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1.发明授权Methods for synthesizing nanometer-sized manganese dioxides having ramsdellite-type crystal structures as well as methods for producing hydroxide ion-derived proton, electron and oxygen using manganese dioxides 有权合成具有斜方晶型晶体结构的纳米级二氧化锰的方法以及使用二氧化锰生产氢氧根离子衍生的质子，电子和氧的方法公开(公告)号：US09586836B2
公开(公告)日：2017-03-07
申请号：US13637499
申请日：2011-03-25
Applicant: Hideki Koyanaka , Masahiko Tsujimoto
Inventor： Hideki Koyanaka , Masahiko Tsujimoto
CPC classification number: C01G45/02 , B82Y30/00 , C01B13/0207 , C01P2002/72 , C01P2004/04 , C01P2004/16 , C01P2004/64 , C23C18/1635 , C23C18/1637 , C23C18/54
Abstract: By means of a series of wet multistage oxidation process comprising: Step 1 for adding an alkaline reagent to an aqueous solution of a manganese compound containing a divalent manganese thereby precipitating a manganese hydroxide; Step 2 for adding an aqueous hydrogen peroxide while keeping the temperature of the water of the aqueous solution comprising the manganese hydroxide at room temperature thereby converting into a manganese oxide; and also Step 3 for adding a dilute acid to the manganese oxide in a state where the water is coexisting, a nanometer-sized manganese dioxide having a ramsdellite-type crystal structure is obtained.
Abstract translation: 通过一系列湿式多级氧化方法，包括：步骤1，用于向含有二价锰的锰化合物的水溶液中加入碱性试剂，从而沉淀氢氧化锰; 步骤2，在将包含氢氧化锰的水溶液的水的温度保持在室温的同时加入过氧化氢水溶液，从而转化为氧化锰; 以及在水共存的状态下，向锰氧化物中添加稀酸的步骤3，得到具有斜前卫型晶体结构的纳米级二氧化锰。
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公开(公告)号：US09922742B2
公开(公告)日：2018-03-20
申请号：US15021448
申请日：2014-09-12
Applicant: Hideki Koyanaka
Inventor： Hideki Koyanaka
IPC: C02F1/42 , G21F9/04 , B01J49/00 , G21F9/12 , B01J20/06 , B01D59/26 , G21F9/06 , B01J20/28 , B01J20/34 , C01B4/00 , B01D15/42 , C02F1/28 , C02F101/00 , C02F103/06 , C02F103/34
CPC classification number: G21F9/12 , B01D15/426 , B01D59/26 , B01J20/06 , B01J20/28033 , B01J20/3433 , B01J20/345 , C01B4/00 , C02F1/281 , C02F2101/006 , C02F2103/06 , C02F2103/34 , C02F2303/16 , G21F9/04 , G21F9/06
Abstract: A method of using hydrogen- or lithium-containing manganese oxide having a spinel crystal structure as a tritium adsorbent to trap tritium from tritium-containing water makes it possible to inexpensively separate tritium from water.
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公开(公告)号：US07335622B2
公开(公告)日：2008-02-26
申请号：US10473890
申请日：2001-10-19
Applicant: Hideki Koyanaka , Toshihiro Kasai
Inventor： Hideki Koyanaka , Toshihiro Kasai
IPC: B01J20/00
CPC classification number: B01J20/0222 , B01J20/0259 , B01J20/0277 , B01J20/06 , B01J20/3078 , B01J20/3085 , B01J20/3204 , B01J20/3236 , B01J20/3433 , B01J20/3475 , B01J2220/42 , B01J2220/58 , C01G45/00 , C02F1/281 , C02F1/283 , C02F1/288 , C02F2101/103
Abstract: A novel technique that is able to efficiently remove, in addition to pentavalent arsenic, trivalent arsenic that has been considered to be difficult to remove. By using a manganese oxygen compound which is characterized by being a product of burning or heating which comprises an oxygen compound of bismuth and an oxygen compound of manganese and by containing manganese as a major component, an aqueous arsenic solution is treated to adsorptively remove the arsenic.
Abstract translation: 除了五价砷以外，能够有效地除去被认为难以除去的三价砷的新技术。 通过使用锰氧化合物，其特征在于作为燃烧或加热的产物，其包含铋的氧化合物和锰的氧化合物，并且以锰为主要成分，处理砷水溶液以吸附去除砷 。
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4.发明申请METHODS FOR SYNTHESIZING NANOMETER-SIZED MANGANESE DIOXIDES HAVING RAMSDELLITE-TYPE CRYSTAL STRUCTURES AS WELL AS METHODS FOR PRODUCING HYDROXIDE ION-DERIVED PROTON, ELECTRON AND OXYGEN USING MANGANESE DIOXIDES 有权用于合成具有RAMSDELLITE型晶体结构的纳米尺寸二氧化硅的方法，作为使用锰锰氧化物生产氢氧化物衍生的原子，电子和氧原子的方法公开(公告)号：US20130064972A1
公开(公告)日：2013-03-14
申请号：US13637499
申请日：2011-03-25
Applicant: Hideki Koyanaka , Masahiko Tsujimoto
Inventor： Hideki Koyanaka , Masahiko Tsujimoto
CPC classification number: C01G45/02 , B82Y30/00 , C01B13/0207 , C01P2002/72 , C01P2004/04 , C01P2004/16 , C01P2004/64 , C23C18/1635 , C23C18/1637 , C23C18/54
Abstract: By means of a series of wet multistage oxidation process comprising: Step 1 for adding an alkaline reagent to an aqueous solution of a manganese compound containing a divalent manganese thereby precipitating a manganese hydroxide; Step 2 for adding an aqueous hydrogen peroxide while keeping the temperature of the water of the aqueous solution comprising the manganese hydroxide at room temperature thereby converting into a manganese oxide; and also Step 3 for adding a dilute acid to the manganese oxide in a state where the water is coexisting, a nanometer-sized manganese dioxide having a ramsdellite-type crystal structure is obtained.
