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    PRESSURE-SENSITIVE ADHESIVE FOR PVC FOILS
    3.
    发明申请
    PRESSURE-SENSITIVE ADHESIVE FOR PVC FOILS 有权
    压敏粘胶用于PVC箔

    公开(公告)号：US20120244350A1

    公开(公告)日：2012-09-27

    申请号：US13514773

    申请日：2010-12-06

    申请人： Carmen-Elena Cimpeanu ,  Cornelis Petrus Beyers ,  Andree Dragon

    发明人： Carmen-Elena Cimpeanu ,  Cornelis Petrus Beyers ,  Andree Dragon

    IPC分类号： C09J4/02 ,  B32B27/36

    CPC分类号： C09J133/08 ,  C08F2/001 ,  C09J7/245 ,  C09J7/385 ,  C09J133/12 ,  C09J133/20 ,  C09J2201/606 ,  C09J2433/00 ,  Y10T428/2887

    摘要： An adhesive is described, in particular for applications on substrate materials made of flexible PVC, comprising a polymer which is obtainable via free-radical polymerization of ethylenically unsaturated compounds and which is composed of at least 50% by weight of soft acrylate monomers with glass transition temperature below 0° C., at least 1% by weight of ethylenically unsaturated nitriles, at least 1% by weight of hard acrylate monomers with glass transition temperature of at least 60° C., at least 0.1% by weight of ethylenically unsaturated acid monomers, and at least 0.01% by weight of monomers having at least two non-conjugated, polymerizable vinyl groups, where the polymerization reaction takes place via staged polymerization, and at least one portion of the soft acrylate monomers is polymerized in a first polymerization stage, and at least one portion of the hard acrylate monomers is polymerized in a second or subsequent polymerization stage. Uses of the adhesive for the bonding of substrates made of flexible PVC are also described, as also are self-adhesive items with a PVC foil as substrate material and with a coating of the adhesive of the invention.

    摘要翻译： 描述了粘合剂，特别是用于由柔性PVC制成的基材上的应用，其包含可通过烯键式不饱和化合物的自由基聚合获得的聚合物，并且其由至少50重量％的具有玻璃化转变的软丙烯酸酯单体 温度低于0℃，至少1重量％的烯属不饱和腈，至少1重量％的玻璃化转变温度至少为60℃的硬质丙烯酸酯单体，至少0.1重量％的烯属不饱和酸 单体和至少0.01重量％的具有至少两个非共轭可聚合乙烯基的单体，其中通过分段聚合进行聚合反应，并且至少一部分软质丙烯酸酯单体在第一聚合阶段中聚合 ，并且至少一部分硬质丙烯酸酯单体在第二或随后的聚合阶段中聚合。 还描述了用于粘合由柔性PVC制成的基底的粘合剂的用途，以及具有PVC箔作为基底材料并具有本发明的粘合剂的涂层的自粘物品。

    ADHESIVE COMPOSITION FOR PLASTICIZER-FREE, SELF-ADHESIVE REMOVABLE LABELS
    4.
    发明申请
    ADHESIVE COMPOSITION FOR PLASTICIZER-FREE, SELF-ADHESIVE REMOVABLE LABELS 审中-公开
    无胶粘剂的自粘组合物，自粘式可拆卸标签

    公开(公告)号：US20110151251A1

    公开(公告)日：2011-06-23

    申请号：US13060283

    申请日：2009-09-01

    申请人： Karl-Heinz Schumacher ,  Carmen-Elena Cimpeanu

    发明人： Karl-Heinz Schumacher ,  Carmen-Elena Cimpeanu

    IPC分类号： B32B7/12 ,  C09J133/08 ,  B32B37/12

    CPC分类号： C09J133/08 ,  C09J2201/606 ,  C09J2203/334 ,  Y10T428/2891

    摘要： A description is given of an adhesive composition which comprises a polymer preferably in the form of an emulsion polymer in dispersion in water. The emulsion polymer has a glass transition temperature of less than −61° C. and is preparable by emulsion polymerization at temperatures less than 80° C. from 80-95% by weight of 2-ethylhexyl acrylate and 5-20% by weight of further, ethylenically unsaturated, free-radically copolymerizable monomers, of which 0.2% to 2% by weight, based on the total amount of monomers, are acid-containing comonomers. The adhesive composition can be used in particular as a pressure-sensitive adhesive for producing plasticizer-free, self-adhesive, redetachable paper labels.

