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10 条记录 (耗时 0.039 秒)

    Process of preparing copolymers of butyl acrylate and 1-(.alpha.-alkyl acrylate)-1-tert-butyl peroxy ethanes
    5.
    发明授权
    Process of preparing copolymers of butyl acrylate and 1-(.alpha.-alkyl acrylate)-1-tert-butyl peroxy ethanes 失效
    制备丙烯酸丁酯和1-（α-烷基丙烯酸酯）-1-叔丁基过氧乙烷的共聚物的方法

    公开(公告)号：US4349649A

    公开(公告)日：1982-09-14

    申请号：US212703

    申请日：1980-11-13

    申请人： Valery N. Pavljuchenko ,  Zinaida M. Pessina ,  Elena D. Vasilieva ,  Sergei S. Ivanchev

    发明人： Valery N. Pavljuchenko ,  Zinaida M. Pessina ,  Elena D. Vasilieva ,  Sergei S. Ivanchev

    IPC分类号： C08L21/00 ,  C08F2/00 ,  C08F2/22 ,  C08F4/40 ,  C08F20/00 ,  C08F220/10 ,  C08F220/18 ,  C08F220/26 ,  C08F220/28

    CPC分类号： C08F220/18 ,  C08F220/28

    摘要： The process for preparing copolymers of butyl acrylate and 1-(.alpha.-alkyl acrylate)-1-tert-butyl peroxy ethanes comprises performing emulsion copolymerization of butyl acrylate and 1-(.alpha.-alkyl acrylate)-1-tert-butyl peroxy ethanes in the presence of an initiating system consisting of sodium metabisulfite in an amount of 0.008 to 1.650% of the total mass of monomers and a compound of the general formula Na.sub.x H.sub.y S.sub.z O.sub.3, where "x" is an integer of 1 or 2, "y" is zero or 1, "z" is an integer of 1 or 2, said compound being in an amount of 0.002 to 0.360% of the total mass of monomers. In accordance to the required characteristics of the copolymers, i.e. extent of the final product swelling and the gel fraction content therein, the initiating system amount is determined from the formula: ##EQU1## c--amount of the initiating system, in % of the mass of initial monomers; .alpha.--extent of the final product swelling, in % of the final product mass;G--gel fraction content of the final product, in % of the final product mass.

    摘要翻译： PCT No.PCT / SU79 / 00015 Sec。 371日期：1980年11月13日 102（e）日期1980年11月6日PCT提交1979年3月13日PCT公布。 第WO80 / 01916号公报 日本1980年9月18日。丙烯酸丁酯和1-（α-烷基丙烯酸酯）-1-叔丁基过氧乙烷的共聚物的制备方法包括丙烯酸丁酯和丙烯酸1-（α-烷基酯）-1 叔丁基过氧乙烷在由偏亚硫酸氢钠组成的引发体系存在下，其量为单体总质量的0.008至1.650％，通式为NaxHySzO 3的化合物，其中“x”为整数1或 2中，“y”为0或1，“z”为1或2的整数，所述化合物的量为单体总质量的0.002〜0.360％。 根据共聚物的所需特性，即最终产物溶胀的程度和其中的凝胶分数含量，起始体系量由起始体系的式： 以初始单体的质量％计; 最终产品的α-延伸溶胀，以最终产品质量的％计; 最终产品的G凝胶分数含量，以最终产品质量的％计。

    Process for producing shock-proof graft copolymers of styrene with synthetic rubber
    6.
    发明授权
    Process for producing shock-proof graft copolymers of styrene with synthetic rubber 失效
    制造苯乙烯与合成橡胶的防震接枝共聚物的方法

    公开(公告)号：US4155956A

    公开(公告)日：1979-05-22

    申请号：US777405

    申请日：1977-03-14

    申请人： Galina Ballova ,  Sergei S. Ivanchev ,  Olga N. Romantsova ,  Larisa F. Maladzyanova ,  Ekaterina I. Egorova ,  Valentina G. Karmakova ,  Marta P. Potiforova ,  Ljudmila N. Trushkina

    发明人： Galina Ballova ,  Sergei S. Ivanchev ,  Olga N. Romantsova ,  Larisa F. Maladzyanova ,  Ekaterina I. Egorova ,  Valentina G. Karmakova ,  Marta P. Potiforova ,  Ljudmila N. Trushkina

