公开(公告)号：US20190010373A1

公开(公告)日：2019-01-10

申请号：US16064578

申请日：2017-01-09

Applicant: Dow Global Technologies LLC

Inventor： Benjamin Haag ,  Andreas Lutz ,  Cathy Grossnickel ,  Raymond F. Bis

IPC: C09J175/08 ,  C09J163/00 ,  C08G59/68 ,  C08G59/06 ,  C08G59/40 ,  C08G18/20 ,  C08G18/32

CPC classification number: C09J175/08 ,  C08G18/10 ,  C08G18/2027 ,  C08G18/3275 ,  C08G59/04 ,  C08G59/06 ,  C08G59/10 ,  C08G59/4021 ,  C08G59/686 ,  C08G65/33348 ,  C09J163/00 ,  C08G18/3215

Abstract: A one-component epoxy-modified polyurethane and/or urea adhesive includes very high levels of reactive urethane group- and/or urea group-containing tougheners, an epoxy resin and epoxy hardener. These adhesives are formulated to cure at high temperatures and surprisingly provide high elongations, excellent thermal stability and good adhesive properties.

公开(公告)号：US20180334596A1

公开(公告)日：2018-11-22

申请号：US15757877

申请日：2016-09-06

Applicant: Dow Global Technologies LLC

Inventor： Andreas Lutz ,  Daniel Schneider ,  Jeannine Flueckiger

IPC: C09J163/04 ,  C09J163/00 ,  C08G18/10 ,  C08G18/62 ,  C08G18/24 ,  C08G18/75 ,  C08G18/32 ,  C08G59/40 ,  C08G65/333

CPC classification number: C09J163/04 ,  A61B5/04001 ,  A61B5/04888 ,  A61B5/0492 ,  A61B5/6877 ,  A61B5/6882 ,  A61B2562/0209 ,  A61B2562/125 ,  A61N1/0551 ,  A61N1/0558 ,  C01B32/182 ,  C08G18/10 ,  C08G18/12 ,  C08G18/24 ,  C08G18/3215 ,  C08G18/4854 ,  C08G18/6204 ,  C08G18/675 ,  C08G18/698 ,  C08G18/73 ,  C08G18/755 ,  C08G18/8067 ,  C08G59/4021 ,  C08G59/686 ,  C08G65/33348 ,  C08L75/08 ,  C09J163/00 ,  C08G18/2825 ,  C08G18/282

Abstract: Epoxy adhesives include a latent curing agent, a reactive toughener having capped isocyanate groups, and certain urea compounds. The toughener is made by chain extending and capping a mixture of isocyanate-terminated prepolymers. The prepolymers include an isocyanate-terminated polyether and an isocyanate-terminated diene polymer. The adhesives have excellent wash-off resistance and excellent ability to adhere to oily substrates.

公开(公告)号：US20170240778A1

公开(公告)日：2017-08-24

申请号：US15325237

申请日：2015-11-03

Applicant: Dow Global Technologies LLC ,  Dow Europe GmbH

Inventor： Glenn G Eagle ,  Andreas Lutz

IPC: C09J11/04 ,  C09J163/00 ,  C08K7/20

CPC classification number: C09J11/04 ,  C08K7/20 ,  C08K7/28 ,  C08K2201/003 ,  C08K2201/005 ,  C09J163/00 ,  C09J2205/102 ,  C09J2463/00

Abstract: A new adhesive composition containing glass beads and having unique properties in automotive related applications. The method of making such new adhesive composition.

公开(公告)号：US20150184039A1

公开(公告)日：2015-07-02

申请号：US14403873

申请日：2013-08-13

Applicant: Dow Global Technologies LLC

Inventor： Andreas Lutz ,  Beda Steiner

IPC: C09J11/08 ,  C09J151/04 ,  C09J163/00

CPC classification number: C09J11/08 ,  C08G59/56 ,  C08G59/66 ,  C08L75/00 ,  C08L75/04 ,  C09J151/04 ,  C09J163/00

Abstract: A 2K epoxy adhesive is provided that has rapid cure time and good strength characteristics. Both the epoxy resin composition and the hardener composition of the 2K epoxy comprise a reactive toughener. Such adhesives are useful in the manufacture and/or repair of large machinery (e.g., automobiles), and are useful for bonding like or unlike materials, such as metal and composites (e.g., carbon fiber or glass fiber composites).