    摘要翻译： 给出了一种粘合剂组合物的描述，该粘合剂组合物包含优选以分散在水中的乳液聚合物形式的聚合物。 乳液聚合物具有小于-61℃的玻璃化转变温度，并且可以通过在低于80℃的温度下通过乳液聚合制备，从80-95重量％的丙烯酸2-乙基己酯和5-20重量％的 此外，基于单体总量的0.2重量％至2重量％的烯属不饱和的自由基共聚单体是含酸的共聚单体。 粘合剂组合物可特别用作用于生产无增塑剂的自粘性可重新纸可再剥离纸标签的压敏粘合剂。

    PAPER AND CARDBOARD PACKAGING WITH BARRIER COATING OF A POLYMER MIXTURE
    5.
    发明申请
    PAPER AND CARDBOARD PACKAGING WITH BARRIER COATING OF A POLYMER MIXTURE 有权
    用聚合物混合物涂布纸和纸板包装

    公开(公告)号：US20120308749A1

    公开(公告)日：2012-12-06

    申请号：US13483762

    申请日：2012-05-30

    申请人： Hermann Seyffer ,  Carmen-Elena Cimpeanu ,  Heiko Diehl

    发明人： Hermann Seyffer ,  Carmen-Elena Cimpeanu ,  Heiko Diehl

    IPC分类号： B32B29/06 ,  B05D7/24 ,  B32B1/02

    CPC分类号： B32B29/06 ,  B32B2255/12 ,  B32B2553/00 ,  D21H11/14 ,  D21H19/10 ,  D21H19/24 ,  D21H19/30 ,  D21H19/82 ,  D21H21/16 ,  D21H27/10 ,  Y10T428/1303 ,  Y10T428/1307

    摘要： Paper or cardboard packaging produced from recycled paper contaminated by mineral oil, where the packaging includes a barrier layer obtained by applying an aqueous polymeric dispersion containing a mixture of at least two polymers A and B. Polymer A is obtained by emulsion polymerization of C1-C4 alkyl(meth)acrylates, acid monomers, e.g., acrylic acid or methacrylic acid, 0-20 wt % of acrylonitrile and 0-10 wt % of further monomers, where the glass transition temperature of copolymer A is greater than +45° C. and the glass transition temperature of polymer B is less than +10° C. The mean value calculated from the glass transition temperatures of the individual polymers is +10 to +45° C. The barrier layer may be situated on one of the surfaces of the packaging or form one of multiple layers of a multilayered packaging coating or be situated as a coating on one side of an inner bag situated within the packaging.

    摘要翻译： 由矿物油污染的再生纸生产的纸或纸板包装，其中包装包含通过施加含有至少两种聚合物A和B的混合物的水性聚合物分散体获得的阻隔层。聚合物A通过C1-C4的乳液聚合 烷基（甲基）丙烯酸酯，酸单体，例如丙烯酸或甲基丙烯酸，0-20重量％的丙烯腈和0-10重量％的其它单体，其中共聚物A的玻璃化转变温度大于+ 45℃。 聚合物B的玻璃化转变温度低于+ 10℃。由各聚合物的玻璃化转变温度计算出的平均值为+ 10〜+ 45℃。阻挡层可以位于 包装或形成多层包装涂料的多层之一，或者作为涂层位于位于包装内的内袋的一侧上。

