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    THERMOPLASTIC ELASTOMER COMPOSITION AND METHOD FOR PRODUCING THE SAME
    1.
    发明申请
    THERMOPLASTIC ELASTOMER COMPOSITION AND METHOD FOR PRODUCING THE SAME 有权
    热塑性弹性体组合物及其制造方法

    公开(公告)号：US20110003928A1

    公开(公告)日：2011-01-06

    申请号：US12865407

    申请日：2009-02-04

    申请人： Daisuke Shimizu ,  Yasuhiro Kusanose ,  Yoshifumi Araki ,  Masahiro Fujiwara

    发明人： Daisuke Shimizu ,  Yasuhiro Kusanose ,  Yoshifumi Araki ,  Masahiro Fujiwara

    IPC分类号： C08L53/02

    CPC分类号： C08F297/046 ,  C08L53/02 ,  C08L77/00 ,  C08L2205/02 ,  C08L2205/03 ,  C08L2312/00 ,  C08L2666/24 ,  C08L2666/04

    摘要： The present invention provides a thermoplastic elastomer composition obtained by dynamically crosslinking, under a melting condition, 100 parts by mass of a block copolymer (I), 1 to 1,000 parts by mass of a polar resin (II), 1 to 500 parts by mass of a modified polymer (III), and 0.01 to 50 parts by mass of a crosslinking agent (IV), wherein the block copolymer (I) comprises at least one polymer block (A) comprising as a main component an alkylene unit, and/or at least one copolymer block (B) comprising as main components an alkylene unit (b-1) and a vinyl aromatic monomer unit (b-2), and comprises at least one unsaturated block (C) comprising as a main component a conjugated diene monomer unit having 5 or more carbon atoms at an end.

    摘要翻译： 本发明提供一种热塑性弹性体组合物，其在熔融条件下动态交联100质量份的嵌段共聚物（I），1〜1000质量份的极性树脂（II），1〜500质量份 的改性聚合物（III）和0.01〜50质量份的交联剂（IV），其中嵌段共聚物（I）包含至少一种包含作为主要成分的亚烷基单元的聚合物嵌段（A）和/ 或至少一种包含亚烷基单元（b-1）和乙烯基芳族单体单元（b-2）的主要组分）的共聚物嵌段（B），并且包含至少一种不饱和嵌段（C），其包含作为主要组分的共轭 在末端具有5个或更多个碳原子的二烯单体单元。

    Thermoplastic elastomer composition and method for producing the same
    2.
    发明授权
    Thermoplastic elastomer composition and method for producing the same 有权
    热塑性弹性体组合物及其制造方法

    公开(公告)号：US08415428B2

    公开(公告)日：2013-04-09

    申请号：US12865407

    申请日：2009-02-04

    申请人： Daisuke Shimizu ,  Yasuhiro Kusanose ,  Yoshifumi Araki ,  Masahiro Fujiwara

    发明人： Daisuke Shimizu ,  Yasuhiro Kusanose ,  Yoshifumi Araki ,  Masahiro Fujiwara

    IPC分类号： C08L53/02 ,  C08L77/00

    CPC分类号： C08F297/046 ,  C08L53/02 ,  C08L77/00 ,  C08L2205/02 ,  C08L2205/03 ,  C08L2312/00 ,  C08L2666/24 ,  C08L2666/04

    摘要： The present invention provides a thermoplastic elastomer composition obtained by dynamically crosslinking, under a melting condition, 100 parts by mass of a block copolymer (I), 1 to 1,000 parts by mass of a polar resin (II), 1 to 500 parts by mass of a modified polymer (III), and 0.01 to 50 parts by mass of a crosslinking agent (IV), wherein the block copolymer (I) comprises at least one polymer block (A) comprising as a main component an alkylene unit, and/or at least one copolymer block (B) comprising as main components an alkylene unit (b-1) and a vinyl aromatic monomer unit (b-2), and comprises at least one unsaturated block (C) comprising as a main component a conjugated diene monomer unit having 5 or more carbon atoms at an end.