Abstract translation: 通过一系列湿式多级氧化方法，包括：步骤1，用于向含有二价锰的锰化合物的水溶液中加入碱性试剂，从而沉淀氢氧化锰; 步骤2，在将包含氢氧化锰的水溶液的水的温度保持在室温的同时加入过氧化氢水溶液，从而转化为氧化锰; 以及在水共存的状态下，向锰氧化物中添加稀酸的步骤3，得到具有斜前卫型晶体结构的纳米级二氧化锰。
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Patent Agency Ranking
公开(公告)号：US20100196746A1
公开(公告)日：2010-08-05
申请号：US12450430
申请日：2008-03-25
Applicant: Hideki Koyanaka
Inventor： Hideki Koyanaka
CPC classification number: B01J35/1014 , B01J23/34 , B01J35/0013 , B01J35/002 , B01J35/06 , B01J35/1019 , B01J35/1038 , B01J35/1061 , B01J37/08 , B82Y30/00 , C01B13/0207 , C01G45/02 , C01P2002/72 , C01P2004/02 , C01P2004/04 , C01P2004/10 , C01P2004/45 , C01P2004/61 , C01P2004/62 , C01P2004/64 , C01P2006/12 , C01P2006/14 , C01P2006/16 , C01P2006/17 , H01M4/8621 , H01M4/9016 , H01M4/92 , H01M8/1016 , H01M8/1246 , H01M2300/0071 , Y02E60/525
Abstract: Provided is a catalyst material comprising aggregates of nanoneedles of mainly R-type manganese dioxide and having a mesoporous structure. With this, water can be oxidatively decomposed under visible light at room temperature to produce oxygen gas, proton and electron. Also provided is a catalyst material comprising aggregates of nanoparticles of mainly hydrogenated manganese dioxide. With this, acetic acid or an inorganic substance can be synthesized from carbon dioxide gas.
Abstract translation: 提供了一种催化剂材料，其包含主要为R型二氧化锰并具有中孔结构的纳米针的聚集体。 由此，水可在室温下在可见光下氧化分解，产生氧气，质子和电子。 还提供了包含主要氢化二氧化锰的纳米颗粒的聚集体的催化剂材料。 由此可以从二氧化碳气体合成乙酸或无机物质。
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6.发明申请公开(公告)号：US20090220775A1
公开(公告)日：2009-09-03
申请号：US12226904
申请日：2007-05-02
Applicant: Fumio Kurosaki , Hideki Koyanaka
Inventor： Fumio Kurosaki , Hideki Koyanaka
CPC classification number: C04B35/62209 , B01J20/20 , B01J20/28083 , B01J20/28085 , B01J21/18 , B01J37/084 , C01B32/00 , C04B35/52 , C04B38/0022 , C04B2111/00793 , C04B2111/0081 , C04B2111/00853 , C04B2111/2046 , C04B2111/52 , C04B2235/5436 , C04B2235/6562 , C04B2235/6584 , Y10T428/26 , C04B38/0054 , C04B38/0067
Abstract: By controlling the heating speed and the pressure in carbonizing a wood powder, a macroporous carbon material is formed. Herein provided are the macroporous carbon material starting from a wood material, and a method for producing it.
Abstract translation: 通过控制加热速度和碳化木粉的压力，形成大孔碳材料。 这里提供的是从木材开始的大孔碳材料及其制造方法。
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7.发明授权Catalysts reforming methane gases into hydrogen and methods for synthesizing the same, and methods for reforming methane gases using said catalysts 有权将甲烷气体重整成氢气的催化剂及其合成方法，以及使用所述催化剂重整甲烷气体的方法公开(公告)号：US09295975B2
公开(公告)日：2016-03-29
申请号：US13807178
申请日：2011-06-24
Applicant: Hideki Koyanaka , Masahiko Tsujimoto
Inventor： Hideki Koyanaka , Masahiko Tsujimoto
IPC: B01J23/00 , B01J25/00 , B01J21/00 , B01J29/00 , B01J23/32 , B01J23/656 , B01J37/03 , B01J37/16 , B01J37/18 , C01B3/40 , C01B3/26 , B01J35/00
CPC classification number: B01J23/6562 , B01J35/002 , B01J35/006 , B01J37/035 , B01J37/16 , B01J37/18 , C01B3/26 , C01B3/40 , C01B2203/0233 , C01B2203/1064 , C01B2203/1241 , Y02P20/52
Abstract: A method for synthesizing a catalyst which reforms a methane gas into a hydrogen gas efficiently at a relatively low temperature comprising a palladium deposition step in which a manganese dioxide having a ramsdellite-type crystal structure is immersed in a palladium-containing aqueous solution to allow the palladium to be deposited on the surface of said manganese dioxide, and a heat treatment step in which said manganese dioxide having the palladium deposited thereon is heated under a reducing atmosphere to change said manganese dioxide to a manganese oxide Mn3O4 having the palladium carried thereon.
