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公开(公告)号:US10792616B2
公开(公告)日:2020-10-06
申请号:US15752112
申请日:2016-08-12
Applicant: BASF Corporation
Inventor: Xiaoming Wang , Xiaofan Yang , Meaghan C. McGuire , Geoffrey M. Johnson , John K. Hochmuth
Abstract: The present disclosure is directed to SCR catalysts, methods for their manufacture, and methods of treating emissions in an exhaust stream with them. The SCR catalysts are produced from pillaring and ion exchanging synthetic phyllosilicates, particularly hydrothermally synthesized phyllosilicates.
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公开(公告)号:US10247071B2
公开(公告)日:2019-04-02
申请号:US15508744
申请日:2015-08-28
Applicant: BASF CORPORATION
Inventor: Xiaoming Wang , Michel Deeba , Xiaolai Zheng , Sven Titlbach , Andreas Sundermann , Stephan Andreas Schunk
IPC: F01N3/10 , B01D53/94 , B01J21/06 , B01J21/08 , B01J23/00 , B01J23/10 , B01J23/58 , B01J23/63 , B01J37/02 , B01J37/03 , B01J37/04 , B01J37/08 , B01J23/46 , B01J35/10 , B01J37/00
Abstract: Composites of mixed metal oxides for an exhaust gas purifying catalyst comprise the following co-precipitated materials by weight of the composite: zirconia in an amount in the range of 55-99%; titania in an amount in the range of 1-25%; a promoter and/or a stabilizer in an amount in the range of 0-20%. These composites are effective as supports for platinum group metals (PGMs), in particular rhodium.
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公开(公告)号:US20180236402A1
公开(公告)日:2018-08-23
申请号:US15752112
申请日:2016-08-12
Applicant: BASF Corporation
Inventor: Xiaoming Wang , Xiaofan Yang , Meaghan C. McGuire , Geoffrey M. Johnson , John K. Hochmuth
Abstract: The present disclosure is directed to SCR catalysts, methods for their manufacture, and methods of treating emissions in an exhaust stream with them. The SCR catalysts are produced from pillaring and ion exchanging synthetic phyllosilicates, particularly hydrothermally synthesized phyllosilicates.
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4.
公开(公告)号:US20130336864A1
公开(公告)日:2013-12-19
申请号:US13916727
申请日:2013-06-13
Applicant: BASF CORPORATION
Inventor: Xiaolai Zheng , Xiaoming Wang , Knut Wassermann
CPC classification number: B01J23/63 , B01D53/945 , B01D2255/2065 , B01D2255/20715 , B01D2255/2092 , B01D2255/908 , B01J35/1019 , B01J35/1042 , B01J35/1047 , B01J37/0215 , B01J37/031 , B01J37/10 , B01J2523/00 , Y02T10/22 , B01J2523/36 , B01J2523/3706 , B01J2523/3712 , B01J2523/48 , B01J2523/31 , B01J2523/3725 , B01J2523/3718
Abstract: Provided are composites of mixed metal oxides comprising: a ceria-zirconia-alumina composite, wherein the alumina is present in an amount in the range of 1 to less than 30% by weight of the composite and the mixed metal oxide composite has a ceria reducibility of at least 50% after 12 hours of hydrothermal aging at 1050° C. In preparation thereof, a ceria-zirconia solid solution can optionally further comprise at least one rare earth oxide other than ceria and the alumina may be formed by using a colloidal alumina precursor. Methods of making and using these composites are also provided.
