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1.发明授权Crosslinkable and foamable composition, crosslinked foam, and shoe midsole comprising the same 有权可交联和可发泡组合物，交联泡沫和包含其的鞋底公开(公告)号：US09493623B2
公开(公告)日：2016-11-15
申请号：US13133238
申请日：2009-12-21
CPC分类号： C08J9/10 , A43B13/04 , A43B13/125 , C08J9/0061 , C08J2201/026 , C08J2323/06 , C08J2323/08 , C08J2453/00 , C08K5/14 , C08L23/0815 , C08L53/025 , C08L2203/14 , C08L53/02
摘要： The present invention provides a crosslinked foam having an excellent balance of various physical properties in terms of lightness, flexibility, permanent compression set, tear strength, impact resilience, and molding stability; a shoe midsole; and a crosslinkable and foamable composition that provides the crosslinked foam and shoe midsole. A crosslinkable and foamable composition comprising (A) an ethylene-based copolymer; (B) a copolymer comprising a vinyl aromatic monomer unit and an unsaturated bond-containing a conjugated diene monomer unit; (C) an organic peroxide; and (D) a foaming agent; a mass ratio of the component (A) to the component (B), (A/B), being from 97/3 to 50/50; and the component (B) comprising 5 mass % or more and 80 mass % or less of the vinyl aromatic monomer unit, and 5 mass % or more and 55 mass % or less of the conjugated diene monomer unit.
摘要翻译： 本发明提供一种交联泡沫体，其轻量，柔韧性，永久压缩永久变形，撕裂强度，冲击弹性和成型稳定性方面的各种物理性质的平衡优异。 鞋中底; 以及提供交联的泡沫和鞋中底的可交联和可发泡的组合物。 一种可交联和可发泡的组合物，其包含（A）乙烯基共聚物; （B）包含乙烯基芳族单体单元和含不饱和键的共轭二烯单体单元的共聚物; （C）有机过氧化物; 和（D）发泡剂; 组分（A）与组分（B）的质量比（A / B）为97/3至50/50; 和包含5质量％以上且80质量％以下的乙烯基芳香族单体单元的成分（B）和5质量％以上且55质量％以下的共轭二烯单体单元。
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2.发明申请CROSSLINKABLE AND FOAMABLE COMPOSITION, CROSSLINKED FOAM, AND SHOE MIDSOLE COMPRISING THE SAME 有权可交联和可泡沫组合物，交联泡沫和包含其的鞋子中间体公开(公告)号：US20110275731A1
公开(公告)日：2011-11-10
申请号：US13133238
申请日：2009-12-21
IPC分类号： C08L23/08
CPC分类号： C08J9/10 , A43B13/04 , A43B13/125 , C08J9/0061 , C08J2201/026 , C08J2323/06 , C08J2323/08 , C08J2453/00 , C08K5/14 , C08L23/0815 , C08L53/025 , C08L2203/14 , C08L53/02
摘要： The present invention provides a crosslinked foam having an excellent balance of various physical properties in terms of lightness, flexibility, permanent compression set, tear strength, impact resilience, and molding stability; a shoe midsole; and a crosslinkable and foamable composition that provides the crosslinked foam and shoe midsole. A crosslinkable and foamable composition comprising (A) an ethylene-based copolymer; (B) a copolymer comprising a vinyl aromatic monomer unit and an unsaturated bond-containing a conjugated diene monomer unit; (C) an organic peroxide; and (D) a foaming agent; a mass ratio of the component (A) to the component (B), (NB), being from 97/3 to 50/50; and the component (B) comprising 5 mass % or more and 80 mass % or less of the vinyl aromatic monomer unit, and 5 mass % or more and 55 mass % or less of the conjugated diene monomer unit.
