising (a) benzoic acid and/or a benzoate, (b) a trialkanolamine, (c) phosphoric acid and/or a phosphate, and (d) at least one selected from mercaptobenzothiazole, its salts, benzotriazole and tolyltriazole, which can exhibit excellent anti-corrosive property to various metals for a long term and can be diluted with an aqueous liquor and can be employed in combination with usual anti-freezing agents.

    摘要翻译: 金属腐蚀抑制剂,其包含(a)苯甲酸和/或苯甲酸酯,(b)三烷醇胺,(c)磷酸和/或磷酸酯,和(d)选自巯基苯并噻唑,其盐,苯并三唑和甲苯基三唑中的至少一种, 其可以对各种金属长期表现出优异的抗腐蚀性,并且可以用含水液体稀释,并且可以与通常的防冻剂组合使用。