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    Catalytic conversion with zeolite ZSM-39
    2.
    发明授权
    Catalytic conversion with zeolite ZSM-39 失效
    用ZSM-39沸石催化转化

    公开(公告)号：US4357233A

    公开(公告)日：1982-11-02

    申请号：US254698

    申请日：1981-04-16

    申请人： Francis G. Dwyer ,  Edwin E. Jenkins

    发明人： Francis G. Dwyer ,  Edwin E. Jenkins

    IPC分类号： B01J29/70 ,  C01B37/02 ,  C01B39/48 ,  C10G35/095 ,  C10G45/64 ,  C10G11/02 ,  C10G35/06 ,  C10G47/02

    CPC分类号： C01B39/48 ,  B01J29/70 ,  C01B37/02 ,  C10G35/095 ,  C10G45/64

    摘要： A new porous zeolite, a method of making same and the use thereof in catalytic conversion of organic compounds. The new product has a composition, expressed in terms of moles of anhydrous oxides per 100 moles of silica as follows:(0-2.5)M.sub.2/n O:(0- 2.5)Al.sub.2 O.sub.3 :(100)SiO.sub.2wherein M is at least one cation having a valence n and wherein the zeolite is characterized by the distinctive X-ray powder diffraction pattern as shown in Table 1 herein. The new zeolite is prepared from a reaction mixture comprising a source of silica, a source of organic compounds of Group VB, alkali metal cations, water and with or without a source of alumina.

    摘要翻译： 一种新的多孔沸石，其制备方法及其在有机化合物的催化转化中的用途。 新产品的组成，以无水氧化物每100摩尔二氧化硅的摩尔数表示，如下：（0-2.5）M2 / nO：（0-2.5）Al2O3：（100）SiO2，其中M是至少一个阳离子 具有价数n，并且其中沸石的特征在于如本文表1所示的独特的X射线粉末衍射图。 新沸石由包含二氧化硅源，VB族有机化合物源，碱金属阳离子，水和有或无氧化铝源的反应混合物制备。

    Zeolite ZSM-39
    3.
    发明授权
    Zeolite ZSM-39 失效
    沸石ZSM-39

    公开(公告)号：US4287166A

    公开(公告)日：1981-09-01

    申请号：US156905

    申请日：1980-06-06

    申请人： Francis G. Dwyer ,  Edwin E. Jenkins

    发明人： Francis G. Dwyer ,  Edwin E. Jenkins

    IPC分类号： B01J29/70 ,  C01B37/02 ,  C01B39/48 ,  C01B33/20 ,  C01B33/28 ,  C07F7/02

    CPC分类号： B01J29/70 ,  C01B37/02 ,  C01B39/48

    摘要： A new porous zeolite, a method of making same and the use thereof in catalytic conversion of organic compounds. The new product has a composition, expressed in terms of moles of anhydrous oxides per 100 moles of silica as follows:(0-2.5)M.sub.2 /nO: (0-2.5)Al.sub.2 O.sub.3 : (100)SiO.sub.2wherein M is at least one cation having a valence n and wherein the zeolite is characterized by the distinctive X-ray powder diffraction pattern as shown in Table 1 herein. The new zeolite is prepared from a reaction mixture comprising a source of silica, a source of organic compounds of Group VB, alkali metal cations, water and with or without a source of alumina.

    摘要翻译： 一种新的多孔沸石，其制备方法及其在有机化合物的催化转化中的用途。 新产品的组成，以无水氧化物每100摩尔二氧化硅的摩尔数表示，如下：（0-2.5）M2 / nO：（0-2.5）Al2O3：（100）SiO2其中M是至少一个阳离子 具有价数n，并且其中沸石的特征在于如本文表1所示的独特的X射线粉末衍射图。 新沸石由包含二氧化硅源，VB族有机化合物源，碱金属阳离子，水和有或没有氧化铝源的反应混合物制备。

    Highly siliceous porous crystalline material and its use in conversion of oxygenates
    5.
    发明授权
    Highly siliceous porous crystalline material and its use in conversion of oxygenates 失效
    高度硅质多孔结晶材料及其在含氧化合物转化中的应用

    公开(公告)号：US5254767A

    公开(公告)日：1993-10-19

    申请号：US623585

    申请日：1984-06-22

    申请人： Francis G. Dwyer

    发明人： Francis G. Dwyer

    IPC分类号： B01J29/70 ,  C07C2/12 ,  C10G45/64 ,  C07C1/20

    CPC分类号： B01J29/7042 ,  C07C2/12 ,  C10G3/49 ,  C10G3/57 ,  C07C2529/70 ,  C10G2300/4006 ,  C10G2300/4012 ,  C10G2300/4018 ,  C10G2400/02 ,  Y02P30/20

    摘要： A new zeolite, designated ZSM-22, is disclosed and claimed. The new zeolite has the composition, in the anhydrous state, expressed in terms of mole ratios of oxides as follows:(x)Q.sub.2 O:(y)M.sub.2/n O:(z)L.sub.2 O.sub.3 :100SiO.sub.2wherein Q.sub.2 O is the oxide form of an organic compound containing an element of Group 5-B (as defined in the Table of the Elements--National Bureau of Standards, Fischer Scientific Co. Catalog No. 5-702-10), e.g., N or P, preferably N, containing at least one alkyl or aryl group having at least 2 carbon atoms, M is an alkali or alkaline earth metal having a valence n, e.g., Na, K, Cs or Li and wherein x=0.01-2.0, y=0-2.0, z=0-5, and L=Al. The zeolite is useful in the process of catalytic conversion of alcohols and/or oxygenates to gasoline-grade hydrocarbons.