摘要翻译： 本发明提供一种交联泡沫体，其轻量，柔韧性，永久压缩永久变形，撕裂强度，冲击弹性和成型稳定性方面的各种物理性质的平衡优异。 鞋中底; 以及提供交联的泡沫和鞋中底的可交联和可发泡的组合物。 一种可交联和可发泡的组合物，其包含（A）乙烯基共聚物; （B）包含乙烯基芳族单体单元和含不饱和键的共轭二烯单体单元的共聚物; （C）有机过氧化物; 和（D）发泡剂; 组分（A）与组分（B）的质量比（NB）为97/3至50/50; 和包含5质量％以上且80质量％以下的乙烯基芳香族单体单元的成分（B）和5质量％以上且55质量％以下的共轭二烯单体单元。
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公开(公告)号：US20110003928A1
公开(公告)日：2011-01-06
申请号：US12865407
申请日：2009-02-04
IPC分类号： C08L53/02
CPC分类号： C08F297/046 , C08L53/02 , C08L77/00 , C08L2205/02 , C08L2205/03 , C08L2312/00 , C08L2666/24 , C08L2666/04
摘要： The present invention provides a thermoplastic elastomer composition obtained by dynamically crosslinking, under a melting condition, 100 parts by mass of a block copolymer (I), 1 to 1,000 parts by mass of a polar resin (II), 1 to 500 parts by mass of a modified polymer (III), and 0.01 to 50 parts by mass of a crosslinking agent (IV), wherein the block copolymer (I) comprises at least one polymer block (A) comprising as a main component an alkylene unit, and/or at least one copolymer block (B) comprising as main components an alkylene unit (b-1) and a vinyl aromatic monomer unit (b-2), and comprises at least one unsaturated block (C) comprising as a main component a conjugated diene monomer unit having 5 or more carbon atoms at an end.
摘要翻译： 本发明提供一种热塑性弹性体组合物，其在熔融条件下动态交联100质量份的嵌段共聚物（I），1〜1000质量份的极性树脂（II），1〜500质量份 的改性聚合物（III）和0.01〜50质量份的交联剂（IV），其中嵌段共聚物（I）包含至少一种包含作为主要成分的亚烷基单元的聚合物嵌段（A）和/ 或至少一种包含亚烷基单元（b-1）和乙烯基芳族单体单元（b-2）的主要组分）的共聚物嵌段（B），并且包含至少一种不饱和嵌段（C），其包含作为主要组分的共轭 在末端具有5个或更多个碳原子的二烯单体单元。
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公开(公告)号：US08415428B2
公开(公告)日：2013-04-09
申请号：US12865407
申请日：2009-02-04
CPC分类号： C08F297/046 , C08L53/02 , C08L77/00 , C08L2205/02 , C08L2205/03 , C08L2312/00 , C08L2666/24 , C08L2666/04
摘要： The present invention provides a thermoplastic elastomer composition obtained by dynamically crosslinking, under a melting condition, 100 parts by mass of a block copolymer (I), 1 to 1,000 parts by mass of a polar resin (II), 1 to 500 parts by mass of a modified polymer (III), and 0.01 to 50 parts by mass of a crosslinking agent (IV), wherein the block copolymer (I) comprises at least one polymer block (A) comprising as a main component an alkylene unit, and/or at least one copolymer block (B) comprising as main components an alkylene unit (b-1) and a vinyl aromatic monomer unit (b-2), and comprises at least one unsaturated block (C) comprising as a main component a conjugated diene monomer unit having 5 or more carbon atoms at an end.
