Mesophilic xylanases
    1.
    发明授权
    Mesophilic xylanases 有权
    嗜中性木聚糖酶

    公开(公告)号:US6140097A

    公开(公告)日:2000-10-31

    申请号:US171850

    申请日:1998-11-16

    IPC分类号: C12N9/24 C12N9/00 C12N9/42

    摘要: Mesophilic xylanases derived from Acremonium cellulolyticus. A mesophilic xylanase I, derived from the mold Acremonium cellulolyticus, capable of non-specifically hydrolyzing xylan mainly into xylose, xylobiose and xylotriose, having an optimal pH at 3.5 and an optimal temperature for action at 55.degree. C. as determined by saccharifying activity for soluble xylan as a substrate and a molecular weight of 30,000 as determined by SDS-polyacrylamide gel electrophoresis. A mesophilic xylanase II having an optimal pH a 3.8, an optimal temperature for action at 55.degree. C. and a molecular weight of 25,500. A mesophilic xylanase III having an optimal pH at 3.5, an optimal temperature for action at 50.degree. C. and a molecular weight of 33,500.

    摘要翻译: PCT No.PCT / JP98 / 00869 Sec。 371日期:1998年11月16日 102(e)1998年11月16日日期PCT提交1998年3月3日PCT公布。 第WO98 / 39423号公报 日期1998年9月11日衍生自解淀粉解淀粉的嗜酸性木聚糖酶。 来源于解淀粉解淀粉的嗜温木聚糖酶I,能够将木聚糖主要分解为木糖,木二糖和木三糖,具有3.5的最佳pH,最适温度为55℃,通过糖化活性测定 可溶性木聚糖作为底物,分子量为30,000,通过SDS-聚丙烯酰胺凝胶电泳测定。 具有最佳pH为3.8的嗜温木聚糖酶II,在55℃下起作用的最佳温度和25,500分子量。 具有3.5的最佳pH的嗜温木聚糖酶III,在50℃下作用的最佳温度和33,500分子量。

    Method for the preparation of a high-quality powder of amorphous silicic
acid
    3.
    发明授权
    Method for the preparation of a high-quality powder of amorphous silicic acid 失效
    制备无定形硅酸高品质粉末的方法

    公开(公告)号:US6068825A

    公开(公告)日:2000-05-30

    申请号:US213376

    申请日:1998-12-17

    申请人: Shuji Tsunematsu

    发明人: Shuji Tsunematsu

    摘要: Disclosed is an improvement in the process for the preparation of amorphous silicic acid particles useful, for example, as a filtration aid comprising the steps of a hydrothermal reaction to prepare calcium silicate particles and decalcification of the calcium silicate particles, after or without undertaking carbonation by the reaction of carbon dioxide, with an acid to form particles of amorphous silicic acid followed by drying of the amorphous silicic acid particles. Different from the conventional methods in which great shrinkage of the amorphous silicic acid cakes wet with water is unavoidable in the drying step to adversely affect the quality of the product, the final step of treatment preceding drying of the wet cake is undertaken in a liquid medium which is a mixture of water and a water-miscible organic solvent such as ethyl alcohol in a specified proportion so that the drying of the wet cake is performed without the disadvantage due to the large surface tension of water responsible to the drying shrinkage of wet cakes.

    摘要翻译: 公开了用于制备无定形硅酸颗粒的方法的改进,所述无定形硅酸颗粒可用作例如作为过滤助剂,其包括以下步骤:水热反应以制备硅酸钙颗粒和脱硅钙硅酸盐颗粒,在或不进行碳酸化之后 二氧化碳与酸反应形成无定形硅酸颗粒,然后干燥无定形硅酸颗粒。 与在干燥步骤中不可避免地使无定形硅酸蛋糕用水湿润的大的收缩率不利地影响产品质量的常规方法不同,在湿滤饼干燥之前的处理的最后步骤在液体介质中进行 其是水和水混溶性有机溶剂如乙醇的混合物,以规定的比例进行,从而干燥湿滤饼的干燥不会因为湿蛋糕的干燥收缩引起的水的表面张力大而不利 。

    Method for the preparation of ultrafine fibrous assembly having twisted
morphology
    5.
    发明授权
    Method for the preparation of ultrafine fibrous assembly having twisted morphology 失效
    制备具有扭曲形态的超细纤维组合物的方法

    公开(公告)号:US5705635A

    公开(公告)日:1998-01-06

    申请号:US752437

    申请日:1996-11-14

    CPC分类号: C07H1/00

    摘要: When a saturated aqueous solution of a bolaform glycolipid represented by the general formula G--NH--CO--(CH.sub.2).sub.n --CO--NH--G, in which G is a residue derived from a D- or L-glucopyranose by excepting the reduced-terminal hydroxyl group and the subscript n is 10, 12 or 14, at a high temperature, e.g., 90 .degree. C. or higher, is cooled at a controlled rate of 0.5 .degree. C./minute or lower, crystallite growth of the precipitates proceeds to form an ultrafine fibrous assembly of up to several hundreds .mu.m length having a twisted fibrous morphology of right- or left-hand screw. The twisted fibrous assembly thus obtained has usefulness as a functional material in the field of fine chemicals and in the fields of electronic and information technologies.

