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公开(公告)号：US4744970A
公开(公告)日：1988-05-17
申请号：US600174
申请日：1984-04-13
IPC分类号： C10G11/02 , B01J20/10 , B01J29/00 , B01J29/85 , C01B37/04 , C01B37/08 , C01B39/04 , C01B39/10 , C07C2/12 , C07C2/54 , C07C5/02 , C07C5/22 , C07C5/27 , C07C5/41 , C10G11/00 , C10G49/08 , C01B25/00 , B01J29/02 , C01B33/26
CPC分类号： C07C5/41 , B01J29/85 , C01B37/08 , C07C2/12 , C07C2/54 , C07C5/02 , C07C5/224 , C07C5/2716 , C07C2529/84
摘要： Crystalline molecular sieves having three-dimensional microporous framework structures of CoO.sub.2, AlO.sub.2, SiO.sub.2, PO.sub.2 and tetrahedral units are disclosed. These molecular sieves have an empirical chemical composition on an anhydrous basis expressed by the formula:mR: (Co.sub.w Al.sub.x P.sub.y Si.sub.z)O.sub.2wherein "R" represents at least one organic templating agent present in the intracrystalline pore system; "m" represents the molar amount of "R" present per mole of (Co.sub.w Al.sub.x P.sub.y Si.sub.z)O.sub.2 ; and "w", "x", "y" and "z" represent the mole fractions of cobalt, aluminum, phosphorus and silicon, respectively, present as tetrahedral oxides. Their use as adsorbents catalysts, etc. is also disclosed.
摘要翻译： 公开了具有CoO 2，AlO 2，SiO 2，PO 2和四面体单元的三维微孔骨架结构的结晶分子筛。 这些分子筛具有以下公式表示的无水基础上的经验化学组成：mR：（CowAlxPySiz）O 2，其中“R”表示存在于晶体内孔系统中的至少一种有机模板剂; “m”表示每摩尔（CowAlxPySiz）O 2存在的“R”摩尔量; 和“w”，“x”，“y”和“z”分别表示作为四面体氧化物存在的钴，铝，磷和硅的摩尔分数。 还公开了它们作为吸附剂催化剂等的用途。
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公开(公告)号：US4793984A
公开(公告)日：1988-12-27
申请号：US600312
申请日：1984-04-13
申请人： Brent M. Lok , Bonita K. Marcus , Lawrence D. Vail , Edith M. Flanigen , Robert L. Patton , Stephen T. Wilson
发明人： Brent M. Lok , Bonita K. Marcus , Lawrence D. Vail , Edith M. Flanigen , Robert L. Patton , Stephen T. Wilson
IPC分类号： B01J20/18 , B01J29/04 , B01J29/85 , C01B37/06 , C01B37/08 , C01B39/04 , C01B39/10 , C01B39/12 , C07B61/00 , C07C2/12 , C07C2/54 , C07C2/70 , C07C2/86 , C07C4/06 , C07C4/08 , C07C5/02 , C07C5/22 , C07C5/27 , C07C5/41 , C01B25/26 , B01J27/182
CPC分类号： C07C5/41 , B01J29/85 , C01B37/06 , C01B37/08 , C07C2/12 , C07C2/54 , C07C4/06 , C07C5/02 , C07C5/224 , C07C5/2716 , C07C2527/173 , C07C2529/84 , Y10S423/30
摘要： Crystalline molecular sieves having three-dimensional microporous framework structures of ELO.sub.2, AlO.sub.2, SiO.sub.2 and PO.sub.2 framework oxide units are disclosed. The molecular sieves have an empirical chemical composition on an anhydrous basis expressed by the formula:mR: (EL.sub.w Al.sub.x P.sub.y Si.sub.z)O.sub.2wherein "R" represents at least one organic templating agent present in the intracrystalline pore system: "m" represents the molar amount of "R" present per mole of (El.sub.w Al.sub.x P.sub.y Si.sub.z)O.sub.2 ; "EL" represents at least one element capable of forming a framework oxide unit; and "w", "x", "y" and "z" represent the mole fractions of element(s) "EL", aluminum, phosphorus and silicon, respectively, present as framework oxides. Their use as adsorbents, catalysts, etc. is also disclosed.
