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    Polyolefin-substituted amines grafted with poly(aromatic-N-monomers) for oleaginous compositions
    1.
    发明授权
    Polyolefin-substituted amines grafted with poly(aromatic-N-monomers) for oleaginous compositions 失效
    与聚（芳族-N-单体）接枝的聚烯烃取代的胺用于油性组合物

    公开(公告)号：US5633326A

    公开(公告)日：1997-05-27

    申请号：US668313

    申请日：1996-06-26

    申请人： Abhimanyu O. Patil ,  Robert D. Lundberg ,  Antonio Gutierrez

    发明人： Abhimanyu O. Patil ,  Robert D. Lundberg ,  Antonio Gutierrez

    IPC分类号： C08F8/30 ,  C08F8/32 ,  C08F271/00 ,  C10L1/22 ,  C10L1/238 ,  C10L1/24 ,  C10L1/30 ,  C10L10/00 ,  C10M143/00 ,  C10M143/12 ,  C10M149/00 ,  C10M159/12 ,  C10M159/16

    CPC分类号： C08F271/00 ,  C08F8/32 ,  C08F8/42 ,  C10L1/221 ,  C10L1/238 ,  C10L1/2475 ,  C10L1/303 ,  C10L10/04 ,  C10M143/00 ,  C10M143/12 ,  C10M149/00 ,  C10M159/12 ,  C10M159/16 ,  C08F2800/10 ,  C10M2205/00 ,  C10M2205/02 ,  C10M2215/04 ,  C10M2215/042 ,  C10M2215/26 ,  C10M2217/00 ,  C10M2217/02 ,  C10M2217/04 ,  C10M2217/042 ,  C10M2217/043 ,  C10M2217/046 ,  C10M2217/06 ,  C10M2227/00

    摘要： Novel polymers comprising polyolefin-substituted amines grafted with aromatic N-containing monomers such as aniline, have been found to provide oil soluble polymers having dispersant and antioxidant properties in oleaginous compositions, including fuel and lubricating oils. The polymers of this invention are further useful in electrical applications. These materials are formed by a process which comprises: (a) contacting an amine compound having at least two reactive nitrogen moieties with at least one long chain hydrocarbon-substituted reactant in an amount and under conditions sufficient to form a N-containing polymer adduct containing reactive amine groups, and (b) contacting the N-containing polymer adduct with at least one aromatic N-containing monomer under polymerization conditions to graft said N-containing polymer adduct with aromatic N-containing polymer segments. The long chain hydrocarbon-substituted reactant can comprise materials such as (i) long chain hydrocarbons substituted with mono- or dicarboxylic acid, anhydride or ester groups; (ii) halogenated long chain hydrocarbons; (iii) mixtures of formaldehyde and a long chain hydrocarbyl substituted phenol; and (iv) mixtures of formaldehyde and a reaction product formed by reaction of long chain hydrocarbons substituted with mono- or dicarboxylic acid, anhydride or ester groups and an amino-substituted, optionally hydrocarbyl-substituted phenol.

    摘要翻译： 已经发现包含与芳族含N单体如苯胺接枝的聚烯烃取代的胺的新型聚合物在含油组合物（包括燃料和润滑油）中提供具有分散剂和抗氧化性能的油溶性聚合物。 本发明的聚合物在电气应用中更有用。 这些材料通过一种方法形成，该方法包括：（a）使具有至少两个反应性氮部分的胺化合物与至少一种长链烃取代的反应物以足以形成含有N的聚合物加合物的量和条件 反应性胺基，和（b）在聚合条件下使含N聚合物加合物与至少一种含芳族N的单体接触，以使含有N的聚合物链段与含N的聚合物链段接枝。 长链烃取代的反应物可以包括以下材料，例如（i）被单或二羧酸，酸酐或酯基取代的长链烃; （ii）卤代长链烃; （iii）甲醛和长链烃基取代的苯酚的混合物; 和（iv）甲醛和通过用单或二羧酸，酸酐或酯基和氨基取代的任选被烃基取代的苯酚取代的长链烃反应形成的反应产物的混合物。