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    Foamable composition, process for producing the same and foam
    1.
    发明授权
    Foamable composition, process for producing the same and foam 有权

    公开(公告)号：US10179850B2

    公开(公告)日：2019-01-15

    申请号：US13581952

    申请日：2011-03-08

    申请人： Yasuhiro Kusanose ,  Mika Horiuchi ,  Yoshifumi Araki

    发明人： Yasuhiro Kusanose ,  Mika Horiuchi ,  Yoshifumi Araki

    IPC分类号： C08J9/00 ,  C08L23/08 ,  C08J9/06 ,  C08L53/02 ,  A43B1/14 ,  A43B13/04

    摘要： The present invention provides a foam which maintains high hardness while being lightweight and has excellent peel strength and permanent compression set, and a foamable composition used to obtain the aforementioned foam. A foamable composition comprising (A) an olefin-based copolymer; (B) a copolymer that is (B-I) and/or (B-II) described below, (B-I) a vinyl aromatic-based copolymer comprising a vinyl aromatic compound and a conjugated diene, and/or a vinyl aromatic-based copolymer comprising a vinyl aromatic compound and alkylene, (B-II) an ethylene-based copolymer having an unsaturated group; (C) an inorganic filler; (D) an organic silane coupling agent; and (E) a foaming agent; wherein a mass ratio of the component (A) to the component (B), (A/B), is from 5/95 to 100/0; an amount of the component (C) is from 0.5 to 35 mass parts, and an amount of the component (E) is from 0.1 to 20 mass parts, based on 100 mass parts of a total amount of the components (A) and (B); and an amount of the component (D) is from 0.1 to 50 mass parts, based on 100 mass parts of the component (C).

    Foamable Composition, Process for Producing the Same and Foam
    3.
    发明申请
    Foamable Composition, Process for Producing the Same and Foam 审中-公开
    可发泡组合物，其制造方法和泡沫

    公开(公告)号：US20120322905A1

    公开(公告)日：2012-12-20

    申请号：US13581952

    申请日：2011-03-08

    申请人： Yasuhiro Kusanose ,  Mika Horiuchi ,  Yoshifumi Araki

    发明人： Yasuhiro Kusanose ,  Mika Horiuchi ,  Yoshifumi Araki

    IPC分类号： C08L23/04 ,  C08J9/00 ,  C08K3/36 ,  C08L9/06 ,  C08K3/22

    CPC分类号： C08L23/0869 ,  A43B1/14 ,  A43B13/04 ,  C08J9/0042 ,  C08J9/0066 ,  C08J9/06 ,  C08J2201/026 ,  C08J2323/08 ,  C08J2453/02 ,  C08L23/0815 ,  C08L23/0853 ,  C08L53/02 ,  C08L2203/14 ,  C08L2205/025 ,  C08L2205/03 ,  C08L2205/035 ,  C08L2310/00 ,  C08L2312/08 ,  C08L2666/44

    摘要： The present invention provides a foam which maintains high hardness while being lightweight and has excellent peel strength and permanent compression set, and a foamable composition used to obtain the aforementioned foam. A foamable composition comprising (A) an olefin-based copolymer; (B) a copolymer that is (B-I) and/or (B-II) described below, (B-I) a vinyl aromatic-based copolymer comprising a vinyl aromatic compound and a conjugated diene, and/or a vinyl aromatic-based copolymer comprising a vinyl aromatic compound and alkylene,(B-II) an ethylene-based copolymer having an unsaturated group; (C) an inorganic filler; (D) an organic silane coupling agent; and (E) a foaming agent; wherein a mass ratio of the component (A) to the component (B), (A/B), is from 5/95 to 100/0; an amount of the component (C) is from 0.5 to 35 mass parts, and an amount of the component (E) is from 0.1 to 20 mass parts, based on 100 mass parts of a total amount of the components (A) and (B); and an amount of the component (D) is from 0.1 to 50 mass parts, based on 100 mass parts of the component (C).