    摘要翻译: 当由通式G-NH-CO-(CH2)n-CO-NH-G表示的bolaform糖脂的饱和水溶液,其中G是衍生自D-或L-吡喃葡萄糖的残基, 末端羟基和下标n为10,12或14,在高温例如90℃或更高温度下以0.5℃/分钟或更低的受控速率冷却,析出物的微晶生长进行 以形成长达数百μm长度的超细纤维组合物,其具有右旋或左旋螺杆的扭曲的纤维形态。 由此获得的扭曲纤维组合物作为精细化学品领域和电子和信息技术领域的功能材料是有用的。

    7-substituted-2-oxa�3.2.0!heptan-6-one compound and method for the
preparation thereof
    6.
    发明授权
    7-substituted-2-oxa�3.2.0!heptan-6-one compound and method for the preparation thereof 失效
    7-取代-2-氧杂[3.2.0]庚-6-酮化合物及其制备方法

    公开(公告)号:US5700931A

    公开(公告)日:1997-12-23

    申请号:US654521

    申请日:1996-05-29

    CPC分类号: C07D491/04 A01N43/90

    摘要: Disclosed is a novel .beta.-lactam compound, a 7-substituted-2-oxa-7-azabicyclo�3.2.0!heptan-6-one represented by the general formula ##STR1## in which R is an alkyl, cycloalkyl, aryl, halogen-substituted aryl or alkaryl group, having usefulness as an intermediate for the synthesis of various biologically active compounds. The compound can be prepared by the reaction of an isocyanate compound RNCO, R being the same as above, and 2,3-dihydrofuran, preferably, under pressurization up to 2000 atmospheres or higher.

    摘要翻译: 公开了一种新的β-内酰胺化合物,由通式“IMAGE”表示的7-取代-2-氧杂-7-氮杂双环[3.2.0]庚-6-酮,其中R是烷基,环烷基,芳基, 卤素取代的芳基或烷芳基,其作为用于合成各种生物活性化合物的中间体具有有用性。 化合物可以通过异氰酸酯化合物RNCO,与上述相同的R和2,3-二氢呋喃的反应来制备,优选在加压至2000个大气压或更高的条件下进行。

    Grain boundary-free crystalline body of manganese-based composite oxide
and method for the preparation thereof
    7.
    发明授权
    Grain boundary-free crystalline body of manganese-based composite oxide and method for the preparation thereof 失效
    锰基复合氧化物的无边界晶体及其制备方法

    公开(公告)号:US5665664A

    公开(公告)日:1997-09-09

    申请号:US552620

    申请日:1995-11-03

    CPC分类号: H01L43/10 C30B13/00 C30B29/22

    摘要: Proposed is a grain boundary-free crystalline body of a perovskite structure having a chemical composition of the formula Pr.sub.1-x M.sub.x MnO.sub.3, in which M is calcium or strontium and the subscript x is a number of 0.3 to 0.5, which exhibits a magnetoresistance behavior with a phase transition between an insulator phase and a ferromagnetic metallic phase accompanied by the phenomenon of hysteresis. This grain boundary-free crystalline body can be obtained by subjecting a sintered body of a powder blend consisting of the oxides of praseodymium, manganese and calcium or strontium to a crystal growing treatment by the floating zone-melting method in an atmosphere of oxygen.

    摘要翻译: 提出具有式Pr1-xMxMnO3的化学组成的钙钛矿结构的无晶界结晶体,其中M为钙或锶,下标x为0.3至0.5的数,其表现出具有磁阻特性的 伴随着滞后现象的绝缘体相和强磁性金属相之间的相变。 该无晶界结晶体可以通过使氧化镨,锰和钙或锶的氧化物组成的粉末共混物的烧结体在氧气气氛中通过漂浮区熔融法进行结晶生长处理来获得。

    Dielectric thin film of substituted lead titanate
    8.
    发明授权
    Dielectric thin film of substituted lead titanate 失效
    取代钛酸铅的介电薄膜

    公开(公告)号:US5571495A

    公开(公告)日:1996-11-05

    申请号:US510270

    申请日:1995-08-02

    摘要: Proposed is a dielectric thin film of a substituted lead titanate having a chemical composition expressed by the formulaPb(Ti.sub.1-x M.sub.x)O.sub.3in which the subscript x is a positive number in the range from 0.05 to 0.50 and M is an element selected from the group consisting of niobium, tantalum, vanadium, antimony, bismuth, arsenic, tungsten, hafnium, germanium, tin, aluminum and gallium substituting for a part of the titanium atoms in the perovskite crystal lattice of lead titanate. Different from thin films of unsubstituted lead titanate or conventional substituted lead titanates, the above defined dielectric thin films of the invention are free from the disadvantage that the dielectric constant of the thin film is greatly decreased when the thickness of the thin film is so small as to be 1 .mu.m or smaller so that the dielectric constant of the inventive dielectric thin film having a thickness of 0.5 .mu.m or even smaller can be as large as 10 times of that of the thin film of unsubstituted lead titanate having the same thickness.