    摘要翻译： 本发明提供一种热塑性弹性体组合物，其在熔融条件下动态交联100质量份的嵌段共聚物（I），1〜1000质量份的极性树脂（II），1〜500质量份 的改性聚合物（III）和0.01〜50质量份的交联剂（IV），其中嵌段共聚物（I）包含至少一种包含作为主要成分的亚烷基单元的聚合物嵌段（A）和/ 或至少一种包含亚烷基单元（b-1）和乙烯基芳族单体单元（b-2）的主要组分）的共聚物嵌段（B），并且包含至少一种不饱和嵌段（C），其包含作为主要组分的共轭 在末端具有5个或更多个碳原子的二烯单体单元。

    CROSSLINKABLE AND FOAMABLE COMPOSITION, CROSSLINKED FOAM, AND SHOE MIDSOLE COMPRISING THE SAME
    4.
    发明申请
    CROSSLINKABLE AND FOAMABLE COMPOSITION, CROSSLINKED FOAM, AND SHOE MIDSOLE COMPRISING THE SAME 有权
    可交联和可泡沫组合物，交联泡沫和包含其的鞋子中间体

    公开(公告)号：US20110275731A1

    公开(公告)日：2011-11-10

    申请号：US13133238

    申请日：2009-12-21

    申请人： Daisuke Shimizu ,  Yoshifumi Araki ,  Katsumi Suzuki ,  Yasuhiro Kusanose ,  Mika Horiuchi

    发明人： Daisuke Shimizu ,  Yoshifumi Araki ,  Katsumi Suzuki ,  Yasuhiro Kusanose ,  Mika Horiuchi

    IPC分类号： C08L23/08

    CPC分类号： C08J9/10 ,  A43B13/04 ,  A43B13/125 ,  C08J9/0061 ,  C08J2201/026 ,  C08J2323/06 ,  C08J2323/08 ,  C08J2453/00 ,  C08K5/14 ,  C08L23/0815 ,  C08L53/025 ,  C08L2203/14 ,  C08L53/02

    摘要： The present invention provides a crosslinked foam having an excellent balance of various physical properties in terms of lightness, flexibility, permanent compression set, tear strength, impact resilience, and molding stability; a shoe midsole; and a crosslinkable and foamable composition that provides the crosslinked foam and shoe midsole. A crosslinkable and foamable composition comprising (A) an ethylene-based copolymer; (B) a copolymer comprising a vinyl aromatic monomer unit and an unsaturated bond-containing a conjugated diene monomer unit; (C) an organic peroxide; and (D) a foaming agent; a mass ratio of the component (A) to the component (B), (NB), being from 97/3 to 50/50; and the component (B) comprising 5 mass % or more and 80 mass % or less of the vinyl aromatic monomer unit, and 5 mass % or more and 55 mass % or less of the conjugated diene monomer unit.

    摘要翻译： 本发明提供一种交联泡沫体，其轻量，柔韧性，永久压缩永久变形，撕裂强度，冲击弹性和成型稳定性方面的各种物理性质的平衡优异。 鞋中底; 以及提供交联的泡沫和鞋中底的可交联和可发泡的组合物。 一种可交联和可发泡的组合物，其包含（A）乙烯基共聚物; （B）包含乙烯基芳族单体单元和含不饱和键的共轭二烯单体单元的共聚物; （C）有机过氧化物; 和（D）发泡剂; 组分（A）与组分（B）的质量比（NB）为97/3至50/50; 和包含5质量％以上且80质量％以下的乙烯基芳香族单体单元的成分（B）和5质量％以上且55质量％以下的共轭二烯单体单元。

    Hydrogenated Block Copolymers and Crosslinking Compositions Containing the Same
    6.
    发明申请
    Hydrogenated Block Copolymers and Crosslinking Compositions Containing the Same 有权
    氢化嵌段共聚物和含有它的交联组合物