    IPC分类号： C08F4/38 ,  C08F279/02

    CPC分类号： C08F4/38 ,  C08F279/02

    摘要： The process for producing shock-proof graft copolymers of styrene with synthetic rubber consists in that rubber is dissolved in styrene at a maximum temperature of 75.degree. C. The resultant solution is subjected to prepolymerization by being heated to 75-85.degree. C. in the presence of a plasticizer and a peroxide initiating agent. The peroxide initiator is essentially a composition of the following formulation (in parts by weight): diacylated peroxides of aliphatic acids C.sub.3 -C.sub.5, 2 to 8; diacylated peroxides of aliphatic acids C.sub.6 -C.sub.9, 80 to 89; diacylated peroxides of aliphatic acids C.sub.10 -C.sub.12, 7 to 14. The prepolymerization process proceeds until the 25-40 percent styrene conversion. The result is the prepolymer which is exposed to aqueous-suspension polymerization by being heated in an aqueous medium to maximum 140.degree. C. at a prepolymer-to-water volume ratio ranging within 5:3 and 10:3, respectively, in the presence of peroxide polymerization; initiators and a stabilizing system, consisting of 0.15-1.5 wt. % tricalcium phosphate, 0.003-0.02 wt. % of a mixture of disubstituted sodium alkylsulphates of a general formula as such: R--OSO.sub.3 Na, where R is a hydrocarbon radical, containing 8 to 18 carbon atoms, and 0.15-0.35 wt. % calcium carbonate.The process is distinguished for a simple flowsheet; it involves no molecular-weight modifier. Copolymers produced according to the proposed process feature high physico-mechanical characteristics.

    摘要翻译： 制造苯乙烯与合成橡胶的防震接枝共聚物的方法是将橡胶溶解在最高温度为75℃的苯乙烯中。所得溶液通过加热至75-85℃进行预聚合 存在增塑剂和过氧化物引发剂。 过氧化物引发剂基本上是以下配方的组合物（重量份）：脂肪酸C3-C5，2-8的二酰化过氧化物; 脂肪酸C6-C9，80-89的二酰化过氧化物; 脂肪酸C10-C12，7-14的二酰化过氧化物。预聚合过程进行到25-40％苯乙烯转化。 其结果是通过在水性介质中加热至约140℃，预聚物与水的体积比分别在5:3和10:3的范围内分别暴露于水悬浮聚合的预聚物 过氧化物聚合; 引发剂和稳定体系，由0.15-1.5wt。 磷酸三钙，0.003-0.02重量％ ％的通式如下的二取代烷基硫酸钠的混合物：R-OSO3Na，其中R是含有8至18个碳原子的烃基，和0.15-0.35wt。 ％碳酸钙。

    .alpha.,.alpha.-azo-bis-isobutyric acid .alpha.,.omega.-bis alkyl ester derivatives and method for preparing same
    9.
    发明授权
    .alpha.,.alpha.-azo-bis-isobutyric acid .alpha.,.omega.-bis alkyl ester derivatives and method for preparing same 失效
    α，α-偶氮双异丁酸α，ω-二烷基酯衍生物及其制备方法

    公开(公告)号：US4290945A

    公开(公告)日：1981-09-22

    申请号：US91774

    申请日：1979-11-06

    申请人： Anatoly A. Syrov ,  Sergei S. Ivanchev ,  Oleg N. Primachenko ,  Valentina A. Demidova ,  Boris V. Polozov ,  Vladimir I. Fionov ,  Evgeny N. Barantsevich

    发明人： Anatoly A. Syrov ,  Sergei S. Ivanchev ,  Oleg N. Primachenko ,  Valentina A. Demidova ,  Boris V. Polozov ,  Vladimir I. Fionov ,  Evgeny N. Barantsevich

    IPC分类号： C07C245/04 ,  C08F4/04 ,  C07C107/00

    CPC分类号： C07C245/04 ,  C08F4/04

    摘要： Novel compounds according to the present invention, i.e. derivatives of .alpha.,.omega.-bis-alkyl esters of isobutyric acid having the formula: ##STR1## A method for preparing the above-specified novel compounds consists in reacting .alpha.,.alpha.'-azo-bis-isobutyric acid dinitrile and a saturated alkyl monohydric alcohol derivative of the formula ROH, wherein R: ##STR2## with gaseous hydrogen chloride in an organic solvent medium in the presence of 0.5-5% by mass of a water-soluble ether at a temperature within the range of from -5.degree. to +6.degree. C., followed by treating the resulting reaction mixture with water at a temperature of from 0.degree. to -5.degree. C. and isolation of the desired product.The novel compounds according to the present invention are useful as initiators for a radical-type polymerization of ethylenically unsaturated compounds, as well as the starting products for the manufacture of reactive polymers by a simplified process.