摘要翻译： 本发明提供一种热塑性弹性体组合物，其在熔融条件下动态交联100质量份的嵌段共聚物（I），1〜1000质量份的极性树脂（II），1〜500质量份 的改性聚合物（III）和0.01〜50质量份的交联剂（IV），其中嵌段共聚物（I）包含至少一种包含作为主要成分的亚烷基单元的聚合物嵌段（A）和/ 或至少一种包含亚烷基单元（b-1）和乙烯基芳族单体单元（b-2）的主要组分）的共聚物嵌段（B），并且包含至少一种不饱和嵌段（C），其包含作为主要组分的共轭 在末端具有5个或更多个碳原子的二烯单体单元。
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5.发明申请Crosslinked Composition, Method for Producing Crosslinked Composition, and Molded Product 有权交联组合物，生成交联组合物的方法和成型产品公开(公告)号：US20140357798A1
公开(公告)日：2014-12-04
申请号：US14344682
申请日：2012-09-14
申请人： Daisuke Shimizu , Yoshifumi Araki , Katsumi Suzuki
发明人： Daisuke Shimizu , Yoshifumi Araki , Katsumi Suzuki
CPC分类号： C08L9/06 , C08K3/011 , C08K2003/2296 , C08L9/00 , C08L23/16 , C08L53/025 , C08L2205/02 , C08L2205/03 , C08L2312/04 , C08L23/10 , C08L25/08
摘要： A crosslinked composition is obtained by crosslinking a composition, containing: 1 to 99 parts by mass of a vinyl aromatic copolymer rubber (I) comprising 5 to 70% by mass of a vinyl aromatic monomer unit and 0.1 to 30% by mass of a conjugated diene monomer unit and having one or more tan δ peak temperatures between 75° C. and 125° C.; 99 to 1 parts by mass of an ethylenic copolymer rubber (II); 10 to 100 parts by mass of an olefinic resin (III) based on 100 parts by mass of a total amount of the vinyl aromatic copolymer rubber (I) and the ethylenic copolymer rubber (II); and 0.01 to 50 parts by mass of a crosslinking agent (IV) based on 100 parts by mass of the total amount of the vinyl aromatic copolymer rubber (I) and the ethylenic copolymer rubber (II).
摘要翻译： 通过交联组合物获得交联组合物，该组合物含有：1〜99质量份的含有乙烯基芳族单体单元5〜70质量％的乙烯基芳族共聚物橡胶（I）和0.1〜30质量％的共轭 二烯单体单元，并且在75℃和125℃之间具有一个或多个tanδ峰值温度。 99〜1质量份乙烯类共聚物橡胶（II）; 基于100质量份的乙烯基芳族共聚物橡胶（I）和乙烯类共聚物橡胶（II）的总量，将10〜100质量份的烯烃树脂（III） 相对于乙烯基芳香族共聚物橡胶（I）和乙烯类共聚物橡胶（II）的总量100质量份，交联剂（IV）为0.01〜50质量份。
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6.发明授权Crosslinked composition, method for producing crosslinked composition, and molded product 有权交联组合物，交联组合物的制造方法和成型体公开(公告)号：US09365706B2
公开(公告)日：2016-06-14
申请号：US14344682
申请日：2012-09-14
申请人： Daisuke Shimizu , Yoshifumi Araki , Katsumi Suzuki
发明人： Daisuke Shimizu , Yoshifumi Araki , Katsumi Suzuki
CPC分类号： C08L9/06 , C08K3/011 , C08K2003/2296 , C08L9/00 , C08L23/16 , C08L53/025 , C08L2205/02 , C08L2205/03 , C08L2312/04 , C08L23/10 , C08L25/08
摘要： A crosslinked composition is obtained by crosslinking a composition, containing: 1 to 99 parts by mass of a vinyl aromatic copolymer rubber (I) comprising 5 to 70% by mass of a vinyl aromatic monomer unit and 0.1 to 30% by mass of a conjugated diene monomer unit and having one or more tan δ peak temperatures between 75° C. and 125° C.; 99 to 1 parts by mass of an ethylenic copolymer rubber (II); 10 to 100 parts by mass of an olefinic resin (III) based on 100 parts by mass of a total amount of the vinyl aromatic copolymer rubber (I) and the ethylenic copolymer rubber (II); and 0.01 to 50 parts by mass of a crosslinking agent (IV) based on 100 parts by mass of the total amount of the vinyl aromatic copolymer rubber (I) and the ethylenic copolymer rubber (II).