摘要翻译： 公开了具有ELO2，AlO2，SiO2和PO2骨架氧化物单元的三维微孔骨架结构的结晶分子筛。 分子筛具有由下式表示的无水基础上的经验化学组成：mR：（ELwAlxPySiz）O 2其中“R”表示存在于晶体内孔系统中的至少一种有机模板剂：“m”表示“ 每摩尔（ElwAlxPySiz）O2存在R“ “EL”表示能够形成骨架氧化物单元的至少一种元素; 和“w”，“x”，“y”和“z”分别表示作为骨架氧化物存在的元素“EL”，铝，磷和硅的摩尔分数。 还公开了它们作为吸附剂，催化剂等的用途。
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公开(公告)号：US4857288A
公开(公告)日：1989-08-15
申请号：US50017
申请日：1987-05-15
申请人： Bonita K. Marcus , Brent M. Lok
发明人： Bonita K. Marcus , Brent M. Lok
摘要： Novel crystalline aluminosilicate composition denominated LZ-135 and having uniform pore diameters of approximately 4.3 Angstroms is prepared hydrothermally from a reaction mixture containing as essential reagents, water, an alkali or alkaline earth oxide, alumina, silica and as the templating agent a mixture of the ion species tetramethylammonium ions and tetraethylammonium.
摘要翻译： 以含有作为必需试剂，水，碱金属或碱土金属氧化物，氧化铝，二氧化硅和作为模板剂的反应混合物水热制备名为LZ-135并具有约4.3埃均匀孔径的新型结晶硅铝酸盐组合物， 离子物质四甲基铵离子和四乙基铵。
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公开(公告)号：US4846956A
公开(公告)日：1989-07-11
申请号：US250407
申请日：1988-09-28
CPC分类号： C07C5/41 , B01J29/85 , C01B37/08 , C07C2/12 , C07C2/54 , C07C5/02 , C07C5/224 , C07C5/2716 , C07C2527/173 , C07C2529/84
摘要： Crystalline molecular sieves having three-dimensional microporous framework structures of MnO.sub.2, AlO.sub.2, SiO.sub.2 and PO.sub.2 tetrahedral oxide units are disclosed. These molecular sieves have an empirical chemical composition on an anhydrous basis expressed by the formula:mR: (Mn.sub.w Al.sub.x P.sub.y Si.sub.z)O.sub.2wherein "R" represents at least one organic templating agent present in the intracrystalline pore system; "m" represents the molar amount of "R" present per mole of (Mn.sub.w Al.sub.x P.sub.y Si.sub.z)O.sub.2 ; and "w", "x", "y" and "z" represent the mole fractions of manganese, aluminum, phosphorus and silicon, respectively, present as tetrahedral oxides. Their use as adsorbents, catalysts, etc. is also disclosed.