    摘要翻译： 根据本发明的新型化合物，即具有下式的异丁酸的α，ω-双 - 烷基酯的衍生物：其中R： 制备上述新化合物的方法在于使α，α'-偶氮双异丁酸二氰酯与式ROH的饱和烷基一元醇衍生物反应，其中R： 在0.5〜5质量％的水溶性醚存在下，在-5℃〜+ 6℃的温度范围内，用有机溶剂介质中的气态氯化氢进行图像＆lt; IMAGE＆gt;＆lt; IMAGE＆gt; ，然后在0〜-5℃的温度下用水处理得到的反应混合物，并分离所需产物。 根据本发明的新化合物可用作烯属不饱和化合物的自由基聚合的引发剂，以及通过简化方法制备反应性聚合物的起始产物。

    Hydroperoxide derivatives of hydroxyethylated compounds and method of producing same
    10.
    发明授权
    Hydroperoxide derivatives of hydroxyethylated compounds and method of producing same 失效
    羟乙基化合物的氢过氧化物衍生物及其生产方法

    公开(公告)号：US4283553A

    公开(公告)日：1981-08-11

    申请号：US78037

    申请日：1979-09-24

    申请人： Sergei S. Ivanchev ,  Anatoly A. Syrov ,  Valery N. Pavljuchenko ,  Ninel N. Lesnikova ,  Diana A. Rozhkova

    发明人： Sergei S. Ivanchev ,  Anatoly A. Syrov ,  Valery N. Pavljuchenko ,  Ninel N. Lesnikova ,  Diana A. Rozhkova

    IPC分类号： B01F17/42 ,  C07C409/20 ,  C08F2/32 ,  C08F4/32 ,  C08G65/321 ,  C08G65/324 ,  C08G65/329 ,  C08G65/331 ,  C08G65/332 ,  C11D3/39 ,  C07C69/66 ,  C07C43/11 ,  C07C179/025

    CPC分类号： C07C409/20 ,  C07C409/40 ,  C08G65/321 ,  C08G65/324 ,  C08G65/329 ,  C08G65/331 ,  C08G65/332 ,  C11D3/3945 ,  C07C2101/08 ,  C07C2101/14 ,  C07C2102/42

    摘要： Disclosed are novel hydroperoxide derivatives of hydroxyethylated compounds of the general formula: ##STR1## a-whole number 10 to 30, b, c are absent, R=n-alkyl from C.sub.8 to C.sub.20, secondary alkyl of C.sub.14, C.sub.15 and ##STR2## where R.sub.2 =n-alkyl from C.sub.8 to C.sub.12 ##STR3## where R.sub.3 and R.sub.4 =R.sub.8 --C.dbd.O, where R.sub.8 =--CH.sub.3 or H, if R.sub.6,7,9 =H R.sub.5 is absent or ##STR4## where R.sub.9 =--CH.sub.3 or H, if R.sub.6,7,8 =H, R.sub.5 is absent; R.sub.10 =n-alkyl of C.sub.1 to C.sub.9 of R.sub.3 .noteq.R.sub.4 R.sub.5 =--CH.sub.2 if R.sub.6,7,8,9 =H; if R.sub.5 is absent, R.sub.1 is acyclic and is ##STR5## R.sub.6 =--CH.sub.3 or H, if R.sub.7,8,9 =H, R.sub.5 is absent, R.sub.7 =--CH.sub.3 or H, if R.sub.6,8,9 =H, R.sub.5 is absent, with x=--O--, b-whole number of 8 to 24, (a+c)-whole number of 6 to 30R=R.sub.1According to the invention, a method of producing novel hydroperoxide derivatives of hydroxyethylated compounds resides in that certain hydroxyethylated compounds are caused to interact with specific derivatives of dienes and maleic anhydride followed by ozonization of the resulting product.

    摘要翻译： 公开了以下通式的羟乙基化化合物的新型氢过氧化物衍生物： a-全数10至30，b，c不存在，R = C 8至C 20的正烷基，C 14，C 15的仲烷基， 其中R 2 = C 8至C 12的正烷基，其中R 3和R 4 = R 8 -C = O，其中R 8 = -CH 3或H，如果R6,7,9 = H R5不存在或其中R 9 = -CH 3或H，如果R6,7,8 = H，则R5不存在; R 10 = R 3的C 1至C 9的正烷基。R 5 = = CH 2，如果R6,7,8,9 = H; 如果R 5不存在，则R 1是无环的，如果R 7,8,9 = H，R 5不存在，R 7 = -CH 3或H，如果R6,8,9 = H，R5 不存在，x = -O-，b-全数8〜24，（a + c） - 孔数6〜30 R = R1根据本发明，生产羟乙基化化合物的新型氢过氧化物衍生物的方法 导致某些羟乙基化化合物与二烯和马来酸酐的特定衍生物相互作用，随后所得产物被臭氧化。