摘要翻译： 通过交联组合物获得交联组合物，该组合物含有：1〜99质量份的含有乙烯基芳族单体单元5〜70质量％的乙烯基芳族共聚物橡胶（I）和0.1〜30质量％的共轭 二烯单体单元，并且在75℃和125℃之间具有一个或多个tanδ峰值温度。 99〜1质量份乙烯类共聚物橡胶（II）; 基于100质量份的乙烯基芳族共聚物橡胶（I）和乙烯类共聚物橡胶（II）的总量，将10〜100质量份的烯烃树脂（III） 相对于乙烯基芳香族共聚物橡胶（I）和乙烯类共聚物橡胶（II）的总量100质量份，交联剂（IV）为0.01〜50质量份。
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7.发明授权Hydrogenated block copolymers and crosslinking compositions containing the same 有权氢化嵌段共聚物和含有它们的交联组合物公开(公告)号：US08772415B2
公开(公告)日：2014-07-08
申请号：US12375672
申请日：2007-08-07
IPC分类号： C08F136/04 , C08F8/04 , C08L53/02
CPC分类号： C08F8/04 , C08F297/04 , C08L51/006 , C08L53/025 , C08L67/02 , C08L69/00 , C08L2666/02 , C08L2666/24 , C08L2666/04
摘要： The disclosure provides a hydrogenated straight-chain block copolymer, obtained by selective hydrogenation of a straight-chain block copolymer.
摘要翻译： 本公开提供了通过直链嵌段共聚物的选择性氢化获得的氢化直链嵌段共聚物。
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8.发明申请Hydrogenated Block Copolymers and Crosslinking Compositions Containing the Same 有权氢化嵌段共聚物和含有它的交联组合物公开(公告)号：US20100087559A1
公开(公告)日：2010-04-08
申请号：US12375672
申请日：2007-08-07
IPC分类号： C08F136/04 , C08F8/04 , C08L53/02
CPC分类号： C08F8/04 , C08F297/04 , C08L51/006 , C08L53/025 , C08L67/02 , C08L69/00 , C08L2666/02 , C08L2666/24 , C08L2666/04
摘要： A hydrogenated block copolymer obtained by selective hydrogenation of a block copolymer comprising at least two polymer blocks (A) which each comprise vinyl aromatic monomer units as the main component and may be the same or different from each other, at least two polymer blocks (B) which each comprise monomer units derived from a conjugated diene of 5 or more carbon atoms as the main component and may be the same or different from each other, and one or more polymer blocks (C) which each comprise monomer units derived from a conjugated diene of 4 or more carbon atoms as the main component and may be the same or different from each other and/or one or more random copolymer blocks (D) which each comprise monomer units (d-1) derived from a conjugated diene of 4 or more carbon atoms and vinyl aromatic monomer units (d-2) as the main components, wherein the degree of hydrogenation of olefinically unsaturated double bonds of the blocks (B) is 50% or below; the degrees of hydrogenation of olefinically unsaturated double bonds of the blocks (C) and (D) are 80% or above; the content of vinyl aromatic monomer units in the block copolymer is 10 to 85% by weight; the contents of A, B, C and D in the block copolymer are 10 to 70% by weight, 1 to 15% by weight, 0 to 85% by weight and 0 to 85% by weight respectively with the proviso that the sum of C and D is 25 to 85% by weight and the sum total of A, B, C and D is 100% by weight; and the weight-average molecular weight (M) of A satisfies the relationship: M≧20000/[l+{content (%) of (d-2)}/20].
