公开(公告)号：US08324128B2

公开(公告)日：2012-12-04

申请号：US10535066

申请日：2003-11-10

申请人： Erling Rytter ,  Sigrid Eri ,  Dag Schanke

发明人： Erling Rytter ,  Sigrid Eri ,  Dag Schanke

IPC分类号： B01J23/75

CPC分类号： C10G2/332 ,  B01J23/75 ,  B01J23/8896 ,  B01J35/023 ,  B01J35/10 ,  B01J35/1019 ,  B01J35/1042 ,  B01J35/1061 ,  C10G2300/703

摘要： A catalyst for use in a Fischer-Tropsch synthesis reaction which comprises cobalt supported on alumina, in which: the catalyst average particle size is in the range 20 to 100 μm; the specific surface area of the impregnated and calcined catalyst particles is greater than 80 m2/g; the average pore size of the impregnated and calcined catalyst is at least 90 Å (9 nm); and the pore volume of the impregnated and calcined catalyst is greater than 0.35 cm3/g.

摘要翻译： 一种用于费 - 托合成反应的催化剂，其包含负载在氧化铝上的钴，其中：催化剂平均粒度为20-100μm; 浸渍和煅烧的催化剂颗粒的比表面积大于80m 2 / g; 浸渍和煅烧的催化剂的平均孔径至少为（9nm）; 并且浸渍和煅烧催化剂的孔体积大于0.35cm 3 / g。

公开(公告)号：US20080064770A1

公开(公告)日：2008-03-13

申请号：US10535066

申请日：2003-11-10

申请人： Erling Rytter ,  Sigrid Eri ,  Dag Schanke

发明人： Erling Rytter ,  Sigrid Eri ,  Dag Schanke

IPC分类号： B01J35/10 ,  B01J23/72 ,  C07C1/04 ,  B01J35/02

CPC分类号： C10G2/332 ,  B01J23/75 ,  B01J23/8896 ,  B01J35/023 ,  B01J35/10 ,  B01J35/1019 ,  B01J35/1042 ,  B01J35/1061 ,  C10G2300/703

摘要： A catalyst for use in a Fischer-Tropsch synthesis reaction which comprises cobalt supported on alumina, in which: the catalyst average particle size is in the range 20 to 100 μm; the specific surface area of the impregnated and calcined catalyst particles is greater than 80 m2/g; the average pore size of the impregnated and calcined catalyst is at least 90 Å (9 nm); and the pore volume of the impregnated and calcined catalyst is greater than 0.35 cm3g.

摘要翻译： 一种用于费 - 托合成反应的催化剂，其包含负载在氧化铝上的钴，其中：催化剂平均粒径在20-100μm的范围内; 浸渍和煅烧的催化剂颗粒的比表面积大于80m 2 / g; 浸渍和煅烧的催化剂的平均孔径至少为（9nm）; 并且浸渍和煅烧的催化剂的孔体积大于0.35cm 3。

公开(公告)号：US06696501B2

公开(公告)日：2004-02-24

申请号：US10149060

申请日：2002-09-19

申请人： Dag Schanke ,  Roger Hansen ,  Jostein Sogge ,  Karina Heitnes Hofstad ,  Margrete H. Wesenberg ,  Erling Rytter

发明人： Dag Schanke ,  Roger Hansen ,  Jostein Sogge ,  Karina Heitnes Hofstad ,  Margrete H. Wesenberg ,  Erling Rytter

IPC分类号： C07C2700

CPC分类号： C10G2/32 ,  C01B3/382 ,  C01B2203/0233 ,  C01B2203/0244 ,  C01B2203/043 ,  C01B2203/062 ,  C01B2203/0844 ,  C01B2203/0894 ,  C01B2203/1052 ,  C01B2203/1241 ,  C01B2203/1258 ,  C01B2203/127 ,  C01B2203/141 ,  C01B2203/143 ,  C01B2203/146 ,  C01B2203/148 ,  C01B2203/82 ,  C07C1/0485

