PRESSURE-SENSITIVE ADHESIVE FOR PVC FOILS
    1.
    发明申请
    PRESSURE-SENSITIVE ADHESIVE FOR PVC FOILS 有权
    压敏粘胶用于PVC箔

    公开(公告)号:US20120244350A1

    公开(公告)日:2012-09-27

    申请号:US13514773

    申请日:2010-12-06

    IPC分类号: C09J4/02 B32B27/36

    摘要: An adhesive is described, in particular for applications on substrate materials made of flexible PVC, comprising a polymer which is obtainable via free-radical polymerization of ethylenically unsaturated compounds and which is composed of at least 50% by weight of soft acrylate monomers with glass transition temperature below 0° C., at least 1% by weight of ethylenically unsaturated nitriles, at least 1% by weight of hard acrylate monomers with glass transition temperature of at least 60° C., at least 0.1% by weight of ethylenically unsaturated acid monomers, and at least 0.01% by weight of monomers having at least two non-conjugated, polymerizable vinyl groups, where the polymerization reaction takes place via staged polymerization, and at least one portion of the soft acrylate monomers is polymerized in a first polymerization stage, and at least one portion of the hard acrylate monomers is polymerized in a second or subsequent polymerization stage. Uses of the adhesive for the bonding of substrates made of flexible PVC are also described, as also are self-adhesive items with a PVC foil as substrate material and with a coating of the adhesive of the invention.

    摘要翻译: 描述了粘合剂,特别是用于由柔性PVC制成的基材上的应用,其包含可通过烯键式不饱和化合物的自由基聚合获得的聚合物,并且其由至少50重量%的具有玻璃化转变的软丙烯酸酯单体 温度低于0℃,至少1重量%的烯属不饱和腈,至少1重量%的玻璃化转变温度至少为60℃的硬质丙烯酸酯单体,至少0.1重量%的烯属不饱和酸 单体和至少0.01重量%的具有至少两个非共轭可聚合乙烯基的单体,其中通过分段聚合进行聚合反应,并且至少一部分软质丙烯酸酯单体在第一聚合阶段中聚合 ,并且至少一部分硬质丙烯酸酯单体在第二或随后的聚合阶段中聚合。 还描述了用于粘合由柔性PVC制成的基底的粘合剂的用途,以及具有PVC箔作为基底材料并具有本发明的粘合剂的涂层的自粘物品。

    Pressure-sensitive adhesive for PVC foils
    2.
    发明授权
    Pressure-sensitive adhesive for PVC foils 有权
    PVC箔压敏胶

    公开(公告)号:US09404023B2

    公开(公告)日:2016-08-02

    申请号:US13514773

    申请日:2010-12-06

    摘要: An adhesive is described, in particular for applications on substrate materials made of flexible PVC, comprising a polymer which is obtainable via free-radical polymerization of ethylenically unsaturated compounds and which is composed of at least 50% by weight of soft acrylate monomers with glass transition temperature below 0° C., at least 1% by weight of ethylenically unsaturated nitriles, at least 1% by weight of hard acrylate monomers with glass transition temperature of at least 60° C., at least 0.1% by weight of ethylenically unsaturated acid monomers, and at least 0.01% by weight of monomers having at least two non-conjugated, polymerizable vinyl groups, where the polymerization reaction takes place via staged polymerization, and at least one portion of the soft acrylate monomers is polymerized in a first polymerization stage, and at least one portion of the hard acrylate monomers is polymerized in a second or subsequent polymerization stage. Uses of the adhesive for the bonding of substrates made of flexible PVC are also described, as also are self-adhesive items with a PVC foil as substrate material and with a coating of the adhesive of the invention.

    摘要翻译: 描述了粘合剂,特别是用于由柔性PVC制成的基材上的应用,其包含可通过烯键式不饱和化合物的自由基聚合获得的聚合物,并且其由至少50重量%的具有玻璃化转变的软丙烯酸酯单体 温度低于0℃,至少1重量%的烯属不饱和腈,至少1重量%的玻璃化转变温度至少为60℃的硬质丙烯酸酯单体,至少0.1重量%的烯属不饱和酸 单体和至少0.01重量%的具有至少两个非共轭可聚合乙烯基的单体,其中通过分段聚合进行聚合反应,并且至少一部分软质丙烯酸酯单体在第一聚合阶段中聚合 ,并且至少一部分硬质丙烯酸酯单体在第二或随后的聚合阶段中聚合。 还描述了用于粘合由柔性PVC制成的基底的粘合剂的用途,以及具有PVC箔作为基底材料并具有本发明的粘合剂的涂层的自粘物品。