Abstract translation: 提供2K环氧胶粘剂，其具有快速固化时间和良好的强度特性。 环氧树脂组合物和2K环氧树脂的固化剂组合物均包含反应性增韧剂。 这种粘合剂可用于大型机械（例如汽车）的制造和/或修理，并且可用于粘合或类似或不同的材料，例如金属和复合材料（例如，碳纤维或玻璃纤维复合材料）。

公开(公告)号：US20150166857A1

公开(公告)日：2015-06-18

申请号：US14636508

申请日：2015-03-03

Applicant: Dow Global Technologies LLC

Inventor： Ming Ming ,  Shaoguang Feng ,  Yan Fei Liu ,  Robert DJ Froese ,  Andreas Lutz ,  Glenn G. Eagle ,  Gary L. Jialanella ,  Eric E. Cole ,  Michael R. Golden

IPC: C09J163/00

CPC classification number: C09J163/00 ,  C08G59/621 ,  C08G59/686 ,  C08L61/06 ,  C09J163/04

Abstract: Epoxy adhesive compositions contain a heat-activatable catalyst. The heat-activatable catalyst includes a tertiary amine catalyst and a novolac resin that has a weight average molecular weight of at least 3000. One-component epoxy adhesive formulations that contain the heat-activatable catalyst have unexpectedly good storage stability.

Abstract translation: 环氧粘合剂组合物含有可热活化的催化剂。 可热活化的催化剂包括叔胺催化剂和重均分子量为至少3000的酚醛清漆树脂。含有可热活化催化剂的单组分环氧粘合剂制剂意外地具有良好的储存稳定性。

公开(公告)号：US20180258329A1

公开(公告)日：2018-09-13

申请号：US15755080

申请日：2016-08-31

Applicant: Dow Global Technologies LLC

Inventor： Felix Koch ,  Sergio Grunder ,  Andreas Lutz

IPC: C09J163/00 ,  C09J11/04 ,  C09J11/06

CPC classification number: C09J163/00 ,  C08G18/698 ,  C08G18/8067 ,  C08G59/4021 ,  C08G59/5033 ,  C08G59/5073 ,  C08K7/04 ,  C08L75/04 ,  C09J11/04 ,  C09J11/06 ,  C09J2400/12 ,  C09J2400/20 ,  C09J2475/00

Abstract: One-component toughened epoxy structural adhesives contain fibrous mineral fillers that have an aspect ratio of ≥6. The presence of the fibrous filler leads to a significant increase in elastic modulus while having little if any adverse effect on other properties such as dynamic impact peel resistance.

公开(公告)号：US20180251633A1

公开(公告)日：2018-09-06

申请号：US15756347

申请日：2016-09-06

Applicant: Dow Global Technologies LLC

Inventor： Andreas Lutz ,  Daniel Schneider ,  Sergio Grunder ,  Bindu Krishnan

IPC: C08L75/04 ,  C08G18/12 ,  C08G18/32 ,  C08G18/48 ,  C08G18/69 ,  C08G18/80 ,  C09J163/00

CPC classification number: C08L75/04 ,  C08G18/12 ,  C08G18/3215 ,  C08G18/4854 ,  C08G18/698 ,  C08G18/8064 ,  C08G18/8067 ,  C08G18/8077 ,  C08G18/808 ,  C09J163/00 ,  C08G18/675

Abstract: The invention is directed to a toughener for epoxy adhesives, the toughener comprising both soft and rubber units, and may be described as a capped soft-rubber PU toughener. The invention includes the tougheners and methods of making them, as well as adhesives comprising the inventive tougheners, methods of using the tougheners and adhesives comprising them, and cured inventive adhesives and products comprising them.

公开(公告)号：US20170022402A1

公开(公告)日：2017-01-26

申请号：US15121090

申请日：2015-03-19

Applicant: DOW GLOBAL TECHNOLOGIES LLC

Inventor： Andreas Lutz ,  Jeannine Flueckiger ,  Benjamin Alexander Haag ,  Regina Ditschuneit

IPC: C09J163/00 ,  C09J11/08 ,  B05D3/02 ,  C09J5/06

CPC classification number: C09J163/00 ,  B05D3/0272 ,  C09J5/06 ,  C09J9/00 ,  C09J11/08 ,  C09J2459/00 ,  C09J2463/00 ,  C09J2467/00

Abstract: An epoxy adhesive composition is provided that has superior wash-off resistance after pre-gelling, and may be used, for example, in manufacturing processes, for example, in the automobile industry. The composition also provides unique viscosity profile after pre-gelling to significantly reduce failure mode in subsequent processing steps. In preferred embodiments the adhesive composition comprises an epoxy type resin and a gelling agent selected from polyesterdiols and polyvinyl butyrals.

