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    Substrates provided with a microstructured surface, methods for the production thereof, and their use
    1.
    发明授权
    Substrates provided with a microstructured surface, methods for the production thereof, and their use 失效
    具有微结构表面的基板，其制造方法及其用途

    公开(公告)号：US06649266B1

    公开(公告)日：2003-11-18

    申请号：US09959023

    申请日：2001-10-15

    申请人： Frank Gross ,  Martin Mennig ,  Peter W. Oliveira ,  Helmut Schmidt ,  Stefan Sepeur

    发明人： Frank Gross ,  Martin Mennig ,  Peter W. Oliveira ,  Helmut Schmidt ,  Stefan Sepeur

    IPC分类号： B32B1700

    CPC分类号： C09K3/18 ,  B05D1/40 ,  B05D5/08 ,  B08B17/06 ,  B08B17/065 ,  B29C59/026 ,  B29C2059/023 ,  Y10T428/31 ,  Y10T428/315 ,  Y10T428/31612 ,  Y10T428/31663

    摘要： Substrates provided with a microstructured surface have a surface layer which (a) comprises a composition comprising condensates of one or more hydrolysable compounds of at least one element M from main groups III to V and/or transition groups II to IV of the Periodic Table of the Elements, at least some of these compounds containing not only hydrolysable groups A but also non-hydrolysable, carbon-containing groups B and the total molar ratio of groups A to groups B in the parent monomeric starting compounds being from 10:1 to 1:2, from 0.1 to 100 mol % of the groups B being groups B′ containing on average from 5 to 30 fluorine atoms which are attached to one or more aliphatic carbon atoms distanced from M by at least two atoms, and (b) has a microstructuring of such kind that the contact angle with respect to water or hexadecane is at least 5° higher than the contact angle of a corresponding smooth surface. The substrates provided with a microstructured surface are particularly suitable as transparent or translucent easy-to-clean systems.

    摘要翻译： 提供有微结构化表面的底物具有表面层，其表面层包含一种组合物，该组合物包含至少一种元素M的主要组III至V的一种或多种可水解化合物的缩合物和/或周期表的转变基团II至IV的组合物 元素，这些化合物中的至少一些化合物不仅含有可水解基团A，而且含有不可水解的含碳基团B，并且母体单体起始化合物中基团A与基团B的总摩尔比为10:1至1 2，0.1〜100摩尔％的基团B为含有平均5〜30个氟原子的基团B'，其通过至少两个原子与一个或多个与M离开的一个或多个脂族碳原子连接，（b）具有 这种微结构化使得相对于水或十六烷的接触角比相应的光滑表面的接触角高至少5°。具有微结构化表面的基底特别合适 作为透明或半透明的易于清洁的系统。

    USE OF A COATING AGENT THAT CURES AT ROOM TEMPERATURE
    3.
    发明申请
    USE OF A COATING AGENT THAT CURES AT ROOM TEMPERATURE 审中-公开
    在室温下使用涂层剂的用途

    公开(公告)号：US20120177835A1

    公开(公告)日：2012-07-12

    申请号：US13496634

    申请日：2010-09-15

    申请人： Stefan Sepeur ,  Frank Gross ,  Hans Goetz ,  Thomas Isleib

    发明人： Stefan Sepeur ,  Frank Gross ,  Hans Goetz ,  Thomas Isleib

    IPC分类号： C23F13/00 ,  C23F11/00 ,  C23C4/00 ,  C23C4/06 ,  C23C26/00

    CPC分类号： C09D5/08 ,  C01P2004/61 ,  C09C1/62 ,  C09C1/644 ,  C09D5/021 ,  C09D5/082 ,  C09D5/10 ,  C09K3/30 ,  C23C18/1216 ,  C23C18/127

    摘要： The invention relates to the use of a coating agent that cures at room temperature.In order to provide a room-temperature-curing coating agent for preventing cathodic corrosion and for application as an aerosol or as brush-on paint, it is proposed that the coating agent be produced by the following method: a) Mixing 5 to 95 wt. % metal alkoxide with 5 to 95 wt. % metal pigment, b) Adding a solvent and up to 10 wt. % (relative to the amount of solid matter) of a catalyst, the catalyst being selected from the group consisting of Lewis acids, organic acids and bases, inorganic bases, functional silanes, in particular aminosilanes, inorganic acids, in particular sulphuric or phosphoric acid, phosphates or blocked phosphates, the coating agent being applied onto a metallic substrate and subsequently dried at room temperature.