Abstract translation: 提供了包含二氧化铈 - 氧化锆 - 氧化铝复合材料的复合金属氧化物的复合材料,其中氧化铝的存在量为复合材料的1至小于30重量%,并且混合金属氧化物复合材料具有二氧化铈还原性 在1050℃下水热老化12小时后至少为50%。在其制备中,二氧化铈 - 氧化锆固溶体可以任选地还可包含至少一种除二氧化铈之外的稀土氧化物,氧化铝可以通过使用胶态氧化铝 前体 还提供了制备和使用这些复合材料的方法。
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公开(公告)号:US09931596B2
公开(公告)日:2018-04-03
申请号:US15503903
申请日:2015-10-21
Applicant: BASF CORPORATION
Inventor: Xiaolai Zheng , Chunxin Ji , Wen-Mei Xue , Matthew J. Schladt , Xiaoming Wang , Tian Luo , Michel Deeba , Knut Wassermann
CPC classification number: B01D53/945 , B01D53/9418 , B01D53/9477 , B01D2255/1021 , B01D2255/1023 , B01D2255/1025 , B01D2255/2042 , B01D2255/2065 , B01D2255/20715 , B01D2255/20761 , B01D2255/2092 , B01D2255/50 , B01D2255/502 , B01D2255/9022 , B01D2255/912 , B01D2255/9207 , B01J23/56 , B01J23/63 , B01J29/005 , B01J29/40 , B01J29/46 , B01J29/7007 , B01J29/76 , B01J29/7615 , B01J29/763 , B01J29/80 , B01J29/85 , B01J35/0006 , B01J37/0244 , B01J37/0246 , B01J2523/00 , Y02T10/24 , B01J2523/25 , B01J2523/31 , B01J2523/37 , B01J2523/3712 , B01J2523/48 , B01J2523/824 , B01J2523/822 , B01J2523/828
Abstract: An emissions treatment system for an exhaust stream of an internal combustion engine including hydrocarbons, carbon monoxide, and nitrogen oxides is provided. The disclosed system can include an exhaust conduit in fluid communication with the internal combustion engine via an exhaust manifold; a first three-way conversion catalyst (TWC-1) located downstream of the internal combustion engine in the exhaust conduit; an SCR-HCT catalyst comprising a selective catalytic reduction catalyst and a hydrocarbon trap downstream of the TWC-1 in the exhaust conduit; and a third catalyst downstream of the SCR-HCT combination in the exhaust conduit, the third catalyst comprising a platinum group metal (PGM) e.g., in an amount effective to oxidize hydrocarbons. Methods of making and using such systems and components thereof are also provided.
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公开(公告)号:US20190105636A1
公开(公告)日:2019-04-11
申请号:US16094646
申请日:2017-02-28
Applicant: BASF Corporation
Inventor: Xiaoming Wang , Michel Deeba
Abstract: The present disclosure provides a three-way conversion (TWC) catalyst composition suitable for at least partial conversion of gaseous hydrocarbons (HC), carbon monoxide (CO), and nitrogen oxides (NOx). Generally, the catalyst composition comprises a platinum group metal component impregnated into a porous refractory oxide support, wherein the porous refractory oxide support has an average pore radius ranging from about 250 Å to about 5,000 Å, a total intrusion volume of at least about 1.8 ml/g, and a porosity of at least about 80%.
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7.
公开(公告)号:US20190178128A1
公开(公告)日:2019-06-13
申请号:US16278654
申请日:2019-02-18
Applicant: BASF Corporation
Inventor: Xiaoming Wang , Michel Deeba , Xiaolai Zheng , Sven Titlbach , Andreas Sundermann , Stephan Andreas Schunk
IPC: F01N3/10 , B01J23/46 , B01D53/94 , B01J37/02 , B01J37/03 , B01J37/04 , B01J37/08 , B01J21/06 , B01J23/00 , B01J23/10 , B01J23/63
Abstract: Composites of mixed metal oxides for an exhaust gas purifying catalyst comprise the following co-precipitated materials by weight of the composite: zirconia in an amount in the range of 55-99%; titania in an amount in the range of 1-25%; a promoter and/or a stabilizer in an amount in the range of 0-20%. These composites are effective as supports for platinum group metals (PGMs), in particular rhodium.