摘要： A method is described for conversion of natural gas or other fossil fuels to higher hydrocarbons, comprising the following steps: a) reaction of natural gas with steam and oxygenic gas in at least one reforming zone in order to produce a synthesis gas consisting primarily of hydrogen and CO, in addition to some carbon dioxide; b) passing said synthesis gas to a Fisher-Tropsch reactor in order to produce a crude synthesis stream consisting of lower hydrocarbons, water and non-converted synthesis gas; c) separation of said crude synthesis stream in a recovery zone, into a crude product stream mainly containing heavier hydrocarbons, a water stream and a tail gas stream mainly containing the remaining constituents; which is charaterized in that the method also comprises the following steps; d) stream reformation of at least part of the tail gas in a separate steam reformer; e) introduction of the reformed tail gas into the gas stream before this is led into the Fischer-Tropsch reactor.

摘要翻译： 描述了将天然气或其他化石燃料转化为高级烃的方法，其包括以下步骤：a）在至少一个重整区中天然气与蒸汽和含氧气体的反应，以便产生主要由氢组成的合成气 和CO，除了一些二氧化碳; b）将所述合成气送入费 - 托反应器，以产生由低级烃，水和未转化的合成气组成的粗合成料流; c）将回收区中的所述粗合成物流分离成主要含有较重烃的粗产物流，主要含有剩余组分的水流和尾气流; 其特征在于该方法还包括以下步骤： d）在单独的蒸汽重整器中重新形成尾气中的至少一部分; e）在将其引入费 - 托反应器之前，将重整后的尾气引入气流中。

公开(公告)号：US20130184360A1

公开(公告)日：2013-07-18

申请号：US13811588

申请日：2011-07-15

申请人： Sigrid Eri ,  Erling Rytter ,  Rune Myrstad

发明人： Sigrid Eri ,  Erling Rytter ,  Rune Myrstad

IPC分类号： C10G2/00

CPC分类号： C10G2/332 ,  B01J21/04 ,  B01J23/005 ,  B01J23/75 ,  B01J23/755 ,  B01J23/78 ,  B01J23/8896 ,  B01J23/8913 ,  B01J33/00 ,  B01J35/1019 ,  B01J35/1033 ,  B01J37/0201 ,  B01J37/0207 ,  B01J37/14 ,  B01J37/18 ,  C10G2/342 ,  C10G2300/703 ,  C10G2300/705

摘要： A method of preparing a Fischer-Tropsch catalyst for handling, storage, transport and deployment, including the steps of impregnating a porous support material with a source of cobalt, calcining the impregnated support material activating the catalyst, and passivating the activated catalyst.

摘要翻译： 一种制备用于处理，储存，运输和展开的费 - 托催化剂的方法，包括用钴源浸渍多孔载体材料，煅烧浸渍的活化催化剂的载体材料和钝化活化的催化剂的步骤。

公开(公告)号：US09156022B2

公开(公告)日：2015-10-13

申请号：US13816054

申请日：2011-07-19

申请人： Manoj M. Koranne ,  Erling Rytter ,  Sigrid Eri ,  Oyvind Borg

发明人： Manoj M. Koranne ,  Erling Rytter ,  Sigrid Eri ,  Oyvind Borg

IPC分类号： B01J23/00 ,  B01J21/04 ,  B01J23/06 ,  B01J23/755 ,  B01J35/10 ,  B01J37/00 ,  B01J37/02 ,  C10G2/00

CPC分类号： B01J23/005 ,  B01J21/04 ,  B01J23/06 ,  B01J23/755 ,  B01J35/1019 ,  B01J35/1038 ,  B01J35/1042 ,  B01J35/1047 ,  B01J37/0045 ,  B01J37/0201 ,  C10G2/33 ,  C10G2/334

摘要： The invention relates to a novel method of preparing attrition resistance spinel supports for Fischer Tropsch catalysts. The process comprises: (a) combining aluminum oxide, metal compound capable of forming spinel phase, and soluble compound of a trivalent aluminum; (b) mixing the combination resulting in (a) in a manner sufficient to form a slurry comprising the aforementioned combination; and (c) processing the mixture of (b) under conditions sufficient to form metal aluminate spinel composition. Metal aluminate spinel, for example, is formed in the last step by calcining the mixture from (b) at a temperature in the range of 700 to 1300° C., but the process is also capable, of producing attrition resistant supports (e.g., having a DI of 5 or less) at a relatively lower temperature in the range of 700 to 1050° C. The invention also produces the attrition resistance with lower metal loadings than that reported for prior attrition resistant spinel supports.