摘要翻译： 公开了具有MnO 2，AlO 2，SiO 2和PO 2四面体氧化物单元的三维微孔骨架结构的结晶分子筛。 这些分子筛具有无水基础上的经验化学组成，其由下式表示：mR：（MnwAlxPySiz）O 2其中“R”表示存在于晶体内孔系统中的至少一种有机模板剂; “m”表示每摩尔（MnwAlxPySiz）O 2存在的“R”摩尔量; 和“w”，“x”，“y”和“z”分别表示作为四面体氧化物存在的锰，铝，磷和硅的摩尔分数。 还公开了它们作为吸附剂，催化剂等的用途。
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5.发明授权Processes for the use of cobalt-aluminum-phosphorus-silicon-oxide molecular sieve compositions 失效使用钴 - 铝 - 磷 - 氧化硅分子筛组合物的方法
公开(公告)号：US4824554A
公开(公告)日：1989-04-25
申请号：US149590
申请日：1988-01-28
IPC分类号： B01J29/85 , C01B37/08 , C07C2/12 , C07C2/54 , C07C5/02 , C07C5/22 , C07C5/27 , C07C5/41 , C10G47/02 , C07C2/68 , C07C4/12
CPC分类号： C07C5/41 , B01J29/85 , C01B37/08 , C07C2/12 , C07C2/54 , C07C5/02 , C07C5/224 , C07C5/2716 , C07C2527/173 , C07C2529/84
摘要： Crystalline molecular sieves having three-dimensional microporous framework structures of CoO.sub.2, AlO.sub.2, SiO.sub.2, PO.sub.2 and tetrahedral units are disclosed. These molecular sieves have an empirical chemical composition on an anhydrous basis expressed by the formula:mR: (Co.sub.w Al.sub.x P.sub.y Si.sub.z)O.sub.2wherein "R" represents at least one organic templating agent present in the intracrystalline pore system; "m" represents the molar amount of "R" present per mole of (Co.sub.w Al.sub.x P.sub.y Si.sub.z)O.sub.2 ; and "w", "x", "y" and "z" represent the mole fractions of cobalt, aluminum, phosphorus and silicon, respectively, present as tetrahedral oxides. Their use as adsorbents, catalysts, etc. is also disclosed.
摘要翻译： 公开了具有CoO 2，AlO 2，SiO 2，PO 2和四面体单元的三维微孔骨架结构的结晶分子筛。 这些分子筛具有以下公式表示的无水基础上的经验化学组成：mR：（CowAlxPySiz）O 2，其中“R”表示存在于晶体内孔系统中的至少一种有机模板剂; “m”表示每摩尔（CowAlxPySiz）O 2存在的“R”摩尔量; 和“w”，“x”，“y”和“z”分别表示作为四面体氧化物存在的钴，铝，磷和硅的摩尔分数。 还公开了它们作为吸附剂，催化剂等的用途。
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公开(公告)号：US5160717A
公开(公告)日：1992-11-03
申请号：US545153
申请日：1990-06-28
CPC分类号： C01B39/065 , B01J29/89 , C07C2/12 , C07C5/02 , C07C5/41 , C07C2529/89
摘要： Titanium-aluminum-silicon-oxide molecular sieves having three-dimensional microporous crystalline framework structures of tetrahedral oxide units TiO.sub.2, AlO.sub.2 and SiO.sub.2 are disclosed having use as molecular sieves and as catalyst compositions in hydrocarbon conversion and other processes.
摘要翻译： 公开了具有四面体氧化物单元TiO 2，AlO 2和SiO 2的三维微孔结晶骨架结构的钛 - 铝 - 氧化硅分子筛，其用作烃转化和其它方法中的分子筛和催化剂组合物。
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公开(公告)号：US5013335A
公开(公告)日：1991-05-07
申请号：US247642
申请日：1988-09-22
申请人： Bonita K. Marcus
发明人： Bonita K. Marcus
CPC分类号： B01J20/18 , B01D53/02 , Y10S95/902
摘要： Ammonia, particularly aqueous ammonia is sequestered in unexpected large amounts on zeolite molecular sieves having high proportions of silica with respect to alumina in their crystal frameworks. While conventional adsorption mechanisms are to some degree involved, it is apparent from the fact that the characteristic odor of ammonia is not detectable by the human sense of smell over the ammonia-loaded adsorbents indicates that other mechanisms are operable. These properties provide the basis for processes and products which are useful in removing ammonia from an environment to alleviate health hazards or unpleasant odor.
摘要翻译： 在其晶体框架中，相对于氧化铝具有高比例的二氧化硅的沸石分子筛，氨在特别是氨水中被多次螯合。 虽然传统的吸附机理在某种程度上涉及到，但是由于氨的特征气味在氨负载的吸附剂上不能被人的嗅觉感觉到，因此其他机制是可操作的，这是显而易见的。 这些性质为从环境中去除氨以减轻健康危害或令人不愉快的气味有用的方法和产品提供依据。
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公开(公告)号：US4855154A
公开(公告)日：1989-08-08
申请号：US206276
申请日：1988-06-14
CPC分类号： B01D53/02 , B01J20/18 , Y10S208/02
摘要： Marine oils are deodorized by contact with an effective amount of crystalline siliceous molecular sieves having strongly organophilic properties and pore diameters of at least 5.5 Angstroms. The molecular sieves selectively adsorb odorous organic amines and other odor-producing molecular species, such as aldehydes and ketones, without alteration of the essential unsaturated fatty acid triglycerides.