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公开(公告)号:US10883402B2
公开(公告)日:2021-01-05
申请号:US16278654
申请日:2019-02-18
Applicant: BASF CORPORATION
Inventor: Xiaoming Wang , Michel Deeba , Xiaolai Zheng , Sven Titlbach , Andreas Sundermann , Stephan Andreas Schunk
IPC: B01J21/06 , B01J23/00 , B01J23/10 , B01J37/02 , B01J37/03 , B01J37/04 , B01J37/08 , F01N3/10 , B01J23/63 , B01D53/94 , B01J23/46 , B01J23/58 , B01J35/10 , B01J37/00
Abstract: Composites of mixed metal oxides for an exhaust gas purifying catalyst comprise the following co-precipitated materials by weight of the composite: zirconia in an amount in the range of 55-99%; titania in an amount in the range of 1-25%; a promoter and/or a stabilizer in an amount in the range of 0-20%. These composites are effective as supports for platinum group metals (PGMs), in particular rhodium.
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公开(公告)号:US10850265B2
公开(公告)日:2020-12-01
申请号:US14741756
申请日:2015-06-17
Applicant: BASF Corporation
Inventor: Xiaofan Yang , John K. Hochmuth , Wen-Mei Xue , Xiaoming Wang , Matthew Tyler Caudle , Ahmad Moini , Dustin O. Hollobaugh , Qi Fu , Michael Breen
IPC: B01D53/94 , B01J29/89 , B01J29/76 , B01J35/04 , B01J35/02 , B01J37/02 , B01J35/00 , B01J29/04 , C01B39/06 , B01J29/80 , B01J29/63 , B01J29/10
Abstract: Described is a selective catalytic reduction catalyst comprising a zeolitic framework material of silicon and aluminum atoms, wherein a fraction of the silicon atoms are isomorphously substituted with a tetravalent metal. The catalyst can include a promoter metal such that the catalyst effectively promotes the reaction of ammonia with nitrogen oxides to form nitrogen and H2O selectively over a temperature range of 150 to 650° C. In another aspect, described is a selective catalytic reduction composite comprising an SCR catalyst material and an ammonia storage material comprising a transition metal having an oxidation state of IV. The SCR catalyst material promotes the reaction of ammonia with nitrogen oxides to form nitrogen and H2O selectively over a temperature range of 150° C. to 600° C., and the SCR catalyst material is effective to store ammonia at temperatures of 400° C. and above. A method for selectively reducing nitrogen oxides, and a method for simultaneously selectively reducing nitrogen oxide and storing ammonia are also described. Additionally, an exhaust gas treatment system is also described.
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10.
公开(公告)号:US20170284251A1
公开(公告)日:2017-10-05
申请号:US15508744
申请日:2015-08-28
Applicant: BASF CORPORATION
Inventor: Xiaoming Wang , Michel Deeba , Xiaolai Zheng , Sven Titlbach , Andreas Sundermann , Stephan Andreas Schunk
CPC classification number: F01N3/101 , B01D53/945 , B01D2255/102 , B01D2255/1025 , B01D2255/204 , B01D2255/2061 , B01D2255/2063 , B01D2255/2065 , B01D2255/2066 , B01D2255/2068 , B01D2255/20707 , B01D2255/20715 , B01D2255/20776 , B01D2255/30 , B01J21/066 , B01J23/002 , B01J23/10 , B01J23/46 , B01J23/464 , B01J23/58 , B01J23/63 , B01J35/1014 , B01J37/0018 , B01J37/0201 , B01J37/0215 , B01J37/0219 , B01J37/0225 , B01J37/0236 , B01J37/0244 , B01J37/0248 , B01J37/03 , B01J37/031 , B01J37/04 , B01J37/08 , B01J2523/00 , Y02T10/22 , B01J2523/25 , B01J2523/31 , B01J2523/48 , B01J2523/824 , B01J2523/3706 , B01J2523/47 , B01J2523/822
Abstract: Composites of mixed metal oxides for an exhaust gas purifying catalyst comprise the following co-precipitated materials by weight of the composite: zirconia in an amount in the range of 55-99%; titania in an amount in the range of 1-25%; a promoter and/or a stabilizer in an amount in the range of 0-20%. These composites are effective as supports for platinum group metals (PGMs), in particular rhodium.
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