摘要翻译： 本发明涉及一种制备费托催化剂的耐磨性尖晶石载体的新方法。 该方法包括：（a）将氧化铝，能够形成尖晶石相的金属化合物和三价铝的可溶性化合物结合起来; （b）混合所得到的（a）以足以形成包含上述组合的浆料的方式的组合; 和（c）在足以形成金属铝酸盐尖晶石组合物的条件下处理（b）的混合物。 例如，金属铝酸盐尖晶石通过在700至1300℃的温度下煅烧来自（b）的混合物在最后步骤中形成，但是该方法还能够生产耐磨载体（例如， 在相对较低的温度下在700至1050℃的范围内具有5或更小的DI。本发明还产生具有比对于现有的耐磨尖晶石载体报告的金属负载更低的耐磨性。

公开(公告)号：US09249359B2

公开(公告)日：2016-02-02

申请号：US13811588

申请日：2011-07-15

申请人： Sigrid Eri ,  Erling Rytter ,  Rune Myrstan

发明人： Sigrid Eri ,  Erling Rytter ,  Rune Myrstan

IPC分类号： B01J21/04 ,  B01J33/00 ,  B01J37/14 ,  B01J37/18 ,  B01J23/75 ,  C10G2/00 ,  B01J23/755 ,  B01J23/78 ,  B01J23/889 ,  B01J23/89 ,  B01J35/10 ,  B01J23/00 ,  B01J37/02

CPC分类号： C10G2/332 ,  B01J21/04 ,  B01J23/005 ,  B01J23/75 ,  B01J23/755 ,  B01J23/78 ,  B01J23/8896 ,  B01J23/8913 ,  B01J33/00 ,  B01J35/1019 ,  B01J35/1033 ,  B01J37/0201 ,  B01J37/0207 ,  B01J37/14 ,  B01J37/18 ,  C10G2/342 ,  C10G2300/703 ,  C10G2300/705

摘要： A method of preparing a Fischer-Tropsch catalyst for handling, storage, transport and deployment, including the steps of impregnating a porous support material with a source of cobalt, calcining the impregnated support material, activating the catalyst, and passivating the activated catalyst.

摘要翻译： 一种制备用于处理，储存，运输和展开的费 - 托催化剂的方法，包括用钴源浸渍多孔载体材料，煅烧浸渍的载体材料，活化催化剂和钝化活化的催化剂的步骤。

公开(公告)号：US08969231B2

公开(公告)日：2015-03-03

申请号：US13378581

申请日：2010-08-31

申请人： Erling Rytter ,  Sigrid Eri ,  Rune Myrstad ,  Odd Asbjørn Lindvåg

发明人： Erling Rytter ,  Sigrid Eri ,  Rune Myrstad ,  Odd Asbjørn Lindvåg

IPC分类号： B01J38/04 ,  B01J38/06 ,  B01J38/10 ,  B01J38/12 ,  B01J38/16 ,  B01J23/00 ,  B01J23/02 ,  B01J23/08 ,  B01J23/10 ,  B01J23/32 ,  B01J23/40 ,  B01J23/42 ,  B01J23/44 ,  B01J23/56 ,  B01J23/58 ,  B01J23/60 ,  B01J23/70 ,  B01J23/74 ,  B01J20/00 ,  B01J21/04 ,  B01J23/89 ,  B01J23/75 ,  B01J23/80 ,  B01J23/889 ,  B01J35/10 ,  B01J37/02 ,  B01J37/10 ,  B01J37/12 ,  B01J37/14 ,  B01J37/16 ,  B01J37/18 ,  C10G2/00