    摘要翻译： 本发明涉及在室温下固化的包衣剂的用途。 为了提供用于防止阴极腐蚀并用作气溶胶或刷涂料的室温固化涂料，建议通过以下方法制备涂料：a）将5至95重量份 。 ％的金属醇盐与5〜95wt。 ％金属颜料，b）添加溶剂和最多10重量％ 催化剂选自路易斯酸，有机酸和碱，无机碱，功能性硅烷，特别是氨基硅烷，无机酸，特别是硫酸或磷酸的％（相对于固体物质的量） ，磷酸盐或封闭的磷酸盐，将涂覆剂施加到金属基底上，随后在室温下干燥。

    Method of Producing a Self-Cleaning Surface
    4.
    发明申请
    Method of Producing a Self-Cleaning Surface 审中-公开
    生产自清洁表面的方法

    公开(公告)号：US20090263586A1

    公开(公告)日：2009-10-22

    申请号：US12227366

    申请日：2007-05-07

    申请人： Stefan Goedicke ,  Frank Gross ,  Stefan Sepeur

    发明人： Stefan Goedicke ,  Frank Gross ,  Stefan Sepeur

    IPC分类号： B05D3/00 ,  B32B17/10 ,  B32B27/06 ,  B32B27/08

    CPC分类号： B08B17/065 ,  B05D7/542 ,  B08B17/06 ,  B82Y30/00 ,  C08K3/22 ,  C08K5/05 ,  C09D1/00 ,  C09D5/00 ,  C09D7/63 ,  C09D7/67 ,  C09D7/68 ,  C09D7/69 ,  C09D7/70 ,  Y10T428/31612 ,  Y10T428/31663

    摘要： The invention relates to a method of producing a self-cleaning surface on a substrate.To provide a method according to the preamble, with which surfaces can be produced which are self-cleaning indoors as well and even in the dark, it is suggested according to the invention that a coating with hydrophilic surface components be applied to the substrate and a structure formed in the nanometer range or a combined structure in the nano- and micrometer ranges.The invention surprisingly demonstrates that the principles underlying the Lotus effect® apply not only to hydrophobic but also hydrophilic surfaces.

    摘要翻译： 本发明涉及在衬底上制造自清洁表面的方法。 为了提供根据前序部分的方法，通过该方法可以产生在室内以及甚至在黑暗中自清洁的表面，根据本发明，建议将具有亲水表面组分的涂层施加到基底上，并且 在纳米范围内形成的结构或纳米和微米范围内的组合结构。 本发明令人惊奇地表明，莲花效应（R）的基本原理不仅适用于疏水而且亲水的表面。

    METHOD OF PRODUCING PHENOLATE ESTER COMPOUNDS
    5.
    发明申请
    METHOD OF PRODUCING PHENOLATE ESTER COMPOUNDS 审中-公开
    苯酚酯化合物的制备方法

    公开(公告)号：US20120059116A1

    公开(公告)日：2012-03-08

    申请号：US13319784

    申请日：2010-05-04

    申请人： Stefan Sepeur ,  Frank Gross

    发明人： Stefan Sepeur ,  Frank Gross

    IPC分类号： C09D183/08 ,  C08G77/26 ,  B82Y30/00

    CPC分类号： C23C18/14 ,  C07F7/1804 ,  C09D183/04 ,  C23C18/1216 ,  C23C18/122 ,  C23C18/1254 ,  C23C18/127 ,  C25D13/02 ,  C25D13/04

    摘要： The invention relates to phenolic ester compounds.In order to create a new product class which is suited as coating material, a compound is created within the scope of the invention, having a chemical structure of the following formula: [R1—Ph—O]aX(R2)b(R3)c(OR)n-a-b-c where X=Si, Ti, Zr, Mo, Mn, Cr, W, Hf, Ge, Sn, Pb where n=4 or X=B, V, Al, Ga, In where n=3 or X=Zn, Ni, Cu, alkaline earth where n=2 R1=O—H, H, O—Y or an organic side chain Y=an element which is different from or the same as X and has appropriate substituents R2=alkyl group or functional organic side chain R3=an organic side chain which is the same as or different from R2 Ph=aryl group R=alkyl group a is an integer between 1 and n; b=0 or 1 and c=0 or 1, and a+b+c=n. A compound is thus obtained, in which an aryl group is linked into an ester by way of an O—X group. Surprisingly, it was found that materials which resist hydrolysis and are highly stable towards chemicals are obtained by the transesterification of silanes with phenolic compounds.