    USE OF POLYELECTROLYTE COMPLEXES FOR PRODUCING POLYMER FOILS WITH OXYGEN-BARRIER PROPERTIES
    6.
    发明申请
    USE OF POLYELECTROLYTE COMPLEXES FOR PRODUCING POLYMER FOILS WITH OXYGEN-BARRIER PROPERTIES 有权
    用于生产具有氧阻挡性能的聚合物箔的聚电解质复合材料的应用

    公开(公告)号：US20120148855A1

    公开(公告)日：2012-06-14

    申请号：US13389680

    申请日：2010-08-17

    申请人： Carmen-Elena Cimpeanu ,  Thomas Breiner ,  Dieter Urban ,  Karl-Heinz Schumacher ,  Volker Schaedler ,  Heiko Diehl ,  Hermann Seyffer

    发明人： Carmen-Elena Cimpeanu ,  Thomas Breiner ,  Dieter Urban ,  Karl-Heinz Schumacher ,  Volker Schaedler ,  Heiko Diehl ,  Hermann Seyffer

    IPC分类号： B32B27/08 ,  B05D7/02 ,  B05D1/36 ,  C09D133/14 ,  C09D139/02

    CPC分类号： B05D5/00 ,  B05D7/00 ,  B05D7/56 ,  Y10T428/31928

    摘要： The use of polyelectrolyte complexes is described, for providing an oxygen barrier to packaging materials made of polymer foils. Polymeric components of the polyelectrolyte complex are applied in polymerized form to the polymer foil. The polymer foil is either coated with an aqueous dispersion comprising a dispersed polyelectrolyte complex previously produced by water-in-water emulsion polymerization, or is coated with a composition comprising a polyelectrolyte complex produced from anionic polymer and from cationic surfactant, or the polymer foil is coated with at least three alternating layers, where respectively one of two adjacent layers comprises an anionic polyelectrolyte component and the other of two adjacent layers comprises a cationic polyelectrolyte component, and polyelectrolyte complexes form at the opposite, adjacent interfaces of the alternating layers.

    摘要翻译： 描述了使用聚电解质络合物，用于为由聚合物箔制成的包装材料提供氧阻隔。 将聚电解质复合物的聚合物组分以聚合形式施加到聚合物箔上。 聚合物箔片涂覆有预先由水包水乳液聚合制备的分散的聚电解质络合物的水性分散体，或涂覆有包含由阴离子聚合物和阳离子表面活性剂产生的聚电解质络合物的组合物，或聚合物箔是 涂覆有至少三个交替层，其中两个相邻层中的一个分别包含阴离子聚电解质组分，并且两个相邻层中的另一个包含阳离子聚电解质组分，并且在交替层的相对的相邻界面处形成聚电解质络合物。

    Pressure-sensitive adhesive for PVC foils
    8.
    发明授权
    Pressure-sensitive adhesive for PVC foils 有权
    PVC箔压敏胶

    公开(公告)号：US09404023B2

    公开(公告)日：2016-08-02

    申请号：US13514773

    申请日：2010-12-06

    申请人： Carmen-Elena Cimpeanu ,  Cornelis Petrus Beyers ,  Andree Dragon

    发明人： Carmen-Elena Cimpeanu ,  Cornelis Petrus Beyers ,  Andree Dragon

    IPC分类号： C09J133/08 ,  C09J133/10 ,  C09J133/20 ,  C09J133/12 ,  C08F2/00 ,  C09J7/02

    CPC分类号： C09J133/08 ,  C08F2/001 ,  C09J7/245 ,  C09J7/385 ,  C09J133/12 ,  C09J133/20 ,  C09J2201/606 ,  C09J2433/00 ,  Y10T428/2887

    摘要： An adhesive is described, in particular for applications on substrate materials made of flexible PVC, comprising a polymer which is obtainable via free-radical polymerization of ethylenically unsaturated compounds and which is composed of at least 50% by weight of soft acrylate monomers with glass transition temperature below 0° C., at least 1% by weight of ethylenically unsaturated nitriles, at least 1% by weight of hard acrylate monomers with glass transition temperature of at least 60° C., at least 0.1% by weight of ethylenically unsaturated acid monomers, and at least 0.01% by weight of monomers having at least two non-conjugated, polymerizable vinyl groups, where the polymerization reaction takes place via staged polymerization, and at least one portion of the soft acrylate monomers is polymerized in a first polymerization stage, and at least one portion of the hard acrylate monomers is polymerized in a second or subsequent polymerization stage. Uses of the adhesive for the bonding of substrates made of flexible PVC are also described, as also are self-adhesive items with a PVC foil as substrate material and with a coating of the adhesive of the invention.