CPC分类号： B01J23/8913 ,  B01J21/04 ,  B01J23/75 ,  B01J23/80 ,  B01J23/8896 ,  B01J23/894 ,  B01J23/8953 ,  B01J35/1019 ,  B01J35/1038 ,  B01J35/1042 ,  B01J37/0205 ,  B01J37/0207 ,  B01J37/10 ,  B01J37/12 ,  B01J37/14 ,  B01J37/16 ,  B01J37/18 ,  C10G2/331 ,  C10G2/332 ,  C10G2/342 ,  C10G2300/703 ,  Y10S502/524

摘要： A method of producing an alumina-supported cobalt catalyst for use in a Fischer-Tropsch synthesis reaction, which comprises: calcining an initial γ-alumina support material at a temperature to produce a modified alumina support material; impregnating the modified alumina support material with a source of cobalt; calcining the impregnated support material, activating the catalyst with a reducing gas, steam treating the activated catalyst, and activating the steam treated catalyst with a reducing gas.

摘要翻译： 一种制备用于费 - 托合成反应的氧化铝负载的钴催化剂的方法，其包括：在温度下煅烧初始γ-氧化铝载体材料以产生改性的氧化铝载体材料; 用钴源浸渍改性氧化铝载体材料; 煅烧浸渍的载体材料，用还原气体活化催化剂，蒸汽处理活化的催化剂，以及用还原气体活化蒸汽处理的催化剂。

公开(公告)号：US20130199966A1

公开(公告)日：2013-08-08

申请号：US13814905

申请日：2011-07-29

申请人： Manoj M. Koranne ,  Erling Rytter ,  Sigrid Eri ,  Oyvind Borg

发明人： Manoj M. Koranne ,  Erling Rytter ,  Sigrid Eri ,  Oyvind Borg

IPC分类号： B01J23/889 ,  C07C1/04

CPC分类号： B01J23/8896 ,  B01J23/005 ,  B01J23/75 ,  B01J23/8913 ,  B01J35/1014 ,  B01J35/1038 ,  B01J37/0201 ,  B01J37/088 ,  B01J37/18 ,  C07C1/0445 ,  C10G2/33 ,  C10G2/332 ,  C10G2/342 ,  C10G45/58 ,  C10G47/00 ,  C10G2300/1022 ,  C10G2300/703

摘要： A method of producing an aluminium oxide supported catalyst for use in a Fischer-Tropsch synthesis reaction, which comprises: spray-drying a slurry of γ-alumina and a source of a spinel forming metal to form a solid precursor material; calcining the precursor material to form a modified support material including a metal aluminate spinel; impregnating the modified alumina support material with a source of cobalt; calcining the impregnated support material, and activating the catalyst.

摘要翻译： 一种制备用于费 - 托合成反应的氧化铝载体催化剂的方法，其包括：喷雾干燥γ-氧化铝和尖晶石形成金属源的浆料以形成固体前体材料; 煅烧前体材料以形成包含金属铝酸盐尖晶石的改性载体材料; 用钴源浸渍改性氧化铝载体材料; 煅烧浸渍的载体材料，并活化催化剂。

公开(公告)号：US08921252B2

公开(公告)日：2014-12-30

申请号：US13817501

申请日：2011-08-17

申请人： Erling Rytter ,  Sigrid Eri ,  Torild Hulsund Skagseth ,  Oyvind Borg

发明人： Erling Rytter ,  Sigrid Eri ,  Torild Hulsund Skagseth ,  Oyvind Borg

IPC分类号： B01J38/12 ,  C10G3/00 ,  B01J23/94 ,  B01J33/00 ,  B01J35/02 ,  B01J35/10 ,  B01J38/10 ,  C07C1/04 ,  C10G2/00 ,  B01J23/00 ,  B01J23/75