    公开(公告)号：US20100087559A1

    公开(公告)日：2010-04-08

    申请号：US12375672

    申请日：2007-08-07

    申请人： Yasuhiro Kusanose ,  Masahiro Fujiwara ,  Daisuke Shimizu

    发明人： Yasuhiro Kusanose ,  Masahiro Fujiwara ,  Daisuke Shimizu

    IPC分类号： C08F136/04 ,  C08F8/04 ,  C08L53/02

    CPC分类号： C08F8/04 ,  C08F297/04 ,  C08L51/006 ,  C08L53/025 ,  C08L67/02 ,  C08L69/00 ,  C08L2666/02 ,  C08L2666/24 ,  C08L2666/04

    摘要： A hydrogenated block copolymer obtained by selective hydrogenation of a block copolymer comprising at least two polymer blocks (A) which each comprise vinyl aromatic monomer units as the main component and may be the same or different from each other, at least two polymer blocks (B) which each comprise monomer units derived from a conjugated diene of 5 or more carbon atoms as the main component and may be the same or different from each other, and one or more polymer blocks (C) which each comprise monomer units derived from a conjugated diene of 4 or more carbon atoms as the main component and may be the same or different from each other and/or one or more random copolymer blocks (D) which each comprise monomer units (d-1) derived from a conjugated diene of 4 or more carbon atoms and vinyl aromatic monomer units (d-2) as the main components, wherein the degree of hydrogenation of olefinically unsaturated double bonds of the blocks (B) is 50% or below; the degrees of hydrogenation of olefinically unsaturated double bonds of the blocks (C) and (D) are 80% or above; the content of vinyl aromatic monomer units in the block copolymer is 10 to 85% by weight; the contents of A, B, C and D in the block copolymer are 10 to 70% by weight, 1 to 15% by weight, 0 to 85% by weight and 0 to 85% by weight respectively with the proviso that the sum of C and D is 25 to 85% by weight and the sum total of A, B, C and D is 100% by weight; and the weight-average molecular weight (M) of A satisfies the relationship: M≧20000/[l+{content (%) of (d-2)}/20].

    摘要翻译： 通过选择性氢化包含至少两个聚合物嵌段（A）的嵌段共聚物获得的氢化嵌段共聚物，它们各自包含乙烯基芳族单体单元作为主要组分，并且可以彼此相同或不同，至少两个聚合物嵌段（B ），其各自包含衍生自5个或更多个碳原子的共轭二烯作为主要成分的单体单元，并且可以彼此相同或不同，并且一个或多个聚合物嵌段（C）各自包含衍生自共轭 具有4个或更多个碳原子的二烯作为主要组分，并且可以彼此相同或不同，和/或一种或多种无规共聚物嵌段（D），其各自包含衍生自共轭二烯的单体单元（d-1）4 或更多的碳原子和乙烯基芳族单体单元（d-2）作为主要成分，其中嵌段（B）的烯属不饱和双键的氢化度为50％以下; 嵌段（C）和（D）的烯属不饱和双键的氢化度为80％以上; 嵌段共聚物中乙烯基芳族单体单元的含量为10〜85重量％ 嵌段共聚物中A，B，C和D的含量分别为10〜70重量％，1〜15重量％，0〜85重量％，0〜85重量％，条件是 C和D为25〜85重量％，A，B，C和D的总和为100重量％ 并且A的重均分子量（M）满足关系：M≥20000/ [1 + {（d-2）的含量（％）} / 20]。

    Foamable composition, process for producing the same and foam
    9.
    发明授权
    Foamable composition, process for producing the same and foam 有权