    摘要翻译： 本发明提供了一种在重量轻且具有优异的剥离强度和永久压缩永久变形的情况下保持高硬度的泡沫，以及用于获得上述泡沫体的可发泡组合物。 一种可发泡组合物，其包含（A）烯烃类共聚物; （B）下述（BI）和/或（B-II）的共聚物，（BI）包含乙烯基芳族化合物和共轭二烯的乙烯基芳族系共聚物和/或乙烯基芳族系共聚物，其包含 乙烯基芳族化合物和亚烷基，（B-II）具有不饱和基团的乙烯类共聚物; （C）无机填料; （D）有机硅烷偶联剂; 和（E）发泡剂; 其中组分（A）与组分（B）的质量比（A / B）为5/95至100/0; 组分（C）的量为0.5〜35质量份，成分（E）的量为0.1〜20质量份，相对于（A）成分和（A）成分的总量100质量份， B）; 相对于100质量份成分（C），成分（D）的含量为0.1〜50质量份。

    CROSSLINKABLE AND FOAMABLE COMPOSITION, CROSSLINKED FOAM, AND SHOE MIDSOLE COMPRISING THE SAME
    4.
    发明申请
    CROSSLINKABLE AND FOAMABLE COMPOSITION, CROSSLINKED FOAM, AND SHOE MIDSOLE COMPRISING THE SAME 有权
    可交联和可泡沫组合物，交联泡沫和包含其的鞋子中间体

    公开(公告)号：US20110275731A1

    公开(公告)日：2011-11-10

    申请号：US13133238

    申请日：2009-12-21

    申请人： Daisuke Shimizu ,  Yoshifumi Araki ,  Katsumi Suzuki ,  Yasuhiro Kusanose ,  Mika Horiuchi

    发明人： Daisuke Shimizu ,  Yoshifumi Araki ,  Katsumi Suzuki ,  Yasuhiro Kusanose ,  Mika Horiuchi

    IPC分类号： C08L23/08

    CPC分类号： C08J9/10 ,  A43B13/04 ,  A43B13/125 ,  C08J9/0061 ,  C08J2201/026 ,  C08J2323/06 ,  C08J2323/08 ,  C08J2453/00 ,  C08K5/14 ,  C08L23/0815 ,  C08L53/025 ,  C08L2203/14 ,  C08L53/02

    摘要： The present invention provides a crosslinked foam having an excellent balance of various physical properties in terms of lightness, flexibility, permanent compression set, tear strength, impact resilience, and molding stability; a shoe midsole; and a crosslinkable and foamable composition that provides the crosslinked foam and shoe midsole. A crosslinkable and foamable composition comprising (A) an ethylene-based copolymer; (B) a copolymer comprising a vinyl aromatic monomer unit and an unsaturated bond-containing a conjugated diene monomer unit; (C) an organic peroxide; and (D) a foaming agent; a mass ratio of the component (A) to the component (B), (NB), being from 97/3 to 50/50; and the component (B) comprising 5 mass % or more and 80 mass % or less of the vinyl aromatic monomer unit, and 5 mass % or more and 55 mass % or less of the conjugated diene monomer unit.

    摘要翻译： 本发明提供一种交联泡沫体，其轻量，柔韧性，永久压缩永久变形，撕裂强度，冲击弹性和成型稳定性方面的各种物理性质的平衡优异。 鞋中底; 以及提供交联的泡沫和鞋中底的可交联和可发泡的组合物。 一种可交联和可发泡的组合物，其包含（A）乙烯基共聚物; （B）包含乙烯基芳族单体单元和含不饱和键的共轭二烯单体单元的共聚物; （C）有机过氧化物; 和（D）发泡剂; 组分（A）与组分（B）的质量比（NB）为97/3至50/50; 和包含5质量％以上且80质量％以下的乙烯基芳香族单体单元的成分（B）和5质量％以上且55质量％以下的共轭二烯单体单元。

    THERMOPLASTIC ELASTOMER COMPOSITION AND METHOD FOR PRODUCING THE SAME
    7.
    发明申请
    THERMOPLASTIC ELASTOMER COMPOSITION AND METHOD FOR PRODUCING THE SAME 有权
    热塑性弹性体组合物及其制造方法