CPC分类号： C10G3/62 ,  B01J23/005 ,  B01J23/75 ,  B01J23/94 ,  B01J33/00 ,  B01J35/023 ,  B01J35/1014 ,  B01J35/1038 ,  B01J38/10 ,  B01J38/12 ,  C07C1/045 ,  C07C2521/04 ,  C07C2523/36 ,  C07C2523/42 ,  C07C2523/75 ,  C07C2523/889 ,  C07C2523/89 ,  C10G2/332 ,  Y02P20/584 ,  Y02P30/20 ,  Y10S502/514 ,  Y10S502/518

摘要： A process for the regeneration of deactivated catalyst from a Fischer-Tropsch synthesis reactor, the catalyst being a supported cobalt catalyst. The process comprises the following steps: a withdrawal step, in which a portion of deactivated catalyst together with liquid hydrocarbon is withdrawn from the reactor; a concentration step, in which the concentration of the catalyst in the liquid hydrocarbon is increased; a calcination step, in which the deactivated catalyst composition is subjected to an oxidizing gas to oxidize carbonaceous material contained in the deactivated catalyst in to gaseous oxides of the components of the carbonaceous material; and a reactivation step, in which the deactivated catalyst composition is reactivated to produced a regenerated catalyst.

摘要翻译： 一种从费 - 托合成反应器再生失活催化剂的方法，催化剂是负载型钴催化剂。 该方法包括以下步骤：其中一部分失活催化剂与液体烃一起从反应器中排出的抽出步骤; 浓缩步骤，其中液体烃中催化剂的浓度增加; 煅烧步骤，其中使失活的催化剂组合物经受氧化气体以将包含在失活催化剂中的含碳材料氧化成含碳材料的组分的气态氧化物; 和再活化步骤，其中使失活催化剂组合物再活化以产生再生催化剂。

公开(公告)号：US20130143736A1

公开(公告)日：2013-06-06

申请号：US13816054

申请日：2011-07-19

申请人： Manoj M. Koranne ,  Erling Rytter ,  Sigrid Eri ,  Oyvind Borg

发明人： Manoj M. Koranne ,  Erling Rytter ,  Sigrid Eri ,  Oyvind Borg

IPC分类号： B01J23/00 ,  B01J23/755 ,  B01J23/06

CPC分类号： B01J23/005 ,  B01J21/04 ,  B01J23/06 ,  B01J23/755 ,  B01J35/1019 ,  B01J35/1038 ,  B01J35/1042 ,  B01J35/1047 ,  B01J37/0045 ,  B01J37/0201 ,  C10G2/33 ,  C10G2/334

摘要： The invention relates to a novel method of preparing attrition resistance spinel supports for Fischer Tropsch catalysts. The process comprises: (a) combining aluminum oxide, metal compound capable of forming spinel phase, and soluble compound of a trivalent aluminum; (b) mixing the combination resulting in (a) in a manner sufficient to form a slurry comprising the aforementioned combination; and (c) processing the mixture of (b) under conditions sufficient to form metal aluminate spinel composition. Metal aluminate spinel, for example, is formed in the last step by calcining the mixture from (b) at a temperature in the range of 700 to 1300° C., but the process is also capable, of producing attrition resistant supports (e.g., having a DI of 5 or less) at a relatively lower temperature in the range of 700 to 1050° C. The invention also produces the attrition resistance with lower metal loadings than that reported for prior attrition resistant spinel supports.

摘要翻译： 本发明涉及一种制备费托催化剂的耐磨性尖晶石载体的新方法。 该方法包括：（a）将氧化铝，能够形成尖晶石相的金属化合物和三价铝的可溶性化合物结合起来; （b）混合所得到的（a）以足以形成包含上述组合的浆料的方式的组合; 和（c）在足以形成金属铝酸盐尖晶石组合物的条件下处理（b）的混合物。 例如，金属铝酸盐尖晶石通过在700至1300℃的温度下煅烧来自（b）的混合物在最后步骤中形成，但是该方法还能够生产耐磨载体（例如， 在相对较低的温度下在700至1050℃的范围内具有5或更小的DI。本发明还产生具有比对于现有的耐磨尖晶石载体报告的金属负载更低的耐磨性。