Abstract translation: 提供了在预胶化之后具有优异的耐洗涤性的环氧树脂粘合剂组合物，并且可以用于例如在汽车工业中的制造方法中。 该组合物还在预凝胶之后提供独特的粘度分布，以显着降低后续加工步骤中的破坏模式。 在优选实施方案中，粘合剂组合物包含环氧树脂和选自聚酯二醇和聚乙烯醇缩丁醛的胶凝剂。

公开(公告)号：US09416301B2

公开(公告)日：2016-08-16

申请号：US14437285

申请日：2013-03-13

Applicant: DOW GLOBAL TECHNOLOGIES LLC

Inventor： Lirong Zhou ,  Gary L. Jialanella ,  Andreas Lutz

IPC: C09J175/14 ,  C09J7/02 ,  C08G18/48 ,  C08G18/63 ,  C08J3/24 ,  C08F290/06 ,  C08G18/12 ,  C08G18/20 ,  C09J4/06 ,  C09J175/16

CPC classification number: C09J175/14 ,  C08F290/067 ,  C08G18/12 ,  C08G18/2081 ,  C08G18/4841 ,  C08G18/632 ,  C08J3/243 ,  C08J2375/16 ,  C09J4/06 ,  C09J7/22 ,  C09J7/38 ,  C09J175/16

Abstract: A composition comprising: a) one or more isocyanate functional components; b) one or more compounds containing a cycloaliphatic tertiary amine: c) one or more low functional acrylate containing components having about 1 to 4 acrylate groups per molecule; d) one or more high functional acrylate containing components having 5 to about 10 acrylate groups per molecule; and e) one or more compounds containing a peroxide group; wherein the composition is a two component composition and components a) and b) are kept separate from component e) until cure is desired. The composition may be utilized as an adhesive.

Abstract translation: 一种组合物，其包含：a）一种或多种异氰酸酯官能组分; b）一种或多种含有脂环族叔胺的化合物：c）每分子具有约1至4个丙烯酸酯基团的一种或多种低官能丙烯酸酯含量的组分; d）每分子具有5至约10个丙烯酸酯基团的一种或多种高官能丙烯酸酯含量的组分; 和e）一种或多种含有过氧化物基团的化合物; 其中所述组合物是双组分组合物，并且组分a）和b）与组分e）保持分离，直到需要固化。 组合物可以用作粘合剂。

公开(公告)号：US08858752B2

公开(公告)日：2014-10-14

申请号：US14165643

申请日：2014-01-28

Applicant: Dow Global Technologies LLC

Inventor： Andreas Lutz ,  Daniel Schneider

IPC: C09J163/02 ,  C09J163/00 ,  C09J175/00 ,  C08G59/24 ,  C08G71/00 ,  C08G18/48 ,  C08G18/73 ,  B29C65/48 ,  C08G18/12 ,  B32B37/12 ,  C08G18/66 ,  B32B27/38 ,  B32B27/40 ,  C08L75/08 ,  C08L75/04

CPC classification number: C09J163/00 ,  B29C65/4835 ,  B32B37/12 ,  C08G18/12 ,  C08G18/4854 ,  C08G18/6677 ,  C08G18/73 ,  C08L75/04 ,  C08L75/08 ,  C08L2666/20 ,  C08G18/286

Abstract: Structural adhesives are prepared from an elastomeric toughener that contains urethane and/or urea groups, and have terminal isocyanate groups that are capped with ketoxime compound. The adhesives have very good storage stability and cure to form cured adhesives that have good lap shear and impact peel strengths, even at −40° C.

Abstract translation: 结构粘合剂由含有氨基甲酸酯和/或脲基团的弹性体增韧剂制备，并具有用酮肟化合物封端的末端异氰酸酯基团。 粘合剂具有非常好的储存稳定性和固化性，以形成即使在-40℃下具有良好搭接剪切力和抗冲击剥离强度的固化粘合剂。