摘要翻译： 通过选择性氢化包含至少两个聚合物嵌段（A）的嵌段共聚物获得的氢化嵌段共聚物，它们各自包含乙烯基芳族单体单元作为主要组分，并且可以彼此相同或不同，至少两个聚合物嵌段（B ），其各自包含衍生自5个或更多个碳原子的共轭二烯作为主要成分的单体单元，并且可以彼此相同或不同，并且一个或多个聚合物嵌段（C）各自包含衍生自共轭 具有4个或更多个碳原子的二烯作为主要组分，并且可以彼此相同或不同，和/或一种或多种无规共聚物嵌段（D），其各自包含衍生自共轭二烯的单体单元（d-1）4 或更多的碳原子和乙烯基芳族单体单元（d-2）作为主要成分，其中嵌段（B）的烯属不饱和双键的氢化度为50％以下; 嵌段（C）和（D）的烯属不饱和双键的氢化度为80％以上; 嵌段共聚物中乙烯基芳族单体单元的含量为10〜85重量％ 嵌段共聚物中A，B，C和D的含量分别为10〜70重量％，1〜15重量％，0〜85重量％，0〜85重量％，条件是 C和D为25〜85重量％，A，B，C和D的总和为100重量％ 并且A的重均分子量（M）满足关系：M≥20000/ [1 + {（d-2）的含量（％）} / 20]。
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9.发明申请公开(公告)号：US20130122707A1
公开(公告)日：2013-05-16
申请号：US13656589
申请日：2012-10-19
申请人： Daisuke Shimizu , Jong Mun Kim
发明人： Daisuke Shimizu , Jong Mun Kim
IPC分类号： H01L21/31 , H01L21/302
CPC分类号： H01L21/02118 , B05D1/62 , B05D5/00 , H01L21/02274 , H01L21/0273 , H01L21/0332 , H01L21/0337
摘要： Methods of polymer deposition for forming reduced critical dimensions are described. In one embodiment, a substrate is provided into a chamber, the substrate having a patterned layer disposed on an underlying layer formed thereon. The patterned layer includes a plurality of openings, each opening having a sidewall, a bottom, and a critical dimension. A gas mixture is provided into the chamber, the gas mixture having an etching gas and a polymer control gas. The polymer control gas includes a polymerizing fluorocarbon CxFy gas and a C—H bond containing gas. A plasma is formed with the gas mixture and a conformal polymer layer is deposited in the presence of the plasma on the patterned layer to form a reduced critical dimension in each opening. The reduced critical dimension is smaller than the corresponding critical dimension of the opening.
摘要翻译： 描述了用于形成降低的临界尺寸的聚合物沉积的方法。 在一个实施例中，将衬底提供到腔室中，衬底具有设置在其上形成的下层上的图案层。 图案化层包括多个开口，每个开口具有侧壁，底部和临界尺寸。 气体混合物被提供到室中，气体混合物具有蚀刻气体和聚合物控制气体。 聚合物控制气体包括聚合碳氟化合物CxFy气体和含C-H键的气体。 用气体混合物形成等离子体，并且在等离子体存在下在图案化层上沉积保形聚合物层，以在每个开口中形成减小的临界尺寸。 减小的临界尺寸小于开口的相应临界尺寸。
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公开(公告)号：US08205849B2
公开(公告)日：2012-06-26
申请号：US12396742
申请日：2009-03-03
申请人： Daisuke Shimizu
发明人： Daisuke Shimizu
IPC分类号： A47G29/00
CPC分类号： F16M11/10 , F16M11/18 , F16M11/2014 , F16M2200/08 , Y10S248/917 , Y10S248/919 , Y10S248/923
摘要： This display screen turning apparatus includes a first support member of metal supporting a display screen portion and a second support member of metal supporting the first support member to be anteroposteriorly rotatable by a prescribed angle with respect to a vertical plane, and either the first support member or the second support member has a receiving hole, while either the second support member or the first support member integrally has a platelike support shaft of metal inserted into the receiving hole.
摘要翻译： 该显示屏幕转动装置包括支撑显示屏部分的金属的第一支撑构件和支撑第一支撑构件的金属的第二支撑构件，以相对于垂直平面前后旋转预定角度，以及第一支撑构件 或第二支撑构件具有接收孔，而第二支撑构件或第一支撑构件整体地具有插入到容纳孔中的金属板状支撑轴。
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