    摘要翻译： 公开并要求保护名为ZSM-22的新型沸石。 新型沸石的组成为无水状态，以氧化物的摩尔比表示如下：（x）Q2O：（y）M2 / nO：（z）L2O3：100SiO2其中Q2O是有机物的氧化物形式 含有5-B族元素的化合物（如元素 - 国家标准局表，Fischer Scientific Co.目录号5-702-10中所定义），例如N或P，优选N，至少含有 一个具有至少2个碳原子的烷基或芳基，M是价数n的碱金属或碱土金属，例如Na，K，Cs或Li，其中x = 0.01-2.0，y = 0-2.0，z = 0-5，L = Al。 沸石可用于将醇和/或含氧化合物催化转化成汽油级烃的方法。

    Propylation of toluene
    9.
    发明授权
    Propylation of toluene 失效
    甲苯的丙基化

    公开(公告)号：US4049737A

    公开(公告)日：1977-09-20

    申请号：US614731

    申请日：1975-09-18

    申请人： Francis G. Dwyer ,  Donald J. Klocke

    发明人： Francis G. Dwyer ,  Donald J. Klocke

    IPC分类号： C07C2/66 ,  C07C3/52

    CPC分类号： C07C2/66 ,  C07C2521/04 ,  C07C2529/40

    摘要： Propylation of toluene with selective production of cymene is accomplished by vapor phase reaction of toluene and propylene at a temperature between about 400.degree. and about 600.degree. F. in the presence of a catalyst comprising a crystalline aluminosilicate zeolite, said zeolite having a silica to alumina ratio of at least about 12 and a constraint index, as hereinafter defined, within the approximate range of 1 to 12.

    摘要翻译： 在选择性生产甲基异丙苯的情况下甲苯的丙基化是通过在包含结晶硅铝酸盐沸石的催化剂存在下，在约400至约600°F之间的温度下，甲苯和丙烯的气相反应完成的，所述沸石具有二氧化硅与氧化铝 至少约12的比例和如下文所定义的约束指数在1至12的近似范围内。

    Synthesis of zeolite ZSM-5
    10.
    发明授权
    Synthesis of zeolite ZSM-5 失效
    沸石ZSM-5的合成

    公开(公告)号：US4526879A

    公开(公告)日：1985-07-02

    申请号：US520746

    申请日：1983-08-05

    申请人： Francis G. Dwyer ,  Pochen Chu

    发明人： Francis G. Dwyer ,  Pochen Chu

    IPC分类号： B01J29/40 ,  C01B39/40 ,  C01B33/28

    CPC分类号： C01B39/40 ,  B01J29/40 ,  B01J2229/26 ,  B01J2229/42 ,  Y10S423/22

    摘要： As synthesized by conventional technique, zeolite ZSM-5 is crystallized in the presence of substantial amount of tetraalkylammonium cations, the alkyl groups of which contain 2 to 5 carbon atoms, such as, for example, tetrapropylammonium. When synthesized in the conventional way, ZSM-5 contains tetraalkylammonium cations as well as a substantial amount of sodium ions. To obtain a more catalytically active form of ZSM-5, the sodium ions must be exchanged to very low levels. By synthesizing zeolite ZSM-5 according to the present method, i.e., in the presence of a combination of an amine and a halide in the presence of a mutual solvent and with a specifically defined reaction mixture composition, ZSM-5 having different organic nitrogen-containing cations but the same crystal structure as conventionally prepared ZSM-5 is obtained. The ZSM-5 prepared in accordance herewith is very low in sodium content as synthesized and has a crystal size of from about 0.05 microns to about 20 microns.

    摘要翻译： 如通过常规技术合成的，沸石ZSM-5在存在大量四烷基铵阳离子（其烷基含有2至5个碳原子的四烷基铵阳离子）存在下结晶，例如四丙基铵。 当以常规方式合成时，ZSM-5含有四烷基铵阳离子以及大量的钠离子。 为了获得更具催化活性的ZSM-5形式，钠离子必须交换到非常低的水平。 通过根据本发明的方法合成沸石ZSM-5，即在相互溶剂存在下，在胺和卤化物的组合存在下，与特定定义的反应混合物组合物，具有不同有机氮气的ZSM-5， 得到与常规制备的ZSM-5相同的晶体结构。 根据本文制备的ZSM-5的钠含量非常低，并且具有约0.05微米至约20微米的晶体尺寸。