摘要:
An oil-based corrosion inhibitor containing an aliphatic amine, a fatty acid and its ester, and an organotin compound provides improved corrosion resistance to metals and is easily removed when the metals are to be processed.
摘要:
Light stabilizers for synthetic resin compositions and synthetic resin compositions containing such stabilizers are provided, comprising(1) at least one hindered heterocyclic amine having the formula: ##STR1## wherein: X is a bivalent linking radical forming with the ring structure ##STR2## a nitrogen-containing heterocyclic ring having from five to seven ring atoms, preferably piperidine;R.sub.1 and R.sub.2 are each selected from the group consisting of lower alkyl, preferably methyl, and R.sub.1 and R.sub.2 taken together as pentylene (CH.sub.2).sub.5 ;R.sub.3 and R.sub.4 are each selected from the group consisting of lower alkyl, and R.sub.3 and R.sub.4 taken together as one of butylene--(CH.sub.2).sub.4, pentylene--(CH.sub.2).sub.5, and CH.sub.2 --C(CH.sub.3).sub.2 --NH--C(CH.sub.3).sub.2 --CH.sub.2 --;n is 1 or 2; andwhen n is 1, Y.sub.1 is selected from the group consisting of hydrogen, O.sup..cndot., OH, alkyl, alkenyl, alkynyl, aralkyl and acyl having from one to about thirty carbon atoms; andwhen n is 2, Y.sub.1 is selected from the group consisting of alkylene, alkenylene, alkynylene, cycloalkylene and aralkylene having from one to about thirty carbon atoms; together with(2) at least one heterocyclic acid hydrazide having the formula: ##STR3## wherein: R is selected from the group consisting of hydrogen, alkyl, aryl and such groups having hydroxyl, carboxylic acid ester, oxyether and carbonyl groups having from one to about thirty carbon atoms; ##STR4## is the residue of a dicarboxylic or tetracarboxylic acid, wherein Z is selected from the group consisting of alkylene, alkenylene, cycloalkylene, alkylcycloalkylene, arylene and alkylarylene having from one to about thirty carbon atoms, and such radicals bearing free carboxylic acid or carboxylic acid ester groups; andm is 1 or 2.In such combinations, the heterocyclic acid hydrazide, which alone is not a light-stabilizer, synergizes the stabilizing effectiveness of the hindered heterocyclic amine.
摘要:
Disclosed is a method for removing dissolved oxygen from a liquid (e.g., aqueous) system which comprisesadding to said liquid system an effective amount of an oxygen-scavenging chemical selected from 1,2-dihydro-1,2,4,5-tetrazines of the formula ##STR1## wherein R.sub.1 and R.sub.2 are individually selected from lower alkyl groups having 1 to 4 carbon atoms and phenyl.
摘要:
Hydrocarbon-containing materials having a low amount of unsaturation e.g., paraffinic and napththenic hydrocarbons having less than about 10 weight percent unsaturation are stabilized or made more resistant to oxidation employing a polyamines mixture obtained as a heavy by-product residue from the recovery by distillation of a polyamine obtained in the hydrogenation of branched aliphatic dinitriles. In one embodiment an isoparaffinic hydrocarbon obtained by alkylation of an isoparaffin with an olefin is rendered resistant to oxidation.
摘要:
Metal corrosion inhibitor comprising (a) benzoic acid and/or a benzoate, (b) a trialkanolamine, (c) phosphoric acid and/or a phosphate, and (d) at least one selected from mercaptobenzothiazole, its salts, benzotriazole and tolyltriazole, which can exhibit excellent anti-corrosive property to various metals for a long term and can be diluted with an aqueous liquor and can be employed in combination with usual anti-freezing agents.
摘要:
A method for stabilizing organic materials against autoxidation, a composition useful therefor and organic compositions containing the autoxidation stabilizers. The method comprises the steps of adding a compound capable of reducing the peroxide content and a transition metal containing compound to an organic material and thereafter recovering a stabilized composition. The components of the inhibitor may be added separately or simultaneously and the same may be added directly to the organic material or first combined in a concentrated solution and then added to the organic material. The basic and neutral primary, secondary and tertiary amines have been found particularly effective in reducing the peroxide content. Also, the transition metal salts containing cations which easily change valence by a single electron are the most effective transition metal salts. The inhibitor combination is effective in both liquid and solid compositions. The inhibitor combination is particularly effective in both natural and synthetic lubricating oil compositions, grease compositions, polymers and the like. When used at the most effective relative and actual concentrations, the inhibitor combination will yield stability comparable to that exhibited by conventional oxidation inhibitors even though one component is a known oxidation catalyst.
摘要:
Antioxidant compositions are prepared by thermally rearranging tetra-aryl hydrazines and then heating the rearrangement product with sulphur or sulphurising agents.
摘要:
AS ANTIOXIDANT MIXTURE SUITABLE FOR AN AVIATION TURBINE OIL (E.G. AN ESTER OF PENTAERYLTHRITOL) COMPRISES (A) AN ALKYLATED N-PHENYL NAPHTHYLAMINE HAVING AT LEAST ONE ALKYL SUBSTITUENT EACH CONTAINING FROM 3 TO 14 CARBON ATOMS, E.G. N-(TERT-OCTYL PHENYL)-B-NAPHTHYLAMINE AND (B) AN AMINO COMPOUND OF THE FORMULA
WHERE X IS HYDROGEN, HYDROCARBYL CONTAINING UP TO 20 CARBON ATOMS, OR THE GROUP
4-((CH3-)2-N-)PHENYL
E.G. N,N'' TETRAMETHYL DIAMINO DIPHENYL METHANE, THE MOLE RATIO OF (A) TO (B) BEING AT LEAST 1*1. THIS ANTIOXIDANT HAS GOOD ANTIOXIDANT POTENCY TOGETHER WITH LOW CORROSIVE TENDENCIES.
摘要:
AN ANTIOZONANT-ANTIOXIDANT COMPOSITION WHICH IS CRYSTALLINE AND READILY DISPERSIBLE IN ELASTOMERIC POLYMERS COMPRISING A MIXTURE OF, BY WEIGHT, 94-86% SECONDARY AMINE, SAID AMINE CONTAINING 30-65% DIARYL-P-PHENYLENEDIAMINE AND 70-35% N-PHENYL-2-NAPHTHYLAMINE, AND 614% HYDROUS CALCIUM SILICATE AND PROCESS FOR MAKING THE SAME.