    公开(公告)号：US10179850B2

    公开(公告)日：2019-01-15

    申请号：US13581952

    申请日：2011-03-08

    申请人： Yasuhiro Kusanose ,  Mika Horiuchi ,  Yoshifumi Araki

    发明人： Yasuhiro Kusanose ,  Mika Horiuchi ,  Yoshifumi Araki

    IPC分类号： C08J9/00 ,  C08L23/08 ,  C08J9/06 ,  C08L53/02 ,  A43B1/14 ,  A43B13/04

    摘要： The present invention provides a foam which maintains high hardness while being lightweight and has excellent peel strength and permanent compression set, and a foamable composition used to obtain the aforementioned foam. A foamable composition comprising (A) an olefin-based copolymer; (B) a copolymer that is (B-I) and/or (B-II) described below, (B-I) a vinyl aromatic-based copolymer comprising a vinyl aromatic compound and a conjugated diene, and/or a vinyl aromatic-based copolymer comprising a vinyl aromatic compound and alkylene, (B-II) an ethylene-based copolymer having an unsaturated group; (C) an inorganic filler; (D) an organic silane coupling agent; and (E) a foaming agent; wherein a mass ratio of the component (A) to the component (B), (A/B), is from 5/95 to 100/0; an amount of the component (C) is from 0.5 to 35 mass parts, and an amount of the component (E) is from 0.1 to 20 mass parts, based on 100 mass parts of a total amount of the components (A) and (B); and an amount of the component (D) is from 0.1 to 50 mass parts, based on 100 mass parts of the component (C).

    Foamable Composition, Process for Producing the Same and Foam
    10.
    发明申请
    Foamable Composition, Process for Producing the Same and Foam 审中-公开
    可发泡组合物，其制造方法和泡沫

    公开(公告)号：US20120322905A1

    公开(公告)日：2012-12-20

    申请号：US13581952

    申请日：2011-03-08

    申请人： Yasuhiro Kusanose ,  Mika Horiuchi ,  Yoshifumi Araki

    发明人： Yasuhiro Kusanose ,  Mika Horiuchi ,  Yoshifumi Araki

    IPC分类号： C08L23/04 ,  C08J9/00 ,  C08K3/36 ,  C08L9/06 ,  C08K3/22

    CPC分类号： C08L23/0869 ,  A43B1/14 ,  A43B13/04 ,  C08J9/0042 ,  C08J9/0066 ,  C08J9/06 ,  C08J2201/026 ,  C08J2323/08 ,  C08J2453/02 ,  C08L23/0815 ,  C08L23/0853 ,  C08L53/02 ,  C08L2203/14 ,  C08L2205/025 ,  C08L2205/03 ,  C08L2205/035 ,  C08L2310/00 ,  C08L2312/08 ,  C08L2666/44

    摘要： The present invention provides a foam which maintains high hardness while being lightweight and has excellent peel strength and permanent compression set, and a foamable composition used to obtain the aforementioned foam. A foamable composition comprising (A) an olefin-based copolymer; (B) a copolymer that is (B-I) and/or (B-II) described below, (B-I) a vinyl aromatic-based copolymer comprising a vinyl aromatic compound and a conjugated diene, and/or a vinyl aromatic-based copolymer comprising a vinyl aromatic compound and alkylene,(B-II) an ethylene-based copolymer having an unsaturated group; (C) an inorganic filler; (D) an organic silane coupling agent; and (E) a foaming agent; wherein a mass ratio of the component (A) to the component (B), (A/B), is from 5/95 to 100/0; an amount of the component (C) is from 0.5 to 35 mass parts, and an amount of the component (E) is from 0.1 to 20 mass parts, based on 100 mass parts of a total amount of the components (A) and (B); and an amount of the component (D) is from 0.1 to 50 mass parts, based on 100 mass parts of the component (C).

    摘要翻译： 本发明提供了一种在重量轻且具有优异的剥离强度和永久压缩永久变形的情况下保持高硬度的泡沫，以及用于获得上述泡沫体的可发泡组合物。 一种可发泡组合物，其包含（A）烯烃类共聚物; （B）下述（BI）和/或（B-II）的共聚物，（BI）包含乙烯基芳族化合物和共轭二烯的乙烯基芳族系共聚物和/或乙烯基芳族系共聚物，其包含 乙烯基芳族化合物和亚烷基，（B-II）具有不饱和基团的乙烯类共聚物; （C）无机填料; （D）有机硅烷偶联剂; 和（E）发泡剂; 其中组分（A）与组分（B）的质量比（A / B）为5/95至100/0; 组分（C）的量为0.5〜35质量份，成分（E）的量为0.1〜20质量份，相对于（A）成分和（A）成分的总量100质量份， B）; 相对于100质量份成分（C），成分（D）的含量为0.1〜50质量份。