    公开(公告)号：US20110003928A1

    公开(公告)日：2011-01-06

    申请号：US12865407

    申请日：2009-02-04

    申请人： Daisuke Shimizu ,  Yasuhiro Kusanose ,  Yoshifumi Araki ,  Masahiro Fujiwara

    发明人： Daisuke Shimizu ,  Yasuhiro Kusanose ,  Yoshifumi Araki ,  Masahiro Fujiwara

    IPC分类号： C08L53/02

    CPC分类号： C08F297/046 ,  C08L53/02 ,  C08L77/00 ,  C08L2205/02 ,  C08L2205/03 ,  C08L2312/00 ,  C08L2666/24 ,  C08L2666/04

    摘要： The present invention provides a thermoplastic elastomer composition obtained by dynamically crosslinking, under a melting condition, 100 parts by mass of a block copolymer (I), 1 to 1,000 parts by mass of a polar resin (II), 1 to 500 parts by mass of a modified polymer (III), and 0.01 to 50 parts by mass of a crosslinking agent (IV), wherein the block copolymer (I) comprises at least one polymer block (A) comprising as a main component an alkylene unit, and/or at least one copolymer block (B) comprising as main components an alkylene unit (b-1) and a vinyl aromatic monomer unit (b-2), and comprises at least one unsaturated block (C) comprising as a main component a conjugated diene monomer unit having 5 or more carbon atoms at an end.

    摘要翻译： 本发明提供一种热塑性弹性体组合物，其在熔融条件下动态交联100质量份的嵌段共聚物（I），1〜1000质量份的极性树脂（II），1〜500质量份 的改性聚合物（III）和0.01〜50质量份的交联剂（IV），其中嵌段共聚物（I）包含至少一种包含作为主要成分的亚烷基单元的聚合物嵌段（A）和/ 或至少一种包含亚烷基单元（b-1）和乙烯基芳族单体单元（b-2）的主要组分）的共聚物嵌段（B），并且包含至少一种不饱和嵌段（C），其包含作为主要组分的共轭 在末端具有5个或更多个碳原子的二烯单体单元。

    Thermoplastic elastomer composition and method for producing the same
    8.
    发明授权
    Thermoplastic elastomer composition and method for producing the same 有权
    热塑性弹性体组合物及其制造方法

    公开(公告)号：US08415428B2

    公开(公告)日：2013-04-09

    申请号：US12865407

    申请日：2009-02-04

    申请人： Daisuke Shimizu ,  Yasuhiro Kusanose ,  Yoshifumi Araki ,  Masahiro Fujiwara

    发明人： Daisuke Shimizu ,  Yasuhiro Kusanose ,  Yoshifumi Araki ,  Masahiro Fujiwara

    IPC分类号： C08L53/02 ,  C08L77/00

    CPC分类号： C08F297/046 ,  C08L53/02 ,  C08L77/00 ,  C08L2205/02 ,  C08L2205/03 ,  C08L2312/00 ,  C08L2666/24 ,  C08L2666/04

    摘要： The present invention provides a thermoplastic elastomer composition obtained by dynamically crosslinking, under a melting condition, 100 parts by mass of a block copolymer (I), 1 to 1,000 parts by mass of a polar resin (II), 1 to 500 parts by mass of a modified polymer (III), and 0.01 to 50 parts by mass of a crosslinking agent (IV), wherein the block copolymer (I) comprises at least one polymer block (A) comprising as a main component an alkylene unit, and/or at least one copolymer block (B) comprising as main components an alkylene unit (b-1) and a vinyl aromatic monomer unit (b-2), and comprises at least one unsaturated block (C) comprising as a main component a conjugated diene monomer unit having 5 or more carbon atoms at an end.