    摘要翻译： 本发明涉及酚酯化合物。 为了制备适合作为涂料的新产品类，在本发明的范围内产生具有下式的化学结构的化合物：[R1-Ph-O] aX（R2）b（R3） c（OR）nabc其中X = Si，Ti，Zr，Mo，Mn，Cr，W，Hf，Ge，Sn，Pb，其中n = 4或X = B，V，Al，Ga，In，其中n = 3或 X = Zn，Ni，Cu，碱土，其中n = 2 R1 = O-H，H，O-Y或有机侧链Y =与X不同或相同且具有适当取代基的元素R 2 =烷基 基团或官能的有机侧链R3 =与R 2相同或不同的有机侧链Ph =芳基R =烷基a是1和n之间的整数; b = 0或1，c = 0或1，a + b + c = n。 由此得到通过O-X基团将芳基连接到酯中的化合物。 令人惊讶的是，发现耐水解和对化学物质稳定的材料是通过硅烷与酚类化合物的酯交换得到的。

    COATING MATERIAL HAVING CATALYTIC ACTIVITY AND USE OF SAID COATING MATERIAL
    6.
    发明申请
    COATING MATERIAL HAVING CATALYTIC ACTIVITY AND USE OF SAID COATING MATERIAL 审中-公开
    具有催化活性的涂料和涂层材料的使用

    公开(公告)号：US20100081569A1

    公开(公告)日：2010-04-01

    申请号：US12450635

    申请日：2008-04-01

    申请人： Stefan Sepeur ,  Frank Gross ,  Gerald Frenzer

    发明人： Stefan Sepeur ,  Frank Gross ,  Gerald Frenzer

    IPC分类号： B01J21/06 ,  B01J23/10 ,  B01J23/58 ,  B01J23/02 ,  B01J21/02 ,  B01J23/04

    CPC分类号： C09D1/00 ,  B01D53/944 ,  B01D2255/202 ,  B01D2255/204 ,  B01D2255/206 ,  B01D2255/20707 ,  B01D2255/20715 ,  B01D2255/20738 ,  B01D2255/2092 ,  B01D2257/708 ,  B01J21/066 ,  B01J23/02 ,  B01J23/04 ,  B01J23/10 ,  B01J37/0215 ,  B01J37/0219 ,  B01J37/344 ,  C09D5/18 ,  F24C15/005 ,  F24C15/04 ,  Y02A50/235

    摘要： The invention relates to a coating material having catalytic activity for reducing the combustion temperature of soot and organic substances. It also relates to the use of the coating material. In order to create a catalytically active coating material with which an abrasion-proof coating suitable also for optical applications can be produced for the combustion of soot and organic substances, it is proposed within the scope of the invention that the coating material contains at least 20 and less than 50 wt. % of compounds of subgroup metals or of elements of the third and fourth main groups, and between 10 and 80 wt. % of alkali or alkaline earth compounds, the molar proportion of alkali or alkaline earth compounds being higher than the molar proportion of compounds of subgroup metals or of elements of the third and fourth main groups. Surprisingly, the catalytic composition according to the invention permits the production of a colorless, transparent or translucent coating which also shows high abrasion resistance.

    摘要翻译： 本发明涉及具有降低烟灰和有机物质的燃烧温度的催化活性的涂料。 它还涉及涂料的用途。 为了产生催化活性涂层材料，通过该材料可以生产适用于光学应用的耐磨涂层用于烟灰和有机物质的燃烧，在本发明的范围内提出涂层材料含有至少20 和小于50wt。 亚组金属或第三和第四主要元素的化合物的百分比，以及10至80wt。 ％的碱金属或碱土金属化合物，碱金属或碱土金属化合物的摩尔比例高于亚组金属或第三和第四主要元素的摩尔比例。 令人惊奇的是，根据本发明的催化剂组合物允许生产也显示出高耐磨性的无色透明或半透明涂层。