    摘要翻译： 描述了粘合剂，特别是用于由柔性PVC制成的基材上的应用，其包含可通过烯键式不饱和化合物的自由基聚合获得的聚合物，并且其由至少50重量％的具有玻璃化转变的软丙烯酸酯单体 温度低于0℃，至少1重量％的烯属不饱和腈，至少1重量％的玻璃化转变温度至少为60℃的硬质丙烯酸酯单体，至少0.1重量％的烯属不饱和酸 单体和至少0.01重量％的具有至少两个非共轭可聚合乙烯基的单体，其中通过分段聚合进行聚合反应，并且至少一部分软质丙烯酸酯单体在第一聚合阶段中聚合 ，并且至少一部分硬质丙烯酸酯单体在第二或随后的聚合阶段中聚合。 还描述了用于粘合由柔性PVC制成的基底的粘合剂的用途，以及具有PVC箔作为基底材料并具有本发明的粘合剂的涂层的自粘物品。

    Use of polyelectrolyte complexes for producing polymer foils with oxygen-barrier properties
    9.
    发明授权
    Use of polyelectrolyte complexes for producing polymer foils with oxygen-barrier properties 有权
    使用聚电解质复合物制备具有阻氧性能的聚合物薄膜

    公开(公告)号：US08980437B2

    公开(公告)日：2015-03-17

    申请号：US13389680

    申请日：2010-08-17

    申请人： Carmen-Elena Cimpeanu ,  Thomas Breiner ,  Dieter Urban ,  Karl-Heinz Schumacher ,  Volker Schaedler ,  Heiko Diehl ,  Hermann Seyffer

    发明人： Carmen-Elena Cimpeanu ,  Thomas Breiner ,  Dieter Urban ,  Karl-Heinz Schumacher ,  Volker Schaedler ,  Heiko Diehl ,  Hermann Seyffer

    IPC分类号： B32B27/08 ,  B05D7/00 ,  B05D5/00

    CPC分类号： B05D5/00 ,  B05D7/00 ,  B05D7/56 ,  Y10T428/31928

    摘要： The use of polyelectrolyte complexes is described, for providing an oxygen barrier to packaging materials made of polymer foils. Polymeric components of the polyelectrolyte complex are applied in polymerized form to the polymer foil. The polymer foil is either coated with an aqueous dispersion comprising a dispersed polyelectrolyte complex previously produced by water-in-water emulsion polymerization, or is coated with a composition comprising a polyelectrolyte complex produced from anionic polymer and from cationic surfactant, or the polymer foil is coated with at least three alternating layers, where respectively one of two adjacent layers comprises an anionic polyelectrolyte component and the other of two adjacent layers comprises a cationic polyelectrolyte component, and polyelectrolyte complexes form at the opposite, adjacent interfaces of the alternating layers.

    摘要翻译： 描述了使用聚电解质络合物，用于为由聚合物箔制成的包装材料提供氧阻隔。 将聚电解质复合物的聚合物组分以聚合形式施加到聚合物箔上。 聚合物箔片涂覆有预先由水包水乳液聚合制备的分散的聚电解质络合物的水性分散体，或涂覆有包含由阴离子聚合物和阳离子表面活性剂产生的聚电解质络合物的组合物，或聚合物箔是 涂覆有至少三个交替层，其中两个相邻层中的一个分别包含阴离子聚电解质组分，并且两个相邻层中的另一个包含阳离子聚电解质组分，并且在交替层的相对的相邻界面处形成聚电解质络合物。