    摘要翻译： 本发明提供一种热塑性弹性体组合物，其在熔融条件下动态交联100质量份的嵌段共聚物（I），1〜1000质量份的极性树脂（II），1〜500质量份 的改性聚合物（III）和0.01〜50质量份的交联剂（IV），其中嵌段共聚物（I）包含至少一种包含作为主要成分的亚烷基单元的聚合物嵌段（A）和/ 或至少一种包含亚烷基单元（b-1）和乙烯基芳族单体单元（b-2）的主要组分）的共聚物嵌段（B），并且包含至少一种不饱和嵌段（C），其包含作为主要组分的共轭 在末端具有5个或更多个碳原子的二烯单体单元。

    Method for producing hydrogenated conjugated diene copolymer
    9.
    发明授权
    Method for producing hydrogenated conjugated diene copolymer 有权
    氢化共轭二烯共聚物的制备方法

    公开(公告)号：US09546238B2

    公开(公告)日：2017-01-17

    申请号：US14122144

    申请日：2012-05-11

    申请人： Yoshifumi Araki ,  Eiji Sasaya ,  Kenta Shibuya

    发明人： Yoshifumi Araki ,  Eiji Sasaya ,  Kenta Shibuya

    IPC分类号： C08F236/10 ,  C08C19/02 ,  C08F212/08

    CPC分类号： C08F236/10 ,  C08C19/02 ,  C08F212/08 ,  C08F4/48

    摘要： The present invention relates to a method for producing a hydrogenated conjugated diene copolymer including a polymerization step and a hydrogenation step, wherein in the polymerization step, a conjugated diene copolymer having a high vinyl bond amount of a conjugated diene block moiety and a narrow molecular weight distribution can be produced, and in the hydrogenation step, the rate of hydrogenation is high and productivity is excellent.

    摘要翻译： 本发明涉及一种包含聚合步骤和氢化步骤的氢化共轭二烯共聚物的制备方法，其中在聚合步骤中，共轭二烯嵌段部分的乙烯基键量高且分子量窄的共轭二烯共聚物 可以产生分布，并且在氢化步骤中，氢化速率高，生产率优异。

    Thermoplastic elastomer composition
    10.
    发明授权
    Thermoplastic elastomer composition 有权
    热塑性弹性体组合物

    公开(公告)号：US08722799B2

    公开(公告)日：2014-05-13

    申请号：US13133866

    申请日：2009-12-04

    申请人： Yutaka Eguchi ,  Shinichi Shibayama ,  Yoshifumi Araki

    发明人： Yutaka Eguchi ,  Shinichi Shibayama ,  Yoshifumi Araki

    IPC分类号： C08L23/08 ,  C08L23/12 ,  C08L53/02

    CPC分类号： C08L53/025 ,  C08L23/08 ,  C08L2205/02 ,  C08L2207/04 ,  C08L2312/00 ,  C08L2666/24 ,  C08L2666/02 ,  C08L2666/06

    摘要： There is provided a thermoplastic elastomer composition having excellent flexibility, mechanical properties, scratch resistance, abrasion resistance, and low-temperature characteristics. A crosslinked thermoplastic elastomer composition comprising 5 to 70 parts by mass of (C) a hydrogenated product of a block copolymer having at least one conjugated diene monomer unit block and at least one vinyl aromatic monomer unit block, and 20 to 150 parts by mass of (D) an olefin-based resin, based on 100 parts by mass of the total of (A) an ethylene-α-olefin copolymer comprising an ethylene unit and an α-olefin unit having 3 to 20 carbon atoms, and (B) a copolymer having at least one hydrogenated copolymer block mainly composed of a conjugated diene monomer unit and a vinyl aromatic monomer unit, wherein a mass ratio ((A)/(B)) of the (A) component and the (B) component is from 20/80 to 75/25.

    摘要翻译： 提供了具有优异的柔韧性，机械性能，耐刮擦性，耐磨性和低温特性的热塑性弹性体组合物。 一种交联热塑性弹性体组合物，其含有（C）具有至少一个共轭二烯单体单元嵌段和至少一个乙烯基芳香族单体单元嵌段的嵌段共聚物的氢化物，和（C）含有20〜150质量份 （D）烯烃系树脂，以（A）乙烯单元和碳原子数为3〜20的α-烯烃单元的乙烯-α-烯烃共聚物总计为100质量份，（B） 具有至少一个主要由共轭二烯单体单元和乙烯基芳族单体单元组成的氢化共聚物嵌段的共聚物，其中（A）成分和（B）成分的质量比（（A）/（B））为 从20/80到75/25。