Abstract translation: 一种合成催化剂的方法，该催化剂在比较低的温度下，有效地将甲烷气体重整成氢气，所述催化剂包括钯沉积步骤，其中将具有斜前卫型晶体结构的二氧化锰浸入含钯水溶液中以允许 钯沉积在所述二氧化锰的表面上，并且将其上沉积有钯的所述二氧化锰在还原气氛下加热以将所述二氧化锰改变为具有载持在其上的钯的氧化锰Mn 3 O 4的热处理步骤。
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8.发明申请CATALYSTS REFORMING METHANE GASES INTO HYDROGEN AND METHODS FOR SYNTHESIZING THE SAME, AND METHODS FOR REFORMING METHANE GASES USING SAID CATALYSTS 有权催化剂将甲烷气体转化为氢气及其合成方法，以及使用合适的催化剂改性甲烷气体的方法公开(公告)号：US20130195750A1
公开(公告)日：2013-08-01
申请号：US13807178
申请日：2011-06-24
Applicant: Hideki Koyanaka , Masahiko Tsujimoto
Inventor： Hideki Koyanaka , Masahiko Tsujimoto
IPC: B01J23/656 , C01B3/26
CPC classification number: B01J23/6562 , B01J35/002 , B01J35/006 , B01J37/035 , B01J37/16 , B01J37/18 , C01B3/26 , C01B3/40 , C01B2203/0233 , C01B2203/1064 , C01B2203/1241 , Y02P20/52
Abstract: A method for synthesizing a catalyst which reforms a methane gas into a hydrogen gas efficiently at a relatively low temperature comprising a palladium deposition step in which a manganese dioxide having a ramsdellite-type crystal structure is immersed in a palladium-containing aqueous solution to allow the palladium to be deposited on the surface of said manganese dioxide, and a heat treatment step in which said manganese dioxide having the palladium deposited thereon is heated under a reducing atmosphere to change said manganese dioxide to a manganese oxide Mn3O4 having the palladium carried thereon.
Abstract translation: 一种合成催化剂的方法，该催化剂在比较低的温度下，有效地将甲烷气体重整成氢气，所述催化剂包括钯沉积步骤，其中将具有斜前卫型晶体结构的二氧化锰浸入含钯水溶液中， 钯沉积在所述二氧化锰的表面上，并且将其上沉积有钯的所述二氧化锰在还原气氛下加热以将所述二氧化锰改变为具有载持在其上的钯的氧化锰Mn 3 O 4的热处理步骤。
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公开(公告)号：US08465701B2
公开(公告)日：2013-06-18
申请号：US12450430
申请日：2008-03-25
Applicant: Hideki Koyanaka
Inventor： Hideki Koyanaka
IPC: B01J23/34 , C01B13/02 , C01B31/24 , C01G45/02 , C07C53/08 , C07H1/00 , G01N27/00 , H01M10/44 , C07C45/00
CPC classification number: B01J35/1014 , B01J23/34 , B01J35/0013 , B01J35/002 , B01J35/06 , B01J35/1019 , B01J35/1038 , B01J35/1061 , B01J37/08 , B82Y30/00 , C01B13/0207 , C01G45/02 , C01P2002/72 , C01P2004/02 , C01P2004/04 , C01P2004/10 , C01P2004/45 , C01P2004/61 , C01P2004/62 , C01P2004/64 , C01P2006/12 , C01P2006/14 , C01P2006/16 , C01P2006/17 , H01M4/8621 , H01M4/9016 , H01M4/92 , H01M8/1016 , H01M8/1246 , H01M2300/0071 , Y02E60/525
Abstract: Provided is a catalyst material comprising aggregates of nanoneedles of mainly R-type manganese dioxide and having a mesoporous structure. With this, water can be oxidatively decomposed under visible light at room temperature to produce oxygen gas, proton and electron. Also provided is a catalyst material comprising aggregates of nanoparticles of mainly hydrogenated manganese dioxide. With this, acetic acid or an inorganic substance can be synthesized from carbon dioxide gas.
Abstract translation: 提供了一种催化剂材料，其包含主要为R型二氧化锰并具有中孔结构的纳米针的聚集体。 由此，水可在室温下在可见光下氧化分解，产生氧气，质子和电子。 还提供了包含主要氢化二氧化锰的纳米颗粒的聚集体的催化剂材料。 由此可以从二氧化碳气体合成乙酸或无机物质。
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