摘要翻译： 海洋油通过与有效量的具有强亲合性和孔直径至少为5.5埃的结晶硅质分子筛接触来除臭。 分子筛选择性地吸附臭味有机胺和其它产生气味的分子物质，例如醛和酮，而不改变必需的不饱和脂肪酸甘油三酸酯。
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公开(公告)号：US4684617A
公开(公告)日：1987-08-04
申请号：US600179
申请日：1984-04-13
IPC分类号： C10G49/08 , B01J20/18 , B01J29/00 , B01J29/85 , C01B37/08 , C01B39/04 , C07C1/00 , C07C2/12 , C07C2/54 , C07C2/66 , C07C5/02 , C07C5/22 , C07C5/27 , C07C5/41 , C07C6/04 , C07C6/12 , C07C11/02 , C07C15/08 , C07C67/00 , B01J27/14 , C01B25/36
CPC分类号： C07C5/41 , B01J29/85 , C01B37/08 , C07C2/12 , C07C2/54 , C07C5/02 , C07C5/224 , C07C5/2716 , C07C2529/84
摘要： Crystalline molecular sieves having three-dimensional microporous framework structures of TiO.sub.2, AlO.sub.2, SiO.sub.2 and PO.sub.2 tetrahedral units are disclosed. These molecular sieves have an empirical chemical composition on an anhydrous basis expressed by the formula:mR:(Ti.sub.w Al.sub.x P.sub.y Si.sub.z)O.sub.2wherein "R" represents at least one organic templating agent present in the intracrystalline pore system; "m" represents the molar amount of "R" present per mole of (Ti.sub.w Al.sub.x P.sub.y Si.sub.z)O.sub.2 ; and "w", "x", "y" and "z" represent the mole fractions of titanium, aluminum, phosphorus and silicon, respectively, present as tetrahedral oxides. Their use as adsorbents, catalysts, etc. is also disclosed.
摘要翻译： 公开了具有TiO 2，AlO 2，SiO 2和PO 2四面体单元的三维微孔骨架结构的结晶分子筛。 这些分子筛具有由下式表示的无水基础上的经验化学组成：mR：（TiwAlxPySiz）O 2，其中“R”表示存在于晶体内孔系统中的至少一种有机模板剂; “m”表示每摩尔（TiwAlxPySiz）O 2存在的“R”摩尔量; 和“w”，“x”，“y”和“z”分别表示作为四面体氧化物存在的钛，铝，磷和硅的摩尔分数。 还公开了它们作为吸附剂，催化剂等的用途。
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公开(公告)号：US06521208B1
公开(公告)日：2003-02-18
申请号：US09673286
申请日：2000-12-19
申请人： David A. Cooper , William E. Cormier , Elliot P. Hertzenberg , Richard J. Hinchey , Bonita K. Marcus
发明人： David A. Cooper , William E. Cormier , Elliot P. Hertzenberg , Richard J. Hinchey , Bonita K. Marcus
IPC分类号： C01B3924
CPC分类号： B01J20/18 , B01J20/186 , B01J29/084 , B01J2229/36 , C01B39/026 , Y10S423/21
摘要： A hydrophobic zeolite is prepared having high Hydrophobicity Index number by calcining a zeolite with steam under turbulent condition with respect to flow pattern of the zeolite and at a temperature within the range of 650-1000° C.
摘要翻译： 制备疏水性沸石，其具有高的疏水性指数，通过相对于沸石的流动模式在650-1000℃的温度下在湍流条件下用蒸汽煅烧沸石
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