    摘要翻译: 提出了具有由式Pb(Ti1-xMx)O3表示的化学组成的取代的钛酸铅的介电薄膜,其中下标x为0.05至0.50的正数,M为选自 由铌,钽,钒,锑,铋,砷,钨,铪,锗,锡,铝和镓组成的组,代替钛酸铅的钙钛矿晶格中的一部分钛原子。 与未取代的钛酸铅或常规取代的钛酸铅的薄膜不同,本发明的上述限定的电介质薄膜不存在薄膜的介电常数大大降低的缺点,即当薄膜的厚度小至 为1μm以下,本发明的厚度为0.5μm以上的电介质薄膜的介电常数可以达到相同厚度的未取代钛酸铅薄膜的介电常数的10倍以上。

    Carbonaceous ferromagnetics and method for the preparation thereof
    9.
    发明授权
    Carbonaceous ferromagnetics and method for the preparation thereof 失效
    碳质铁磁体及其制备方法

    公开(公告)号:US5556570A

    公开(公告)日:1996-09-17

    申请号:US307055

    申请日:1994-09-16

    申请人: Hisashi Ueda

    发明人: Hisashi Ueda

    CPC分类号: B82Y25/00 H01F1/42

    摘要: The invention provides a carbonaceous ferromagnetic material consisting substantially of carbon alone as prepared by the carbonization of a specific aromatic compound, such as phenazine and indigo, to such an extent that the hydrogen atoms in the starting aromatic compound are eliminated as completely as possible but graphitization of the carbonization product does not take place by conducting the carbonization treatment at a temperature not exceeding 800.degree. C. The carbonization reaction can be promoted by admixing the aromatic compound with a compound of a ferromagnetic metallic element such as cobalt chloride, which is removed from the carbonization product by dissolving away with hydrochloric acid and ammonia water. Elimination of hydrogen atoms from the aromatic compound can be more complete by conducting the heat treatment for the carbonization in an atmosphere containing a halogen-generating agent such as carbon tetrachloride.

    摘要翻译: 本发明提供一种碳质铁磁材料,其基本上由单独的碳组成,通过特定芳族化合物如吩嗪和靛蓝的碳化制备,使得起始芳族化合物中的氢原子尽可能完全消除,但石墨化 的碳化反应不能通过在不超过800℃的温度进行碳化处理而发生。碳化反应可以通过将芳族化合物与诸如氯化钴的铁磁性金属元素的化合物混合来促进,该化合物被从 碳酸化产物用盐酸和氨水溶解掉。 通过在含有卤素发生剂如四氯化碳的气氛中进行碳化的热处理,可以更加完全地从芳族化合物中除去氢原子。

    Method for the recovery of gold value
    10.
    发明授权
    Method for the recovery of gold value 失效
    金价回收方法

    公开(公告)号:US5429660A

    公开(公告)日:1995-07-04

    申请号:US307062

    申请日:1994-09-16

    IPC分类号: C22B3/42

    摘要: An efficient method is proposed for the recovery of gold value contained in an aqueous solution even in a very low concentration of the ppb level. Namely, an aqueous acidic solution containing gold value in the form of complex gold anions, e.g., chloro complex anions of gold, is contacted with a solid ion exchanger which is prepared by the adsorption of a 2-hydroxyethyl tri(C.sub.8-12)alkyl ammonium halide on porous resin beads of a polymer of methacrylic acid ester so that the complex gold anions are adsorbed by the ion exchange reaction to form ion pairs with the quaternary ammonium cations. The thus adsorbed complex gold anions coupled with the quaternary ammonium cations can be eluted out of the adsorbent with an organic solvent such as alcohols and ketones in a quantitative yield of recovery.

    摘要翻译: 提出了一种有效的方法,即使在非常低浓度的ppb水平下,也能够回收水溶液中所含的金值。 即,将金属阴离子形式的金价例如金配阴离子金的酸性水溶液与固体离子交换剂接触,所述固体离子交换剂是通过吸附2-羟乙基三(C 8-12)烷基 卤化铵在甲基丙烯酸酯的聚合物的多孔树脂珠上,使得复合金阴离子被离子交换反应吸附以形成与季铵阳离子的离子对。 如此吸附的复合金阴离子与季铵阳离子结合可以用有机溶剂如醇和酮以定量的​​回收率从吸附剂中洗出。