    Alkali-Resistant Sol-Gel Coating
    7.
    发明申请
    Alkali-Resistant Sol-Gel Coating 审中-公开
    耐碱溶胶 - 凝胶涂层

    公开(公告)号：US20090238986A1

    公开(公告)日：2009-09-24

    申请号：US11922297

    申请日：2006-06-12

    申请人： Frank Gross ,  Gerd Schlick ,  Stefan Sepeur

    发明人： Frank Gross ,  Gerd Schlick ,  Stefan Sepeur

    IPC分类号： B05D1/04 ,  C08G77/14 ,  C09D183/06 ,  B05D1/28 ,  B05D1/02 ,  B05D1/18 ,  B05D3/12 ,  B05D3/02

    CPC分类号： C09D183/04 ,  C09D183/08

    摘要： The invention relates to alkali-resistant sol-gel coatings, a process for producing alkali-resistant sol-gel coatings and use thereof.To provide alkali-resistant sol-gel coatings, a coating is proposed within the scope of the invention that consists of a hydrolysable silane of the compounds TEOS, MTEOS or higher-chain alkyl silanes (di- tri- and tetrafunctional silanes), but preferably TEOS, MTEOS or mixtures thereof and a condensation catalyst based on a) secondary or tertiary bases (e.g. amino, mercaptosilanes) and/or b) Lewis acids as metal alkoxides, such as aluminium alkoxides, zirconium alkoxides and titanium alkoxides where the ratio (in wt. %) of hydroysable silane to condensation catalyst is between 99:1 and 70:30.

    摘要翻译： 本发明涉及耐碱性溶胶 - 凝胶涂层，一种生产耐碱性溶胶 - 凝胶涂层的方法及其应用。 为了提供耐碱性溶胶 - 凝胶涂层，在本发明的范围内提出了由化合物TEOS，MTEOS或高级烷基硅烷（二 - 和四官能硅烷）的可水解硅烷组成的涂层，但优选 TEOS，MTEOS或其混合物和基于a）仲或叔碱（例如氨基，巯基硅烷）和/或b）路易斯酸作为金属醇盐的缩合催化剂，例如醇铝，烷氧基锆和烷氧化钛，其中 可水解硅烷至缩合催化剂的重量百分比为99：1至70:30。

    Airbag module with an airbag and a tubular gas generator that can be fastened to a module housing
    10.
    发明授权
    Airbag module with an airbag and a tubular gas generator that can be fastened to a module housing 失效
    具有气囊的气囊模块和可以紧固到模块壳体的管状气体发生器

    公开(公告)号：US08141898B2

    公开(公告)日：2012-03-27

    申请号：US13051940

    申请日：2011-03-18

    申请人： Stefan Hamels ,  Tobias Fechner ,  Frank Gross ,  Christian Kempe

    发明人： Stefan Hamels ,  Tobias Fechner ,  Frank Gross ,  Christian Kempe

    IPC分类号： B60R21/20

    CPC分类号： B60R21/2171

    摘要： An airbag module with an airbag and a tubular gas generator fastened to a module housing is provided. Said tubular gas generator having gas outlet openings along the periphery thereof and can be fastened to the module housing by means of only a clamping ring that is movable over the tubular gas generator and over a section of the module housing. The clamping ring has in axial direction elongated sections being separated from each other and continuing axial in the opposite direction. The module housing has in its bottom an opening for inserting the tubular gas generator, wherein on the module housing below this opening a support for the tubular gas generator is provided. The clamping ring is designed such that said clamping ring reaches below the support after positioning the tubular gas generator with the elongated section by axial moving in direction of the center of the tubular gas generator.

    摘要翻译： 提供一种具有安全气囊的安全气囊模块和固定在模块外壳上的管状气体发生器。 所述管式气体发生器具有沿着其周边的气体出口，并且可以仅通过可在管式气体发生器上方并在模块壳体的一部分上方的夹紧环紧固到模块壳体。 夹紧环在轴向上具有细长部分，彼此分离并在相反方向上轴向延伸。 模块壳体的底部具有用于插入管状气体发生器的开口，其中在该开口下方的模块壳体上设置有用于管状气体发生器的支撑件。 夹紧环设计成使得所述夹紧环通过在管状气体发生器的中心的方向上轴向移动而将管状气体发生器与细长部分定位之后到达支撑件下方。